四川盆地东部地区下志留统龙马溪组页岩储层特征

四川盆地是中国西南部重要的含油气盆地,在东部和南部地区下志留统龙马溪组页岩广泛发育。在川东南、鄂西渝东地区的勘探井中志留系具有良好的气显示。研究区龙马溪组厚65～516m,底部为一套海侵沉积的富含笔石的黑色页岩,龙马溪组向上和向东砂质和钙质含量增加,演变为浅水陆棚沉积。龙马溪组主要由层状-非层状泥/页岩、白云质粉砂岩、层状钙质泥/页岩、泥质粉砂岩、层状-非层状粉砂质泥/页岩、粉-细粒砂岩、钙质结核、富含有机质非层状页岩8种岩相组成。总有机碳含量(TOC)为0.2%～6.7%。有机质以II型干酪根为主,Ro为2.4%～3.6%。页岩中石英矿物含量在2%～93%,主要呈纹层状或分散状分布,主要为陆源碎屑外源成因。龙马溪组页岩岩心孔隙度为0.58%～0.67%,渗透率为0.01×10-3μm2～0.93×10-3μm2。扫描电镜下龙马溪组页岩微孔隙度为2%左右,主要包括晶间孔和粒内孔,孔隙直径为100nm～50μm。页岩储层的形成机理主要为有利矿物组合、成岩作用和有机质热裂解作用。龙马溪组与美国Barnett页岩具有一定差异,主要表现在龙马溪组页岩埋藏较深、热演化程度较高、含气量较低、储层较致密、以陆源成因石英为主。对于评价下志留统龙马溪组页岩气勘探前景而言,今后须重点加强针对龙马溪组底部黑色硅质岩系石英成因、成熟度、埋藏史、含气量等方面的研究,以及进行详细的古地貌和古环境恢复。

榴辉岩的地震波性质:对苏鲁超高压变质带地壳成分和折返机制的探讨

本文总结了榴辉岩的高温高压弹性波速测量结果,并将其应用于苏鲁超高压变质带地震资料的解释。由于榴辉岩具有高密度和高波速,它们和长英质片麻岩、大理岩、石英岩、角闪岩、麻粒岩、蛇纹石化橄榄岩的界面可以产生强反射。如果俯冲的陆壳物质以榴辉岩与围岩互层的形式在上地幔保留下来,就可能在造山带的上地幔产生地震反射。根据CCSD孔区地震剖面所建立的地壳成分模型表明:苏鲁超高压带地壳浅部的高速层可归因于夹在花岗质片麻岩、副片麻岩、角闪岩等岩石中的榴辉岩和超基性岩;中地壳主要由中酸性片麻岩、斜长角闪岩和副片麻岩组成;下地壳以中基性麻粒岩为主。在该超高压变质带现今的深部地壳,榴辉岩含量很少或几乎没有。因此,折返的超高压变质岩是以构造岩片的形式沿一系列剪切带逆冲并覆盖在正常的中下地壳之上,深部榴辉岩的缺乏可能与下地壳拆沉作用无关。

Hydrothermal Dolomite in the Upper Sinian (Upper Proterozoic) Dengying Formation, East Sichuan Basin, China

Hydrothermal Dolomite （HTD） is present in the Upper Sinian （Upper Proterozoic） Dengying Formation, east Sichuan Basin, China. The strata are comprised by primary dolomite. The HTD has various textures, including zebra dolomite, subhorizontal sheet-like cavities filled by saddle dolomite and breccias cemented by saddle dolomites as well occur as a fill of veins and fractures. Also co-occur MVT type lead-zinc ores in the study area. The δ13C and δ18O isotopes of HTD in the Upper Sinian Dengying Formation are lighter than those of the host rocks, while STSr/86Sr is higher. The apparent difference in carbon, oxygen and strontium isotopes, especially the large difference in S7Sr/S6Sr isotopes ratio indicate crystallization from hot basinal and/or hydrothermal fluids. Saddle dolomite was precipitated at temperatures of 270-320℃. The diagenetic parasequences of mineral assemblage deposited in the Dengying Formation are： （1） dolomite host rock →sphalerite-galena-barite-fluorite; （2） dolomite host rock →saddle dolomite →quartz; （3） dolomite host rock →saddle dolomite→bitumen; （4） dolomite host rock →saddle dolomite →barite. The mean chemical composition of the host dolomite matrix and HTD didn＇t change much during hydrothermal process. The fluids forming the HTDs in the Dengying Formation were mixtures of freshwater from the unconformity at the top of Sinian, fluids from diagenetic compaction and hydrocarbon generation ＆ expulsion from the Lower Cambrian Niutitang Formation mudstones or the Doushantuo Formation silty mudstones, and hydrothermal fluids from the basement. The hydrocarbon reservoirs associated with the HTD were mostly controlled by the basement faults and fractures and karsting processes at the unconformity separating Sinian and Cambrian strata. The hydrocarbon storage spaces of HTD included dissolved cavities and intercrystalline pores. Dissolution cavities are extensive at the top of Dengying Formation, up to about 46m below the unconformity between Sinian and Cambrian and were generated mainly during karstification. Hydrothermal alteration enhanced the reservoir property of the Dengying Formation dolomites with 3%-5% increase in porosity. No agreement has been reached why zebra dolomite occurs only in the Upper Sinian strata, which would indicate that HTD mineralization occurred during two different periods, each of them related to major extensional tectonic event. The early one related to the Xingkai taphrogenesis （Z2-C1） and the later one to the Emei taphrogenesis （D2-T2）. But, all the data from saddle dolomite suggest that the predominant crystallization occurred during the latter event.

Reservoir Characteristics and Preservation Conditions of Longmaxi Shale in the Upper Yangtze Block, South China

The Upper Ordovician-Lower Silurian Longmaxi Shale in the Upper Yangtze block represents one of the most important shale gas plays in China. The shale composition, porosity, organic thermal maturity, and methane sorption were investigated at the Qilongcun section in the Dingshan area, southeastern Sichuan Basin. The results show that the Upper Ordovician-Lower Silurian Longmaxi Shale contains： （1） sapropelic I organic matter; （2） a 40-m thick bedded sequence where total organic carbon （TOC） content is 〉 2%; （3） a 30-m thick layer at the base of the Longmaxi Shale with a brittle mineral content higher than 50%; and （4） a mean methane adsorption capacity of 1.80 cm3/g （7 MPa pressure）. A positive correlation between TOC and sorbed gas indicates that organic matter content exerts an important control on methane storage capacity. Based on the analysis of the shale reservoir characteristics, the lower member of the Longmaxi Shale can thus be considered a favorable stratum for shale gas exploration and exploitation. It has similar reservoir characteristics with the Longmaxi Shale in the Jiaoshiba area tested with a high-yield industrial gas flow. However, based on tectonic analysis, differences in the level of industrial gas flow between the low-yield study area and the high-yield Jiaoshiba area may result from different tectonic preservation conditions. Evidence from these studies indicates the shale gas potential of the Longmaxi Shale is constrained by the reservoir and preservation conditions.

Elastic and Seismic Properties of Dabie-Sulu Ultrahigh Pressure Metamorphic Rocks

Lame modulus （λ） and shear modulus （μ） are among the most important, intrinsic, elastic constants of rocks. Using 7. and μ could be much more advantageous than using P- and S-wave velocities （Vp and Vs）. Here we quantified these equivalent isotropic elastic moduli for 115 representative rocks from the ultrahigh pressure （UHP） metamorphic terrane of the Dabie-Sulu orogenic belt （China） and their variations with pressure （P）, temperature （T）, density （p）, Vp, Vs and mineralogical composition. Both moduli increase nonlinearly and linearly with increasing pressure at low （〈200-300 MPa） and high （〉200-300 MPa） pressures, respectively. In the regime of high pressures, 7. and IX decrease quasi-linearly with increasing temperature with temperature derivatives dλ/dT and dμ/dT generally in the range of -10×10-3 to -1×10-3 GPa/℃. Dehydration of water-bearing minerals such as serpentine in peridotites and chlorite in retrograde eciogites results in an abrupt drop in 7. while μ remains almost unchanged. In Z-p, μ-p and 7.-IX plots, the main categories of UHP rocks can be characterized. Serpentinization leads to significant decreases in μ and 7. as serpentine has extremely low values of Z, μ and p. Eclogites, common mafic rocks （mafic gneiss, metagabbro and amphibolite）, and felsic rocks （orthogneiss and paragneiss） have high, moderate and low μ and λ values, respectively. For pyroxenes and olivines, λ increases but μ decreases with increasing Fe/Mg ratios. For plagioclase feldspars, both Z and μ exhibit a significant positive correlation with anorthite content. SiO2-rich felsic rocks and quartzites are deviated remarkably from the general trend lines of the acid-intermediate-mafic rocks in Vs-p, μ-p, λ-Vp,λ-Vs and μ-λ diagrams because quartz has extremely low λ （-8.1 GPa） and p （2.65 g/cm3） but moderate μ （44.4 GPa） values. Increasing the contents of garnet, rutile, ilmenite and magnetite results in a significant increase in the λ and μ values of the UHP metamorphic rocks. However, either λ or μ is insensitive to the compositional variations for pyralspite （pyrope-almandine-spessartine） solution series. The results provide potentially improved constraints on characterization of crustal composition based on the elastic properties of rocks and in situ seismic data from deep continental roots.

Multi-Stage Basin Development and Hydrocarbon Accumulations： A Review of the Sichuan Basin at Eastern Margin of the Tibetan Plateau

Sichuan Basin is one of the uppermost petroliferous basins in China. It experienced three evolutionary phases which were marine carbonate platform （Ediacaran to Late Triassic）, Indosinian-Yanshanian orogeny foreland basin （Late Triassic to Late Cretaceous） and uplift and tectonic modification （Late Cretaceous to Quaternary）. The present-day tectonics of the Sichuan Ba- sin and its periphery are characterized by three basic elements which are topography, basement type and surface structure, and two settings （plate margin and interior）. Therefore, be subdivided into five units which have different structure and tectonic history. The basin contains five different sets of source rocks with thickness up to 2 500 m. These source rocks were well preserved due to the presence of Middel-Lower Triassic evaporites （〉-200 m） and thick terrestrial sediments filling in the Indosinian-Yanshanian foreland basin （〉3 000 m）. The uplift and erosion since Late Cretaceous has significant influence on cross-strata migration and accumulation of oil and gas. The multi-phase evolution of the basin and its superimposed tectonic elements, good petroleum geologic conditions and diverse petroleum systems reveal its bright exploration prospects.