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离子排斥色谱结合光度检测的水质监测系统用于测定离子型营养物(英文) 被引量:2
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作者 Daisuke KOZAKI Nobutake NAKATANI +2 位作者 Masanobu MORI Nobukazu NAKAGOSHI Kazuhiko TANAKA 《色谱》 CAS CSCD 北大核心 2012年第7期721-727,共7页
A unified ion-exclusion chromatography(IEC) system for monitoring anionic and cationic nutrients like NH + 4,NO 2,NO 3,phosphate ion,silicate ion and HCO 3 was developed and applied to several environmental waters.The... A unified ion-exclusion chromatography(IEC) system for monitoring anionic and cationic nutrients like NH + 4,NO 2,NO 3,phosphate ion,silicate ion and HCO 3 was developed and applied to several environmental waters.The IEC system consisted of four IEC methodologies,including the IEC with ultraviolet(UV) detection at 210 nm for determining NH + 4 on anion-exchange separation column in OH form connected with anion-exchange UV-conversion column in I form in tandem,the IEC with UV-detection at 210 nm for determining simultaneously NO 2 and NO 3 on cation-exchange separation column in H + form,the IEC with UV-detection at 210 nm for determining HCO 3 on cation-exchange separation column in H + form connected with anion-exchange UV-conversion column in I form in tandem,and the IEC with visible-detection based on molybdenum-blue reaction for determining simultaneously silicate and phosphate ions on cation-exchange separation column in H + form.These IEC systems were combined through three manually-driven 6-port column selection valves to select each separation column to determine selectively the ionic nutrients.Using this sequential water quality monitoring system,the analytical performances such as calibration linearity,reproducibility,detection limit and recovery were also tested under the optimized chromatographic conditions.This novel water quality monitoring system has been applied successfully for the determination of the ionic eutrophication components in sub-urban river waters. 展开更多
关键词 ion-exclusion chromatography(IEC) anionic and cationic nutrients column selection valve water eluent
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水为洗脱剂的静电离子色谱-增强电导检测法测定常见无机阴离子(英文)
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作者 Daisuke KOZAKI Kazuhiko TANAKA Nobutake NAKATANI 《色谱》 CAS CSCD 北大核心 2012年第4期361-364,共4页
To enhance the conductivity detection sensitivity of common anions(Na-anions) in electrostatic ion chromatography(EIC) by elution with water,a conductivity enhancement column packed with strong acid cation exchange re... To enhance the conductivity detection sensitivity of common anions(Na-anions) in electrostatic ion chromatography(EIC) by elution with water,a conductivity enhancement column packed with strong acid cation exchange resin in the H-form was inserted between an octadecyl silane(ODS)-silica separation column modified with zwitterionic surfactant(CHAPS: 3-{(3-cholamidopropyl)-dimethylammonio}propanesulfonate) and a conductivity detector.Specifically,the Na-anion pairing is converted to H-anion pairing after the EIC separation and then detected sensitively by the conductivity detector.The effects of conductivity enhancement and suppression in the EIC by the enhanced conductivity detection were characterized for the common strong acid anions such as SO2-4,Cl-,NO-3,I-and ClO-4 and weak acid anions such as F-,NO-2,HCOO-,CH3COO-and HCO-3.For the conductivity enhancement effect in the EIC,it is found that the conductivity of measured for all strong acid anions(Na-anions) was enhanced according to the theoretical conductivity predicted for H-anions and that of the measured for weak acid anions was suppressed depending on their pKa of H-anions.For the calibration linearity in the EIC,the strong acid anions were linear(r2=0.99-1.00) because the degree of dissociation is almost 1.0 over all the concentration range and that of the weak acid anions was non-linear because the degree of dissociation decreased by increasing the concentration of the weak acid anions.In conclusion,the EIC by enhanced conductivity detection was recognized to be useful only for the strong acid anions in terms of conductivity detection and calibration linearity. 展开更多
关键词 electrostatic ion chromatography(EIC) common anions conductivity enhancement water eluent
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