Wetland Purification Pattern for Surface Runoff Pollution of Coastal Highway in Liaoning Province

Taking surface runoff of Coastal Highway in Liaoning Province as research object,this paper analyzed water quality characteristics of runoff and flow rules of pollutants. It proposed using constructed wetland treatment technique in the drainage system from the perspective of effectively removing major pollutants. Using the constructed wetland k- C* model and relevant experience,parameters of constructed wetland can be obtained. The basic model is as follows: constructed wetland lies in two sides of the road,and surface runoff sewage is collected and treated separately with 1 km road section as the collection unit. The wetland area in one side is 191. 6 m2,average water depth is 0. 5 m,wetland width is 8 m,and wetland length is 24 m.

Atmospheric-Pressure DBD Cold Plasma for Preparation of High Active Au/P25 Catalysts for Low-Temperature CO Oxidation

Cold plasma generated by dielectric barrier discharge （DBD） at atmospheric pressure was adopted for preparation of commercial TiO2 Degussa P25 supported Au catalysts （Au/P25- P） with the assistance of the deposition-precipitation procedure. The influences of the plasma reduction time and calcination on the performance of the Au/P25-P catalysts were investigated. CO oxidation was performed to investigate the catalytic activity of the Au/P25 catalysts. The results show that DBD cold plasma for the fabrication of Au/P25-P catalysts is a fast process, and Au/P25-P （4 min） exhibited the highest CO oxidation activity due to the complete reduction of Au compounds and less consumption of oxygen vacancies. In order to form more oxygen vacancies active species, Au/P25-P was calcined to obtain Au/P25-PC catalysts. Interestingly, Au/P25- PC exhibited the highest activity for CO oxidation among the Au/P25 samples. The results of transmission electron microscopy （TEM） indicated that the smaller size and high distribution of Au nanoparticles are the mean reasons for a high performance of Au/P25-PC. Atmospheric- pressure DBD cold plasma was proved to be of great efficiency in preparing high performance supported Au catalysts.

Synthesis of Cu-Doped Mixed-Phase TiO_2 with the Assistance of Ionic Liquid by Atmospheric-Pressure Cold Plasma

An atmospheric-pressure dielectric barrier discharge （DBD） gas-liquid cold plasma was employed to synthesize Cu-doped TiO~ nanoparticles in an aqueous solution with the assistance of [C2MIM]BF4 ionic liquid （IL） and using air as the working gas. The influences of the discharge voltage, IL and the amount of copper nitrite were investigated. X-ray diffraction, N2 adsorption-desorption measurements and UV-Vis spectroscopy were adopted to characterize the samples. The results showed that the specific surface area of TiO2 was promoted with Cu-doping （from 57.6 m^2.g^-1 to 106.2 m^2.g^-1 with 3% Cu-doping）, and the content of anatase was increased. Besides, the band gap energy of TiO~ with Cu-doping decreased according to the UV-Vis spec- troscopy test. The 3%Cu-IL-TiO2 samples showed the highest eificiency in degrading methylene blue （MB） dye solutions under simulated sunlight with an apparent rate constant of 0.0223 min-1, which was 1.2 times higher than that of non-doped samples. According to the characterization results, the reasons for the high photocatalytic activity were discussed.

Theoretical study on damage bifurcation of unstable failure process of quasi-brittle materials

To obtain the damage effect in the process of elasto-plasticity deformation of quasi-brittle materials, the isotropic damage loading-unloading function and damage variable were introduced to non-continuous bifurcation. The critical bifurcation orientation and its corresponding hardening modulus for quasi-brittle materials were derived considering the effect of stiffness degradation and volumetric dilatancy under the assumption of isotropic damage. The relationships of localized orientation angle and maximal hardening modulus dependent on degree of damage and initial Poisson's ratio of rock were explored. Comparative analyses were conducted to study the bifurcation of uniaxial tension-compression samples under the conditions of plane stress and plane strain. It is shown that as the initial Poisson's ratio or degree of damage increases, the localization orientation angle of the plane uniaxial compression sample tends to be initiated to decrease. However, the localization orientation angle of the plane uniaxial tension sample tends to be initiated to increase. The sum of orientation angle under tension and compression conditions is 90°. There are plane stress and plane strain cases of the maximum hardening modulus that is independent of the uniaxial compression and tension.

Influence of O2 Flux on Compositions and Properties of ITO Films Deposited at Room Temperature by Direct-Current Pulse Magnetron Sputtering

Indium tin oxide （ITO） films were deposited on glass substrates at room temperature by dc pulse magnetron sputtering. Varying 02 flux, ITO films with different properties are obtained. Both x-ray diffractometer and x-ray photoelectron spectrometer are used to study the change of crystalline structures and bonding structures of ITO films, respectively. Electrical properties are measured by four-point probe measurements. The results indicate that the chemical structures and compositions of ITO films strongly depend on the O2 flux. With increasing O2 flux, ITO films display better crystallization, which could decrease the resistivity of films. On the contrary, ITO films contain less O vacancies with increasing O2 flux, which could worsen the conductive properties of films. Without any heat treatment onto the samples, the resistivity of the ITO film could reach 6.0 × 10^-4 Ω·cm, with the optimal deposition parameter of 0.2 scem O2 flux.

Synthesis and characterization of a novel amphiphilic biodegradable β-cyclodextrin/poly(γ-benzyl L-glutamate) copolymer

β-Cyclodextrin/poly（γ-benzyl L-glutamate） （β-CD-PBLG） copolymers were synthesized by ring-opening polymerization of N- carboxy-γ-benzyl L-glutamate anhydride （BLG-NCA） in N,N-dimethylformamide （DMF） initiated by mono-amino-β-cyclodextrin（H2N-β-CD）. The structures of the copolymers were confirmed by IR, ^1H NMR and GPC. The fluorescence technique was used to determine the critical micelle concentrations （CMC） of copolymer micell solution, the diameter and the distribution of micelles were characterized by DLS. The results showed that BLG-NCA could be initiated by H2N-β-CD to produce copolymer. The nanomicells were formed by these copolymers in water.

Fracture mechanics analysis in frost breakage of reservoir revetment on cold regions

Reservoir revetment in cold regions is often damaged by frost due to the joint action of low-temperatures and cryogenic environment in winter. This damage reduces or even eliminates the function ofthe reservoir revelrnent. In this paper, practical problems in engineering were analyzed for the drainage pumping station of Tuanjie Reservoir. Based on a tradifional method of analysis and calculalion, fiacture mechanics was iricorporated to provide quantitative analysis and calculation on the problem of anti-freeze damage from the viewpoint of fracture mechanics. Thus, a new idea is put forward to resolve anti-freefing ofreservoir slope proteclion in cold regions.

Novel organometallic aromatic polyester based on ferrocene

A novel polyester containing ferrocenyl was prepared by low-temperature interface polycondensation of 1,1'-ferrocenedicarboxylic acid chloride with 4-(4-hydroxyphenyl)-2,3-phthalazin-1-one(DHPZ),which is a twisted non-coplanar heterocyclic bisphenol-like monomer.The newly generated polymer was evaluated based on characterization of its solubility,viscosity measurements,elemental analysis,FTIR spectroscopy,differential scanning calorimetric and thermogravimetric studies.

Preparation of Monodisperse Spherical SiO_2 by Microwave Hydrothermal Method and Kinetics of Dehydrated Hydroxyl

Monodisperse spherical SiO2 particles were successfully synthesized in 2-propanol-H2O-NH3 system by the microwave hydrothermal method using ammonia as catalyst. To investigate the influences on the size of spherical SiO2 particles, factors such as ammonia concentration, reaction temperature, stirring intensity and reactants mol ratio have been studied. The orthogonal experiments were carried out. The as-prepared SiO2 particles were characterized by X-ray diffraction （XRD）, transmission electron microscopy （TEM）, Fourier transform infrared spectroscopy （FTIR） and differential thermal analysis （DTA）. The results indicated that the size of SiO2 particles increased greatly with the increase in ammonia concentration, temperature and reactants mol ratio, but increased slightly with the increase in stirring intensity. Monodisperse spherical Si02 particles were amorphous with perfect sphere and uniform size. Hydroxyl was detected in SiO2. Kinetic parameters were calculated, and finally the reaction rate equation of dehydrated hydroxyl was obtained.

Design and simulation of blue/violet sensitive photodetectors in silicon-on-insulator

According to Lambert’s law,a novel structure of photodetectors,namely photodetectors in siliconon-insulator,is proposed.By choosing a certain thickness value for the SOI layer,the photodetector can absorb blue/violet light effectively and affect the responsivity of the long wavelength in the visible and near-infrared region,making a blue/violet filter unnecessary.The material of the SOI layer is high-resistivity floating-zone silicon which can cause the neutral N type SOI layer to become fully depleted after doping with a P type impurity.This can improve the collection efficiency of short-wavelength photogenerated carriers.The device structure was optimized through numerical simulation,and the results show that the photodiode is a kind of high performance photodetector in the blue/violet region.

Synthesis and properties of a novel polyester containing bithiazole

A novel Schiff base type polyester containing 2,2′-diamino-4,4′-bithiazole （DABT） was prepared by low-temperature interface polycondensation of 1,4-benzenedicarbonyl dichloride with 4,4′-（4,4′-bithiazole-2,2′-diylbis（imine-2,1-diyl）diphenol （BDDP）, which is derived from a 2,2′-diamino-4,4′-blthiazole （DABT） Schiff base reacted with a 4-hydroxybenzaldehyde monomer. The newly generated polyester was evaluated based on characterization of its solubility, FTIR spectroscopy, elemental analysis, X-ray diffraction measurements and thermogravimetric analysis （TGA） studies.