Negative air ions(NAIs)benefit the mental and physical health of humans,but rapid urbanization can decrease the abundance of NAIs.Quantifying the spatial and seasonal distribution of NAIs and determining the factors t...Negative air ions(NAIs)benefit the mental and physical health of humans,but rapid urbanization can decrease the abundance of NAIs.Quantifying the spatial and seasonal distribution of NAIs and determining the factors that infl uence the concentration during urbanization is thus essential.In the present study of a typical developing urban district in southern China,negative air ion concentrations(NAICs)in 60 forests sites and 30 urban green spaces were quantifi ed on seven consecutive days in each of the four seasons.Large seasonal variations in NAIC were revealed in forests and urban green spaces with trough values in summer.NAIC progressively decreased from forests to urban green spaces and was infl uenced by local land morphology,vegetation characteristics,and climatic factors.The vast,heavily vegetated northeastern region was the richest area for NAIs,whereas the narrow central region(urbanized area)was the poorest,implying dramatic impacts of urbanization on the spatial distribution of NAIs.The relationship between air temperature and NAIC was better fi tted with a quadratic equation than a linear equation.Moreover,the NAIC was more sensitive to local morphology in urban green spaces than in urban forests,indicating the vulnerability of NAIs in urbanized areas.Therefore,the appropriate design of local urban morphology is critical.展开更多
In the process of using high-pressure flat membranes to treat coal chemical wastewater,the effects of high-pressure flat membranes on the concentration of salt ions and the removal of pollutants were studied under the...In the process of using high-pressure flat membranes to treat coal chemical wastewater,the effects of high-pressure flat membranes on the concentration of salt ions and the removal of pollutants were studied under the conditions of different concentrations of influent TDS,COD and silicon dioxide.The results showed that when the concentration of influent TDS was 35 000-55 000 mg/L,the economic benefit of high-pressure flat membrane operation was the best,and the concentration ratio of high-pressure flat membranes was stable,varying from 3.3 to 3.6.As the concentration of influent organic matter ranged from 100 to 1 800 mg/L,the removal rate of organic matter ranged from 60% to 79%.In addition,the retention rate of high-pressure flat membranes to silicon dioxide was more than 90%.展开更多
The SWAT model was applied to analyze the temporal-spatial distribution patterns of non-point source pollution loads and the difference of pollution loads of different land use types in Xixi Watershed of Jinjiang Basi...The SWAT model was applied to analyze the temporal-spatial distribution patterns of non-point source pollution loads and the difference of pollution loads of different land use types in Xixi Watershed of Jinjiang Basin. The results showed that both yearly nitrogen and phosphorus pollution loads were evenly distributed during 1973 to 1979,the annual TN pollution from non-point source was 1530 t,or 6. 3 kg / ha,and the annual TP pollution from non-point source was 270 t,or 1. 1 kg / ha during 1973 to 1979 in the watershed. Considerable differences were identified on both monthly nitrogen and phosphorus pollution loads. The TN and TP pollution loads during the flood season( from April to September) accounted for 76. 2% and 75. 8% of the annual load respectively. There were great differences in both TN and TP pollution loads of different land use types in the study area,and the pollution load of both farmland and orchard was higher than that of the other land use types. TN and TP pollution loads of farmland accounted for 66% and 83% of total watershed. There was a great spatial difference in the nonpoint source pollution load of the study area. The critical source areas of non-point source pollution are mainly located at Guanqiao Town,Longmen Town,Changkeng Town,Shangqing Town and Dapu Town,where the efforts of controlling pollution should be made.展开更多
Climate warming is one of the important environmental issues with global concern. The Bloomberg News has recorded temperature changes in the recent 135 years. As the hottest year, in 2014 the global surface temperatur...Climate warming is one of the important environmental issues with global concern. The Bloomberg News has recorded temperature changes in the recent 135 years. As the hottest year, in 2014 the global surface temperature was as high as 1.39 degrees Fahrenheit, 0.68 degrees Celsius higher than the average in long-term. The severity of this issue has been proved with the refresh of the highest record^([1]) and the increasing temperature as well as people's personal experience. There is a demand of in-depth discussion about comprehensive and efficient reduction of carbon and greenhouse gas emission and the development of low carbon economy, with garbage classification as the most efficient breach but also most easily to be neglected by people. This article attempts to find a feasible method of carbon emission reduction from the perspective of garbage classification and resource recycling and make quantitative estimation of its value combined with local practice and data in Chengdu.展开更多
The structural properties of jadeite at high pressures (0.000 1-30 GPa) are investigated using plane-wave pseudopotential density functional theory method. As a function of pressure, the monoclinic cell parameters w...The structural properties of jadeite at high pressures (0.000 1-30 GPa) are investigated using plane-wave pseudopotential density functional theory method. As a function of pressure, the monoclinic cell parameters were calculated and the compressibility coefficients are 0.002 6, 0.002 3 and 0.002 6 GPal, respectively. The bond length, bond angle and distortion variation were studied in order to obtain the information of polyhedral compression. The pressure-volume equation of state was con- sidered in order to obtain the bulk modulus K0. Comparison between the calculated K0 values and the experimental data suggested that the model provides reasonable insights into crystallographic and physical properties of jadeite.展开更多
The problem of nitrate accumulation in aerobic tank and total nitrogen excessive discharge in effluent was very common in traditional livestock and poultry farming wastewater treatment systems owing to the lengthy pro...The problem of nitrate accumulation in aerobic tank and total nitrogen excessive discharge in effluent was very common in traditional livestock and poultry farming wastewater treatment systems owing to the lengthy process flow and low process control level.A strain LYX of aerobic bacterium was isolated from the activated sludge of a wastewater treatment system in a pig farm,which could remove nitrate effectively in aerobic tank and was identified Pseudomonas mendocina by 16S rRNA sequencing.Under the condition of nitrate as the sole nitrogen source,this strain removed over 90%of NO_(3)^(−)-N with an initial concentration of 110 mg/L under aerobic conditions within 48 hours.Among them,37.9%of NO_(3)^(−)-N was assimilated into Bio-N,about 51.9%was reduced to gaseous nitrogen and less than 0.5%of nitrogen was replaced by NO_(3)^(−)-N and NH_(4)^(+)-N,9.7%NO_(3)^(−)-N remained in the effluent at the end.At the same time,four key genes(napA,nirK,norB and nosZ)related to nitrate nitrogen removal were expressed during the denitrification process of P.mendocina LYX,in which the transcription level of the indicator genes of this aerobic denitrifying bacterium(napA)was the highest.In addition,it was found with the 15N tracer technique that inoculation of this strain on sludge increased the amount of nitrogen loss from 9.26 nmol N/(g·h)to 23.835 nmol N/(g·h).Therefore,P.medocina LYX is a potential bioagent for advanced nitrogen removal by assimilating and reducing nitrate simultaneously in aerobic tanks.展开更多
The anaerobic-anoxic oxidation ditch(A^(2)/O OD)process is popularly used to eliminate nutrients from domestic wastewater.In order to identify the existence of denitrifying phosphorus removing bacteria(DPB),evaluate t...The anaerobic-anoxic oxidation ditch(A^(2)/O OD)process is popularly used to eliminate nutrients from domestic wastewater.In order to identify the existence of denitrifying phosphorus removing bacteria(DPB),evaluate the contribution of DPB to biological nutrient removal,and enhance the denitrifying phosphorus removal in the A^(2)/O OD process,a pilot-scale A^(2)/O OD plant(375 L)was conducted.At the same time batch tests using sequence batch reactors(12 L and 4 L)were operated to reveal the significance of anoxic phosphorus removal.The results indicated that:The average removal efficiency of COD,NH^(+)_(4),PO^(3–)_(4),and TN were 88.2%,92.6%,87.8%,and 73.1%,respectively,when the steady state of the pilotscale A^(2)/O OD plant was reached during 31–73 d,demonstrating a good denitrifying phosphorus removal performance.Phosphorus uptake took place in the anoxic zone by poly-phosphorus accumulating organisms NO^(-)_(2) could be used as electron receptors in denitrifying phosphorus removal,and the phosphorus uptake rate with NO^(-)_(2) as the electron receptor was higher than that with NO^(–)_(3) when the initial concentration of either NO^(-)_(2) or NO^(–)_(3) was 40 mg/L.展开更多
Bromate ion (BrO3-) removal from drinking water by powdered activated carbons (PACs) in bath mode was evaluated under various operational conditions. Six kinds of PACs, including wood-based carbon, fruit-based car...Bromate ion (BrO3-) removal from drinking water by powdered activated carbons (PACs) in bath mode was evaluated under various operational conditions. Six kinds of PACs, including wood-based carbon, fruit-based carbon, coal-based carbon, and these three carbons thermally deoxidized in a nitrogen atmosphere, were selected to investigate their capacity on BrO3- removal. With the highest zeta potential value and being richly mesoporous, coal-based carbon had a high and an excellent BrO3- adsorption efficiency. The removal content of BrO3- by per gram of coal-based carbon was 0.45 mg within 5 hr in 100 μg/L bromate solution. The surface characteristics of PACs and bromide formation revealed that both physical and chemical PACs properties simultaneously affected the adsorptionreduction process. Under acidic conditions, PACs possessed high zeta value and adequate basic groups and exhibited neutral or positive charges, promoting BrO3- adsorption-reduction on the carbon surface. Interestingly, the PACs thermally deoxidized in N2 atmosphere optimized their properties, e.g. increasing their zeta values and decreasing the oxygen content which accelerated the BrO3- removal rate. The maximum adsorption capacity of fruit-based carbon was the highest among all tested carbons (99.6 mg/g), possibly due to its highest pore volume. Remarkably, the thermal regeneration of PACs in N2 atmosphere could completely recover the adsorption capacity of PACs. The kinetic data obtained from carbons was analyzed using pseudo second-order and intraparticle diffusion models, with results showing that the intraparticle diffusion was the more applicable model to describe adsorption of BrO3- onto PACs.展开更多
基金The authors acknowledge the volunteers who helped with the fi eld investigations.
文摘Negative air ions(NAIs)benefit the mental and physical health of humans,but rapid urbanization can decrease the abundance of NAIs.Quantifying the spatial and seasonal distribution of NAIs and determining the factors that infl uence the concentration during urbanization is thus essential.In the present study of a typical developing urban district in southern China,negative air ion concentrations(NAICs)in 60 forests sites and 30 urban green spaces were quantifi ed on seven consecutive days in each of the four seasons.Large seasonal variations in NAIC were revealed in forests and urban green spaces with trough values in summer.NAIC progressively decreased from forests to urban green spaces and was infl uenced by local land morphology,vegetation characteristics,and climatic factors.The vast,heavily vegetated northeastern region was the richest area for NAIs,whereas the narrow central region(urbanized area)was the poorest,implying dramatic impacts of urbanization on the spatial distribution of NAIs.The relationship between air temperature and NAIC was better fi tted with a quadratic equation than a linear equation.Moreover,the NAIC was more sensitive to local morphology in urban green spaces than in urban forests,indicating the vulnerability of NAIs in urbanized areas.Therefore,the appropriate design of local urban morphology is critical.
文摘In the process of using high-pressure flat membranes to treat coal chemical wastewater,the effects of high-pressure flat membranes on the concentration of salt ions and the removal of pollutants were studied under the conditions of different concentrations of influent TDS,COD and silicon dioxide.The results showed that when the concentration of influent TDS was 35 000-55 000 mg/L,the economic benefit of high-pressure flat membrane operation was the best,and the concentration ratio of high-pressure flat membranes was stable,varying from 3.3 to 3.6.As the concentration of influent organic matter ranged from 100 to 1 800 mg/L,the removal rate of organic matter ranged from 60% to 79%.In addition,the retention rate of high-pressure flat membranes to silicon dioxide was more than 90%.
基金Supported by Key Technology Project of State Administration of Work Safety Supervision for Prevention and Control of Major Safety Accidents in 2015(Shandong-0052-2015AQ)Shandong Natural Science Foundation(ZR20-14EEP009)+1 种基金Binzhou Science and Technology Development Program(2013ZC1001)Research Fund of Binzhou University(BZXYG1414)
文摘The SWAT model was applied to analyze the temporal-spatial distribution patterns of non-point source pollution loads and the difference of pollution loads of different land use types in Xixi Watershed of Jinjiang Basin. The results showed that both yearly nitrogen and phosphorus pollution loads were evenly distributed during 1973 to 1979,the annual TN pollution from non-point source was 1530 t,or 6. 3 kg / ha,and the annual TP pollution from non-point source was 270 t,or 1. 1 kg / ha during 1973 to 1979 in the watershed. Considerable differences were identified on both monthly nitrogen and phosphorus pollution loads. The TN and TP pollution loads during the flood season( from April to September) accounted for 76. 2% and 75. 8% of the annual load respectively. There were great differences in both TN and TP pollution loads of different land use types in the study area,and the pollution load of both farmland and orchard was higher than that of the other land use types. TN and TP pollution loads of farmland accounted for 66% and 83% of total watershed. There was a great spatial difference in the nonpoint source pollution load of the study area. The critical source areas of non-point source pollution are mainly located at Guanqiao Town,Longmen Town,Changkeng Town,Shangqing Town and Dapu Town,where the efforts of controlling pollution should be made.
文摘Climate warming is one of the important environmental issues with global concern. The Bloomberg News has recorded temperature changes in the recent 135 years. As the hottest year, in 2014 the global surface temperature was as high as 1.39 degrees Fahrenheit, 0.68 degrees Celsius higher than the average in long-term. The severity of this issue has been proved with the refresh of the highest record^([1]) and the increasing temperature as well as people's personal experience. There is a demand of in-depth discussion about comprehensive and efficient reduction of carbon and greenhouse gas emission and the development of low carbon economy, with garbage classification as the most efficient breach but also most easily to be neglected by people. This article attempts to find a feasible method of carbon emission reduction from the perspective of garbage classification and resource recycling and make quantitative estimation of its value combined with local practice and data in Chengdu.
基金supported by the National Natural Science Foundation of China(Nos.41172051,40872039 and 90714002)the Specialized Research Fund for the Doctoral Program of Higher Education of China(No.20060491504)
文摘The structural properties of jadeite at high pressures (0.000 1-30 GPa) are investigated using plane-wave pseudopotential density functional theory method. As a function of pressure, the monoclinic cell parameters were calculated and the compressibility coefficients are 0.002 6, 0.002 3 and 0.002 6 GPal, respectively. The bond length, bond angle and distortion variation were studied in order to obtain the information of polyhedral compression. The pressure-volume equation of state was con- sidered in order to obtain the bulk modulus K0. Comparison between the calculated K0 values and the experimental data suggested that the model provides reasonable insights into crystallographic and physical properties of jadeite.
基金This work was financially supported by the National Key R&D Program of China(Grant No.2016YFC0400706)the National Natural Science Foundation of China(Grant Nos.41671481 and 41977340)+1 种基金the Science&Technology Plan Project of Guangdong(No.2016B020240003)Key-Area Research and Development Program of Guangdong Province(No.2019B110205004).We would like to thank Professor Hong YG and Dr.Wu JP(Guangzhou University)for their warmful help on 15N labeling test and analysis.
文摘The problem of nitrate accumulation in aerobic tank and total nitrogen excessive discharge in effluent was very common in traditional livestock and poultry farming wastewater treatment systems owing to the lengthy process flow and low process control level.A strain LYX of aerobic bacterium was isolated from the activated sludge of a wastewater treatment system in a pig farm,which could remove nitrate effectively in aerobic tank and was identified Pseudomonas mendocina by 16S rRNA sequencing.Under the condition of nitrate as the sole nitrogen source,this strain removed over 90%of NO_(3)^(−)-N with an initial concentration of 110 mg/L under aerobic conditions within 48 hours.Among them,37.9%of NO_(3)^(−)-N was assimilated into Bio-N,about 51.9%was reduced to gaseous nitrogen and less than 0.5%of nitrogen was replaced by NO_(3)^(−)-N and NH_(4)^(+)-N,9.7%NO_(3)^(−)-N remained in the effluent at the end.At the same time,four key genes(napA,nirK,norB and nosZ)related to nitrate nitrogen removal were expressed during the denitrification process of P.mendocina LYX,in which the transcription level of the indicator genes of this aerobic denitrifying bacterium(napA)was the highest.In addition,it was found with the 15N tracer technique that inoculation of this strain on sludge increased the amount of nitrogen loss from 9.26 nmol N/(g·h)to 23.835 nmol N/(g·h).Therefore,P.medocina LYX is a potential bioagent for advanced nitrogen removal by assimilating and reducing nitrate simultaneously in aerobic tanks.
基金This work was supported by the National Natural Science Foundation of China—the Abroad Young Scholar Foundation(Grant No.50628808)the National Key Technologies Research and Development Program of China during the 11th Five-year Plan Period(Grant No.2006BAC19B02).
文摘The anaerobic-anoxic oxidation ditch(A^(2)/O OD)process is popularly used to eliminate nutrients from domestic wastewater.In order to identify the existence of denitrifying phosphorus removing bacteria(DPB),evaluate the contribution of DPB to biological nutrient removal,and enhance the denitrifying phosphorus removal in the A^(2)/O OD process,a pilot-scale A^(2)/O OD plant(375 L)was conducted.At the same time batch tests using sequence batch reactors(12 L and 4 L)were operated to reveal the significance of anoxic phosphorus removal.The results indicated that:The average removal efficiency of COD,NH^(+)_(4),PO^(3–)_(4),and TN were 88.2%,92.6%,87.8%,and 73.1%,respectively,when the steady state of the pilotscale A^(2)/O OD plant was reached during 31–73 d,demonstrating a good denitrifying phosphorus removal performance.Phosphorus uptake took place in the anoxic zone by poly-phosphorus accumulating organisms NO^(-)_(2) could be used as electron receptors in denitrifying phosphorus removal,and the phosphorus uptake rate with NO^(-)_(2) as the electron receptor was higher than that with NO^(–)_(3) when the initial concentration of either NO^(-)_(2) or NO^(–)_(3) was 40 mg/L.
基金supported by the National High Technology Research and Development Program(863) of China(No. 2006AA06Z307)the National Natural Science Found for Creative Research Groups of China(No.50921064)
文摘Bromate ion (BrO3-) removal from drinking water by powdered activated carbons (PACs) in bath mode was evaluated under various operational conditions. Six kinds of PACs, including wood-based carbon, fruit-based carbon, coal-based carbon, and these three carbons thermally deoxidized in a nitrogen atmosphere, were selected to investigate their capacity on BrO3- removal. With the highest zeta potential value and being richly mesoporous, coal-based carbon had a high and an excellent BrO3- adsorption efficiency. The removal content of BrO3- by per gram of coal-based carbon was 0.45 mg within 5 hr in 100 μg/L bromate solution. The surface characteristics of PACs and bromide formation revealed that both physical and chemical PACs properties simultaneously affected the adsorptionreduction process. Under acidic conditions, PACs possessed high zeta value and adequate basic groups and exhibited neutral or positive charges, promoting BrO3- adsorption-reduction on the carbon surface. Interestingly, the PACs thermally deoxidized in N2 atmosphere optimized their properties, e.g. increasing their zeta values and decreasing the oxygen content which accelerated the BrO3- removal rate. The maximum adsorption capacity of fruit-based carbon was the highest among all tested carbons (99.6 mg/g), possibly due to its highest pore volume. Remarkably, the thermal regeneration of PACs in N2 atmosphere could completely recover the adsorption capacity of PACs. The kinetic data obtained from carbons was analyzed using pseudo second-order and intraparticle diffusion models, with results showing that the intraparticle diffusion was the more applicable model to describe adsorption of BrO3- onto PACs.