Support Vector Regression Model of Chlorophyll-<i>a</i>during Spring Algal Bloom in Xiangxi Bay of Three Gorges Reservoir, China

To study the relationship between chlorophyll-a and environmental variables during spring algal bloom in Xiangxi Bay of Three Gorges Reservoir, the support vector regression (SVR) model was established. In surveys, 11 stations have been investigated and 264 samples were collected weekly from March 4 to May 13 in 2007 and February 16 to May 10 in 2008. The parameters in SVR model were optimized by leave one out cross validation. The squared correlation coefficient R2 and the cross validated squared correlation coefficient Q2 of the optimal SVR model are 0.8202 and 0.7301, respectively. Compared with stepwise multiple linear regression and back propagation artificial neural network models using external validation, the SVR model has been shown to perform well for regression with the predictive squared correlation coefficient R2pred value of 0.7842 for the test set.

Study on Phosphorus Characteristics in Sediments of Xiangxi Bay, China Three-Gorge Reservoir

To explore the environment influence of the sediments in Xiangxi Bay (China Three-Gorge Reservoir), spatial and temporal distribution characteristics of total phosphorus (TP), phosphorus fractions, dissolved total phosphorus (DTP) of pore water and overlying water in the sediments were investigated. In surveys, the sampling was undertaken from six sites of Xiangxi Bay on 29 March 2009 and 28 March 2010. TP contents ranged from 1111.29 mg/kg to 1941.29 mg/kg with the mean value of 1533.09 mg/kg in 2009 spring and 1600.48 mg/kg in 2010 spring. Five fractions of sedimentary phosphorus, including loosely sorbed phosphorus (NH4Cl-P), redox-sensitive phosphorus (BD-P), metal oxide bound phosphorus (NaOH-P), calcium bound phosphorus (HCl-P), and residual phosphorus (Res-P), were separately quantified. DTP of pore water and overlying water all have positive correlations with NH4Cl-P and BD-P, which indicated that NH4Cl-P and BD-P were the main fractions that can easily release phosphorus in the sediments of Xiangxi Bay.

An eco-environmental friendly operation: An effective method to mitigate the harmful blooms in the tributary bays of Three Gorges Reservoir

Harmful algal blooms, which frequently occur in different tributaries, have become a serious water quality problem of the Three Gorges Reservoir (TGR) since its initial filling. A three-year monitoring campaign from 2008 to 2010 was conducted to identify the controlling factors of algal blooms and effective preventive measures. The following results were obtained: 1) Layered and bidirectional currents, called intrusive density currents, dominate the tributary bays of the TGR year round; 2) continuously increasing water level can make the intruding density current shift from the middle to the surface, and surface intrusive water can reduce the surface water temperature and break the stable stratification of the tributary; 3) the appearing or fading away of algal blooms is closely associated with fluctuations in the TGR water level. Thus, the water level fluctuation patterns of different "tide-types" may prevent the occurrence of algal blooms in the spring and summer, and the "stair-type" tides may control autumn blooms during the impounding period. These methods were feasible and effective throughout the actual TGR's operation in 2009 2011. These patterns formed an eco-environmentally friendly operation (EEFO) to mitigate algal blooms. As an in situ treatment with easier operation and less negative impact and loss, compared with chemical and filter-feeding fish methods, the EEFO is currently considered as the most feasible remedial measure to remit the eco-environmental problems at the Three Gorges Dam (TGD).

Impact of wetting-drying cycles and acidic conditions on the soil aggregate stability of yellow‒brown soil

Soil aggregate is the basic structural unit of soil,which is the foundation for supporting ecosystem functions,while its composition and stability is significantly affected by the external environment.This study was conducted to explore the effect of external environment(wetting-drying cycles and acidic conditions)on the soil aggregate distribution and stability and identify the key soil physicochemical factors that affect the soil aggregate stability.The yellow‒brown soil from the Three Gorges Reservoir area(TGRA)was used,and 8 wetting-drying conditions(0,1,2,3,4,5,10 and 15 cycles)were simulated under 4 acidic conditions(pH=3,4,5 and 7).The particle size distribution and soil aggregate stability were determined by wet sieving method,the contribution of environmental factors(acid condition,wetting-drying cycle and their combined action)to the soil aggregate stability was clarified and the key soil physicochemical factors that affect the soil aggregate stability under wetting-drying cycles and acidic conditions were determined by using the Pearson’s correlation analysis,Partial least squares path modeling(PLS‒PM)and multiple linear regression analysis.The results indicate that wetting-drying cycles and acidic conditions have significant effects on the stability of soil aggregates,the soil aggregate stability gradually decreases with increasing number of wetting-drying cycles and it obviously decreases with the increase of acidity.Moreover,the combination of wetting-drying cycles and acidic conditions aggravate the reduction in the soil aggregate stability.The wetting-drying cycles,acidic conditions and their combined effect imposes significant impact on the soil aggregate stability,and the wetting-drying cycles exert the greatest influence.The soil aggregate stability is significantly correlated with the pH,Ca^(2+),Mg^(2+),maximum disintegration index(MDI)and soil bulk density(SBD).The PLS‒PM and multiple linear regression analysis further reveal that the soil aggregate stability is primarily influenced by SBD,Ca^(2+),and MDI.These results offer a scientific basis for understanding the soil aggregate breakdown mechanism and are helpful for clarifying the coupled effect of wetting-drying cycles and acid rain on terrestrial ecosystems in the TGRA.

Diel and seasonal variation of methane and carbon dioxide fluxes at Site Guojiaba, the Three Gorges Reservoir

In order to investigate the CH4 and CO2 fluxes across the water-gas interface and identify their controlling factors, four diel field campaigns and one monthly sampling campaign during June 2010-May 2011 were carried out at a site near the Three Gorges Dam, China. The averaged CH4 and CO2 fluxes across the air-water interface from the site were much less than those reported from reservoirs in tropic and temperate regions, and from the natural river channels of the Yangtze River. CH4 Fluxes at the site were very low compared to most other reservoirs or natural lakes. One of the most important reasons may be due to the oxidation of CH4 in the water column owing to the great water depth and high DO in water in the Three Gorges Reservoir. The averaged monthly CH4 and CO2 fluxes at the site during the observation year were 0.05 mg/（m^2·hr） and 104.43 mg/（m^2·hr） respectively with the maximum occurred in July 2010. The monthly CO2 fluxes during the observation year were positively correlated to the surface water temperature, and negatively correlated to the air pressure and the surface water pH. The CO2 flux showed a positive correlation with DOC to some extent, although not significantly, which indicated that allochthonous organic C was a major source of CO2 and biogeochemical processes in this reservoir were C-limited. The significantly positive correlation between the reservoir outflow and the seasonal gas flux indicate the disturbance condition of the water body dominated the seasonal gas emission.

Ice storm damage to oak forests in subtropical China

Ice storms,as important sources of frequent and injurious disturbances,drive forest dynamics in the Northern Hemisphere.However,stand-level differential vulnerability to ice storms and the associated factors that predispose forest stands remain unclear.This is particularly concerning in the subtropics where the frequency of ice storms is predicted to increase with global warming.Here we assessed how the impact on three forest stands(early and late secondary-growth forests,and old-growth forests)differed after an extreme ice storm during 20–21 March 2022,and identified the abiotic and biotic factors that determine the damage intensity in the Shennongjia World Natural Heritage Site,a biodiversity conservation hotspot in central China.We found a stand-specific‘middomain effect’where the late secondary-growth forest sustained the most severe damage,the early secondarygrowth forest sustained the least,and the old-growth forest suffered an intermediate amount.‘Crown broken’was the most severe damage type across all three forest stands,although the proportion of‘branch broken’was also high in the old-growth forest.Topography played a significant role in determining the vulnerability of the early secondary-growth forest to severe ice storms whereas the forest structure and composition were important factors in explaining the damage rates in the old-growth forest,although they differed among the damage categories.In contrast,topography,forest structure and composition generally explain the intensity of damage in the late secondary-growth forests.Our results highlight that,in subtropical forests,the intensity of damage caused by severe ice storms and related determining factors are stand-level dependent.We also suggest exploring potential management strategies(e.g.,slow-growing hardwood species that can resist storms should be the main species for reforestation in early secondary-growth forests)to mitigate the risk of future severe ice storms,as well as other wind-related climatic extremes.

Parasite-host network analysis provides insights into the evolution of two mistletoe lineages(Loranthaceae and Santalaceae)

Mistletoes are ecologically important parasitic plants,with> 1600 species from five lineages worldwide.Mistletoe lineages exhibit distinct patterns of species diversification and host specificity,however,the mechanisms underlying these differences are poorly understood.In this study,we analysed a comprehensive parasite-host network,including 280 host species from 60 families and 22 mistletoe species from two lineages(Santalaceae and Loranthaceae) in Xishuangbanna,located in a biodiversity hotspot of tropical Asia.We identified the factors that predict the infection strength of mistletoes.We also detected host specificity and the phylogenetic signal of mistletoes and their hosts.We found that this interaction network could be largely explained by a model based on the relative abundance of species.Host infection was positively correlated with diameter at breast height and tree coverage,but negatively correlated with wood density.Overall,closely related mistletoe species tend to interact more often with similar hosts.However,the two lineages showed a significantly different network pattern.Rates of host generality were higher in Loranthaceae than in Santalaceae,although neither lineage showed phylogenetic signal for host generality.This study demonstrates that the neutral interaction hypothesis provides suitable predictions of the mistletoe-host interaction network,and mistletoe species show significant phylogenetic signals for their hosts.Our findings also indicate that high species diversification in Loranthaceae may be explained by high rates of host generality and the evolutionary history shared by Loranthaceae species with diverse host plants in the tropics.

Effects of salinity on embryonic and larval development of Chinese mitten crab Eriocheir sinensis(Decapoda: Brachyura) and salinity-induced physiological changes

To investigate the effects of salinity on early development of Chinese mitten crab ( Eriocheir sinensis ), and the salinity tolerance mechanism of embryos, different developmental stages of embryos (gastrula, eyespot and pre-hatching stage), and hatched stage I zoea and megalopa, were exposed to a range of salinities (1, 5, 10, 15 (control), 20, 25, 30, 35 and 40). Hatching, survival and molting were monitored. Effects of 24-hour hypersaline (35) and hyposaline (1) stress on egg diameter, water content, Na +/K +-ATPase (NKA) activity, and crustacean hyperglycemic hormone (CHH) gene mRNA expression in embryos and megalopa, are reported. Embryos are more tolerant of low (≤ 5) than high (≥25) salinities, with optimum ranges for gastrula and pre-hatching stage embryos being 5-20, and for eyespot embryo and stage I zoea, 10-20. Most megalopa can molt to the first juvenile instar by day 5 at salinities between 1 and 40, whereas molting of megalopa stages was delayed at 40. Hypersaline conditions resulted in a loss of moisture, reduction of egg volume, and a signifi cant increase in NKA activity and CHH mRNA expression at some developmental stages. Hyposaline conditions did not affect moisture content or egg volume, but resulted in decreased NKA activity and CHH mRNA expression in embryos. For megalopa stages, NKA activity was significantly upregulated following both hypo- and hypersaline stress. Our results suggest high salinity will inhibit development and hatching of E. sinensis embryos, and low salinity will affect the survival of their stage I zoea. Increased NKA activity in embryos and megalopa stages might indicate a hyporegulation response under hypersaline conditions. These findings provide useful information for spawning ground protection of indigenous E . sinensis and enrich the knowledge of embryonic tolerance mechanisms of hyperregulating crustaceans following osmotic stress.

Fish Assemblage Responses to a Low-head Dam Removal in the Lancang River

Dam removal is becoming an effective approach for aquatic biodiversity restoration in damming river in order to balance the aquatic ecosystem conservation with large-scale cascade damming. However, the effects of dam removal on fish communities in Asian mountainous rivers, which are dominated by Cypriniformes fishes, are still not well known. To determine whether dam removal on a mountainous river benefit restoration of fish diversity, we investigated the response of fish assemblage to dam removal using a before-after-control-impact design in two tributaries of the Lancang River(dam removal river: the Jidu River, and control river: the Fengdian River). Fish surveys were conducted one year prior to dam removal(2012) and three years(2013–2015) following dam removal. We observed rapidly and notably spatio-temporal changes in fish biodiversity metrics and assemblage structure, occurring in the Jidu River within the first year after dam removal. Overall, fish species richness, density and Shannon-Wiener diversity all increased immediately in above-and below-dam sites, and maintained a stable level in subsequent years, compared to unchanged situation in the control river. All sites in the Jidu River experienced shifts in fish composition after dam removal, with the greatest temporal changes occurred in sites below-and above-the former dam, resulting in a temporal homogenization tendency in the dam removed river. These findings suggest that dam removal can benefit the recovery of habitat conditions and fish community in Asian mountainous rivers, but the results should be further evaluated when apply to other dammed rivers since the dam age, fluvial geomorphology and situation of source populations could all affect the responses of fish assemblages.

Initial response of fish trophic niche to hydrological alteration in the upstream of Three Gorges Dam

Introduction:Damming is one of the dramatic impacts to river food webs due to habitat fragmentation and changes in the hydrological regimes.The world’s largest dam,the Three Gorges Dam(TGD),has been constructed in the middle of Yangtze River since 2003.The objective of this study was to understand the effects of altered hydrological regime on the trophic structure of fish food web along the hydrological gradient in the TGD.Methods:Fish samples were collected from an upstream,a midstream and a downstream site of the Yangtze River upstream of the TGD in May and September of 2004.Muscle tissue of each fish species was determined for stable isotopic compositions(δ^(13)C and δ^(15)N)which were used to calculate isotope-based Bayesian community-wide trophic metrics.Results:Stable isotope trophic niche analysis reveals reduced utilization of basal resource and trophic niche space at the midstream and downstream sites.By contrast,community trophic diversity and species redundancy were higher at the downstream than the upstream and midstream,likely as the result of reduced the spectrum of basal resources.These findings suggested that the negative impacts on the overall trophic niche space from reduced flow,increased water depth and stagnancy occurred only one year after the completion of the TGD.Conclusions:Altered hydrological regimes posed multiple impacts to the aquatic food web.Reduced flow and increased water depth within TGD has posed initial effects to the fish community trophic structure.Further collections ana analysis of ecological data to compare the fish trophic structure revealed in this study are needed to assess the long-term impacts of TGD on fish community structure and resources utilization.

Effect of Zn application methods on Zn distribution and bioavailability in wheat pearling fractions of two wheat genotypes

Pearling is an effective method for evaluating the distribution of chemical components in wheat grain. Five pearling fractions （representing approximately 20% of the original sample weight） of wheat grain were obtained using the JNMJ3 rice polisher for two cultivars with different methods of Zinc （Zn） application; the residual portion （approximately 80%） was ground as flour. Results showed that folJar or soil＋foliar Zn application methods effectively increased Zn concentrations and bioavailability in whole grain and pearling fractions, but soil Zn application was ineffective in field conditions. In addition, the concentrations of Zn, Fe, Mn and Cu within wheat grain showed a diminishing trend from the outer layer to the inner portions of the wheat grain as the pearling level increased. These results cleady showed the distribution of minerals in wheat grain, especially in the outer part of the grain （bran）. The results also suggest that precise milling techniques combined with foliar Zn ap- plication could improve the Zn and Fe nutritional qualities of consumed flour and mitigate human Zn and Fe deficiencies.

Variation of resistance and infectivity between Pseudomonas fluorescens SBW25 and bacteriophage Ф2 and its therapeutic implications

Dear Editor,Studies of the coevolutionary dynamics between Pseudomonas fluorescens SBW25 and bacteriophageФ2 can explore host resistance and parasite infectivity with applications in the ecological and therapeutic fields.Coevolutionary dynamics determine the efficacy of phage-based therapy.In the study described here,bacterial resistance and phage infectivity fluctuated with

Numerical Study on Characteristics of Supercavitating Flow Around the Variable-Lateral-Force Cavitator

A control scheme named the variable-lateral-force cavitator, which is focused on the control of lift force, drag force and lateral forces for underwater supercavity vehicles was proposed, and the supercavitating flow around the cavitator was investigated numerically using the mixture multiphase flow model. It is verified that the forces of pitching, yawing, drag and lift, as well as the supercavity size of the underwater vehicle can be effectively regulated through the movements of the control element of the variable-lateral-force cavitator in the radial and circumferential directions. In addition, if the control element on either side protrudes to a height of 5% of the diameter of the front cavitator, an amount of forces of pitching and yawing equivalent to 30% of the drag force will be produced, and the supercavity section appears concave inwards simultaneously. It is also found that both the drag force and lift force of the variable-lateral-force cavitator decline as the angle of attack increases.

Numerical simulation of two droplets impacting upon a dynamic liquid film

The impact of droplets on the liquid film is widely involved in industrial and agricultural fields.In recent years,plenty of works are limited to dry walls or stationary liquid films,and the research of multi-droplet impact dynamic films is not sufficient.Based on this,this paper employs a coupled level set and volume of fluid(CLSVOF) method to numerically simulate two-droplet impingement on a dynamic liquid film.In our work,the dynamic film thickness,horizontal central distance between the droplets,droplets’ initial impact speed,and simultaneously the flow velocity of the moving film are analyzed.The evolution phenomenon and mechanism caused by the collision are analyzed in detail.We find that within a certain period of time,the droplet spacing does not affect the peripheral crown height;when the droplet spacing decreases or the initial impact velocity increases,the height of the peripheral crown increases at the beginning,and then,because the crown splashed under Rayleigh-Plateau instability,this results in the reduction of the crown height.At the same time,it is found that when the initial impact velocity increases,the angle between the upstream peripheral jet and the dynamic film becomes larger.The more obvious the horizontal movement characteristics,the more restrained the crown height;the spread length increases with the increase of the dynamic film speed,droplet spacing and the initial impact velocity.When the liquid film is thicker,more fluid enters the crown,due to the crown being unstable,the surface tension is not enough to overcome the weight of the rim at the end of the crown,resulting in droplets falling off.

Adsorption of trichlorphon on phyllosilicate minerals:Effect of low-molecular-weight organic acids

The use of trichlorphon in large quantities causes a large number of organic pollutants to enter water, sediments, and soils. Phyllosilicate minerals are considered effective adsorbents for organic pollutants. However, the adsorption behavior of organic pollutants on soil minerals affected by low-molecular-weight organic acids(LMWOAs) is not fully understood. In this study, the effect of LMWOAs on the adsorption behavior of trichlorphon on phyllosilicate minerals was investigated using a combination of adsorption measurements and molecular spectroscopic techniques(attenuated total reflection-Fourier transform infrared spectroscopy(ATR-FTIR) and X-ray photoelectron spectroscopy(XPS)). The adsorption of trichlorphon onto kaolinite(KAO) and montmorillonite(MON) was suppressed by increasing pH, indicating that electrostatic interaction played a key role in adsorption, especially at low pH. In the presence of citric acid(CA), there was an obvious promotion of trichlorphon adsorption on KAO and MON. In the presence of oxalic acid(OA), the adsorption of trichlorphon on KAO was promoted, whereas the adsorption on MON was inhibited, especially at pH 4.0. The presence of CA and OA increased the adsorption by increasing the exposure of hydrophobic sites of KAO and MON. The results from ATR-FTIR and XPS also indicated that the hydrophobic Si–O sites of phyllosilicate minerals were the preferred adsorption sites for trichlorphon in the presence of CA and OA, probably driven by the hydrophobic effect. However, the weak effect of OA on MON caused an increase in the electrostatic repulsion between MON and trichlorphon molecules, thus inhibiting adsorption. This study is significant for a deeper understanding of self-purification of soil and sediment systems in the presence of organic pollutants.

Piezoelectric materials for pollutants degradation: State-of-the-art accomplishments and prospects

Piezoelectric catalysis, a new catalytic method, is widely used in the field of environmental sanitation, including waste water treatment and dye degradation. However, in the face of the growing environmental pollution problem, the efficiency of piezoelectric catalysis is still hampered by the stress variation in the natural environment. Therefore, it is particularly important to improve the catalytic efficiency of piezoelectric materials. We divide piezoelectric materials into two categories: inorganic piezoelectric materials and organic piezoelectric materials. Then the mainstream inorganic piezoelectric materials are divided into four subcategories, namely:(1) MTiO_(3)(M = Ba, Sr),(2) bi-class catalytic materials,(3) MoX_(2)(X = S,Se), and(4) ZnO piezoelectric materials. The mainstream organic piezoelectric materials are divided into PVDF and g-C_(3)N_(4)materials. At the same time, the above materials are summarized to explain the excellent performance of materials from the perspective of structure and piezoelectric principle. In addition,we summarized the modification methods that can be applied to piezoelectric materials:(1) Morphology methods,(2) composites with heterojunctions, and(3) surface modification. Finally, we summarized the prospects of piezoelectric materials in the field of environment and water treatment.

Effects of the sand content of muddy water content on one-dimensional vertical infiltration characteristics and dense layer formation characteristics

Muddy water irrigation,an effective water-saving irrigation method,has been widely used in the Yellow River Basin in China.To investigate the effect of sand content on water infiltration and dense layer formation under one-dimensional vertical infiltration of muddy water,muddy water infiltration experiments were performed in the laboratory,and five sand contents of muddy water(S=0%,3%,6%,9%,and 12%)were used.Models were established to describe the relationship between the cumulative infiltration amount[I(t)]and the infiltration duration(t);the relationship among the migration distance of the wetting front(Z),S,and t;the thickness of the sedimentary layer[H(t)];and the relationship between S and t.The results revealed that I(t)and Z decreased significantly with the increase of sand contents,while H(t)increased significantly with the increase of sand contents.I(t)and Z were in the range of 7 cm and 20 cm for each treatment,respectively.The variation in I(t)with t fitted Kostiakov and Philip models,and the coefficients of determination were all greater than 0.99.With the increase in S,the infiltration coefficient gradually decreased,the infiltration index gradually increased,and the sorptivity gradually decreased.The particle composition of the sedimentary layer was similar to that of the argillaceous sediment,and the content of particles with a size of less than 2 mm in the sedimentary layer was lower than that of the argillaceous sediment.Compared with the original soil,the content of particles with a size of less than 0.05 mm and physical clay particles(diameter less than 0.01 mm)in the soil with an infiltration depth of 0-2 cm increased.The retention layer was from the topsoil to the infiltration depth of approximately 2 cm.This study can provide a scientific basis for further research on soil infiltration mechanisms under muddy water.

Conflicting selection pressures on seed size and germination caused by carnivorous seed dispersers

Plants produce nutritious,fleshy fruits that attract various animals to facilitate seed dispersal and recruitment dynamic.Species-specific differential selection of seed size by multiple frugivorous disperser assemblages may affect the subsequent germination of the ingested seeds.However,there is little empirical evidence supporting this association.In the present study,we documented conflicting selection pressures exerted on seed size and germination by five frugivorous carnivores on a mammal-dispersed pioneer tree,the date-plum persimmon(Diospyros lotus),in a subtropical forest.Fecal analyses revealed that these carnivores acted as primary seed dispersers of D.lotus.We also observed that seed sizes were selected based on body mass and were species-specific,confirming the“gape limitation”hypothesis;three small carnivores(the masked palm civet Paguma larvata,yellow-throated marten Martes flavigula,and Chinese ferret-badger Melogale moschata)significantly preferred to disperse smaller seeds in comparison with control seeds obtained directly from wild plants whereas the largest Asiatic black bears(Ursus thibetanus)ingested larger seeds.Seeds dispersed by medium-sized hog badgers(Arctonyx albogularis)were not significantly different from control seeds.However,regarding the influence of gut passage on seed germination,three arboreal dispersal agents(martens,civets,and bears)enhanced germination success whereas terrestrial species(ferret-badgers and hog badgers)inhibited the germination process compared with undigested control seeds.These conflicting selection pressures on seed size and germination may enhance the heterogeneity of germination dynamics and thus increase species fitness through diversification of the regeneration niche.Our results advance our understanding of seed dispersal mechanisms and have important implications for forest recruitment and ecosystem dynamics.

Fluorine-doped BiVO_(4) photocatalyst: Preferential cleavage of C−N bond for green degradation of glyphosate

With increasing concerns on the environment and human health,the degradation of glyphosate through the formation of less toxic intermediates is of great importance.Among the developed methods for the degradation of glyphosate,photodegradation is a clean and efficient strategy.In this work,we report a new photocatalyst by doping F ion on BiVO_(4) that can efficiently degrade glyphosate and reduce the toxic emissions of aminomethylphosphonic acid(AMPA)through the selective(P)−C−Ncleavage in comparison of BiVO_(4) catalyst.The results demonstrate that the best suppression of AMPA formation was achieved by the catalyst of 0.3F@BiVO_(4) at pH=9(AMPA formation below10%).In situ attenuated total reflectance Fourier transforms infrared(ATR-FTIR)spectroscopy indicates that the adsorption sites of glyphosate on BiVO_(4) and 0.3F@BiVO_(4) are altered due to the difference in electrostatic interactions.Such an absorption alteration leads to the preferential cleavage of the C−Nbond on the N−C−P skeleton,thereby inhibiting the formation of toxic AMPA.These results improve our understanding of the photodegradation process of glyphosate catalyzed by BiVO_(4)-based catalysts and pave a safe way for abiotic degradation of glyphosate.

Ecotourist trail-use affects the taxonomic, functional and phylogenetic diversity of mammals in a protected area: lessons for conservation management

Ecotourism,by definition,aims to engage peoples’interest in wildlife and the environment.The use of tourist roads and trails to access sites within protected areas(PAs)can detrimentally affect the behavior and distribution of species.The way mammals respond to anthropogenic pressures may differ across taxonomic,functional,and phy-logenetic groups;nevertheless,how ecotourist trail-use affects these different diversity remains under-investigated.Here,we assessed 6 metrics of taxonomic,phylogenetic,and functional diversity for a mammal community in a PA in central China,recording how Trail use(using Trail type as a proxy)and habitat variables affected sightings and signs of mammals across 60 replicate 0.5 km transects.We then examined how Trail use affected the taxonomic,functional,and phylogenetic diversity indices of species(>1 kg).Using generalized liner mixed modeling,we identified that more used trail types had a greater adverse effect on all diversity richness indices than did less used trail types.Consequently,tourist pressure was associated with a general tendency to homogenize the site’s mammal community.In contrast,the effects of Trail Types on all diversity evenness indices were non-significant.Further-more,more developed and more heavily used trail types had a greater,significant negative effect on taxonomic,functional,and phylogenetic richness,whereas these richness indices were unaffected by minor trail types,used less intensively.As a general principle,lower biodiversity indices reduce ecosystem resilience,and so it is vital to better understand these responses to balance public access against biodiversity management in PAs.