Scavenging abilities of the ethylenediamine, diethylenetriamine and tris(2-aminoethyl)amine functionalized resins derived from the low cross-linked glycidyl methacrylate-styrene gels in relation to the selected transi...Scavenging abilities of the ethylenediamine, diethylenetriamine and tris(2-aminoethyl)amine functionalized resins derived from the low cross-linked glycidyl methacrylate-styrene gels in relation to the selected transition metal ions and organic (acid chlorides) electrophiles were explored. The synergetic effects of the solvents were found for the metal ion uptake. In this case a pair of solvents capable simultaneously to swell the hydrophobic core of the resins and interact with the polar amine groups turned out to be a more effective medium for activation of the nucleophilic functionalities of the resins. The resin with ethylenediamine moieties proved to be effective in scavenging acyl chlorides from methylene chloride as well. However, it did not provide complete removing sulphonyl chlorides from the solutions. These organic electrophiles were removed effectively by the resins bearing tris(2-aminoethyl)amine functionalities.展开更多
Clinching can be used for effective joining of different metallic materials, e.g., different grades of carbon and alloy steels, aluminum and its alloys and others. This is an alternative joining method to traditional ...Clinching can be used for effective joining of different metallic materials, e.g., different grades of carbon and alloy steels, aluminum and its alloys and others. This is an alternative joining method to traditional methods involving screws, rivets or welding. Clinching is applied in many fields of manufacturing industry. Future applications of clinch joining require advances in quality and among others things, combination with other processes, e.g., hybrid joining by clinching and adhesive bonding. Although the static strength of clinched joints is lower than that of the others joints （e.g., pressure welded joints）, the fatigue strength is comparable. But there is a lack of information about fatigue strength of clinched joints. The static and low cyclic fatigue strengths of mechanically clinched joints were determined experimentally. The load-displacement curves of static strength were compared with low cyclic fatigue strength curves. It was observed the effect of strain hardening for clinched joint of low carbon steels （DC4） under cyclic loading.展开更多
Ball burnishing is a plastic deformation process used as a surface smoothing and surface improvement finishing treatment after turning or milling processes. This process changes the surface stereometrics of the previo...Ball burnishing is a plastic deformation process used as a surface smoothing and surface improvement finishing treatment after turning or milling processes. This process changes the surface stereometrics of the previously machining surface. Burnishing with hydrostatic tools can be easily and effectively used on both conventional and Computer Numeric Control(CNC) machines. The existing research of the burnishing process mainly focuses on the functional surface characterization, for example, surface roughness, wear resistance, surface layer hardness, etc. There is a lack of references reporting a detailed analysis of 3D parameters calculation with a mathematical model to evaluate the results of the ball burnishing. This paper presents the effect of ball burnishing process parameters with hydrostatic tools on the resulting surface structure geometry. The surface topography parameters were calculated using the Taly Map software. Studies were conducted based on Hartley’s static, determined plan. Such a plan can be built on a hypersphere or hypercube. In this work, a hypercube was used. In the case of Hartley’s plan makes it possible to define the regression equation in the form of a polynomial of the second degree. The input process parameters considered in this study include the burnishing rate, applied pressure, and line-to-line pitch. The significant influence of these parameters was confirmed and described as a mathematical power model. The results also showed a positive effect of hydrostatic burnishing on the roughness and geometric structure of the surface.展开更多
The manuscript presents changes of macrostructure and microstructure of plate and shaft castings made of cobalt alloy MAR-M509. They have different values of geometric module M within the range of 0.91 -5.56 mm that h...The manuscript presents changes of macrostructure and microstructure of plate and shaft castings made of cobalt alloy MAR-M509. They have different values of geometric module M within the range of 0.91 -5.56 mm that have been created with multilayer ceramic shell moulds （MSC） of different initial temperatures of 200-1000 ℃ at the moment of pouring. It has been stated that decrease of initial temperature of MSC and value M causes increase in casting fine-granularity, distance reduction between dendrite branches λ2 and refinement of initial carbides in irregular ternary eutectic γ＋M23C6 ＋MC.展开更多
文摘Scavenging abilities of the ethylenediamine, diethylenetriamine and tris(2-aminoethyl)amine functionalized resins derived from the low cross-linked glycidyl methacrylate-styrene gels in relation to the selected transition metal ions and organic (acid chlorides) electrophiles were explored. The synergetic effects of the solvents were found for the metal ion uptake. In this case a pair of solvents capable simultaneously to swell the hydrophobic core of the resins and interact with the polar amine groups turned out to be a more effective medium for activation of the nucleophilic functionalities of the resins. The resin with ethylenediamine moieties proved to be effective in scavenging acyl chlorides from methylene chloride as well. However, it did not provide complete removing sulphonyl chlorides from the solutions. These organic electrophiles were removed effectively by the resins bearing tris(2-aminoethyl)amine functionalities.
文摘Clinching can be used for effective joining of different metallic materials, e.g., different grades of carbon and alloy steels, aluminum and its alloys and others. This is an alternative joining method to traditional methods involving screws, rivets or welding. Clinching is applied in many fields of manufacturing industry. Future applications of clinch joining require advances in quality and among others things, combination with other processes, e.g., hybrid joining by clinching and adhesive bonding. Although the static strength of clinched joints is lower than that of the others joints （e.g., pressure welded joints）, the fatigue strength is comparable. But there is a lack of information about fatigue strength of clinched joints. The static and low cyclic fatigue strengths of mechanically clinched joints were determined experimentally. The load-displacement curves of static strength were compared with low cyclic fatigue strength curves. It was observed the effect of strain hardening for clinched joint of low carbon steels （DC4） under cyclic loading.
文摘Ball burnishing is a plastic deformation process used as a surface smoothing and surface improvement finishing treatment after turning or milling processes. This process changes the surface stereometrics of the previously machining surface. Burnishing with hydrostatic tools can be easily and effectively used on both conventional and Computer Numeric Control(CNC) machines. The existing research of the burnishing process mainly focuses on the functional surface characterization, for example, surface roughness, wear resistance, surface layer hardness, etc. There is a lack of references reporting a detailed analysis of 3D parameters calculation with a mathematical model to evaluate the results of the ball burnishing. This paper presents the effect of ball burnishing process parameters with hydrostatic tools on the resulting surface structure geometry. The surface topography parameters were calculated using the Taly Map software. Studies were conducted based on Hartley’s static, determined plan. Such a plan can be built on a hypersphere or hypercube. In this work, a hypercube was used. In the case of Hartley’s plan makes it possible to define the regression equation in the form of a polynomial of the second degree. The input process parameters considered in this study include the burnishing rate, applied pressure, and line-to-line pitch. The significant influence of these parameters was confirmed and described as a mathematical power model. The results also showed a positive effect of hydrostatic burnishing on the roughness and geometric structure of the surface.
文摘The manuscript presents changes of macrostructure and microstructure of plate and shaft castings made of cobalt alloy MAR-M509. They have different values of geometric module M within the range of 0.91 -5.56 mm that have been created with multilayer ceramic shell moulds （MSC） of different initial temperatures of 200-1000 ℃ at the moment of pouring. It has been stated that decrease of initial temperature of MSC and value M causes increase in casting fine-granularity, distance reduction between dendrite branches λ2 and refinement of initial carbides in irregular ternary eutectic γ＋M23C6 ＋MC.
