This paper reports obtaining of useful and high-value materials from sesame seed cake (SSC). For this purpose, SSC sample was burned for 30 s using Nd: YAG laser with output power 60 W. The products of this process an...This paper reports obtaining of useful and high-value materials from sesame seed cake (SSC). For this purpose, SSC sample was burned for 30 s using Nd: YAG laser with output power 60 W. The products of this process and non-burned SSC were characterized by X-ray diffractometer (XRD), energy dispersive x-ray (EDX) and Fourier transform infrared (FTIR) so as to investigate its crystal structure and chemical components. XRD results of the SSC before burning process showed amorphous silica, rhombohedral phase of carbon, monoclinic phase of aluminum chloride, the hexagonal phase of moissanite-4H, (yellow, black) and hexagonal phase of graphite-2H, C (black). While the results of the burned SSC sample showed that the burning process using the power of Nd: YAG laser cased in appearing of crystalline hexagonal phase for silica and Carbon Nitride and converting the rhombohedral phase of Carbon into hexagonal phase. FTIR showed a number of absorbance peaks assigned to silica.展开更多
In this study, nano ferrite materials were produced to replace costive industrial materials<span style="font-family:;" "=""> </span><span style="font-family:Verdana;"&...In this study, nano ferrite materials were produced to replace costive industrial materials<span style="font-family:;" "=""> </span><span style="font-family:Verdana;"><span style="font-size:10.0pt;font-family:" color:#943634;"=""><span style="font-family:Verdana;white-space:normal;">[1]</span></span><span style="font-size:10.0pt;font-family:;" "=""></span><span style="font-size:10.0pt;font-family:" times="" new="" roman","serif";"=""><span></span></span></span><span></span><span><span></span></span><span style="font-family:Verdana;">.</span><span style="font-family:;" "=""> </span><span style="font-family:Verdana;">Ferrite nanoparticles are the interesting material due to their rich and unique physical and chemical properties. They find applications in catalysis, bio-processing, medicine, magnetic recording, adsorption, devices etc.</span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">Using co-participation method, five nano ferrite samples Zn</span><sub><span style="font-family:Verdana;">0.5</span></sub><span style="font-family:Verdana;">Mg</span><sub><span style="font-family:Verdana;">0.5-x</span></sub><span style="font-family:Verdana;">Li</span><sub><span style="font-family:Verdana;">2x</span></sub><span style="font-family:Verdana;">Fe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">4</span></sub><span style="font-family:Verdana;"> (x = 0.00, 0.10, 0.20, 0.30 and 0.40) were prepared. The electrical and optical properties of the Zn</span><sub><span style="font-family:Verdana;">0.5</span></sub><span style="font-family:Verdana;">Mg</span><sub><span style="font-family:Verdana;">0.5-x</span></sub><span style="font-family:Verdana;">Li</span><sub><span style="font-family:Verdana;">2x</span></sub><span style="font-family:Verdana;">Fe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">4</span></sub><span style="font-family:Verdana;"> samples were studied using the Ultraviolet-visible (UV-Vis) spectroscopy. The results verified that the formation of the absorption coefficient of the five samples of Zn</span><sub><span style="font-family:Verdana;">0.5</span></sub><span style="font-family:Verdana;">Mg</span><sub><span style="font-family:Verdana;">0.5-x</span></sub><span style="font-family:Verdana;">Li</span><sub><span style="font-family:Verdana;">2x</span></sub><span style="font-family:Verdana;">Fe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">4</span></sub><span style="font-family:Verdana;"> increased with the increase of Lithium (Li</span><sub><span style="font-family:Verdana;">2x</span></sub><span style="font-family:Verdana;">). The energy band gap of the Zn</span><sub><span style="font-family:Verdana;">0.5</span></sub><span style="font-family:Verdana;">Mg</span><sub><span style="font-family:Verdana;">0.5-x</span></sub><span style="font-family:Verdana;">Li</span><sub><span style="font-family:Verdana;">2x</span></sub><span style="font-family:Verdana;">Fe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">4</span></sub><span style="font-family:Verdana;"> samples ranged </span></span><span style="font-family:Verdana;">from</span><span style="font-family:Verdana;"> 3.28 to 3.12</span><span style="font-family:;" "=""> </span><span style="font-family:Verdana;">eV</span><span style="font-family:;" "=""> </span><span style="font-family:Verdana;">[1]</span><span style="font-family:;" "=""></span><span style="font-family:" minion="" pro="" capt","serif";"=""><span></span></span><span style="font-family:Verdana;">.</span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">The extinction coefficient (K) for five samples of Zn</span><sub><span style="font-family:Verdana;">0.5</span></sub><span style="font-family:Verdana;">Li</span><sub><span style="font-family:Verdana;">2x</span></sub><span style="font-family:Verdana;">Mg</span><sub><span style="font-family:Verdana;">0.5-x</span></sub><span style="font-family:Verdana;">Fe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">4</span></sub><span style="font-family:Verdana;"> increased with the increase of Lithium (Li</span><sub><span style="font-family:Verdana;">2x</span></sub><span style="font-family:Verdana;">) at 338 nm f</span></span><span style="font-family:Verdana;">ro</span><span style="font-family:Verdana;">m 0.074 to 0.207. The high magnitude of optical conductivity is (1.34</span><span style="font-family:;" "=""> </span><span style="font-family:Verdana;">×</span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">10</span><sup><span style="font-family:Verdana;">12</span></sup><span style="font-family:Verdana;"> sec<span style="font-size:10px;"><sup>-1</sup></span></span><span style="font-family:Verdana;">) and the maximum value of electrical conductivity is 42</span></span><span style="font-family:;" "=""> </span><span style="font-family:Verdana;">(Ω<sup>.</sup></span><span style="font-family:;" "=""><span><span style="font-family:Verdana;">cm)<span style="font-size:10px;"><sup>-1</sup></span></span><span style="font-family:Verdana;">. This may due to the electrical and optical properties of lithium.</span></span></span>展开更多
Co-precipitation is an important issue in chemical analysis, where it is often undesirable, but in some cases, it can be exploited. The Zn0.5Mn0.5−xLi2xFe2O4 nanomaterials (x = 0.0, 0.1, 0.2, 0.3 and 0.4) wa...Co-precipitation is an important issue in chemical analysis, where it is often undesirable, but in some cases, it can be exploited. The Zn0.5Mn0.5−xLi2xFe2O4 nanomaterials (x = 0.0, 0.1, 0.2, 0.3 and 0.4) was afforded by utilizing co-precipitation method. The structural and optical characteristics were analyzed for the samples employing X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR) and Ultraviolet-visible spectrophotometer (UV-Vis). XRD revealed that the structure of certain nanoparticles is a cubic spinel with space group (Fd-3m) and crystallite size in the scale 124 - 150 nm. Lattice parameter was determined to increments with Li+1 and that may occur due to the larger ionic radius of the Li1+ ion. FTIR spectroscopy confirmed the form of spinel ferrite and explicated the properties of absorption bands approximately 593, 1111, 1385, 1640, 2922 and 3430. The energy band gap was estimated for all samples with diverse ratios and was observed in the range of 2.58 - 2.52 eV.展开更多
The samples of Zn0.5CuxMg0.5-xFe2O4 nanoparticle ferrites, with x= 0.0, 0.1, 0.2, 0.3, 0.4 were successfully synthesised. Structural and optical properties were investigated by X-ray Diffraction (XRD), Fourier Transfo...The samples of Zn0.5CuxMg0.5-xFe2O4 nanoparticle ferrites, with x= 0.0, 0.1, 0.2, 0.3, 0.4 were successfully synthesised. Structural and optical properties were investigated by X-ray Diffraction (XRD), Fourier Transform Infrared spectros-copy (FTIR) and UV-visible spectroscopy. The structural studies showed that all the samples prepared through the Co-precipitation method was a single phase of a face-cantered-Cubic (FCC) spinel symmetry structures with space group (SG): Fd-3m. In the series Zn0.5CuxMg0.5-xFe2O4, the lattice parameter was found to be 8.382 ? for x = 0 and was found to increase with copper con-centration. The grain size obtained from the XRD data analyses was found to be in the range of 15.97 to 28.33 nm. The increased in the grain size may be due to the large ionic radius of Mg2+ (0.86 ?) compared with Cu2+ (0.73 ?). The FTIR spectroscopy confirmed the formation of spinel ferrite and showed the characteristics absorption bands around 580, 1112, 1382, 1682, 1632 and 2920 cm-1. The energy band gap was calculated for samples were found to be in the range 4.04 to 4.67 eV.展开更多
Nanoferrite materials had been synthesized to produce new alternate substance for reducing the rare or high cost of industrial materials. In this work, the Zn0.5Mg0.5-xLi2xFe2O4 nanoferrite (x = 0.00, 0.10, 0.20, 0.30...Nanoferrite materials had been synthesized to produce new alternate substance for reducing the rare or high cost of industrial materials. In this work, the Zn0.5Mg0.5-xLi2xFe2O4 nanoferrite (x = 0.00, 0.10, 0.20, 0.30 and 0.40) was prepared by co-precipitation approach. Structural and optical properties were investigated for the Zn0.5Mg0.5-xLi2xFe2O4 series by X-ray diffraction (XRD), Fourier transforms infrared (FTIR) and ultraviolet-visible (UV-Vis) spectroscopies. The XRD data showed that all samples of Zn0.5Mg0.5-xLi2xFe2O4 series possess a cubic spinel with a space group (Fd-3m) structure and crystallite size decreased from 116 to 96 nm with a doping ratio. Lattice parameter founded to increases with Li1+ ratio that result in the larger ionic radius of the Li1+ cation. FTIR result verified the formation of spinel structure by appearance of the absorption bands around 420, 580 cm-1. The energy band gap computed for Zn0.5Mg0.5-xLi2xFe2O4 samples and it founded in the range of 3.28 - 3.12eV.展开更多
文摘This paper reports obtaining of useful and high-value materials from sesame seed cake (SSC). For this purpose, SSC sample was burned for 30 s using Nd: YAG laser with output power 60 W. The products of this process and non-burned SSC were characterized by X-ray diffractometer (XRD), energy dispersive x-ray (EDX) and Fourier transform infrared (FTIR) so as to investigate its crystal structure and chemical components. XRD results of the SSC before burning process showed amorphous silica, rhombohedral phase of carbon, monoclinic phase of aluminum chloride, the hexagonal phase of moissanite-4H, (yellow, black) and hexagonal phase of graphite-2H, C (black). While the results of the burned SSC sample showed that the burning process using the power of Nd: YAG laser cased in appearing of crystalline hexagonal phase for silica and Carbon Nitride and converting the rhombohedral phase of Carbon into hexagonal phase. FTIR showed a number of absorbance peaks assigned to silica.
文摘In this study, nano ferrite materials were produced to replace costive industrial materials<span style="font-family:;" "=""> </span><span style="font-family:Verdana;"><span style="font-size:10.0pt;font-family:" color:#943634;"=""><span style="font-family:Verdana;white-space:normal;">[1]</span></span><span style="font-size:10.0pt;font-family:;" "=""></span><span style="font-size:10.0pt;font-family:" times="" new="" roman","serif";"=""><span></span></span></span><span></span><span><span></span></span><span style="font-family:Verdana;">.</span><span style="font-family:;" "=""> </span><span style="font-family:Verdana;">Ferrite nanoparticles are the interesting material due to their rich and unique physical and chemical properties. They find applications in catalysis, bio-processing, medicine, magnetic recording, adsorption, devices etc.</span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">Using co-participation method, five nano ferrite samples Zn</span><sub><span style="font-family:Verdana;">0.5</span></sub><span style="font-family:Verdana;">Mg</span><sub><span style="font-family:Verdana;">0.5-x</span></sub><span style="font-family:Verdana;">Li</span><sub><span style="font-family:Verdana;">2x</span></sub><span style="font-family:Verdana;">Fe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">4</span></sub><span style="font-family:Verdana;"> (x = 0.00, 0.10, 0.20, 0.30 and 0.40) were prepared. The electrical and optical properties of the Zn</span><sub><span style="font-family:Verdana;">0.5</span></sub><span style="font-family:Verdana;">Mg</span><sub><span style="font-family:Verdana;">0.5-x</span></sub><span style="font-family:Verdana;">Li</span><sub><span style="font-family:Verdana;">2x</span></sub><span style="font-family:Verdana;">Fe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">4</span></sub><span style="font-family:Verdana;"> samples were studied using the Ultraviolet-visible (UV-Vis) spectroscopy. The results verified that the formation of the absorption coefficient of the five samples of Zn</span><sub><span style="font-family:Verdana;">0.5</span></sub><span style="font-family:Verdana;">Mg</span><sub><span style="font-family:Verdana;">0.5-x</span></sub><span style="font-family:Verdana;">Li</span><sub><span style="font-family:Verdana;">2x</span></sub><span style="font-family:Verdana;">Fe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">4</span></sub><span style="font-family:Verdana;"> increased with the increase of Lithium (Li</span><sub><span style="font-family:Verdana;">2x</span></sub><span style="font-family:Verdana;">). The energy band gap of the Zn</span><sub><span style="font-family:Verdana;">0.5</span></sub><span style="font-family:Verdana;">Mg</span><sub><span style="font-family:Verdana;">0.5-x</span></sub><span style="font-family:Verdana;">Li</span><sub><span style="font-family:Verdana;">2x</span></sub><span style="font-family:Verdana;">Fe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">4</span></sub><span style="font-family:Verdana;"> samples ranged </span></span><span style="font-family:Verdana;">from</span><span style="font-family:Verdana;"> 3.28 to 3.12</span><span style="font-family:;" "=""> </span><span style="font-family:Verdana;">eV</span><span style="font-family:;" "=""> </span><span style="font-family:Verdana;">[1]</span><span style="font-family:;" "=""></span><span style="font-family:" minion="" pro="" capt","serif";"=""><span></span></span><span style="font-family:Verdana;">.</span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">The extinction coefficient (K) for five samples of Zn</span><sub><span style="font-family:Verdana;">0.5</span></sub><span style="font-family:Verdana;">Li</span><sub><span style="font-family:Verdana;">2x</span></sub><span style="font-family:Verdana;">Mg</span><sub><span style="font-family:Verdana;">0.5-x</span></sub><span style="font-family:Verdana;">Fe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O</span><sub><span style="font-family:Verdana;">4</span></sub><span style="font-family:Verdana;"> increased with the increase of Lithium (Li</span><sub><span style="font-family:Verdana;">2x</span></sub><span style="font-family:Verdana;">) at 338 nm f</span></span><span style="font-family:Verdana;">ro</span><span style="font-family:Verdana;">m 0.074 to 0.207. The high magnitude of optical conductivity is (1.34</span><span style="font-family:;" "=""> </span><span style="font-family:Verdana;">×</span><span style="font-family:;" "=""> </span><span style="font-family:;" "=""><span style="font-family:Verdana;">10</span><sup><span style="font-family:Verdana;">12</span></sup><span style="font-family:Verdana;"> sec<span style="font-size:10px;"><sup>-1</sup></span></span><span style="font-family:Verdana;">) and the maximum value of electrical conductivity is 42</span></span><span style="font-family:;" "=""> </span><span style="font-family:Verdana;">(Ω<sup>.</sup></span><span style="font-family:;" "=""><span><span style="font-family:Verdana;">cm)<span style="font-size:10px;"><sup>-1</sup></span></span><span style="font-family:Verdana;">. This may due to the electrical and optical properties of lithium.</span></span></span>
文摘Co-precipitation is an important issue in chemical analysis, where it is often undesirable, but in some cases, it can be exploited. The Zn0.5Mn0.5−xLi2xFe2O4 nanomaterials (x = 0.0, 0.1, 0.2, 0.3 and 0.4) was afforded by utilizing co-precipitation method. The structural and optical characteristics were analyzed for the samples employing X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR) and Ultraviolet-visible spectrophotometer (UV-Vis). XRD revealed that the structure of certain nanoparticles is a cubic spinel with space group (Fd-3m) and crystallite size in the scale 124 - 150 nm. Lattice parameter was determined to increments with Li+1 and that may occur due to the larger ionic radius of the Li1+ ion. FTIR spectroscopy confirmed the form of spinel ferrite and explicated the properties of absorption bands approximately 593, 1111, 1385, 1640, 2922 and 3430. The energy band gap was estimated for all samples with diverse ratios and was observed in the range of 2.58 - 2.52 eV.
文摘The samples of Zn0.5CuxMg0.5-xFe2O4 nanoparticle ferrites, with x= 0.0, 0.1, 0.2, 0.3, 0.4 were successfully synthesised. Structural and optical properties were investigated by X-ray Diffraction (XRD), Fourier Transform Infrared spectros-copy (FTIR) and UV-visible spectroscopy. The structural studies showed that all the samples prepared through the Co-precipitation method was a single phase of a face-cantered-Cubic (FCC) spinel symmetry structures with space group (SG): Fd-3m. In the series Zn0.5CuxMg0.5-xFe2O4, the lattice parameter was found to be 8.382 ? for x = 0 and was found to increase with copper con-centration. The grain size obtained from the XRD data analyses was found to be in the range of 15.97 to 28.33 nm. The increased in the grain size may be due to the large ionic radius of Mg2+ (0.86 ?) compared with Cu2+ (0.73 ?). The FTIR spectroscopy confirmed the formation of spinel ferrite and showed the characteristics absorption bands around 580, 1112, 1382, 1682, 1632 and 2920 cm-1. The energy band gap was calculated for samples were found to be in the range 4.04 to 4.67 eV.
文摘Nanoferrite materials had been synthesized to produce new alternate substance for reducing the rare or high cost of industrial materials. In this work, the Zn0.5Mg0.5-xLi2xFe2O4 nanoferrite (x = 0.00, 0.10, 0.20, 0.30 and 0.40) was prepared by co-precipitation approach. Structural and optical properties were investigated for the Zn0.5Mg0.5-xLi2xFe2O4 series by X-ray diffraction (XRD), Fourier transforms infrared (FTIR) and ultraviolet-visible (UV-Vis) spectroscopies. The XRD data showed that all samples of Zn0.5Mg0.5-xLi2xFe2O4 series possess a cubic spinel with a space group (Fd-3m) structure and crystallite size decreased from 116 to 96 nm with a doping ratio. Lattice parameter founded to increases with Li1+ ratio that result in the larger ionic radius of the Li1+ cation. FTIR result verified the formation of spinel structure by appearance of the absorption bands around 420, 580 cm-1. The energy band gap computed for Zn0.5Mg0.5-xLi2xFe2O4 samples and it founded in the range of 3.28 - 3.12eV.