Freely available data of sulfur dioxide (SO2), ammonia (NH3), nitrogen dioxide (NO2), ozone (O3), and particulate matter (PM) observed in Arctic cities (north of 59.99 N) between 1972 and 2016 were compiled into an ai...Freely available data of sulfur dioxide (SO2), ammonia (NH3), nitrogen dioxide (NO2), ozone (O3), and particulate matter (PM) observed in Arctic cities (north of 59.99 N) between 1972 and 2016 were compiled into an air-quality inventory of samples taken for limited periods. For cities with multiple years of data, air-quality climatology was determined in terms of daily means in the annual course. Mean urban air-quality climatology was calculated for regions of similar insolation, emission standards, topography, Köppen-Geiger classification, and city size. Urban concentrations of PM precursors (SO2, NH3, NO2), PM2.5 and PM10 (PM with diameter less than 2.5 and 10 μm) were assessed in the sense of climatology with evidence from current knowledge. Typically, annual SO2 and NO2 means were lower for small than large Arctic cities, but can vary more than an order of magnitude over short distance. Cities seeing seasonal sea-ice had W-shaped mean annual courses of daily O3, while other cities had a spring maximum. Typically, annual means of urban pollutants in North America exceeded those in Scandinavia except for O3, where the opposite was true. Annual mean urban PM2.5 and PM10 concentrations varied from 1.6 to 21.2 μg·m-3 and 2 to 18.2 μg·m-3, respectively. Since PM10 encompasses PM2.5, annual PM10 means must be at least 21.2 μg·m-3. According to rural-to-urban ratios of species, seasonal transport of pollutants from wildfires, shipping, and the Kola Peninsula mining area occurred at some sites in Interior Alaska, western and northern Norway, respectively. Concurrent SO2 and PM or NO2 and PM measurements revealed combustion or traffic as major contributors to urban concentrations. Recommendations for potential future measurements of Arctic urban air quality were given based on the assessments of climatology and inventory.展开更多
The impacts of low and high-frequency variability from teleconnections between large scale atmospheric processes and local weather as well as emissions changes on concentrations of particulate matter of 2.5 μm or les...The impacts of low and high-frequency variability from teleconnections between large scale atmospheric processes and local weather as well as emissions changes on concentrations of particulate matter of 2.5 μm or less in diameter ([PM2.5]) were examined for the Fairbanks Metropolitan Area (FMA). October to March and May to August mean [PM2.5] were 1.8 and 3.1 μg·m-3 higher for positive than negative annual mean Pacific Decadal Oscillation. Annual mean [PM2.5] were 3.8 μg·m-3 lower for positive than negative Southern Oscillation Index. On 1999-2018 average, [PM2.5] decreased 2.9 μg·m-3·decade-1. On average over October to March, decadal and inter-annual variability caused higher or similar differences in mean observed [PM2.5] and its species than emission-control measures. The 2006 implementation of Tier 2 for new vehicles decreased observed sulfate concentrations the strongest (~4.95 μg·m-3·decade-1) of all occurred emissions changes. On average, observed [PM2.5] showed elevated values at all sites when wind blew from directions of hot springs. The same was found for the sulfate, ammonium and non-metal components of PM2.5. Observations showed that these geothermal waters contain sulfate, ammonia, boric acid and non-metals. Hot springs of such composition are known to emit hydrogen sulfide and ammonia that can serve as precursors for ammonium and sulfate aerosols.展开更多
文摘Freely available data of sulfur dioxide (SO2), ammonia (NH3), nitrogen dioxide (NO2), ozone (O3), and particulate matter (PM) observed in Arctic cities (north of 59.99 N) between 1972 and 2016 were compiled into an air-quality inventory of samples taken for limited periods. For cities with multiple years of data, air-quality climatology was determined in terms of daily means in the annual course. Mean urban air-quality climatology was calculated for regions of similar insolation, emission standards, topography, Köppen-Geiger classification, and city size. Urban concentrations of PM precursors (SO2, NH3, NO2), PM2.5 and PM10 (PM with diameter less than 2.5 and 10 μm) were assessed in the sense of climatology with evidence from current knowledge. Typically, annual SO2 and NO2 means were lower for small than large Arctic cities, but can vary more than an order of magnitude over short distance. Cities seeing seasonal sea-ice had W-shaped mean annual courses of daily O3, while other cities had a spring maximum. Typically, annual means of urban pollutants in North America exceeded those in Scandinavia except for O3, where the opposite was true. Annual mean urban PM2.5 and PM10 concentrations varied from 1.6 to 21.2 μg·m-3 and 2 to 18.2 μg·m-3, respectively. Since PM10 encompasses PM2.5, annual PM10 means must be at least 21.2 μg·m-3. According to rural-to-urban ratios of species, seasonal transport of pollutants from wildfires, shipping, and the Kola Peninsula mining area occurred at some sites in Interior Alaska, western and northern Norway, respectively. Concurrent SO2 and PM or NO2 and PM measurements revealed combustion or traffic as major contributors to urban concentrations. Recommendations for potential future measurements of Arctic urban air quality were given based on the assessments of climatology and inventory.
文摘The impacts of low and high-frequency variability from teleconnections between large scale atmospheric processes and local weather as well as emissions changes on concentrations of particulate matter of 2.5 μm or less in diameter ([PM2.5]) were examined for the Fairbanks Metropolitan Area (FMA). October to March and May to August mean [PM2.5] were 1.8 and 3.1 μg·m-3 higher for positive than negative annual mean Pacific Decadal Oscillation. Annual mean [PM2.5] were 3.8 μg·m-3 lower for positive than negative Southern Oscillation Index. On 1999-2018 average, [PM2.5] decreased 2.9 μg·m-3·decade-1. On average over October to March, decadal and inter-annual variability caused higher or similar differences in mean observed [PM2.5] and its species than emission-control measures. The 2006 implementation of Tier 2 for new vehicles decreased observed sulfate concentrations the strongest (~4.95 μg·m-3·decade-1) of all occurred emissions changes. On average, observed [PM2.5] showed elevated values at all sites when wind blew from directions of hot springs. The same was found for the sulfate, ammonium and non-metal components of PM2.5. Observations showed that these geothermal waters contain sulfate, ammonia, boric acid and non-metals. Hot springs of such composition are known to emit hydrogen sulfide and ammonia that can serve as precursors for ammonium and sulfate aerosols.
