A new compound [Zn3（C7NO4H3）3Cl4]·[C6NO2H6]4·4H2O （I） has been synthesized and structurally characterized by X-ray crystallography.It crystallizes in monoclinic,space group C2/c with a=16.9018（14）,b=12...A new compound [Zn3（C7NO4H3）3Cl4]·[C6NO2H6]4·4H2O （I） has been synthesized and structurally characterized by X-ray crystallography.It crystallizes in monoclinic,space group C2/c with a=16.9018（14）,b=12.6902（10）,c=25.1170（2）,β=90.54°,V=5387.0（8）3,Z=4,Zn3C45H41Cl4N7O24,Mr=1401.76,Dc=1.728 g/cm3,F（000）=2840,μ（MoKa）=1.615 mm-1,the R= 0.0758 and wR=0.2060 for 3468 observed reflections （I 〉 2σ（I））.Analysis of single-crystal X-ray diffraction data shows that compound I displays an interesting example of 3D supramolecular networks with perfect neutral and ionic hydrogen bonding array.展开更多
基金supported by the Natural Science Foundation of Fujian Province (2006F3042)
文摘A new compound [Zn3（C7NO4H3）3Cl4]·[C6NO2H6]4·4H2O （I） has been synthesized and structurally characterized by X-ray crystallography.It crystallizes in monoclinic,space group C2/c with a=16.9018（14）,b=12.6902（10）,c=25.1170（2）,β=90.54°,V=5387.0（8）3,Z=4,Zn3C45H41Cl4N7O24,Mr=1401.76,Dc=1.728 g/cm3,F（000）=2840,μ（MoKa）=1.615 mm-1,the R= 0.0758 and wR=0.2060 for 3468 observed reflections （I 〉 2σ（I））.Analysis of single-crystal X-ray diffraction data shows that compound I displays an interesting example of 3D supramolecular networks with perfect neutral and ionic hydrogen bonding array.
