Hydrogen energy became the most significant energy as the current demand gradually starts to increase. Hydrogen energy is an important key solution to tackle the global temperature rise. The key important factor of hy...Hydrogen energy became the most significant energy as the current demand gradually starts to increase. Hydrogen energy is an important key solution to tackle the global temperature rise. The key important factor of hydrogen production is the hydrogen economy. Hydrogen production technologies are commercially available, while some of these technologies are still under development. This paper reviews the hydrogen production technologies from both fossil and non-fossil fuels such as (steam reforming, partial oxidation, auto thermal, pyrolysis, and plasma technology). Additionally, water electrolysis technology was reviewed. Water electrolysis can be combined with the renewable energy to get eco-friendly technology. Currently, the maximum hydrogen fuel productions were registered from the steam reforming, gasification, and partial oxidation technologies using fossil fuels. These technologies have different challenges such as the total energy consumption and carbon emissions to the environment are still too high. A novel non-fossil fuel method [ammonia NH3] for hydrogen production using plasma technology was reviewed. Ammonia decomposition using plasma technology without and with a catalyst to produce pure hydrogen was considered as compared case studies. It was showed that the efficiency of ammonia decomposition using the catalyst was higher than ammonia decomposition without the catalyst. The maximum hydrogen energy efficiency obtained from the developed ammonia decomposition system was 28.3% with a hydrogen purity of 99.99%. The development of ammonia decomposition processes is continues for hydrogen production, and it will likely become commercial and be used as a pure hydrogen energy source.展开更多
Superlubricity refers to a sliding regime in which contacting surfaces move over one another without generating much adhesion or friction[1].From a practical application point of view,this will be the most ideal tribo...Superlubricity refers to a sliding regime in which contacting surfaces move over one another without generating much adhesion or friction[1].From a practical application point of view,this will be the most ideal tribological situation for many moving mechanical systems mainly because friction consumes large amounts of energy and causes greenhouse gas emissions[2].Superlubric sliding can also improve performance and durability of these systems.In this paper,we attempt to provide an overview of how controlled or targeted bulk,surface,or tribochemistry can lead to superlubricity in diamond-like carbon(DLC)films.Specifically,we show that how providing hydrogen into bulk and near surface regions as well as to sliding contact interfaces of DLC films can lead to super-low friction and wear.Incorporation of hydrogen into bulk DLC or near surface regions can be done during deposition or through hydrogen plasma treatment after the deposition.Hydrogen can also be fed into the sliding contact interfaces of DLCs during tribological testing to reduce friction.Due to favorable tribochemical interactions,these interfaces become very rich in hydrogen and thus provide super-low friction after a brief run-in period.Regardless of the method used,when sliding surfaces of DLC films are enriched in hydrogen,they then provide some of the lowest friction coefficients(i.e.,down to 0.001).Time-of-flight secondary ion mass spectrometer(TOF-SIMS)is used to gather evidence on the extent and nature of tribochemical interactions with hydrogen.Based on the tribological and surface analytical findings,we provide a mechanistic model for the critical role of hydrogen on superlubricity of DLC films.展开更多
Boosting the resilience of power systems is a core requirement of smart grids. In fact, resilience enhancement is crucial to all critical infrastructure systems.In this study, we review the current research on system ...Boosting the resilience of power systems is a core requirement of smart grids. In fact, resilience enhancement is crucial to all critical infrastructure systems.In this study, we review the current research on system resilience enhancement within and beyond smart grids. In addition, we elaborate on resilience definition and resilience quantification and discuss several challenges and opportunities for system resilience enhancement. This study aims to deepen our understanding of the concept of resilience and develop a wide perspective on enhancing the system resilience for critical infrastructures.展开更多
In this paper,an improved active stabilization strategy of the interface converters in microgrid applications is proposed on the basis of the passivity-based stability criterion(PBSC).As a critical part of AC and DC h...In this paper,an improved active stabilization strategy of the interface converters in microgrid applications is proposed on the basis of the passivity-based stability criterion(PBSC).As a critical part of AC and DC hybrid microgrids,the DC microgrid is taken as an example.In particular,a stabilization method with a proportional-integral(PI)controller and firstorder high-pass filter(HPF)is proposed to meet the passivity requirements of the overall control diagram with respect to the output voltage.Meanwhile,an output current feedback control loop is introduced to ensure the output impedance passivity.Moreover,a small-signal model of the parallel interface converter system is established to comprehensively study the influence of control parameters on the passivity of the converters.Based on the active stabilization method proposed in this study,by manipulating the control diagram of each interface converter,the passivity and stability of the DC microgrids with variable configuration can be guaranteed.Therefore,a generic and simplified design approach is realized.A simulation model with three interface converters is implemented in MATLAB/Simulink,and the effectiveness of the proposed passivity-based active stabilization algorithm is verified by using this simulation model.展开更多
Advanced building controls and energy optimization for new constructions and retrofits rely on accurate weather data.Traditionally,most studies utilize airport weather information as the decision inputs.However,most b...Advanced building controls and energy optimization for new constructions and retrofits rely on accurate weather data.Traditionally,most studies utilize airport weather information as the decision inputs.However,most buildings are in environments that are quite different than those at the airport miles away.Tree cover,adjacent buildings,and micro-climate effects caused by the larger surrounding area can all yield deviations in air temperature,humidity,solar irradiance,and wind that are large enough to influence design and operation decisions.In order to overcome this challenge,there are many prior studies on developing weather forecasting algorithms from micro-to meso-scales.This paper reviews and complies knowledge on common weather data resources,data processing methodologies and forecasting techniques of weather information.Commonly used statistical,machine learning and physical-based models are discussed and presented as two major categories:deterministic forecasting and probabilistic forecasting.Finally,evaluation metrics for forecasting errors are listed and discussed.展开更多
In this study,we mainly focus on the structural morphology and inter-atomic bonding state of tribofilms resulting from a highly-hydrogenated amorphous carbon(a-C:H) film in order to ascertain the underlying mechanisms...In this study,we mainly focus on the structural morphology and inter-atomic bonding state of tribofilms resulting from a highly-hydrogenated amorphous carbon(a-C:H) film in order to ascertain the underlying mechanisms for its superlubric behavior(i.e.,less than 0.01 friction coefficient).Specifically,we achieved superlubricity(i.e.,friction coefficients of down to 0.003) with this film in dry nitrogen and argon atmospheres especially when the tribo-pair is made of an a-C:H coated Si disk sliding against an a-C:H coated steel ball,while the a-C:H coated disk against uncoated ball does not provide superlubricity.We also found that the state of superlubricity is more stable in argon than in nitrogen and the formation of a smooth and uniformly-thick carbonaceous tribofilm appears to be one of the key factors for the realization of such superlubricity.Besides,the interfacial morphology of sliding test pairs and the atomic-scale bond structure of the carbon-based tribofilms also play an important role in the observed superlubric behavior of a-C:H films.Using Raman spectroscopy and high resolution transmission electron microscopy,we have compared the structural differences of the tribofilms produced on bare and a-C:H coated steel balls.For the a-C:H coated ball as mating material which provided superlow friction in argon,structural morphology of the tribofilm was similar or comparable to that of the original a-C:H coating;while for the bare steel ball,the sp^2-bonded C fraction in the tribofilm increased and a fingerprint-like nanocrystalline structure was detected by high resolution transmission electron microscopy(HRTEM).We also calculated the shear stresses for different tribofilms,and established a relationship between the magnitude of the shear stresses and the extent of sp^3-sp^2 phase transformation.展开更多
Energy and material losses due to friction and wear in mechanical systems account for huge economic and environmental burdens.Approximately one-third of the world’s primary energy consumption is attributed to frictio...Energy and material losses due to friction and wear in mechanical systems account for huge economic and environmental burdens.Approximately one-third of the world’s primary energy consumption is attributed to friction;in addition,about 80%of the equipment failure is caused by wear in friction processes.Even relatively small improvements in the tribology of mechanical systems would reap enormous societal benefits.Superlubricity is a state in which two contacting surfaces exhibit almost no resistance to sliding,and the friction force between the two sliding surfaces nearly vanishes.Improvement of superlubricity technology and our understanding of its mechanism play an important role for saving energy in industry as well as our daily life.Consequently,superlubricity has attracted a large amount of attention from researchers in many fields,which is leading to a revolution in engineering technology.展开更多
Solving for detailed chemical kinetics remains one of the major bottlenecks for computational fluid dynamics simulations of reacting flows using a finite-rate-chemistry approach.This has motivated the use of neural ne...Solving for detailed chemical kinetics remains one of the major bottlenecks for computational fluid dynamics simulations of reacting flows using a finite-rate-chemistry approach.This has motivated the use of neural networks to predict stiff chemical source terms as functions of the thermochemical state of the combustion system.However,due to the nonlinearities and multi-scale nature of combustion,the predicted solution often diverges from the true solution when these machine learning models are coupled with a computational fluid dynamics solver.This is because these approaches minimize the error during training without guaranteeing successful integration with ordinary differential equation solvers.In the present work,a novel neural ordinary differential equations approach to modeling chemical kinetics,termed as ChemNODE,is developed.In this machine learning framework,the chemical source terms predicted by the neural networks are integrated during training,and by computing the required derivatives,the neural network weights are adjusted accordingly to minimize the difference between the predicted and ground-truth solution.A proof-of-concept study is performed with ChemNODE for homogeneous autoignition of hydrogen-air mixture over a range of composition and thermodynamic conditions.It is shown that ChemNODE accurately captures the chemical kinetic behavior and reproduces the results obtained using the detailed kinetic mechanism at a fraction of the computational cost.展开更多
Weather forecasting has been a critical component to predict and control building energy consumption for better building energy management.Without accessibility to other data sources,the onsite observed temperatures o...Weather forecasting has been a critical component to predict and control building energy consumption for better building energy management.Without accessibility to other data sources,the onsite observed temperatures or the airport temperatures are used in forecast models.In this paper,we present a novel approach by utilizing the crowdsourcing weather data from neighboring personal weather stations(PWS)to improve the weather forecast accuracy around buildings using a general spatial-temporal modeling framework.The final forecast is based on the ensemble of local forecasts for the target location using neighboring PWSs.Our approach is distinguished from existing literature in various aspects.First,we leverage the crowdsourcing weather data from PWS in addition to public data sources.In this way,the data is at much finer time resolution(e.g.,at 5-minute frequency)and spatial resolution(e.g.,arbitrary location vs grid).Second,our proposed model incorporates spatial-temporal correlation information of weather variables between the target building and a set of neighboring PWSs so that underlying correlations can be effectively captured to improve forecasting performance.We demonstrate the performance of the proposed framework by comparing to the benchmark models on temperature forecasting for a building located at an arbitrary location at San Antonio,Texas,USA.In general,the proposed model framework equipped with machine learning technique such as Random Forest can improve forecasting by 50%compares with persistent model and has 90%chance to outperform airport forecast in short-term forecasting.In a real-time setting,the proposed model framework can provide more accurate temperature forecasting results compared with using airport temperature forecast for most forecast horizon.Moreover,we analyze the sensitivity of model parameters to gain insights on how crowdsourcing data from the neighboring personal weather stations impacts forecasting performance.Finally,we implement our model in other cities such as Syracuse and Chicago to test the model’s performance in different landforms and climate types.展开更多
文摘Hydrogen energy became the most significant energy as the current demand gradually starts to increase. Hydrogen energy is an important key solution to tackle the global temperature rise. The key important factor of hydrogen production is the hydrogen economy. Hydrogen production technologies are commercially available, while some of these technologies are still under development. This paper reviews the hydrogen production technologies from both fossil and non-fossil fuels such as (steam reforming, partial oxidation, auto thermal, pyrolysis, and plasma technology). Additionally, water electrolysis technology was reviewed. Water electrolysis can be combined with the renewable energy to get eco-friendly technology. Currently, the maximum hydrogen fuel productions were registered from the steam reforming, gasification, and partial oxidation technologies using fossil fuels. These technologies have different challenges such as the total energy consumption and carbon emissions to the environment are still too high. A novel non-fossil fuel method [ammonia NH3] for hydrogen production using plasma technology was reviewed. Ammonia decomposition using plasma technology without and with a catalyst to produce pure hydrogen was considered as compared case studies. It was showed that the efficiency of ammonia decomposition using the catalyst was higher than ammonia decomposition without the catalyst. The maximum hydrogen energy efficiency obtained from the developed ammonia decomposition system was 28.3% with a hydrogen purity of 99.99%. The development of ammonia decomposition processes is continues for hydrogen production, and it will likely become commercial and be used as a pure hydrogen energy source.
基金supported by the U.S.Department of Energy,Office of Energy Efficiency and Renewable Energy,under Contract No.DE-AC02-06CH11357。
文摘Superlubricity refers to a sliding regime in which contacting surfaces move over one another without generating much adhesion or friction[1].From a practical application point of view,this will be the most ideal tribological situation for many moving mechanical systems mainly because friction consumes large amounts of energy and causes greenhouse gas emissions[2].Superlubric sliding can also improve performance and durability of these systems.In this paper,we attempt to provide an overview of how controlled or targeted bulk,surface,or tribochemistry can lead to superlubricity in diamond-like carbon(DLC)films.Specifically,we show that how providing hydrogen into bulk and near surface regions as well as to sliding contact interfaces of DLC films can lead to super-low friction and wear.Incorporation of hydrogen into bulk DLC or near surface regions can be done during deposition or through hydrogen plasma treatment after the deposition.Hydrogen can also be fed into the sliding contact interfaces of DLCs during tribological testing to reduce friction.Due to favorable tribochemical interactions,these interfaces become very rich in hydrogen and thus provide super-low friction after a brief run-in period.Regardless of the method used,when sliding surfaces of DLC films are enriched in hydrogen,they then provide some of the lowest friction coefficients(i.e.,down to 0.001).Time-of-flight secondary ion mass spectrometer(TOF-SIMS)is used to gather evidence on the extent and nature of tribochemical interactions with hydrogen.Based on the tribological and surface analytical findings,we provide a mechanistic model for the critical role of hydrogen on superlubricity of DLC films.
基金supported by the Key Program of National Natural Science Foundation of China (Grant No. 51537010)the National Basic Research Program (973 Program) (Grant No. 2013CB228206)supported by the U.S. Department of Energy’s Office of Electricity Delivery and Energy Reliability
文摘Boosting the resilience of power systems is a core requirement of smart grids. In fact, resilience enhancement is crucial to all critical infrastructure systems.In this study, we review the current research on system resilience enhancement within and beyond smart grids. In addition, we elaborate on resilience definition and resilience quantification and discuss several challenges and opportunities for system resilience enhancement. This study aims to deepen our understanding of the concept of resilience and develop a wide perspective on enhancing the system resilience for critical infrastructures.
基金This work was supported in part by the National Natural Science Foundation of China(Nos.51137003,61233008 and 51520105011)and in part by the Special Project of International Scientific and Technological Cooperation of China(No.2015DFR70850).
文摘In this paper,an improved active stabilization strategy of the interface converters in microgrid applications is proposed on the basis of the passivity-based stability criterion(PBSC).As a critical part of AC and DC hybrid microgrids,the DC microgrid is taken as an example.In particular,a stabilization method with a proportional-integral(PI)controller and firstorder high-pass filter(HPF)is proposed to meet the passivity requirements of the overall control diagram with respect to the output voltage.Meanwhile,an output current feedback control loop is introduced to ensure the output impedance passivity.Moreover,a small-signal model of the parallel interface converter system is established to comprehensively study the influence of control parameters on the passivity of the converters.Based on the active stabilization method proposed in this study,by manipulating the control diagram of each interface converter,the passivity and stability of the DC microgrids with variable configuration can be guaranteed.Therefore,a generic and simplified design approach is realized.A simulation model with three interface converters is implemented in MATLAB/Simulink,and the effectiveness of the proposed passivity-based active stabilization algorithm is verified by using this simulation model.
基金This work was supported by the U.S.Department of Energy,Office of Energy Efficiency and Renewable Energy through its Building Technologies Office.The submitted manuscript has been created by UChicago Argonne,LLC,Operator of Argonne National Laboratory(“Argonne”)Argonne,a U.S.Department of Energy Office of Science laboratory,is operated under Contract No.DE AC02-06CH11357The views expressed in this article are the authors’own and do not necessarily represent the views of the U.S.Department of Energy or the United States Government.
文摘Advanced building controls and energy optimization for new constructions and retrofits rely on accurate weather data.Traditionally,most studies utilize airport weather information as the decision inputs.However,most buildings are in environments that are quite different than those at the airport miles away.Tree cover,adjacent buildings,and micro-climate effects caused by the larger surrounding area can all yield deviations in air temperature,humidity,solar irradiance,and wind that are large enough to influence design and operation decisions.In order to overcome this challenge,there are many prior studies on developing weather forecasting algorithms from micro-to meso-scales.This paper reviews and complies knowledge on common weather data resources,data processing methodologies and forecasting techniques of weather information.Commonly used statistical,machine learning and physical-based models are discussed and presented as two major categories:deterministic forecasting and probabilistic forecasting.Finally,evaluation metrics for forecasting errors are listed and discussed.
基金supported by the National Basic Research Program of China (Grant No.2011CB013404)National Natural Science Foundation of China(Grant Nos.51321092,51527901 and 51375010)
文摘In this study,we mainly focus on the structural morphology and inter-atomic bonding state of tribofilms resulting from a highly-hydrogenated amorphous carbon(a-C:H) film in order to ascertain the underlying mechanisms for its superlubric behavior(i.e.,less than 0.01 friction coefficient).Specifically,we achieved superlubricity(i.e.,friction coefficients of down to 0.003) with this film in dry nitrogen and argon atmospheres especially when the tribo-pair is made of an a-C:H coated Si disk sliding against an a-C:H coated steel ball,while the a-C:H coated disk against uncoated ball does not provide superlubricity.We also found that the state of superlubricity is more stable in argon than in nitrogen and the formation of a smooth and uniformly-thick carbonaceous tribofilm appears to be one of the key factors for the realization of such superlubricity.Besides,the interfacial morphology of sliding test pairs and the atomic-scale bond structure of the carbon-based tribofilms also play an important role in the observed superlubric behavior of a-C:H films.Using Raman spectroscopy and high resolution transmission electron microscopy,we have compared the structural differences of the tribofilms produced on bare and a-C:H coated steel balls.For the a-C:H coated ball as mating material which provided superlow friction in argon,structural morphology of the tribofilm was similar or comparable to that of the original a-C:H coating;while for the bare steel ball,the sp^2-bonded C fraction in the tribofilm increased and a fingerprint-like nanocrystalline structure was detected by high resolution transmission electron microscopy(HRTEM).We also calculated the shear stresses for different tribofilms,and established a relationship between the magnitude of the shear stresses and the extent of sp^3-sp^2 phase transformation.
文摘Energy and material losses due to friction and wear in mechanical systems account for huge economic and environmental burdens.Approximately one-third of the world’s primary energy consumption is attributed to friction;in addition,about 80%of the equipment failure is caused by wear in friction processes.Even relatively small improvements in the tribology of mechanical systems would reap enormous societal benefits.Superlubricity is a state in which two contacting surfaces exhibit almost no resistance to sliding,and the friction force between the two sliding surfaces nearly vanishes.Improvement of superlubricity technology and our understanding of its mechanism play an important role for saving energy in industry as well as our daily life.Consequently,superlubricity has attracted a large amount of attention from researchers in many fields,which is leading to a revolution in engineering technology.
基金This work was supported by the U.S.Department of Energy,Office of Science under contract DE-AC02-06CH11357The research work was funded by Argonne’s Laboratory Directed Research and Development(LDRD)Innovate project#2020-0203.The authors acknowledge the computing resources available via Bebop,a high-performance computing cluster operated by the Laboratory Computing Resource Center(LCRC)at Argonne National Laboratory.
文摘Solving for detailed chemical kinetics remains one of the major bottlenecks for computational fluid dynamics simulations of reacting flows using a finite-rate-chemistry approach.This has motivated the use of neural networks to predict stiff chemical source terms as functions of the thermochemical state of the combustion system.However,due to the nonlinearities and multi-scale nature of combustion,the predicted solution often diverges from the true solution when these machine learning models are coupled with a computational fluid dynamics solver.This is because these approaches minimize the error during training without guaranteeing successful integration with ordinary differential equation solvers.In the present work,a novel neural ordinary differential equations approach to modeling chemical kinetics,termed as ChemNODE,is developed.In this machine learning framework,the chemical source terms predicted by the neural networks are integrated during training,and by computing the required derivatives,the neural network weights are adjusted accordingly to minimize the difference between the predicted and ground-truth solution.A proof-of-concept study is performed with ChemNODE for homogeneous autoignition of hydrogen-air mixture over a range of composition and thermodynamic conditions.It is shown that ChemNODE accurately captures the chemical kinetic behavior and reproduces the results obtained using the detailed kinetic mechanism at a fraction of the computational cost.
文摘Weather forecasting has been a critical component to predict and control building energy consumption for better building energy management.Without accessibility to other data sources,the onsite observed temperatures or the airport temperatures are used in forecast models.In this paper,we present a novel approach by utilizing the crowdsourcing weather data from neighboring personal weather stations(PWS)to improve the weather forecast accuracy around buildings using a general spatial-temporal modeling framework.The final forecast is based on the ensemble of local forecasts for the target location using neighboring PWSs.Our approach is distinguished from existing literature in various aspects.First,we leverage the crowdsourcing weather data from PWS in addition to public data sources.In this way,the data is at much finer time resolution(e.g.,at 5-minute frequency)and spatial resolution(e.g.,arbitrary location vs grid).Second,our proposed model incorporates spatial-temporal correlation information of weather variables between the target building and a set of neighboring PWSs so that underlying correlations can be effectively captured to improve forecasting performance.We demonstrate the performance of the proposed framework by comparing to the benchmark models on temperature forecasting for a building located at an arbitrary location at San Antonio,Texas,USA.In general,the proposed model framework equipped with machine learning technique such as Random Forest can improve forecasting by 50%compares with persistent model and has 90%chance to outperform airport forecast in short-term forecasting.In a real-time setting,the proposed model framework can provide more accurate temperature forecasting results compared with using airport temperature forecast for most forecast horizon.Moreover,we analyze the sensitivity of model parameters to gain insights on how crowdsourcing data from the neighboring personal weather stations impacts forecasting performance.Finally,we implement our model in other cities such as Syracuse and Chicago to test the model’s performance in different landforms and climate types.