C48H108Ag3BrI3MoN3S4, Mr=1735. 84, cubic, F43c, a = b = c = 24. 577(4) A.V= 14845. 2A3, Z = 8, Dc=1. 553g/cm3, Dv = 1. 560g/cm3. Final R = 0. 061 for 307 unique diffraction data with I≥3σ(I). The anion of the title ...C48H108Ag3BrI3MoN3S4, Mr=1735. 84, cubic, F43c, a = b = c = 24. 577(4) A.V= 14845. 2A3, Z = 8, Dc=1. 553g/cm3, Dv = 1. 560g/cm3. Final R = 0. 061 for 307 unique diffraction data with I≥3σ(I). The anion of the title cluster compound can be viewed as a cubane like structure situated at specific equivalent positions in the unit cell with Td symmetry. One Mo and three Ag atoms, one Br and three Sb atoms, one S, and three I atoms are statistically distributed, individually. The distances of Mo....Ag (or Ag....Ag), Mo-Sb(or Ag -Sb, Ag -Br), and Mo-St(or Ag-I) are 3. 303(3), 2. 701(4) and 2. 741(3) A , respectively.展开更多
文摘C48H108Ag3BrI3MoN3S4, Mr=1735. 84, cubic, F43c, a = b = c = 24. 577(4) A.V= 14845. 2A3, Z = 8, Dc=1. 553g/cm3, Dv = 1. 560g/cm3. Final R = 0. 061 for 307 unique diffraction data with I≥3σ(I). The anion of the title cluster compound can be viewed as a cubane like structure situated at specific equivalent positions in the unit cell with Td symmetry. One Mo and three Ag atoms, one Br and three Sb atoms, one S, and three I atoms are statistically distributed, individually. The distances of Mo....Ag (or Ag....Ag), Mo-Sb(or Ag -Sb, Ag -Br), and Mo-St(or Ag-I) are 3. 303(3), 2. 701(4) and 2. 741(3) A , respectively.
