Materials with a high on-off resistance ratio could become the basis for resistive random-access memory (RRAM). It is assumed that one of RRAM types can be based on hybrid organic-inorganic systems, while particular a...Materials with a high on-off resistance ratio could become the basis for resistive random-access memory (RRAM). It is assumed that one of RRAM types can be based on hybrid organic-inorganic systems, while particular attention is focused on hybrid systems consisting of metal nanoparticles (NP) embedded in organic matrix (OM). In this investigation we created and studied the hybrid organic-inorganic systems made of metal (Ag) nanoparticles embedded in organic semiconductor material CuPc. The LEED patterns and NEXAFS data demonstrate that the CuPc films deposited on Au(001) substrate are highly ordered and molecular planes lie parallel to the gold surface. The metal atoms were deposited on the outer surface of the organic molecular film and self-assembled into nanoparticles due to surface and bulk diffusion. The properties of nano-composite materials seem to be significantly dependent on the microstructure, i.e. the size, concentration, bulk- and size-distribution of nanoparticles;therefore we have studied by high resolution transmission electron microscopy the evolution of morphology of nano-composite films as a function of nominal metal deposition. The filled and empty electronic states of the hybrid organic-inorganic systems, energy level alignment at interfaces formed between metal nanoparticles and the organic semiconductor CuPc as well as the chemical interaction at the NP/OM interface were studied by UPS, XPS and NEXAFS methods.展开更多
In order to study the dynamic response of the material and the physical mechanism of fluid dynamics, an accelerator scenario which can be applied to both hard X-ray free electron laser and high energy electron radiogr...In order to study the dynamic response of the material and the physical mechanism of fluid dynamics, an accelerator scenario which can be applied to both hard X-ray free electron laser and high energy electron radiography is proposed. This accelerator is mainly composed of a 12 GeV linac, an undulator branch and an eRad beamline. In order to characterize a sample＇s dynamic behavior in situ and real-time with XFEL and eRad simultaneously, the linac should be capable of accelerating the two kinds of beam within the same operation mode. Combining in-vacuum and tapering techniques, the undulator branch can produce more than 10zl photons per pulse in 0.1% bandwidth at 42 keV. Finally, an eRad amplifying beamline with 1：10 ratio is proposed as an important complementary tool for the wider view field and density identification ability.展开更多
文摘Materials with a high on-off resistance ratio could become the basis for resistive random-access memory (RRAM). It is assumed that one of RRAM types can be based on hybrid organic-inorganic systems, while particular attention is focused on hybrid systems consisting of metal nanoparticles (NP) embedded in organic matrix (OM). In this investigation we created and studied the hybrid organic-inorganic systems made of metal (Ag) nanoparticles embedded in organic semiconductor material CuPc. The LEED patterns and NEXAFS data demonstrate that the CuPc films deposited on Au(001) substrate are highly ordered and molecular planes lie parallel to the gold surface. The metal atoms were deposited on the outer surface of the organic molecular film and self-assembled into nanoparticles due to surface and bulk diffusion. The properties of nano-composite materials seem to be significantly dependent on the microstructure, i.e. the size, concentration, bulk- and size-distribution of nanoparticles;therefore we have studied by high resolution transmission electron microscopy the evolution of morphology of nano-composite films as a function of nominal metal deposition. The filled and empty electronic states of the hybrid organic-inorganic systems, energy level alignment at interfaces formed between metal nanoparticles and the organic semiconductor CuPc as well as the chemical interaction at the NP/OM interface were studied by UPS, XPS and NEXAFS methods.
基金Supported by China Academy of Engineering Physics(2014A0402016)Institute of Fluid Physics(SFZ20140201)
文摘In order to study the dynamic response of the material and the physical mechanism of fluid dynamics, an accelerator scenario which can be applied to both hard X-ray free electron laser and high energy electron radiography is proposed. This accelerator is mainly composed of a 12 GeV linac, an undulator branch and an eRad beamline. In order to characterize a sample＇s dynamic behavior in situ and real-time with XFEL and eRad simultaneously, the linac should be capable of accelerating the two kinds of beam within the same operation mode. Combining in-vacuum and tapering techniques, the undulator branch can produce more than 10zl photons per pulse in 0.1% bandwidth at 42 keV. Finally, an eRad amplifying beamline with 1：10 ratio is proposed as an important complementary tool for the wider view field and density identification ability.
