Non-destructive techniques of in-situ stress measurement from oriented cored rocks have great potential to be developed as a cost cost-effective and reliable alternative to the conventional overcoring and hydraulic fr...Non-destructive techniques of in-situ stress measurement from oriented cored rocks have great potential to be developed as a cost cost-effective and reliable alternative to the conventional overcoring and hydraulic fracturing methods.The tangent modulus method(TMM)is one such technique that can be applied to oriented cored rocks to measure in-situ stresses.Like the deformation rate analysis(DRA),the rock specimen is subjected to two cycles of uniaxial compression and the stress-tangent modulus curve for the two cycles is obtained from the stress-strain curve.A bending point in the tangent modulus curve of the first cycle is observed,separating it from the tangent modulus curve of the second cycle.The point of separation between the two curves is assumed to be the previously applied maximum stress.A number of experiments were conducted on coal and coal measured rocks(sandstone and limestone)to understand the effect of loading conditions and the time delay.The specimens were preloaded,and cyclic compressions were applied under three different modes of loading,four different strain rates,and time delays of up to one week.The bending point in the stress-tangent modulus curves occurred approximately at the applied pre-stress levels under all three loading modes,and no effect of loading rate was observed on the bending points in TMM.However,a clear effect of time delay was observed on the TMM,contradicting the DRA results.This could be due to the sensitivity of TMM and the range of its applicability,all of which need further investigation for the in-situ stress measurement.展开更多
Recycling waste frying oils for the synthesis of flotation reagents presents a promising avenue for sustainable waste management.Moreover,it offers a cost-effective solution for crafting a specialized collector design...Recycling waste frying oils for the synthesis of flotation reagents presents a promising avenue for sustainable waste management.Moreover,it offers a cost-effective solution for crafting a specialized collector designed to efficiently remove carbonates and enhance phosphate enrichment in froth flotation processes.This study focuses on the synthesis of an anionic collector using the saponification reaction of a frying oil sample,subsequently applied to the flotation of calcite and dolomite.To elucidate the adsorption mechanisms of the frying oil collector(FrOC)and sodium oleate,a reference collector,on fluorapatite,calcite,dolomite,and quartz surfaces,comprehensive experiments were conducted,including zeta potential measurements and Fourier transform infrared spectroscopy.Results revealed diverse adsorption affinities of the molecules towards these minerals.To assess the practical performance of the collector,flotation tests were conducted using a natural phosphate ore mixture,employing a BoxBehnken experimental design.Notably,under optimized conditions(pH 9,1000 g/t of FrOC,3.5 min of conditioning,and 6 min of flotation),FrOC exhibited excellent performance,with calcite and dolomite recoveries exceeding 80%,while apatite recovery in the concentrate fraction remained below 10%.This work exemplifies both circular economy practices and the distinctive approach to sustainable mineral processing.展开更多
基金financially supported by the Australian Coal Association Research Program(ACARP)under project C29010.
文摘Non-destructive techniques of in-situ stress measurement from oriented cored rocks have great potential to be developed as a cost cost-effective and reliable alternative to the conventional overcoring and hydraulic fracturing methods.The tangent modulus method(TMM)is one such technique that can be applied to oriented cored rocks to measure in-situ stresses.Like the deformation rate analysis(DRA),the rock specimen is subjected to two cycles of uniaxial compression and the stress-tangent modulus curve for the two cycles is obtained from the stress-strain curve.A bending point in the tangent modulus curve of the first cycle is observed,separating it from the tangent modulus curve of the second cycle.The point of separation between the two curves is assumed to be the previously applied maximum stress.A number of experiments were conducted on coal and coal measured rocks(sandstone and limestone)to understand the effect of loading conditions and the time delay.The specimens were preloaded,and cyclic compressions were applied under three different modes of loading,four different strain rates,and time delays of up to one week.The bending point in the stress-tangent modulus curves occurred approximately at the applied pre-stress levels under all three loading modes,and no effect of loading rate was observed on the bending points in TMM.However,a clear effect of time delay was observed on the TMM,contradicting the DRA results.This could be due to the sensitivity of TMM and the range of its applicability,all of which need further investigation for the in-situ stress measurement.
基金financially supported through the research program between OCP Group and UM6P under the specific agreement AS34-flotation project
文摘Recycling waste frying oils for the synthesis of flotation reagents presents a promising avenue for sustainable waste management.Moreover,it offers a cost-effective solution for crafting a specialized collector designed to efficiently remove carbonates and enhance phosphate enrichment in froth flotation processes.This study focuses on the synthesis of an anionic collector using the saponification reaction of a frying oil sample,subsequently applied to the flotation of calcite and dolomite.To elucidate the adsorption mechanisms of the frying oil collector(FrOC)and sodium oleate,a reference collector,on fluorapatite,calcite,dolomite,and quartz surfaces,comprehensive experiments were conducted,including zeta potential measurements and Fourier transform infrared spectroscopy.Results revealed diverse adsorption affinities of the molecules towards these minerals.To assess the practical performance of the collector,flotation tests were conducted using a natural phosphate ore mixture,employing a BoxBehnken experimental design.Notably,under optimized conditions(pH 9,1000 g/t of FrOC,3.5 min of conditioning,and 6 min of flotation),FrOC exhibited excellent performance,with calcite and dolomite recoveries exceeding 80%,while apatite recovery in the concentrate fraction remained below 10%.This work exemplifies both circular economy practices and the distinctive approach to sustainable mineral processing.