Multilevel carbon architecture of subnanoscopic silicon for fast‐charging high‐energy‐density lithium‐ion batteries

Silicon(Si)is widely used as a lithium‐ion‐battery anode owing to its high capacity and abundant crustal reserves.However,large volume change upon cycling and poor conductivity of Si cause rapid capacity decay and poor fast‐charging capability limiting its commercial applications.Here,we propose a multilevel carbon architecture with vertical graphene sheets(VGSs)grown on surfaces of subnanoscopically and homogeneously dispersed Si–C composite nanospheres,which are subsequently embedded into a carbon matrix(C/VGSs@Si–C).Subnanoscopic C in the Si–C nanospheres,VGSs,and carbon matrix form a three‐dimensional conductive and robust network,which significantly improves the conductivity and suppresses the volume expansion of Si,thereby boosting charge transport and improving electrode stability.The VGSs with vast exposed edges considerably increase the contact area with the carbon matrix and supply directional transport channels through the entire material,which boosts charge transport.The carbon matrix encapsulates VGSs@Si–C to decrease the specific surface area and increase tap density,thus yielding high first Coulombic efficiency and electrode compaction density.Consequently,C/VGSs@Si–C delivers excellent Li‐ion storage performances under industrial electrode conditions.In particular,the full cells show high energy densities of 603.5 Wh kg^(−1)and 1685.5 Wh L^(−1)at 0.1 C and maintain 80.7%of the energy density at 3 C.

Review of the Global Energy Market in 2023

Global energy consumption reaches anewhighin2023,Due to the impact of COVID-19 and other factors,since 2020,apart from the steady growth in coal consumption,the consumption of oil and natural gas has experienced fluctuations.Statistics from relevant organizations indicate that in 2023,the consumption of oil and coal will reach a new high,and there will be a recovery in the growth of natural gas consumption.During the three years of COVID-19 and the global energy crisis,coal,the most conventional fossil fuel,saved the world.Coupled with the growth in the consumption of oil and natural gas in 2023,it is evident that,amidst the surge of energy transition,all three conventional fossil fuels are silently undertaking the significant responsibility for ensuring the energy needs of human society.

World's Energy Transition and Chinese-style Modern Energy Revolution under Carbon Neutrality(Ⅰ)

Under global consensus on carbon neutrality and the intensification of regional conflicts,new energy has become the primary direction for various countries to achieve energy security and green development.Represented by wind,solar,geothermal,hydrogen and stored energy,and controllable nuclear fusion,the technological and scale advantages of new energy are being continuously strengthened.Low-cost wind,solar,and stored energy will support the global energy transition.The production and utilization of new energy enter a rapid development phase.In 2022,the average global consumption of new energy accounted for 18.2%,and it is expected to reach around 55%by 2050.The distribution of the world's energy resources,consumption regions,technological development,per capita consumption,energy-saving fields,and carbon emissions is uneven.The acceleration of low-carbon development in fossil fuels,the scale-up of renewable energy,and the intelligentization of energy management drives the rapid transition of global energy.

World’s Energy Transition and Chinese-style Modern Energy Revolution under Carbon Neutrality (Ⅱ)

Chinese-style modernization emphasizes the harmonious coexistence of man and nature and actively yet prudently promotes carbon peak and carbon neutrality.It delves deeply into the energy revolution,upholding the following principles:the“independence”of energy production,the“green”energy supply,the“security”of energy reserves,the“efficiency”of energy consumption,the“intelligence”of energy management,and the“economy”of energy costs.Efforts are being made to accelerate the planning and construction of a new type of energy system that is green and smart,with new energy,new electricity,new stored energy,and new smart energy as the mainstays,to ensure energy security.Currently,China is an energy power but not an energy superpower,and its energy consumption structure still needs further optimization.China’s new energy security strategy is composed of energy consumption revolution,energy supply revolution,energy technology revolution,and energy system revolution,complemented by comprehensive strengthening of international cooperation.This approach is aimed at advancing China’s energy revolution and transforming the nation’s energy supply pattern and shifting from a consumption mix in 2022.

Logical Framework for Deepening International Energy Cooperation from the Perspective of Project Practice

Energy cooperation is a key area in the joint construction of the Belt and Road Initiative.To deepen international energy cooperation,it is advisable to place greater emphasis on whole life cycle and systematic planning in project collaboration,government-led initiatives with businesses playing a central role,alongside coordination with non-governmental international institutions,and comprehensive integration of resources.

Dendritic nanoarchitecture imparts ZSM-5 zeolite with enhanced adsorption and catalytic performance in energy applications

The development of zeolites possessing dendritic features represents a great opportunity for the design of novel materials with applications in a large variety of fields and,in particular,in the energy sector to afford its transition towards a low carbon system.In the current work,ZSM-5 zeolite showing a dendritic3D nanoarchitecture has been synthesized by the functionalization of protozeolitic nanounits with an amphiphilic organosilane,which provokes the branched aggregative growth of zeolite embryos.Dendritic ZSM-5 exhibits outstanding accessibility arising from a highly interconnected network of radially-oriented mesopores(3-10 nm)and large cavities(20-80 nm),which add to the zeolitic micropores,thus showing a well-defined trimodal pore size distribution.These singular features provide dendritic ZSM-5 with sharply enhanced performance in comparison with nano-and hierarchical reference materials when tested in a number of energy related applications,such as VOCs(toluene)adsorption(improved capacity),plastics(low-density polyethylene)catalytic cracking(boosted activity)and hydrogen production by methane catalytic decomposition(higher activity and deactivation resistance).

Bottom-up holistic carrier management strategy induced synergistically by multiple chemical bonds to minimize energy losses for efficient and stable perovskite solar cells

The defects from electron transport layer,perovskite layer and their interface would result in carrier nonradiative recombination losses.Poor buried interfacial contact is detrimental to charge extraction and device stability.Here,we report a bottom-up holistic carrier management strategy induced synergistically by multiple chemical bonds to minimize bulk and interfacial energy losses for high-performance perovskite photovoltaics.4-trifluoromethyl-benzamidine hydrochloride(TBHCl)containing–CF_(3),amidine cation and Cl^(-)is in advance incorporated into SnO_(2)colloid solution to realize bottom-up modification.The synergistic effect of multiple functional groups and multiple-bond-induced chemical interaction are revealed theoretically and experimentally.F and Cl^(-)can passivate oxygen vacancy and/or undercoordinated Sn^(4+)defects by coordinating with Sn^(4+).The F can suppress cation migration and modulate crystallization via hydrogen bond with FA^(+),and can passivate lead defects by coordinating with Pb^(2+).The–NH_(2)–C=NH^(+)_(2)and Cl^(-)can passivate cation and anion vacancy defects through ionic bonds with perovskites,respectively.Through TBHCl modification,the suppression of agglomeration of SnO_(2)nanoparticles,bulk and interfacial defect passivation,and release of tensile strains of perovskite films are demonstrated,which resulted in a PCE enhancement from 21.28%to 23.40%and improved stability.With post-treatment,the efficiency is further improved to 23.63%.

Large-Scale Energy Storage for Carbon Neutrality

The shift toward a dual-carbon strategy is expected to instigate extensive and profound changes across virtually all economic sectors and aspects of national life in China.The transformation and upgrading of energy systems and related infrastructure are particularly noteworthy.The future of energy supply will likely be dominated by renewable generation.One of the most significant challenges in this future landscape is the fluctuation and variability of wind and solar power,which often lead to a substantial amount of curtailed wind,solar,and hydropower.Such curtailment has shown an increasing trend,becoming a major obstacle to the swift deployment of renewable power generation.This challenge must be addressed to ensure the successful implementation of the dual-carbon strategy and the dominance of renewable energy in the future.

Encrypted Finite-Horizon Energy-to-Peak State Estimation for Time-Varying Systems Under Eavesdropping Attacks: Tackling Secrecy Capacity

This paper is concerned with the problem of finitehorizon energy-to-peak state estimation for a class of networked linear time-varying systems.Due to the inherent vulnerability of network-based communication,the measurement signals transmitted over a communication network might be intercepted by potential eavesdroppers.To avoid information leakage,by resorting to an artificial-noise-assisted method,we develop a novel encryption-decryption scheme to ensure that the transmitted signal is composed of the raw measurement and an artificial-noise term.A special evaluation index named secrecy capacity is employed to assess the information security of signal transmissions under the developed encryption-decryption scheme.The purpose of the addressed problem is to design an encryptiondecryption scheme and a state estimator such that:1)the desired secrecy capacity is ensured;and 2)the required finite-horizon–l_(2)-l_(∞)performance is achieved.Sufficient conditions are established on the existence of the encryption-decryption mechanism and the finite-horizon state estimator.Finally,simulation results are proposed to show the effectiveness of our proposed encryption-decryption-based state estimation scheme.

The Benefits of Solar Energy on the Provision of Sustainable Affordable Housing in Nigeria

Solar energy is the most abundant form of energy on Earth. Solar energy brings impactful benefits and products that are expected to make homes more reliable, sustainable, and affordable. Thanks to technological advancements like the solar cell, we can gather this energy and turn it into electricity. The construction industry has an exceptional chance of benefiting from this sustainable energy. Many recognised benefits have been spelled forth in the construction industry, such as providing homes with clean energy with no trace of ozone depleting material emission. There are many people in Nigeria who are not linked to the public electric grid, and the energy sector produces and generates less than 58% of the entire amount of energy required. As stated in the Nigeria’s National Energy General Plan, the Sustainable Energy programme aims to enhance the country’s use of solar electricity. This paper focuses on the role of solar energy in the provision of sustainable affordable housing in Nigeria. It considers the description, method, and utilisation of solar energy with a focus on residential and commercial buildings.

Research on Carbon Assets Management of Energy Group

Nowadays,the carbon markets in the world have increasingly matured and carbon trading have flourished in China.In the framework of carbon trading,the carbon emission right has become a tradable special commodity,and it has financial feature and asset feature.Relying on the business entities,carbon assets management joins up the virtual carbon emission right,financial capital and real economy,restructures existing carbon resources of enterprises and impacts the current international economic pattern.At present,however,the carbon assets management systems and market rules of our country remains to be perfect.How to increase the efficiency of carbon asset management,how to further improve the carbon management,how to further improve the carbon asset management method and mechanism have become the common issue of China’s academia and practice.

Analysis on the Toughness Assessment Method and Promotion Countermeasures of China Energy System under the Increasing Uncertainty

Energy security has always been an important topic in the field of energy economy research.Influenced by multiple factors,such as green and low-carbon energy transformation,unexpected geopolitical events,and international financial speculative behavior,the external environment of China energy security has changed and the uncertainty is getting worse.Under this background,the research paradigm of energy security presents new features,such as more diversity,complexity and systematic.This paper explains the theoretical logic of energy system toughness,builds an evaluation model of energy system toughness based on system dynamics theory,and puts forward relevant countermeasures and suggestions to improve energy system toughness through multi-scenario simulation analysis of energy system toughness index.

Energy Companies’Green Finance Strategies in the Context of Carbon Neutrality

In September 2020,Chinese President Xi Jinping solemnly announced the goal of“carbon peaking and carbon neutrality”.Carbon neutrality and green transition requires not only political promotion and fiscal support,but also social capital investment in green industries.Green financing is also an effective way to promote the low-carbon development of China’s energy companies.In this paper,on the basis of defining green finance,we reviewed the policies of green finance in China,described various tools of green finance,summarized green finance business of energy companies,and made case studies.This research combined macro policy and market,and micro industry and enterprise.

Comprehensive Evaluation of New Energy Investment in the Maritime Silk Road(Ⅰ)

Under the policy guidance of collectively building a“Green Belt and Road”,increasing investment in the new energy sector of“Maritime Silk Road”countries is not only an inevitable choice to solve the energy and climate dilemma,but also an opportunity to promote international connectivity and development of marine economy.Based on an investment environment evaluation model previously used in fossil energy sector,this paper applies it to the new energy sector by building suitable and relevant indicators reflecting“Belt and Road”coastal countries’resource and market characteristics.

Comprehensive Evaluation of New Energy Investment in the Maritime Silk Road(Ⅱ)

Analysis of new energy resources,industry and policy of Maritime Silk Road and indicator refinement Renewable resource endowment Due to the impact of complex factors such as the spatial planning of resources in various countries,industrial policies,and the potential for progress in different renewable technologies,it is unreasonable to use only LCOE as the basis for judging the competition or substitution between different types of renewable energy.However,technically exploitable resource,average capacity factor,and levelized cost of energy can fully reflect the comprehensive development potential of three types of renewable resources over a longer time scale.Therefore,this paper selects technically exploitable resource,average capacity factor,and levelized cost of energy as the core secondary indicators reflecting resource endowment.The differences in the quality of renewable resources on a seasonal or shorter time scale are not included in this paper.

Fluorinated soft carbon as an ultra-high energy density potassium-ion battery cathode enabled by a ternary phase K_(x)FC

Fluorinated carbons(CFx)have been widely applied as lithium primary batteries due to their ultra-high energy density.It will be a great promise if CFx can be rechargeable.In this study,we rationally tune the C-F bond strength for the alkaline intercalated CFx via importing an electronegative weaker element K instead of Li.It forms a ternary phase K_(x)FC instead of two phases(LiF+C)in lithium-ion batteries.Meanwhile,we choose a large layer distance and more defects CFx,namely fluorinated soft carbon,to accommodate K.Thus,we enable CFx rechargeable as a potassium-ion battery cathode.In detail fluorinated soft carbon CF_(1.01) presents a reversible specific capacity of 339 mA h g^(-1)(797 Wh kg^(-1))in the 2nd cycle and maintains 330 mA h g^(-1)(726 Wh kg^(-1))in the 15th cycle.This study reveals the importance of tuning chemical bond stability using different alkaline ions to endow batteries with rechargeability.This work provides good references for focusing on developing reversible electrode materials from popular primary cell configurations.

Wind Speed and Power Density Analysis for Sustainable Energy in Batouri, East Region of Cameroon

This paper develops the modeling of wind speed by Weibull distribution in the intention to evaluate wind energy potential and help for designing small wind energy plant in Batouri in Cameroon. The Weibull distribution model was developed using wind speed data collected from a metrological station at the small Airport of Batouri. Four numerical methods (Moment method, Graphical method, Empirical method and Energy pattern factor method) were used to estimate weibull parameters K and C. The application of these four methods is effective using a sample wind speed data set. With some statistical analysis, a comparison of the accuracy of each method is also performed. The study helps to determine that Energy pattern factor method is the most effective (K = 3.8262 and C = 2.4659).

Micro Hydro Power Plant for Sustainable Energy in Rural Electrification: A Case Study in Cameroon

The state of Cameroon, faced with the situation the electricity deficits, is promoting the development of renewable energies in general and to meet rural electrification needs in particular. The purpose of this work is to study the feasibility of the MHP of Batcheu, to show its contribution to sustainable development in this locality and to prove that it is a profitable project. After study, it appears that the waterfall of Batcheu is favourable to the establishment of a MHP with an installed power of 260 kW with an operating diagram corresponding to a Francis turbine. Given that it is a renewable energy that can supply more than 800 households in rural areas, its contribution to sustainable development is obvious. Its investment cost is estimated at 171,465,396 FCFA. It is a profitable project with a payback time of 7 years and 2 months.

Vibration Control of A Flexible Marine Riser System Subject to Input Dead Zone and Extraneous Disturbances

An observer-based adaptive backstepping boundary control is proposed for vibration control of flexible offshore riser systems with unknown nonlinear input dead zone and uncertain environmental disturbances.The control algorithm can update the control law online through real-time data to make the controller adapt to the environment and improve the control precision.Specifically,based on the adaptive backstepping framework,virtual control laws and Lyapunov functions are designed for each subsystem.Three direction interference observers are designed to track the timevarying boundary disturbance.On this basis,the inverse of the dead zone and linear state transformation are used to compensate for the original system and eliminate the adverse effects of the dead zone.In addition,the stability of the closed-loop system is proven by Lyapunov stability theory.All the system states are bounded,and the vibration offset of the riser converges to a small area of the initial position.Finally,four examples of flexible marine risers are simulated in MATLAB to verify the effectiveness of the proposed controller.

Highly Efficient Aligned Ion‑Conducting Network and Interface Chemistries for Depolarized All‑Solid‑State Lithium Metal Batteries

Improving the long-term cycling stability and energy density of all-solid-state lithium(Li)-metal batteries(ASSLMBs)at room temperature is a severe challenge because of the notorious solid–solid interfacial contact loss and sluggish ion transport.Solid electrolytes are generally studied as two-dimensional(2D)structures with planar interfaces,showing limited interfacial contact and further resulting in unstable Li/electrolyte and cathode/electrolyte interfaces.Herein,three-dimensional(3D)architecturally designed composite solid electrolytes are developed with independently controlled structural factors using 3D printing processing and post-curing treatment.Multiple-type electrolyte films with vertical-aligned micro-pillar(p-3DSE)and spiral(s-3DSE)structures are rationally designed and developed,which can be employed for both Li metal anode and cathode in terms of accelerating the Li+transport within electrodes and reinforcing the interfacial adhesion.The printed p-3DSE delivers robust long-term cycle life of up to 2600 cycles and a high critical current density of 1.92 mA cm^(−2).The optimized electrolyte structure could lead to ASSLMBs with a superior full-cell areal capacity of 2.75 mAh cm^(−2)(LFP)and 3.92 mAh cm^(−2)(NCM811).This unique design provides enhancements for both anode and cathode electrodes,thereby alleviating interfacial degradation induced by dendrite growth and contact loss.The approach in this study opens a new design strategy for advanced composite solid polymer electrolytes in ASSLMBs operating under high rates/capacities and room temperature.