To develop a new technique for separating gas mixtures via hydrate formation,a set of medium-sized experimental bubble column reactor equipment was constructed.On the basis of the structure parameters of the ex- perim...To develop a new technique for separating gas mixtures via hydrate formation,a set of medium-sized experimental bubble column reactor equipment was constructed.On the basis of the structure parameters of the ex- perimental bubble column reactor,assuming that the liquid phase was in the axial dispersion regime and the gas phase was in the plug flow regime,in the presence of hydrate promoter tetrahydrofuran(THF),the rate of hydrogen enrichment for CH4+H2 gas mixtures at different operational conditions(such as temperature,pressure,concentra- tion of gas components,gas flow rate,liquid flow rate)were simulated.The heat product of the hydrate reaction and its axial distribution under different operational conditions were also calculated.The results would be helpful not only to setting and optimizing operation conditions and design of multi-refrigeration equipment,but also to hydrate separation technique industrialization.展开更多
The preparation of the iron-based catalysts promoted by cobalt with a small amount of copper and aluminum for the high temperature shift reaction （HTS） with different sequences of adding catalyst raw materials durin...The preparation of the iron-based catalysts promoted by cobalt with a small amount of copper and aluminum for the high temperature shift reaction （HTS） with different sequences of adding catalyst raw materials during neutralization and precipitation was investigated. XRD, BET and particle size distribution （PSD） were used to characterize the prepared catalysts. It was found that the catalyst crystals were all γ-Fe2O3, and the intermediate of the catalyst after aging was Fe3O4. The crystallographic form of the catalyst and its intermediate was not affected by the addition sequence in the neutralization and precipitation process. The results showed that the specific surface area and the particle size of the catalysts depended on the addition sequence to the mother liquor. Cobalt with a small amount of copper and aluminum could increase the specific surface area and decrease the particle size of catalysts.展开更多
In the practice of petroleum industry, adding cold flow improver （CFI） to lower the fuel＇s cold filter plugging point （CFPP） is an effective and economic way for improving the cold flow performance of diesel fuel...In the practice of petroleum industry, adding cold flow improver （CFI） to lower the fuel＇s cold filter plugging point （CFPP） is an effective and economic way for improving the cold flow performance of diesel fuel. This paper described the synthesis and evaluation of the performance of dibehenyl fumarate-vinyl acetate （FV） copolymer for improving the cold flow performance of the tested diesel fuels. The carbon distribution in n-alkanes of the tested diesel samples were analyzed by gas phase chromatography. The structure of the copolymer was confirmed by the 1H NMR spectroscopy. The wax crystals morphologies with and without adding the FV additive were investigated by means of polarizing microscope. The test results indicated that the FV additive could depress CFPP of the tested diesel samples by 2℃ and 4℃, respectively, when dosage of the additive was 0.08 m%. The additive can modify the size and shape of the wax crystals and inhibit the formation of larger wax crystal lattices.展开更多
Commercial application of the DZC Ⅱ-I catalyst developed on the basis of the DZ-1 catalyst was introduced. The application tests of the catalyst under overload had proved that this catalyst demonstrated satisfactory ...Commercial application of the DZC Ⅱ-I catalyst developed on the basis of the DZ-1 catalyst was introduced. The application tests of the catalyst under overload had proved that this catalyst demonstrated satisfactory adaptability to feedstock after continued operation for 20 months with little changes in the bed pressure drop, the reactor inlet temperature and the bed temperature rise. The DZC Ⅱ- 1 catalyst was regarded as the best catalyst for the second-stage hydrogenation of pyrolvsis gasoline.展开更多
基金Supported by the National Natural Science Foundation of China （No.20490207）.
文摘To develop a new technique for separating gas mixtures via hydrate formation,a set of medium-sized experimental bubble column reactor equipment was constructed.On the basis of the structure parameters of the ex- perimental bubble column reactor,assuming that the liquid phase was in the axial dispersion regime and the gas phase was in the plug flow regime,in the presence of hydrate promoter tetrahydrofuran(THF),the rate of hydrogen enrichment for CH4+H2 gas mixtures at different operational conditions(such as temperature,pressure,concentra- tion of gas components,gas flow rate,liquid flow rate)were simulated.The heat product of the hydrate reaction and its axial distribution under different operational conditions were also calculated.The results would be helpful not only to setting and optimizing operation conditions and design of multi-refrigeration equipment,but also to hydrate separation technique industrialization.
文摘The preparation of the iron-based catalysts promoted by cobalt with a small amount of copper and aluminum for the high temperature shift reaction （HTS） with different sequences of adding catalyst raw materials during neutralization and precipitation was investigated. XRD, BET and particle size distribution （PSD） were used to characterize the prepared catalysts. It was found that the catalyst crystals were all γ-Fe2O3, and the intermediate of the catalyst after aging was Fe3O4. The crystallographic form of the catalyst and its intermediate was not affected by the addition sequence in the neutralization and precipitation process. The results showed that the specific surface area and the particle size of the catalysts depended on the addition sequence to the mother liquor. Cobalt with a small amount of copper and aluminum could increase the specific surface area and decrease the particle size of catalysts.
基金supported by the Basic Research Program of the State Key Laboratory of Heavy Oil Processing(200310),China University of Petroleum,Beijing,China.
文摘In the practice of petroleum industry, adding cold flow improver （CFI） to lower the fuel＇s cold filter plugging point （CFPP） is an effective and economic way for improving the cold flow performance of diesel fuel. This paper described the synthesis and evaluation of the performance of dibehenyl fumarate-vinyl acetate （FV） copolymer for improving the cold flow performance of the tested diesel fuels. The carbon distribution in n-alkanes of the tested diesel samples were analyzed by gas phase chromatography. The structure of the copolymer was confirmed by the 1H NMR spectroscopy. The wax crystals morphologies with and without adding the FV additive were investigated by means of polarizing microscope. The test results indicated that the FV additive could depress CFPP of the tested diesel samples by 2℃ and 4℃, respectively, when dosage of the additive was 0.08 m%. The additive can modify the size and shape of the wax crystals and inhibit the formation of larger wax crystal lattices.
文摘Commercial application of the DZC Ⅱ-I catalyst developed on the basis of the DZ-1 catalyst was introduced. The application tests of the catalyst under overload had proved that this catalyst demonstrated satisfactory adaptability to feedstock after continued operation for 20 months with little changes in the bed pressure drop, the reactor inlet temperature and the bed temperature rise. The DZC Ⅱ- 1 catalyst was regarded as the best catalyst for the second-stage hydrogenation of pyrolvsis gasoline.
