Hydrothermal Dolomite (HTD) is present in the Upper Sinian (Upper Proterozoic) Dengying Formation, east Sichuan Basin, China. The strata are comprised by primary dolomite. The HTD has various textures, including z...Hydrothermal Dolomite (HTD) is present in the Upper Sinian (Upper Proterozoic) Dengying Formation, east Sichuan Basin, China. The strata are comprised by primary dolomite. The HTD has various textures, including zebra dolomite, subhorizontal sheet-like cavities filled by saddle dolomite and breccias cemented by saddle dolomites as well occur as a fill of veins and fractures. Also co-occur MVT type lead-zinc ores in the study area. The δ13C and δ18O isotopes of HTD in the Upper Sinian Dengying Formation are lighter than those of the host rocks, while STSr/86Sr is higher. The apparent difference in carbon, oxygen and strontium isotopes, especially the large difference in S7Sr/S6Sr isotopes ratio indicate crystallization from hot basinal and/or hydrothermal fluids. Saddle dolomite was precipitated at temperatures of 270-320℃. The diagenetic parasequences of mineral assemblage deposited in the Dengying Formation are: (1) dolomite host rock →sphalerite-galena-barite-fluorite; (2) dolomite host rock →saddle dolomite →quartz; (3) dolomite host rock →saddle dolomite→bitumen; (4) dolomite host rock →saddle dolomite →barite. The mean chemical composition of the host dolomite matrix and HTD didn't change much during hydrothermal process. The fluids forming the HTDs in the Dengying Formation were mixtures of freshwater from the unconformity at the top of Sinian, fluids from diagenetic compaction and hydrocarbon generation & expulsion from the Lower Cambrian Niutitang Formation mudstones or the Doushantuo Formation silty mudstones, and hydrothermal fluids from the basement. The hydrocarbon reservoirs associated with the HTD were mostly controlled by the basement faults and fractures and karsting processes at the unconformity separating Sinian and Cambrian strata. The hydrocarbon storage spaces of HTD included dissolved cavities and intercrystalline pores. Dissolution cavities are extensive at the top of Dengying Formation, up to about 46m below the unconformity between Sinian and Cambrian and were generated mainly during karstification. Hydrothermal alteration enhanced the reservoir property of the Dengying Formation dolomites with 3%-5% increase in porosity. No agreement has been reached why zebra dolomite occurs only in the Upper Sinian strata, which would indicate that HTD mineralization occurred during two different periods, each of them related to major extensional tectonic event. The early one related to the Xingkai taphrogenesis (Z2-C1) and the later one to the Emei taphrogenesis (D2-T2). But, all the data from saddle dolomite suggest that the predominant crystallization occurred during the latter event.展开更多
The Upper Ordovician-Lower Silurian Longmaxi Shale in the Upper Yangtze block represents one of the most important shale gas plays in China. The shale composition, porosity, organic thermal maturity, and methane sorpt...The Upper Ordovician-Lower Silurian Longmaxi Shale in the Upper Yangtze block represents one of the most important shale gas plays in China. The shale composition, porosity, organic thermal maturity, and methane sorption were investigated at the Qilongcun section in the Dingshan area, southeastern Sichuan Basin. The results show that the Upper Ordovician-Lower Silurian Longmaxi Shale contains: (1) sapropelic I organic matter; (2) a 40-m thick bedded sequence where total organic carbon (TOC) content is 〉 2%; (3) a 30-m thick layer at the base of the Longmaxi Shale with a brittle mineral content higher than 50%; and (4) a mean methane adsorption capacity of 1.80 cm3/g (7 MPa pressure). A positive correlation between TOC and sorbed gas indicates that organic matter content exerts an important control on methane storage capacity. Based on the analysis of the shale reservoir characteristics, the lower member of the Longmaxi Shale can thus be considered a favorable stratum for shale gas exploration and exploitation. It has similar reservoir characteristics with the Longmaxi Shale in the Jiaoshiba area tested with a high-yield industrial gas flow. However, based on tectonic analysis, differences in the level of industrial gas flow between the low-yield study area and the high-yield Jiaoshiba area may result from different tectonic preservation conditions. Evidence from these studies indicates the shale gas potential of the Longmaxi Shale is constrained by the reservoir and preservation conditions.展开更多
Lame modulus (λ) and shear modulus (μ) are among the most important, intrinsic, elastic constants of rocks. Using 7. and μ could be much more advantageous than using P- and S-wave velocities (Vp and Vs). Here...Lame modulus (λ) and shear modulus (μ) are among the most important, intrinsic, elastic constants of rocks. Using 7. and μ could be much more advantageous than using P- and S-wave velocities (Vp and Vs). Here we quantified these equivalent isotropic elastic moduli for 115 representative rocks from the ultrahigh pressure (UHP) metamorphic terrane of the Dabie-Sulu orogenic belt (China) and their variations with pressure (P), temperature (T), density (p), Vp, Vs and mineralogical composition. Both moduli increase nonlinearly and linearly with increasing pressure at low (〈200-300 MPa) and high (〉200-300 MPa) pressures, respectively. In the regime of high pressures, 7. and IX decrease quasi-linearly with increasing temperature with temperature derivatives dλ/dT and dμ/dT generally in the range of -10×10-3 to -1×10-3 GPa/℃. Dehydration of water-bearing minerals such as serpentine in peridotites and chlorite in retrograde eciogites results in an abrupt drop in 7. while μ remains almost unchanged. In Z-p, μ-p and 7.-IX plots, the main categories of UHP rocks can be characterized. Serpentinization leads to significant decreases in μ and 7. as serpentine has extremely low values of Z, μ and p. Eclogites, common mafic rocks (mafic gneiss, metagabbro and amphibolite), and felsic rocks (orthogneiss and paragneiss) have high, moderate and low μ and λ values, respectively. For pyroxenes and olivines, λ increases but μ decreases with increasing Fe/Mg ratios. For plagioclase feldspars, both Z and μ exhibit a significant positive correlation with anorthite content. SiO2-rich felsic rocks and quartzites are deviated remarkably from the general trend lines of the acid-intermediate-mafic rocks in Vs-p, μ-p, λ-Vp,λ-Vs and μ-λ diagrams because quartz has extremely low λ (-8.1 GPa) and p (2.65 g/cm3) but moderate μ (44.4 GPa) values. Increasing the contents of garnet, rutile, ilmenite and magnetite results in a significant increase in the λ and μ values of the UHP metamorphic rocks. However, either λ or μ is insensitive to the compositional variations for pyralspite (pyrope-almandine-spessartine) solution series. The results provide potentially improved constraints on characterization of crustal composition based on the elastic properties of rocks and in situ seismic data from deep continental roots.展开更多
Sichuan Basin is one of the uppermost petroliferous basins in China. It experienced three evolutionary phases which were marine carbonate platform (Ediacaran to Late Triassic), Indosinian-Yanshanian orogeny foreland...Sichuan Basin is one of the uppermost petroliferous basins in China. It experienced three evolutionary phases which were marine carbonate platform (Ediacaran to Late Triassic), Indosinian-Yanshanian orogeny foreland basin (Late Triassic to Late Cretaceous) and uplift and tectonic modification (Late Cretaceous to Quaternary). The present-day tectonics of the Sichuan Ba- sin and its periphery are characterized by three basic elements which are topography, basement type and surface structure, and two settings (plate margin and interior). Therefore, be subdivided into five units which have different structure and tectonic history. The basin contains five different sets of source rocks with thickness up to 2 500 m. These source rocks were well preserved due to the presence of Middel-Lower Triassic evaporites (〉-200 m) and thick terrestrial sediments filling in the Indosinian-Yanshanian foreland basin (〉3 000 m). The uplift and erosion since Late Cretaceous has significant influence on cross-strata migration and accumulation of oil and gas. The multi-phase evolution of the basin and its superimposed tectonic elements, good petroleum geologic conditions and diverse petroleum systems reveal its bright exploration prospects.展开更多
基金funded by National Basic Research Program of China (Grant No. 2012CB214805)
文摘Hydrothermal Dolomite (HTD) is present in the Upper Sinian (Upper Proterozoic) Dengying Formation, east Sichuan Basin, China. The strata are comprised by primary dolomite. The HTD has various textures, including zebra dolomite, subhorizontal sheet-like cavities filled by saddle dolomite and breccias cemented by saddle dolomites as well occur as a fill of veins and fractures. Also co-occur MVT type lead-zinc ores in the study area. The δ13C and δ18O isotopes of HTD in the Upper Sinian Dengying Formation are lighter than those of the host rocks, while STSr/86Sr is higher. The apparent difference in carbon, oxygen and strontium isotopes, especially the large difference in S7Sr/S6Sr isotopes ratio indicate crystallization from hot basinal and/or hydrothermal fluids. Saddle dolomite was precipitated at temperatures of 270-320℃. The diagenetic parasequences of mineral assemblage deposited in the Dengying Formation are: (1) dolomite host rock →sphalerite-galena-barite-fluorite; (2) dolomite host rock →saddle dolomite →quartz; (3) dolomite host rock →saddle dolomite→bitumen; (4) dolomite host rock →saddle dolomite →barite. The mean chemical composition of the host dolomite matrix and HTD didn't change much during hydrothermal process. The fluids forming the HTDs in the Dengying Formation were mixtures of freshwater from the unconformity at the top of Sinian, fluids from diagenetic compaction and hydrocarbon generation & expulsion from the Lower Cambrian Niutitang Formation mudstones or the Doushantuo Formation silty mudstones, and hydrothermal fluids from the basement. The hydrocarbon reservoirs associated with the HTD were mostly controlled by the basement faults and fractures and karsting processes at the unconformity separating Sinian and Cambrian strata. The hydrocarbon storage spaces of HTD included dissolved cavities and intercrystalline pores. Dissolution cavities are extensive at the top of Dengying Formation, up to about 46m below the unconformity between Sinian and Cambrian and were generated mainly during karstification. Hydrothermal alteration enhanced the reservoir property of the Dengying Formation dolomites with 3%-5% increase in porosity. No agreement has been reached why zebra dolomite occurs only in the Upper Sinian strata, which would indicate that HTD mineralization occurred during two different periods, each of them related to major extensional tectonic event. The early one related to the Xingkai taphrogenesis (Z2-C1) and the later one to the Emei taphrogenesis (D2-T2). But, all the data from saddle dolomite suggest that the predominant crystallization occurred during the latter event.
基金supported by Science and Technology Support Program of Sichuan Province(No.15ZC1390)National Natural Science Foundation of China(No.41102064)
文摘The Upper Ordovician-Lower Silurian Longmaxi Shale in the Upper Yangtze block represents one of the most important shale gas plays in China. The shale composition, porosity, organic thermal maturity, and methane sorption were investigated at the Qilongcun section in the Dingshan area, southeastern Sichuan Basin. The results show that the Upper Ordovician-Lower Silurian Longmaxi Shale contains: (1) sapropelic I organic matter; (2) a 40-m thick bedded sequence where total organic carbon (TOC) content is 〉 2%; (3) a 30-m thick layer at the base of the Longmaxi Shale with a brittle mineral content higher than 50%; and (4) a mean methane adsorption capacity of 1.80 cm3/g (7 MPa pressure). A positive correlation between TOC and sorbed gas indicates that organic matter content exerts an important control on methane storage capacity. Based on the analysis of the shale reservoir characteristics, the lower member of the Longmaxi Shale can thus be considered a favorable stratum for shale gas exploration and exploitation. It has similar reservoir characteristics with the Longmaxi Shale in the Jiaoshiba area tested with a high-yield industrial gas flow. However, based on tectonic analysis, differences in the level of industrial gas flow between the low-yield study area and the high-yield Jiaoshiba area may result from different tectonic preservation conditions. Evidence from these studies indicates the shale gas potential of the Longmaxi Shale is constrained by the reservoir and preservation conditions.
基金supported by the Sino Probe-deep exploration in Ministry of land and Resources of China(Sino Probe-07)the knowledge Innovation Program from Guangzhou Institute of Geochemistry,the Chinese Academy of Sciences(GIGCX-09-02)+1 种基金This is contribution No.IS-1386 from GIGCASthe Natural Sciences and Engineering Council of Canada and the Chinese Academy of Geological Sciences for the discovery and research grants(No.1212011121274)
文摘Lame modulus (λ) and shear modulus (μ) are among the most important, intrinsic, elastic constants of rocks. Using 7. and μ could be much more advantageous than using P- and S-wave velocities (Vp and Vs). Here we quantified these equivalent isotropic elastic moduli for 115 representative rocks from the ultrahigh pressure (UHP) metamorphic terrane of the Dabie-Sulu orogenic belt (China) and their variations with pressure (P), temperature (T), density (p), Vp, Vs and mineralogical composition. Both moduli increase nonlinearly and linearly with increasing pressure at low (〈200-300 MPa) and high (〉200-300 MPa) pressures, respectively. In the regime of high pressures, 7. and IX decrease quasi-linearly with increasing temperature with temperature derivatives dλ/dT and dμ/dT generally in the range of -10×10-3 to -1×10-3 GPa/℃. Dehydration of water-bearing minerals such as serpentine in peridotites and chlorite in retrograde eciogites results in an abrupt drop in 7. while μ remains almost unchanged. In Z-p, μ-p and 7.-IX plots, the main categories of UHP rocks can be characterized. Serpentinization leads to significant decreases in μ and 7. as serpentine has extremely low values of Z, μ and p. Eclogites, common mafic rocks (mafic gneiss, metagabbro and amphibolite), and felsic rocks (orthogneiss and paragneiss) have high, moderate and low μ and λ values, respectively. For pyroxenes and olivines, λ increases but μ decreases with increasing Fe/Mg ratios. For plagioclase feldspars, both Z and μ exhibit a significant positive correlation with anorthite content. SiO2-rich felsic rocks and quartzites are deviated remarkably from the general trend lines of the acid-intermediate-mafic rocks in Vs-p, μ-p, λ-Vp,λ-Vs and μ-λ diagrams because quartz has extremely low λ (-8.1 GPa) and p (2.65 g/cm3) but moderate μ (44.4 GPa) values. Increasing the contents of garnet, rutile, ilmenite and magnetite results in a significant increase in the λ and μ values of the UHP metamorphic rocks. However, either λ or μ is insensitive to the compositional variations for pyralspite (pyrope-almandine-spessartine) solution series. The results provide potentially improved constraints on characterization of crustal composition based on the elastic properties of rocks and in situ seismic data from deep continental roots.
基金supported by the National Basic Research Program of China (No. 2012CB214805)the National Natural Science Foundation of China (Nos. 41230313, 41402119, 2017JQ0025, 41472017, 41572111)
文摘Sichuan Basin is one of the uppermost petroliferous basins in China. It experienced three evolutionary phases which were marine carbonate platform (Ediacaran to Late Triassic), Indosinian-Yanshanian orogeny foreland basin (Late Triassic to Late Cretaceous) and uplift and tectonic modification (Late Cretaceous to Quaternary). The present-day tectonics of the Sichuan Ba- sin and its periphery are characterized by three basic elements which are topography, basement type and surface structure, and two settings (plate margin and interior). Therefore, be subdivided into five units which have different structure and tectonic history. The basin contains five different sets of source rocks with thickness up to 2 500 m. These source rocks were well preserved due to the presence of Middel-Lower Triassic evaporites (〉-200 m) and thick terrestrial sediments filling in the Indosinian-Yanshanian foreland basin (〉3 000 m). The uplift and erosion since Late Cretaceous has significant influence on cross-strata migration and accumulation of oil and gas. The multi-phase evolution of the basin and its superimposed tectonic elements, good petroleum geologic conditions and diverse petroleum systems reveal its bright exploration prospects.