A micro-annulus(MA)is defined as a high permeability zone or gap initiating/occurring at the casingcement and cement-formation interfaces during the wellbore life span.An MA can significantly compromise wellbore integ...A micro-annulus(MA)is defined as a high permeability zone or gap initiating/occurring at the casingcement and cement-formation interfaces during the wellbore life span.An MA can significantly compromise wellbore integrity by establishing enhanced fluid flow pathways.This study uses a staged finite element approach to simulate wellbore integrity during various loading steps of wellbore operations under downhole conditions.Particular emphasis is placed on the processes of cement poro-elastic property evolution,volume variation,and pore pressure variation as part of the cement hardening step.The resulting state of stress during the life cycle of a typical injection well(i.e.hardening,completion,and injection)is analyzed to assess the onset and evolution of micro-annuli at various interfaces of the composite wellbore system under downhole conditions.The results show that cement shear failure is observed at the casing-cement interface during pressure testing(excessive wellbore pressure);and tensile debonding failure initiates at the cement-formation interface due to cement shrinkage during hardening and injection-related cooling(thermal cycling).Sensitivity analyses considering several parameters show that:(1)the degree of poro-elastic bulk shrinkage has significant implications for both shear and tensile failure initiation e the less the cement shrinks,the less likely the failure initiation is;(2)cement integrity increases with increasing depth;(3)cement pore pressure evolution has significant implications for tensile failure e if cement pore pressure decreases more,higher temperature differences can be sustained before an MA occurs;and(4)cement temperature fluctuations during hardening promote initiation of debonding failure.In summary,the results presented indicate that establishing downhole conditions to quantitatively analyze MA generation is necessary.The results are different compared to laboratory studies without considering/simulating downhole conditions.The knowledge from this study can raise the awareness of predicting and evaluating MA under downhole conditions and can be used to supplement and improve future laboratory experiments.展开更多
Knowing methane desorption characteristics is essential to define the contribution of adsorbed gas to gas well production.To evaluate the synthetic effect of a clay stabilizer solution on methane desorption kinetics a...Knowing methane desorption characteristics is essential to define the contribution of adsorbed gas to gas well production.To evaluate the synthetic effect of a clay stabilizer solution on methane desorption kinetics and isotherms pertaining to Longmaxi shale,an experimental setup was designed based on the volumetric method.The objective was to conduct experiments on methane adsorption and desorption kinetics and isotherms before and after clay stabilizer treatments.The experimental data were a good fit for both the intraparticle diffusion model and the Freundlich isotherm model.We analyzed the effect of the clay stabilizer on desorption kinetics and isotherms.Results show that clay stabilizer can obviously improve the diffusion rate constant and reduce the methane adsorption amount.Moreover,we analyzed the desorption efficiency before and after treatment as well as the adsorbed methane content.The results show that a higher desorption efficiency after treatment can be observed when the pressure is higher than 6.84 MPa.Meanwhile,the adsorbed methane content before and after treatment all increase when the pressure decreases,and clay stabilizer can obviously promote the adsorbed methane to free gas when the pressure is lower than 19 MPa.This can also be applied to the optimization formulation of slickwater and the design of gas well production.展开更多
Electrical resistivity tomography data were acquired in proximity to the coal combustion residual landfill in an effort to image and analyze seepage pathways through the shallow residual soil and underlying karsted li...Electrical resistivity tomography data were acquired in proximity to the coal combustion residual landfill in an effort to image and analyze seepage pathways through the shallow residual soil and underlying karsted limestone bedrock. The water table is at a depth of more than 45 m. The most prominent subsurface seepage pathways identified on the acquired electrical resistivity tomography data are located immediately adjacent to the toe of the landfill and are attributed to stormwater run-off. The moisture content of the limestone appears to decrease gradually with increasing distance from the toe of the landfill, suggesting there is also a horizontal component of moisture flow in the subsurface. Shallow limestone with higher moisture content generally underlies or is in close proximity to anthropogenic features such as drainage ditches and clay berms that are designed to channel run-off. At one location, electrical resistivity tomography data were acquired along essentially the same traverse at different times of the year, and the resistivity of shallow limestone overall was lower on the data acquired after heavy rains.展开更多
Sediments in Lake Izabal,Guatemala,contain substantial lead (Pb),zinc (Zn),and nickel (Ni).The lack of historical data for heavy metal concentrations in the sediments makes it difficult to determine the sources or eva...Sediments in Lake Izabal,Guatemala,contain substantial lead (Pb),zinc (Zn),and nickel (Ni).The lack of historical data for heavy metal concentrations in the sediments makes it difficult to determine the sources or evaluate whether inputs of metals to the lake have changed through time.We measured the relative abundances and concentrations of Pb,Zn,and Ni by X-Ray Fluorescence core scanning and by Inductively Coupled Plasma Optical Emission Spectrometry in three sediment cores to explore stratigraphic distributions of metals in the lake deposits.High amounts of Pb and Zn in the core taken near the Polochic Delta suggest that galena and sphalerite mining increased Pb and Zn delivery to Lake Izabal between ~1945 and 1965 CE.An up-core Ni increase in the core taken near a different mine on the north shore of Lake Izabal suggests that recent nickel mining operations led to an increase in Ni concentrations in the local sediments,but amounts in the other cores indicate that Ni is not widely distributed throughout the lake.Sediment cores from Lake Izabal are reliable recorders of heavy metal input to the lake,and were measured to establish background metal levels,which would otherwise be unavailable.Concentrations of Pb,Zn,and Ni in older,pre-20th-century Lake Izabal sediments reflect input from natural erosion of bedrock.Our results provide previously unavailable estimates of background metal concentrations in Lake Izabal before the onset of mining.These results are necessary for future monitoring related to mining contamination of the lake ecosystem.展开更多
The shear behavior of a single rock joint in limestone specimens,under a constant normal load(CNL),was analyzed in this study.Test specimens with different asperity roughness were prepared and tested.Goodman's mod...The shear behavior of a single rock joint in limestone specimens,under a constant normal load(CNL),was analyzed in this study.Test specimens with different asperity roughness were prepared and tested.Goodman's model of a rock joint's shear behavior,under CNL,was modified to render a better representation of the data obtained.The model's applicability was validated.The proposed model showed better correlation with experimental data.It also,requires fewer variables.The steps to calculate all the necessary variables for the model are discussed.展开更多
The advanced tensor based concept of pore pressure-stress coupling is used to provide pre-injection analytical estimates of the maximum sustainable pore pressure change, ΔPc, for fluid injection scenarios into generi...The advanced tensor based concept of pore pressure-stress coupling is used to provide pre-injection analytical estimates of the maximum sustainable pore pressure change, ΔPc, for fluid injection scenarios into generic anticline geometries. The heterogeneous stress distribution for different prevailing stress regimes in combination with the Young's modulus(E) contrast between the injection layer and the cap rock and the interbedding friction coefficient, m, may result in large spatial and directional differences of ΔP c. A single value characterizing the cap rock as for horizontal layered injection scenarios is not obtained. It is observed that a higher Young's modulus in the cap rock and/or a weak mechanical coupling between layers amplifies the maximum and minimum ΔPc values in the valley and limb,respectively. These differences in ΔPc imposed by E and m are further ampli fied by different stress regimes. The more compressional the stress regime is, the larger the differences between the maximum and minimum ΔPc values become. The results of this study show that, in general compressional stress regimes yield the largest magnitudes of ΔPc and extensional stress regimes provide the lowest values of ΔPc for anticline formations. Yet this conclusion has to be considered with care when folded anticline layers are characterized by flexural slip and the friction coefficient between layers is low, i.e.μ=0.1. For such cases of weak mechanical coupling, ΔPc magnitudes may range from 0 MPa to 27 MPa, indicating imminent risk of fault reactivation in the cap rock.展开更多
基金The authors would like to thank Chevron ETC for financial support for this study.
文摘A micro-annulus(MA)is defined as a high permeability zone or gap initiating/occurring at the casingcement and cement-formation interfaces during the wellbore life span.An MA can significantly compromise wellbore integrity by establishing enhanced fluid flow pathways.This study uses a staged finite element approach to simulate wellbore integrity during various loading steps of wellbore operations under downhole conditions.Particular emphasis is placed on the processes of cement poro-elastic property evolution,volume variation,and pore pressure variation as part of the cement hardening step.The resulting state of stress during the life cycle of a typical injection well(i.e.hardening,completion,and injection)is analyzed to assess the onset and evolution of micro-annuli at various interfaces of the composite wellbore system under downhole conditions.The results show that cement shear failure is observed at the casing-cement interface during pressure testing(excessive wellbore pressure);and tensile debonding failure initiates at the cement-formation interface due to cement shrinkage during hardening and injection-related cooling(thermal cycling).Sensitivity analyses considering several parameters show that:(1)the degree of poro-elastic bulk shrinkage has significant implications for both shear and tensile failure initiation e the less the cement shrinks,the less likely the failure initiation is;(2)cement integrity increases with increasing depth;(3)cement pore pressure evolution has significant implications for tensile failure e if cement pore pressure decreases more,higher temperature differences can be sustained before an MA occurs;and(4)cement temperature fluctuations during hardening promote initiation of debonding failure.In summary,the results presented indicate that establishing downhole conditions to quantitatively analyze MA generation is necessary.The results are different compared to laboratory studies without considering/simulating downhole conditions.The knowledge from this study can raise the awareness of predicting and evaluating MA under downhole conditions and can be used to supplement and improve future laboratory experiments.
基金supported by the China Scholarship Council(No.201908505143)the Chongqing Research Program of Basic Research and Frontier Technology(No.cstc2017jcyj AX0290/No.cstc2018jcyj AX0563)。
文摘Knowing methane desorption characteristics is essential to define the contribution of adsorbed gas to gas well production.To evaluate the synthetic effect of a clay stabilizer solution on methane desorption kinetics and isotherms pertaining to Longmaxi shale,an experimental setup was designed based on the volumetric method.The objective was to conduct experiments on methane adsorption and desorption kinetics and isotherms before and after clay stabilizer treatments.The experimental data were a good fit for both the intraparticle diffusion model and the Freundlich isotherm model.We analyzed the effect of the clay stabilizer on desorption kinetics and isotherms.Results show that clay stabilizer can obviously improve the diffusion rate constant and reduce the methane adsorption amount.Moreover,we analyzed the desorption efficiency before and after treatment as well as the adsorbed methane content.The results show that a higher desorption efficiency after treatment can be observed when the pressure is higher than 6.84 MPa.Meanwhile,the adsorbed methane content before and after treatment all increase when the pressure decreases,and clay stabilizer can obviously promote the adsorbed methane to free gas when the pressure is lower than 19 MPa.This can also be applied to the optimization formulation of slickwater and the design of gas well production.
文摘Electrical resistivity tomography data were acquired in proximity to the coal combustion residual landfill in an effort to image and analyze seepage pathways through the shallow residual soil and underlying karsted limestone bedrock. The water table is at a depth of more than 45 m. The most prominent subsurface seepage pathways identified on the acquired electrical resistivity tomography data are located immediately adjacent to the toe of the landfill and are attributed to stormwater run-off. The moisture content of the limestone appears to decrease gradually with increasing distance from the toe of the landfill, suggesting there is also a horizontal component of moisture flow in the subsurface. Shallow limestone with higher moisture content generally underlies or is in close proximity to anthropogenic features such as drainage ditches and clay berms that are designed to channel run-off. At one location, electrical resistivity tomography data were acquired along essentially the same traverse at different times of the year, and the resistivity of shallow limestone overall was lower on the data acquired after heavy rains.
基金Missouri University of Science and Technology and a graduate student research grant from the Geological Society of America for supportthe Center for Research in Energy and Environment for help using the ICP-OES。
文摘Sediments in Lake Izabal,Guatemala,contain substantial lead (Pb),zinc (Zn),and nickel (Ni).The lack of historical data for heavy metal concentrations in the sediments makes it difficult to determine the sources or evaluate whether inputs of metals to the lake have changed through time.We measured the relative abundances and concentrations of Pb,Zn,and Ni by X-Ray Fluorescence core scanning and by Inductively Coupled Plasma Optical Emission Spectrometry in three sediment cores to explore stratigraphic distributions of metals in the lake deposits.High amounts of Pb and Zn in the core taken near the Polochic Delta suggest that galena and sphalerite mining increased Pb and Zn delivery to Lake Izabal between ~1945 and 1965 CE.An up-core Ni increase in the core taken near a different mine on the north shore of Lake Izabal suggests that recent nickel mining operations led to an increase in Ni concentrations in the local sediments,but amounts in the other cores indicate that Ni is not widely distributed throughout the lake.Sediment cores from Lake Izabal are reliable recorders of heavy metal input to the lake,and were measured to establish background metal levels,which would otherwise be unavailable.Concentrations of Pb,Zn,and Ni in older,pre-20th-century Lake Izabal sediments reflect input from natural erosion of bedrock.Our results provide previously unavailable estimates of background metal concentrations in Lake Izabal before the onset of mining.These results are necessary for future monitoring related to mining contamination of the lake ecosystem.
文摘The shear behavior of a single rock joint in limestone specimens,under a constant normal load(CNL),was analyzed in this study.Test specimens with different asperity roughness were prepared and tested.Goodman's model of a rock joint's shear behavior,under CNL,was modified to render a better representation of the data obtained.The model's applicability was validated.The proposed model showed better correlation with experimental data.It also,requires fewer variables.The steps to calculate all the necessary variables for the model are discussed.
基金financial support from the US Department of Energy National Energy Technology Laboratory under Grant No.DE-FE0001836
文摘The advanced tensor based concept of pore pressure-stress coupling is used to provide pre-injection analytical estimates of the maximum sustainable pore pressure change, ΔPc, for fluid injection scenarios into generic anticline geometries. The heterogeneous stress distribution for different prevailing stress regimes in combination with the Young's modulus(E) contrast between the injection layer and the cap rock and the interbedding friction coefficient, m, may result in large spatial and directional differences of ΔP c. A single value characterizing the cap rock as for horizontal layered injection scenarios is not obtained. It is observed that a higher Young's modulus in the cap rock and/or a weak mechanical coupling between layers amplifies the maximum and minimum ΔPc values in the valley and limb,respectively. These differences in ΔPc imposed by E and m are further ampli fied by different stress regimes. The more compressional the stress regime is, the larger the differences between the maximum and minimum ΔPc values become. The results of this study show that, in general compressional stress regimes yield the largest magnitudes of ΔPc and extensional stress regimes provide the lowest values of ΔPc for anticline formations. Yet this conclusion has to be considered with care when folded anticline layers are characterized by flexural slip and the friction coefficient between layers is low, i.e.μ=0.1. For such cases of weak mechanical coupling, ΔPc magnitudes may range from 0 MPa to 27 MPa, indicating imminent risk of fault reactivation in the cap rock.