Convenient and integration fabrication process is a key issue for the application of functional nanofibers.A surface functionalization method was developed based on coaxial electrospinning to produce ultraviolet(UV)pr...Convenient and integration fabrication process is a key issue for the application of functional nanofibers.A surface functionalization method was developed based on coaxial electrospinning to produce ultraviolet(UV)protection nanofibers.The titanium dioxide(TiO_(2))nanoparticles suspension was delivered through the shell channel of the coaxial spinneret,by which the aggregation of TiO_(2) nanoparticles was overcome and the distribution uniformity on the surface of polyethylene oxide(PEO)nanofiber was obtained.With the content of TiO_(2) increasing from 0 to 3%(mass fraction),the average diameter of nanofibers increased from(380±30)nm to(480±100)nm.The surface functionalization can be realized during the electrospinning process to gain PEO/TiO_(2) composite nanofibers directly.The uniform distribution of TiO_(2) nanoparticles on the surface of nanofibers enhanced the UV absorption and resistance performance.The maximum UV protection factor(UPF)value of composite nanofibers reaches 2751.This work presented a novel surface-functionalized way for the preparation of composite nanofiber,which has great application potential in the field of micro/nano system integration fabrication.展开更多
Asynchronized surface modification method based on coaxial electrospinning was developed to fabricate high-efficiency photodegradative nanofiber for water purification. TiO_(2) nanoparticles assembled uniformly on the...Asynchronized surface modification method based on coaxial electrospinning was developed to fabricate high-efficiency photodegradative nanofiber for water purification. TiO_(2) nanoparticles assembled uniformly on the surface of polycaprolactone(PCL) nanofibers to form composite nanofibers through one step process. The maximal content of Ti element was 25.6%(mass fraction) in the PCL/TiO_(2) composite nanofibrous membrane, which exhibited hydrophilicity and excellent photodegradation under visible light in water. The Rhodamine B dye degraded 96.17% in 120 min under visible light by the PCL/TiO_(2) composite membrane. The adsorption behavior fitted Langmuir model well and indicated chemical related adsorption. This PCL/TiO_(2) composite nanofibrous membrane has super degradation properties and displays great application potential to environmental protection.展开更多
基金This work was supported by the National Natural Science Foundation of China(No.61772441)the Science and Technology Planning Project of Fujian Province,China(No.2020H6003)+2 种基金the Xiamen Municipal Science and Technology Project,China(No.3502Z20193015)the Fund of the Aviation Key Laboratory of Science and Technology on Inertia,China(No.20180868001)the Fund of Fujian Innovation Center of Additive Manufacturing,China(No.ZCZZ202-31).
文摘Convenient and integration fabrication process is a key issue for the application of functional nanofibers.A surface functionalization method was developed based on coaxial electrospinning to produce ultraviolet(UV)protection nanofibers.The titanium dioxide(TiO_(2))nanoparticles suspension was delivered through the shell channel of the coaxial spinneret,by which the aggregation of TiO_(2) nanoparticles was overcome and the distribution uniformity on the surface of polyethylene oxide(PEO)nanofiber was obtained.With the content of TiO_(2) increasing from 0 to 3%(mass fraction),the average diameter of nanofibers increased from(380±30)nm to(480±100)nm.The surface functionalization can be realized during the electrospinning process to gain PEO/TiO_(2) composite nanofibers directly.The uniform distribution of TiO_(2) nanoparticles on the surface of nanofibers enhanced the UV absorption and resistance performance.The maximum UV protection factor(UPF)value of composite nanofibers reaches 2751.This work presented a novel surface-functionalized way for the preparation of composite nanofiber,which has great application potential in the field of micro/nano system integration fabrication.
基金supported by the National Natural Science Foundation of China (No.51805460)the Science and Technology Planning Project of Fujian Province, China (Nos.2020H6003, 2021J011196)the Fund of Fujian Innovation Center of Additive Manufacturing, China (No.ZCZZ202-31).
文摘Asynchronized surface modification method based on coaxial electrospinning was developed to fabricate high-efficiency photodegradative nanofiber for water purification. TiO_(2) nanoparticles assembled uniformly on the surface of polycaprolactone(PCL) nanofibers to form composite nanofibers through one step process. The maximal content of Ti element was 25.6%(mass fraction) in the PCL/TiO_(2) composite nanofibrous membrane, which exhibited hydrophilicity and excellent photodegradation under visible light in water. The Rhodamine B dye degraded 96.17% in 120 min under visible light by the PCL/TiO_(2) composite membrane. The adsorption behavior fitted Langmuir model well and indicated chemical related adsorption. This PCL/TiO_(2) composite nanofibrous membrane has super degradation properties and displays great application potential to environmental protection.
