Research on the direction of secondary migration of oil by making use of nitrogen compounds as tracers in the No. 6 area of the Melut Basin

This paper discussed the direction of secondary migration of oil in the No. 6 area of the Melut Basin by making use of nitrogen compounds as secondary oil migration tracers. From the results, we have found that the occurrence and compositional characteristics of isomeric-nitrogen compounds in crude oil precisely manifest the fractionation effect of oil migration: with increasing secondary migration distance, the absolute concentrations tend to decrease, and the ratio of nitrogen-shielded isomers to nitrogen-exposed isomers tends to increase. It is considered that the main direction of oil migration in the No. 6 area of the Melut Basin is from north to south.

Depositional Environment and Origin of Inertinite-rich Coal in the Ordos Basin

Inertinite-rich coal is widely distributed in the Ordos Basin,represented by the No.2 coal seam of the Middle Jurassic Yan'an Formation.This paper combined coal petrology and geochemistry to analyze the origin of inertinite,changes in the coal-forming environment and control characteristics of wildfire.Research has shown that there are two forms of inertinite sources in the study area.Alongside typical fusinization,wildfire events also play a substantial role in inertinite formation.There are significant fluctuations in the coal-forming environment of samples at different depths.Coal samples were formed in dry forest swamp with low water levels and strong oxidation,which have a high inertinite content,and the samples formed in wet forest swamp and limnic showed low inertinite content.Conversely,the inertinite content of different origins does not fully correspond to the depositional environment characterized by dryness and oxidation.Nonpyrogenic inertinites were significantly influenced by climatic conditions,while pyrofusinite was not entirely controlled by climatic conditions but rather directly impacted by wildfire events.The high oxygen level was the main factor causing widespread wildfire events.Overall,the combination of wildfire activity and oxidation generates a high content of inertinite in the Middle Jurassic coal of the Ordos Basin.

Quantitative characterization of the brittleness of deep shales by integrating mineral content,elastic parameters,in situ stress conditions and logging analysis

Deep shale reservoirs(3500–4500 m)exhibit significantly different stress states than moderately deep shale reservoirs(2000–3500 m).As a result,the brittleness response mechanisms of deep shales are also different.It is urgent to investigate methods to evaluate the brittleness of deep shales to meet the increasingly urgent needs of deep shale gas development.In this paper,the quotient of Young’s modulus divided by Poisson’s ratio based on triaxial compression tests under in situ stress conditions is taken as SSBV(Static Standard Brittleness Value).A new and pragmatic technique is developed to determine the static brittleness index that considers elastic parameters,the mineral content,and the in situ stress conditions(BIEMS).The coefficient of determination between BIEMS and SSBV reaches 0.555 for experimental data and 0.805 for field data.This coefficient is higher than that of other brittleness indices when compared to SSBV.BIEMS can offer detailed insights into shale brittleness under various conditions,including different mineral compositions,depths,and stress states.This technique can provide a solid data-based foundation for the selection of‘sweet spots’for single-well engineering and the comparison of the brittleness of shale gas production layers in different areas.

Belowground Bud Bank Is Insensitive to Short-Term Nutrient Addition in the Meadow Steppe of Inner Mongolia

Human activities and industrialization have significantly increased soil nutrients,such as nitrogen(N)and phos-phorus(P),profoundly impacting the composition and structure of plant community,as well as the ecosystem functions,especially in nutrient-limited ecosystems.However,as the key propagule pool of perennial grasslands,how belowground bud bank and its relationship with aboveground vegetation respond to short-term changes in soil nutrients was still unclear.In this study,we conducted a short-term(2021–2022)soil fertilization experiment with N addition(10 g N m^(-2) yr^(-1))and P addition(5 g N m^(-2) yr^(-1))in the meadow steppe of Inner Mongolia,China,to explore the responses of belowground bud bank,aboveground shoot population and their relationships(represented by the ratio of bud to shoot density-meristem limitation index(MLI))for the whole community and three plant functional groups(perennial rhizomatous grasses-PR,perennial bunchgrasses-PB,and perennial forbs-PF)to nutrient addition.The short-term nutrient addition had no significant influences on belowground bud density,aboveground shoot density,and MLI of the whole plant community.Plant functional groups showed different responses to soil fertilization.Specifically,N addition significantly increased the bud density and shoot density of PR,especially in combination with P addition.N addition reduced the shoot density of PF but had no influence on its bud density and MLI.Nutrient addition had significant effects on the three indicators of PB.Our study indicates that the belowground bud bank and its relationship with aboveground vegetation in temperate meadow steppe are insensitive to short-term soil fertilization,but plant functional groups exhibit specific responses in terms of population regeneration,which implies that plant community composition and ecosystem functions will be changed under the ongoing global change.

塔里木盆地柯坪-巴楚地区奥陶系层序界面特征及成因分析

通过综合分析塔里木盆地柯坪-巴楚地区露头剖面的宏观组合和微观结构,总结出奥陶系不同级别层序界面的表现特征、成因机制,指导盆地内层序界面的研究。柯坪-巴楚地区奥陶系主要有3个级别的层序界面:一级层序界面发育在构造变革期,如受到造山运动或区域构造隆升作用等影响,表现为角度不整合面、平行不整合等特征;二级层序界面发育在沉积环境重大转换阶段,主要受到全球海平面变化的影响或局部构造运动影响,表现为平行不整合、淹没不整合等特征;三级层序界面与局部构造运动有关,表现为局部平行不整合。层序界面的表现形式包括古土壤层、喀斯特化、地层削截、地层超覆、岩性岩相突变等。通过总结不同层序界面的性质和成因,分析不整合面的规模和发育部位,预测有利岩溶储层发育的区带。

Carbonate Sequence Stratigraphy of a Back-Arc Basin: A Case Study of the Qom Formation in the Kashan Area, Central Iran

The Qom Formation comprises Oligo-Miocene deposits from a marine succession distributed in the Central Basin of Iran. It is composed of five members designated as A-F. Little previous work exists on the sequence stratigraphy. Based on an integrated study of sequence stratigraphy with outcrop data, wells and regional seismic profiles, the Qom Formation is interpreted as a carbonate succession deposited in a mid.Tertiary back-arc basin. There are two second-order sequences （designated as SS1 and SS2） and five third-order sequences （designated as S1-S5）. Five distinct systems tracts including transgressive, highstand, forced regressive, slope margin and Iowstand have been recognized. The relationship between the sequences and lithologic sub-units has been collated and defined （S1 to S5 individually corresponding to A-C1, C2--C4, D-E, the lower and upper portions of F）; a relative sea level change curve and the sequence stratigraphic framework have been established and described in detail. The coincidence of relative sea level change between that of the determined back-arc basin and the world indicates that the sedimentary cycles of the Qom Formation are mainly controlled by eustatic cycles. The variable combination of the systems tracts and special tectonic-depositional setting causally underpin multiple sequence stratigraphic framework styles seen in the carbonates of the back-arc basin revealing： （1） a continental margin basin that developed some form of barrier, characterized by the development of multiple cycles of carbonate-evaporites; （2） a flat carbonate ramp, which occurred on the southern shelf formed by the lack of clastic supply from nearby magmatic islands plus mixed siliciclastics and carbonates that occurred on the northern shelf due to a sufficient clastics supply from the land; and （3） a forced regressive stratigraphic stacking pattern that occured on the southern shelf and in basin lows due to the uplifting of the southern shelf. Thick and widespread aggradational framework limestone usually occurs in the initial sequences （S1 and S3） of the supersequence, which led to preferential oil reservoir deposition but a lack of source and cap rocks, whereas the retrogradational and progradational framework limestone usually occurs in the later sequences （S2 and S4-S5） of the supersequence, which results in two perfect sets of source, reservoir and cap rock assemblies, so that the limestone in sub-member C2-C4 and the F-Member can be predicted as important objects for oil exploration.

Mechanism of diagenetic trap formation in nearshore subaqueous fans on steep rift lacustrine basin slopes—A case study from the Shahejie Formation on the north slope of the Minfeng Subsag, Bohai Basin, China

Diagenetic traps in conglomerate in nearshore subaqueous fans in the steep slope zones of rift basins have been important exploration targets for subtle reservoirs in eastern China. However, the mechanism of how those traps were formed is not clear, which inhibits further exploration for this type of reservoir. In order to solve the problem, we take as an example nearshore subaqueous fans in the upper part of the fourth member of the Shahejie Formation （Es4s） on the north slope of the Minfeng Subsag in the Dongying Sag. Combining different research methods, such as core observation, thin section examination, scanning electron microscope （SEM） observation, fluid-inclusion analysis, carbon and oxygen isotope analysis of carbonate cements, and analysis of core properties, we studied the genetic mechanisms of diagenetic traps on the basis of diagenetic environment evolution and diagenetic evolution sequence in different sub/micro-facies. Conglomerate in Es4s in the north Minfeng Subsag experienced several periods of transition between alkaline and acidic environments as ＂alkaline-acidic-alkaline-acidic-weak alkaline＂. As a result, dissolution and cementation are also very complex, and the sequence is ＂early pyrite cementation / siderite cementation / gypsum cementation / calcite and dolomite cementation- feldspar dissolution / quartz overgrowth quartz dissolution / ferroan calcite cementation / ankerite cementation / lime-mud matrix recrystallization / feldspar overgrowth carbonate dissolution / feldspar dissolution / quartz overgrowth / pyrite cementation＂. The difference in sedimentary characteristics between different sub/micro-facies of nearshore subaqueous fans controls diagenetic characteristics. Inner fan conglomerates mainly experienced compaction and lime-mud matrix recrystallization, with weak dissolution, which led to a reduction in the porosity and permeability crucial to reservoir formation. Lime-mud matrix recrystallization results in a rapid decrease in porosity and permeability in inner fan conglomerates in middle-to-deep layers. Because acid dissolution reworks reservoirs and hydrocarbon filling inhibits cementation, reservoirs far from mudstone layers in middle fan braided channels develop a great number of primary pores and secondary pores, and are good enough to be effective reservoirs of hydrocarbon. With the increase of burial depth, both the decrease of porosity and permeability of inner fan conglomerates and the increase of the physical property difference between inner fans and middle fans enhance the quality of seals in middle-to-deep layers. As a result, inner fan conglomerates can be sealing layers in middle-to-deep buried layers. Reservoirs adjacent to mudstones in middle fan braided channels and reservoirs in middle fan interdistributaries experienced extensive cementation, and tight cemented crusts formed at both the top and bottom of conglomerates, which can then act as cap rocks. In conclusion, diagenetic traps in conglomerates of nearshore subaqueous fans could be developed with inner fan conglomerates as lateral or vertical sealing layers, tight carbonate crusts near mudstone layers in middle fan braided channels as well as lacustrine mudstones as cap rocks, and conglomerates far from mudstone layers in middle fan braided channels as reservoirs. Lime-mud matrix recrystallization of inner fan conglomerates and carbonate cementation of conglomerates adjacent to mudstone layers in middle fan braided channels took place from 32 Ma B.R to 24.6 Ma B.P., thus the formation of diagenetic traps was from 32 Ma B.R to 24.6 Ma B.R and diagenetic traps have a better hydrocarbon sealing ability from 24 Ma B.P.. The sealing ability of inner fans gradually increases with the increase of burial depth and diagenetic traps buried more than 3,200 m have better seals.

Reservoir Characteristics of Lacustrine Shale and Marine Shale:Examples from the Songliao Basin,Bohai Bay Basin and Qiannan Depression

Lacustrine shale from the Qingshankou Formatin of Songliao basin and the Shahejie Formation of Bohai Bay basin, and marine shale from the lower Cambrian Jinmenchong Formation of Qiannan depression were analysed by using rock pyrolysis, TOC （total organic carbon）, XRD （X-ray diffraction）, SEM （scanning electron microscope）, FE-SEM （field emission scanning electron microscope）, high pressure mercury intrusion, and low pressure N2 and CO2 gas adsorption experiments, in aim to reveal their reservoir features. The results show that： （1） the width of micro-pores of all the studied samples mainly ranges from 0.45 to 0.7 nm indicated by CO2 isotherms, and the width of meso-pores is less than 10 nm, with type IV adsorption isotherms and type H2 hysteresis loop, indicative of ＂ink-bottle＂-shaped pores. Good correlations exist among pore volume, surface area and averaged pore diameter, and a good positive correlation exists between micro-pore volume and TOC content; however, there is no obvious correlation between meso-pore volume and TOC content; （2） interparticle pores, pores among the edge of mineral grains and organic matter pores were all identified in marine and lacustrine shale, among which the interparticle pores may be influence by dissolution effect. Not all bitumen develops organic matter pore, and only high to over mature bitumen present pores. Now the description methods of micrometer scale pores developed in shale are very lack. Micro- fractures developed in Jiyang depression and dissolution interparticle pores developed in Songliao Basin should be the accumulation sites for shale oil in lacustrine shale, and can be as sweet spots.

Oil Source and Entrapment Epoch of the Ordovician Oil Reservoir in the Kongxi Burial-Hill Zone, Huanghua Depression, North China

An oil flow obtained from the Middle Ordovician Fengfeng Formation carbonate reservoir in the well KG-3, Kongxi burial-hill zone in 1993 marked a breakthrough in petroleum exploration of the high-mature Lower Palaeozoic strata, North China. Both the Lower member of the Fengfeng Formation and the Second Member of the Upper Majiagou Formation in the Middle Ordovician are supposed to be the main source beds. Oil generation peaks range from 1.0% to 1.6% in Ro, showing a “lag effect” of oil generation in high-mature carbonate source rocks under multicyclic tectonic movement conditions. The Kongxi burial-hill zone adjoins a potential Ordovician source kitchen. The KG-3 Ordovician burial-hill reservoir has undergone two oil filling events, i.e., an early event in the Late Carboniferous-Permian and a more significant late event in the early Eogene.

Changes in the thermodynamic properties of alkaline granite after cyclic quenching following high temperature action

During the development of hot dry rock,the research on thermal fatigue damage caused by thermal shock of cold and heat cycles is the basis that ensures the long-term utilization of geothermal resources,but there are not enough relevant studies at present.Based on this,the thermal damage tests of granite at different temperatures(250,350,450°C)and quenching cycles(1,5,10,15 cycles)were carried out.Preliminary reveals the damage mechanism and heat transfer law of the quenching cycle effect on hot dry rock.The results show that with the increase of temperature and cycles,the uneven thermal expansion of minerals and the thermal shock caused by quenching promote the crack development of granite,resulting in the decrease of P-wave velocity,thermal conductivity and uniaxial compressive strength of granite.Meanwhile,the COMSOL was used to simulate the heat transfer of hot dry rock under different heat treatment conditions.It concluded that the increase in the number of quenching cycles reduced the heat transfer capacity of the granite,especially more than 10 quenching cycles,which also reflects that the thermal fatigue damage leads to a longer time for the temperature recovery of the hot dry rock mass.In addition,the three-dimensional nonlinear fitting relationship among thermal conductivity,temperature and cycle number was established for the first time,which can better reveal the change rule of thermal conductivity after quenching thermal fatigue effect of hot dry rock.The research results provide theoretical support for hot dry rock reservoir reconstruction and production efficiency evaluation.

Tectonics-palaeogeomorphology in rift basins: controlling effect on the sequence architecture

The relationship between deposition and tectonics of sedimentary basins has been a significant subject in recent years.Using typical rift basins such as the Nanpu Sag as an example,combined with the analysis of the tectonics-palaeogeomorphology of basins,we undertook a detailed study of the differences of the third-order sequences in different basins,the combination of depositional systems within the sequence framework and the distribution of depocenters and subsidence centers.Our results revealed a significant relationship between the tectonics-palaeogeomorphology of rift basins and the filling styles of sedimentary sequences.The basin structure plays a primary role in controlling the development of the third-order sequences and the boundary of these sequences is easily formed in basins with gentle slopes,shallow water and a small area.The characteristics of the tectonics-palaeogeomorphology of rift basins are dominated by half-grabens of extensional faults,which affect the temporal and spatial combination of sedimentary systems within the sequences as well as the distribution of depocenters and subsidence centers.Based on the development rules of the faults dominating the half-grabens of extensional faults,rift basins are classified into two types： the single fault segmented-linkage type and the multi-fault combination type.The main controlling factors of the temporal and spatial combination of sedimentary systems and the distribution of depocenters and subsidence centers in different basins are different.The characteristics of early segmentation and later linkage of the faults play a critical role in controlling the sedimentary system combination within the sequence framework and the temporal and spatial differences of depocenters and subsidence centers of the single fault segmented-linkage rift basins,while the differences in fault activities are the dominating factors of the multi-fault combination rift basins.

Formation Dynamics and Quantitative Prediction of Hydrocarbons of the Superpressure System in the Dongying Sag

Based on the theory of formation dynamics of oil/gas pools, the Dongying sag can be divided into three dynamic systems regarding the accumulation of oil and gas： the superpressure closed system, the semi-closed system and the normal pressure open system. Based on the analysis of genesis of superpressure in the superpressure closed system and the rule of hydrocarbon expulsion, it is found that hydrocarbon generation is related to superpressure, which is the main driving factor of hydrocarbon migration. Micro fractures formed by superpressure are the main channels for hydrocarbon migration. There are three dynamic patterns for hydrocarbon expulsion： free water drainage, hydrocarbon accumulation and drainage through micro fissures. In the superpressure closed system, the oil-driving-water process and oil/gas accumulation were completed in lithologic traps by way of such two dynamic patterns as episodic evolution of superpressure systems and episodic pressure release of faults. The oil-bearing capacity of lithologic traps is intimately related to reservoir-forming dynamic force. Quantitative evaluation of dynamic conditions for pool formation can effectively predict the oil-bearing capability of traps.

Geochemical characteristics of noble gases in natural gas and their application in tracing natural gas migration in the middle part of the western Sichuan Depression, China

Noble gases in natural gas, from Xiaoquan, Xinchang, Hexingchang and Fenggu gas reservoirs in the middle part of the western Sichuan Depression, China, were analysed. Results show that the volume content of crustal noble gases accounts for 97.9% to 99.7% of the total noble gas content, indicating that the noble gases in the study area are very largely derived from the crust. Moreover, the 40Ar time-accumulating effect of source rocks is used to determine the complex relationship between gases and source rocks in this area, and the results agree well with that from analysis of source rock light hydrocarbons. Due to the short migration distance, the separation of 4He and 40Ar is not significant in Xujiahe natural gas and Lower and Middle Jurassic natural gas, so it is difficult to trace natural gas migration. However, this separation characteristic of 4He and 40Ar in Middle and Upper Jurassic natural gas is significant, which indicates that natural gas migration was from the Middle Jurassic to Upper Jurassic formations. In addition, the variation trends of 3He/4He ratio and δ13C1 value indicates that natural gas migration is from the Xujiahe formation to the Jurassic layer in the study area.

Inconsistency of changes in uniaxial compressive strength and P-wave velocity of sandstone after temperature treatments

It is generally accepted that the uniaxial compressive strength(UCS)and P-wave velocity of rocks tend to decrease simultaneously with increasing temperature.However,based on a great number of statistical data and systematic analysis of the microstructure variation of rocks with temperature rising and corresponding propagation mechanism of elastic wave,the results show that(1)There are three different trends for the changes of UCS and P-wave velocity of sandstone when heated from room temperature(20C or 25C)to 800C:(i)Both the UCS and P-wave velocity decrease simultaneously;(ii)The UCS increases initially and then decreases,while the P-wave velocity decreases continuously;and(iii)The UCS increases initially and then fluctuates,while the P-wave velocity continuously decreases.(2)The UCS changes at room temperaturee400C,400Ce600C,and 600Ce800C are mainly attributed to the discrepancy of microstructure characteristics and quartz content,the transformation plasticity of clay minerals,and the balance between the thermal cementation and thermal damage,respectively.(3)The inconsistency in the trends of UCS and P-wave velocity changes is caused by the change of quartz content,phase transition of water and certain minerals.

Geological characteristics of the southern segment of the Late Sinian–Early Cambrian Deyang-Anyue rift trough in Sichuan Basin, SW China

Based on the latest drilling, seismic and field outcrop data, the geological characteristics(e.g. strata, development and sedimentary evolution) of the southern segment of the Late Sinian–Early Cambrian Deyang–Anyue rift trough in the Sichuan Basin are analyzed. First, the strata in the southern segment are complete. The first to second members of Dengying Formation(Deng 1 + Deng 2) are found with relatively stable thickness(400–550 m), and the third to fourth members(Deng 3+ Deng 4) show great thickness difference between the marginal trough and the inner trough, which is up to 250 m. The Cambrian Maidiping Formation and Qiongzhusi Formation in southern Sichuan Basin are relatively thin, with the thickness changing greatly and frequently. Second, the Deyang–Anyue rift trough extended southward during the Deng 4 period, affecting southern Sichuan Basin. Compared to the middle and northern segments of the rift trough, the southern segment is generally wide, gentle and shallow, with multiple steps, and alternating uplifts and sags, which are distributed in finger shape. Third, the Deng 1 + Deng 2 in southern Sichuan Basin records the dominance of carbonate platform and unobvious sedimentary differentiation, and the Deng 4 exhibits obvious sedimentary differentiation, namely, basin–slope–secondary slope–slope–secondary slope–platform margin–restricted platform, from the inner trough to the marginal trough. Fourth, the rift trough in southern Sichuan Basin has evolved in four stages: stabilization of Deng 1–Deng 2, initialization of Deng 3–Deng 4, filling of Maidiping–Qiongzhusi, and extinction of Canglangpu Formation.

Integrated petrophysical log characterization for tight carbonate reservoir effectiveness: A case study from the Longgang area, Sichuan Basin, China

Ultra-low porosity and permeability, inhomogeneous fracture distribution, and complex storage space together make the effectiveness evaluation of tight carbonate reservoirs difficult. Aiming at the carbonate reservoirs of the Da＇anzhai Formation in the Longgang area of the Sichuan Basin, based on petrophysical experiments and logging response characteristics, we investigated the storage properties of matrix pores and the characteristics of fracture development to establish a method for the characterization of effectiveness of tight reservoirs. Mercury injection and nuclear magnetic resonance （NMR） experiments show that the conventional relationship between porosity and permeability cannot fully reflect the fluid flow behavior in tight matrix pores. Under reservoir conditions, the tight reservoirs still possess certain storage space and permeability, which are controlled by the characteristic structures of the matrix porosity. The degree of fracture development is crucial to the productivity and quality of tight reservoirs. By combining the fracture development similarity of the same type of reservoirs and the fracture development heterogeneity in the same block, a three-level classification method of fracture development was established on the basis of fracture porosity distribution and its cumulative features. According to the actual production data, based on the effectiveness analysis of the matrix pores and fast inversion of fracture parameters from dual laterolog data, we divided the effective reservoirs into three classes： Class I with developed fractures and pores, and high-intermediate productivity; Class II with moderately developed fractures and pores or of fractured type, and intermediate-low productivity; Class III with poorly developed fractures and matrix pores, and extremely low productivity. Accordingly log classification standards were set up. Production data shows that the classification of effective reservoirs is highly consistent with the reservoir productivity level, providing a new approach for the effectiveness evaluation of tight reservoirs.

Pore Structure and Permeability Characterization of Highrank Coal Reservoirs: A Case of the Bide-Santang Basin, Western Guizhou, South China

The methods of nuclear magnetic resonance(NMR)spectroscopy,mercury injection porosimetry(MIP),and gas-water relative permeability(GWRP)were used to reveal the pore structure and permeability characteristics of high-rank coal reservoirs in the Bide-Santang basin,western Guizhou,South China,to provide guidance for coalbed methane(CBM)exploration and exploitation and obtain direct insights for the development of CBM wells.The results indicate that the coal reservoirs in the study area are characterized by well-developed adsorption pores and poorly developed seepage pores.The bimodal NMR transverse relaxation time(T2)spectra and the mutation in the fractal characteristic of the MIP pore volume indicate poor connectivity between the adsorption pores and the seepage pores.As a result,the effective porosity is relatively low,with an average of 1.70%.The irreducible water saturation of the coal reservoir is relatively high,with an average of 66%,leading to a low gas relative permeability under irreducible water saturation.This is the main reason for the low recovery of high-rank CBM reservoirs,and effective enhanced CBM recovery technology urgently is needed.As a nondestructive and less time-consuming technique,the NMR is a promising method to quantitatively characterize the pores and fractures of coals.

Analysis of petrophysical cutoffs of reservoir intervals with production capacity and with accumulation capacity in clastic reservoirs

Methodologies have been developed for calculating cutoffs of reservoir intervals with production capacity （RIPC） and reservoir intervals with accumulation capacity （RIAC） according to the types of pore throat structures and dynamic force by using data from petrophysical analysis, production tests and mercury injection. The data are from clastic reservoirs in the third member （Es3） and the fourth member （Es4） of the Shahejie Formation in the Shengtuo area on the North Slope of the Dongying Sag, Jiyang Depression, China. The method of calculating cutoffs of RIPC is summarized as follows： 1） determination of permeability cutoffs of RIPC; 2） classification of types of pore-throat structures according to mercury injection data and then relating porosity to permeability and determining the relationship between porosity and permeability according to each type of pore-throat structure; and 3） calculating porosity cutoffs of RIPC using established correlation between porosity and permeability according to the type of pore throat structure. The method of calculating cutoffs of RIAC includes： 1） establishing a functional relationship between oil-water interracial tension and formation temperature; 2） calculating limiting values of maximum connected pore-throat radii according to formation temperature and dynamic forces of each reservoir interval; 3） correlating permeability with maximum connected pore-throat radius and then obtaining permeability cutoffs of RIAC; and 4） calculating porosity cutoffs on the basis of permeability cutoffs according to specific correlations, suitable for the type of porethroat structure. The results of this study show that porosity and permeability cutoffs of clastic reservoirs decrease with depth. For a fixed permeability cutoff, the porosity cutoff of R1PC varies because the type of pore throat is different. At a fixed temperature, porosity and permeability cutoffs of RIAC decrease as dynamic force increases. For a fixed permeability cutoff of effective hydrocarbon accumulation, the porosity cutoff also varies with different types of pore throat.

Mineralization of a Proterozoic Sulfide Black Smoker Chimney and Thermophilous Microorganisms in Eastern Hebei,China

A sulfide black smoker chimney exists in the Gaobanhe seabed exhalation massive sulfide deposit in the Xingiong-Kuancheng secondary fault basin of the Proterozoic Yaniiao rift trough in Hebei Province, taking the shape of mounds, individually about 2-3 cm high. Abundant fossils of thermophilous bacteria and algae in perfect preservation are found in the ore surrounding the black smoker chimney. Scanning electron microscopy （SEM） and molecular biomarker studies on the microorganismai ore fabric show that the microorganism in the sulfide ore is in fact a sedimentary product of probiotic bacteria and algae. In the special food chain based on black smoker chimney at ancient seabed- thermophilous bacteria, the thermophilous bacteria and algae reproduce in large quantity. Intermittently erupting of fluid from the chimney creats conditions for formation of sulfide deposit. In the process of exhalation action of hot fluid, thermophilous bacteria and algae grow and reproduce around the sulfide black smoker chimney, absorbing mineralizing substances brought by the fluid. Massive sulfide deposits are formed in this process of absorption of seabed black smoker chimney exhalation-mineralizing fluid pulsation-thermophilous microorganism.

Geochemistry and mineralogy of platinum-group elements(PGE)in chromites from CentralnoyeⅠ,Polar Urals,Russia

The Polar Urals region of northern Russia is well known for large chromium （Cr）-bearing massifs with major chromite orebodies, including the Centralnoye I deposit in the Ray-Iz ultramafic massif of the Ural ophiolite belt. New data on platinum （Pt）-group elements （PGE）, geochemistry and mineralogy of the host dunite shows that the deposit has anomalous iridium （Ir） values. These values indicate the predominance of ruthenium--osmium--iridium （Ru--Os--Ir）-bearing phases among the platinum-group mineral （PGM） assemblage that is typical of mantle-hosted chromite ores. Low Pt values in chromites and increased Pt values in host dunites might reflect the presence of cumulus PGM grains. The most abundant PGM found in the chromite is erlichmanite （up to 15 μm）. Less common are cuproiridsite （up to 5 μm）, irarsite （up to 4--5 μm）, and laurite （up to 4 μm）. The predominant sulfide is heazlewoodite, in intergrowth with Ni--Fe alloys, sporadically with pentlandite, and rarely with pure nickel. Based on the average PGE values and esti- mated Cr-ore resources, the Centralnoye I deposit can be considered as an important resource of PGE.