In this paper, the dielectric properties of CO2, CO2/air, CO2/O2, CO2/N2, CO2/CF4, CO2/CH4, CO2/He, C02/H2, CO2/NH3 and CO2/CO were investigated based on the Boltzmann equation analysis, in which the reduced critical ...In this paper, the dielectric properties of CO2, CO2/air, CO2/O2, CO2/N2, CO2/CF4, CO2/CH4, CO2/He, C02/H2, CO2/NH3 and CO2/CO were investigated based on the Boltzmann equation analysis, in which the reduced critical electric field strength （E/N）cr of the gases was derived from the calculated electron energy distribution function （EEDF） by solv- ing the Boltzmann transport equation. In this work, it should be noted that the fundamental data were carefully selected by the published experimental results and calculations to ensure the validity of the calculation. The results indicate that if He, H2, N2 and CH4, in which there axe high ionization coefficients or a lack of attachment reactions, are added into CO2, the dielectric properties will decrease. On the other hand, air, O2, NH3 and CFa （ranked in terms of （E/N）cr value in increasing order） have the potential to improve the dielectric property of CO2 at room temperature.展开更多
Air plasma has been widely applied in industrial manufacture. In this paper, both dry and humid air plasmas＇ thermodynamic and transport properties are calculated in temperature 300 100000 K and pressure 0.1-100 atm....Air plasma has been widely applied in industrial manufacture. In this paper, both dry and humid air plasmas＇ thermodynamic and transport properties are calculated in temperature 300 100000 K and pressure 0.1-100 atm. To build a more precise model of real air plasma, over 70 species are considered for composition. Two different methods, the Gibbs free energy minimization method and the mass action law method, are used to deternfinate the composition of the air plasma in a different temperature range. For the transport coefficients, the simplified Chapman-Enskog method developed by Devoto has been applied using the most recent collision integrals. It is found that the presence of CO2 has almost no effect on the properties of air plasma. The influence of H2O can be ignored except in low pressure air plasma, in which the saturated vapor pressure is relatively high. The results will serve as credible inputs for computational simulation of air plasma.展开更多
基金supported in part by the National Key Basic Research Program of China(973 Program)(No.2015CB251002)the Science and Technology Project Funds of the Grid State Corporation of China(No.SGSNK00KJJS1501564)+2 种基金National Natural Science Foundation of China(Nos.51221005,51577145)the Fundamental Research Funds for the Central Universities of Chinathe Program for New Century Excellent Talents in University,China
文摘In this paper, the dielectric properties of CO2, CO2/air, CO2/O2, CO2/N2, CO2/CF4, CO2/CH4, CO2/He, C02/H2, CO2/NH3 and CO2/CO were investigated based on the Boltzmann equation analysis, in which the reduced critical electric field strength （E/N）cr of the gases was derived from the calculated electron energy distribution function （EEDF） by solv- ing the Boltzmann transport equation. In this work, it should be noted that the fundamental data were carefully selected by the published experimental results and calculations to ensure the validity of the calculation. The results indicate that if He, H2, N2 and CH4, in which there axe high ionization coefficients or a lack of attachment reactions, are added into CO2, the dielectric properties will decrease. On the other hand, air, O2, NH3 and CFa （ranked in terms of （E/N）cr value in increasing order） have the potential to improve the dielectric property of CO2 at room temperature.
基金supported by the National Key Basic Research Program of China(973 Program)(No.2015CB251002)National Natural Science Foundation of China(Nos.51521065,51577145)+2 种基金the Science and Technology Project Funds of the Grid State Corporation(SGTYHT/13-JS-177)the Fundamental Research Funds for the Central UniversitiesState Grid Corporation Project(GY71-14-004)
文摘Air plasma has been widely applied in industrial manufacture. In this paper, both dry and humid air plasmas＇ thermodynamic and transport properties are calculated in temperature 300 100000 K and pressure 0.1-100 atm. To build a more precise model of real air plasma, over 70 species are considered for composition. Two different methods, the Gibbs free energy minimization method and the mass action law method, are used to deternfinate the composition of the air plasma in a different temperature range. For the transport coefficients, the simplified Chapman-Enskog method developed by Devoto has been applied using the most recent collision integrals. It is found that the presence of CO2 has almost no effect on the properties of air plasma. The influence of H2O can be ignored except in low pressure air plasma, in which the saturated vapor pressure is relatively high. The results will serve as credible inputs for computational simulation of air plasma.
