Synthesis of Au nanorods in a low pH solution via seed-media method

The gold （Au） nanorods with various aspect ratios are obtained by a seed-media method in low pH growth solution. Transmission electron microscopy （TEM） and UV-visible spectrophotometry are utilized to characterize the Au nanorods, and the longitudinal absorption peak positions of Au nanorods show different shifting trends of the growth evolutions in various low pH （1~3） solutions. Other influential factors on the shape of Au nanorod are also systematically studied under low pH reaction condition. The positions of longitudinal peak shift between 600 nm and 900 nm, with the aspect ratios of Au nanorods varying from 2 to 5 both in the simulation and experimental results. The simulation results are in agreement with experimental ones.

Modeling relationships between the network distance and travel time dynamics for assessing equity of accessibility to urban parks

Static models of accessibility are usually based on the fixed distance or Average Travel Time(ATT)models.Because of ignoring the traffic as a dynamic process affecting the accessibility through the change of Travel Time(TT),these models lead to unperceived temporal inequities.In contrast to the consideration of the temporal Variation of TT(VTT)in the previous studies,the variation of traffic-related TT and its relations with network distance has not been considered.In this study,relations between VTT and network distance to access urban parks in Tehran megacity has been modeled.Traffic maps at five times of day are used to produce TT maps of Traffic Analysis Zones(TAZs)to their 3-closest parks.Comparison of the Gini coefficients of accessibility show significant inequities of accessibility at different times of day.Relations between the distance,ATT,and TT_(max) are modeled by statistical analysis.Results show both TT and TTmax have significant positive relations with distance and traffic and reach their maximum at 6 p.m.Observation of significant relations between distance,ATT,TT_(max),and VTT provides interesting knowledge for the conversion of temporal measures of equity(TT)to a physical measure of equity(distance).A simple application of these findings for effective management of the spatiotemporal inequities is the definition of critical distances from public services.As an example,to decrease the TT_(max) of TAZs to less than 12 min,their maximum distance to the closest parks should be less than 4 km.The developed approach can be adopted for the accessibility evaluation of the other public services,particularly the health and education centers.