In order to meet the pressing demand for wide-area communication required by the Global Energy Interconnection(GEI),accelerating the construction of satellite-terrestrial Integra怕d networks that can achieve network e...In order to meet the pressing demand for wide-area communication required by the Global Energy Interconnection(GEI),accelerating the construction of satellite-terrestrial Integra怕d networks that can achieve network extension and seamless global coverage has become the focus of power communication tech no logy development.In this study,we propose a satellite-terrestrial integrated network model that can support interconnection and interoperation on the IP layer between the satellite system and the怕rrestrial segment of the existing power communication system.First,the composition and function of the satellite-terrestrial collaborative network are explained.Then,the IP-based protocol stack is described,and a typical applicati on experime nt is con ducted to illustrate the particular process of this protocol stack.Fin ally,a use case of IP interconn ection that depends on GEO satellite communication is detailed.The experime ntal study has showed that the satellite-terrestrial collaborative network can efficiently support various IP applications for the GEI.展开更多
The dependence on portable devices and electrical vehicles has triggered the awareness on the energy storage systems with ever-growing energy density.Lithium metal batteries(LMBs)has revived and attracted considerable...The dependence on portable devices and electrical vehicles has triggered the awareness on the energy storage systems with ever-growing energy density.Lithium metal batteries(LMBs)has revived and attracted considerable attention due to its high volumetric(2046 m Ah cm-3),gravimetric specific capacity(3862 m Ah g^(-1))and the lowest reduction potential(-3.04 V vs.SHE.).However,during the electrochemical process of lithium anode,the growth of lithium dendrite constitutes the biggest stumbling block on the road to LMBs application.The undesirable dendrite not only limit the Coulombic efficiency(CE)of LMBs,but also cause thermal runaway and other safety issues due to short-circuits.Understanding the mechanisms of lithium nucleation and dendrite growth provides insights to solve these problems.Herein,we summarize the electrochemical models that inherently describe the lithium nucleation and dendrite growth,such as the thermodynamic,electrodeposition kinetics,internal stress,and interface transmission models.Essential parameters of temperature,current density,internal stress and interfacial Li+flux are focused.To improve the LMBs performance,state-of-the-art optimization procedures have been developed and systematically illustrated with the intrinsic regulation principles for better lithium anode stability,including electrolyte optimization,artificial interface layers,threedimensional hosts,external field,etc.Towards practical applications of LMBs,the current development of pouch cell LMBs have been further introduced with different assembly systems and fading mechanism.However,challenges and obstacles still exist for the development of LMBs,such as in-depth understanding and in-situ observation of dendrite growth,the surface protection under extreme condition and the self-healing of solid electrolyte interface.展开更多
Proton exchange membrane fuel cells(PEMFC)have attracted much attention because of their high energy conversion efficiency,high power density and zero emission of pollutants.However,the high cost of the cathode platin...Proton exchange membrane fuel cells(PEMFC)have attracted much attention because of their high energy conversion efficiency,high power density and zero emission of pollutants.However,the high cost of the cathode platinum group metal(PGM)catalysts creates a barrier for the large-scale application of PEMFC.Tremendous efforts have been devoted to the development of low-cost PGM-free catalysts,especially the Fe-N-C catalysts,to replace the expensive PGM catalysts.However,the characterization methods and evaluation standards of the catalysts varies,which is not conducive to the comparison of PGM-free catalysts.U.S.Department of energy(DOE)is the only authority that specifies the testing standards and activity targets for PGM-free catalysts.In this review,the major breakthroughs of Fe-N-C catalysts are outlined with the reference of DOE standards and targets.The preparation and characteristics of these highly active Fe-N-C catalysts are briefly introduced.Moreover,the efforts on improving the mass transfer and the durability issue of Fe-N-C fuel cell are discussed.Finally,the prospective directions concerning the comprehensive evaluation of the Fe-N-C catalysts are proposed.展开更多
A microgrid is hard to control due to its reduced inertia and increased uncertainties. To overcome the challenges of microgrid control, advanced controllers need to be developed.In this paper, a distributed, two-level...A microgrid is hard to control due to its reduced inertia and increased uncertainties. To overcome the challenges of microgrid control, advanced controllers need to be developed.In this paper, a distributed, two-level, communication-economic control scheme is presented for multiple-bus microgrids with each bus having multiple distributed generators(DGs) connected in parallel. The control objective of the upper level is to calculate the voltage references for one-bus subsystems. The objectives of the lower control level are to make the subsystems' bus voltages track the voltage references and to enhance load current sharing accuracy among the local DGs. Firstly, a distributed consensusbased power sharing algorithm is introduced to determine the power generations of the subsystems. Secondly, a discrete-time droop equation is used to adjust subsystem frequencies for voltage reference calculations. Finally, a Lyapunov-based decentralized control algorithm is designed for bus voltage regulation and proportional load current sharing. Extensive simulation studies with microgrid models of different levels of detail are performed to demonstrate the merits of the proposed control scheme.展开更多
A hybrid of line commutated converters(LCCs)and modular multi-level converters(MMCs)can provide the advantages of both the technologies.However,the commutation failure still exists if the LCC operates as an inverter i...A hybrid of line commutated converters(LCCs)and modular multi-level converters(MMCs)can provide the advantages of both the technologies.However,the commutation failure still exists if the LCC operates as an inverter in a hybrid LCC/MMC system.In this paper,the system behavior during a commutation failure is investigated.Both halfbridge and full-bridge MMCs are considered.Control strategies are examined through simulations conducted in PSCAD/EMTDC.Additionally,commutation failure protection strategies for multi-terminal hybrid LCC/MMC systems with AC and DC circuit breakers are studied.This paper can contribute to the protection design of future hybrid LCC/MMC systems against commutation failures.展开更多
The effects of humidity on the ground-level resultant electric field around positive DC conductors were studied both experimentally and numerically. Experiments were carried out in an artificial climate chamber, the r...The effects of humidity on the ground-level resultant electric field around positive DC conductors were studied both experimentally and numerically. Experiments were carried out in an artificial climate chamber, the results of which showed that the photon count and the groundlevel resultant electric field strength both increased with increasing relative humidity. Numerical calculations for different values of relative humidity were carried out, including solutions of the positive corona inception voltage and the ion-flow field, for which a photoionization model and the upstream finite element method were employed, respectively. In order to analyze the effects of humidity, three main factors were considered: the ionization coefficient, the attachment coefficient in the photoionization model and the modified ion mobility of the charged water particles. The results indicated that, with increasing relative humidity, increasing values of the effective ionization coefficient were responsible for a reduction in the inception voltage, and the reduction reinforced the ground-level resultant electric field. Moreover, due to the charged water particles and the lower ion mobility with increasing relative humidity, the space charge density distribution was enhanced, which also strengthened the ground-level resultant electric field.展开更多
Hydrogen can serve as a carrier to store renewable energy in large scale.However,hydrogen storage still remains a challenge in the current stage.It is difficult to meet the technical requirements applying the conventi...Hydrogen can serve as a carrier to store renewable energy in large scale.However,hydrogen storage still remains a challenge in the current stage.It is difficult to meet the technical requirements applying the conventional storage of compressed gaseous hydrogen in high-pressure tanks or the solid-state storage of hydrogen in suitable materials.In the present work,a gaseous and solid-state(G-S)hybrid hydrogen storage system with a low working pressure below 5 MPa for a 10 kW hydrogen energy storage experiment platform is developed and validated.A Ti-Mn type hydrogen storage alloy with an effective hydrogen capacity of 1.7 wt%was prepared for the G-S hybrid hydrogen storage system.The G-S hybrid hydrogen storage tank has a high volumetric hydrogen storage density of 40.07 kg H_(2)m^(-3) and stores hydrogen under pressure below5 MPa.It can readily release enough hydrogen at a temperature as low as-15C when the FC system is not fully activated and hot water is not available.The energy storage efficiency of this G-S hybrid hydrogen storage system is calculated to be 86.4%-95.9%when it is combined with an FC system.This work provides a method on how to design a G-S hydrogen storage system based on practical demands and demonstrates that the G-S hybrid hydrogen storage is a promising method for stationary hydrogen storage application.展开更多
With the growing amounts of multi-micro grids,electric vehicles,smart home,smart cities connected to the Power Distribution Internet of Things(PD-IoT)system,greater computing resource and communication bandwidth are r...With the growing amounts of multi-micro grids,electric vehicles,smart home,smart cities connected to the Power Distribution Internet of Things(PD-IoT)system,greater computing resource and communication bandwidth are required for power distribution.It probably leads to extreme service delay and data congestion when a large number of data and business occur in emergence.This paper presents a service scheduling method based on edge computing to balance the business load of PD-IoT.The architecture,components and functional requirements of the PD-IoT with edge computing platform are proposed.Then,the structure of the service scheduling system is presented.Further,a novel load balancing strategy and ant colony algorithm are investigated in the service scheduling method.The validity of the method is evaluated by simulation tests.Results indicate that the mean load balancing ratio is reduced by 99.16%and the optimized offloading links can be acquired within 1.8 iterations.Computing load of the nodes in edge computing platform can be effectively balanced through the service scheduling.展开更多
The AC/DC hybrid distribution network is one of the trends in distribution network development, which poses great challenges to the traditional distribution transformer. In this paper, a new topology suitable for AC/D...The AC/DC hybrid distribution network is one of the trends in distribution network development, which poses great challenges to the traditional distribution transformer. In this paper, a new topology suitable for AC/DC hybrid distribution network is put forward according to the demands of power grid, with advantages of accepting DG and DC loads, while clearing DC fault by blocking the clamping double sub-module(CDSM) of input stage. Then, this paper shows the typical structure of AC/DC distribution network that is hand in hand. Based on the new topology, this paper designs the control and modulation strategies of each stage, where the outer loop controller of input stage is emphasized for its twocontrol mode. At last, the rationality of new topology and the validity of control strategies are verified by the steady and dynamic state simulation. At the same time, the simulation results highlight the role of PET in energy regulation.展开更多
This paper introduces the implementation and data analysis associated with a state-wide power quality monitoring and analysis system in China. Corporation specifications on power quality monitors as well as on communi...This paper introduces the implementation and data analysis associated with a state-wide power quality monitoring and analysis system in China. Corporation specifications on power quality monitors as well as on communication protocols are formulated for data transmission. Big data platform and related technologies are utilized for data storage and computation. Compliance verification analysis and a power quality performance assessment are conducted, and a visualization tool for result presentation is finally presented.展开更多
A novel antibacterial acrylate polymer composite modified with capsaicin was successfully synthesized by a two-step reaction.Capsaicin and acryloyl chloride were firstly esterified,and then applied to solution polymer...A novel antibacterial acrylate polymer composite modified with capsaicin was successfully synthesized by a two-step reaction.Capsaicin and acryloyl chloride were firstly esterified,and then applied to solution polymerization with acrylate monomers and styrene.The yield of the esterified products was about 85.3%.The polymer was characterized by Fourier transform infrared spectroscopy(FTIR),gel permeation chromatography(GPC),thermogravimetric analysis(TGA),contact angle(CA)and antibacterial ring tests.The number-average molecular weight(M_n)of the polymer was 27214,based on the capsaicin-acrylate dosage of 6.5 wt%.The TGA revealed a stable thermal property.The contact angles of the polymers films on tinplate increased from 77.5°to 86.2°with the increasing amount of capsaicin-acrylate.The antibacterial tests demonstrated excellent antimicrobial capability of the polymers.展开更多
A Monte Carlo Potts model was developed to simulate the recrystallization process of a cold-rolled ultra-thin grain-oriented silicon steel.The orientation and image quality data from electron backscatter diffraction m...A Monte Carlo Potts model was developed to simulate the recrystallization process of a cold-rolled ultra-thin grain-oriented silicon steel.The orientation and image quality data from electron backscatter diffraction measurements were used as input information for simulation.Three types of nucleation mechanisms,namely,random nucleation,high-stored-energy site nucleation(HSEN),and high-angle boundary nucleation(HABN),were considered for simulation.In particular,the nucleation and growth behaviors of Goss-oriented({011}<100>)grains were investigated.Results showed that Goss grains had a nucleation advantage in HSEN and HABN.The amount of Goss grains was the highest according to HABN,and it matched the experimental measurement.However,Goss grains lacked a size advantage across all mechanisms during the recrystallization process.展开更多
The DC electrical resistivity-temperature characteristic is an important property for insulating materials to operate at a high stress level.In order to improve the DC electrical resistivity at elevated temperature in...The DC electrical resistivity-temperature characteristic is an important property for insulating materials to operate at a high stress level.In order to improve the DC electrical resistivity at elevated temperature in a targeted way,a positive temperature coefficient(PTC)material(Ba Ti O3-based compound(BT60))was selected as the filler in this paper,whose electrical resistivity has a PTC effect when the temperature exceeds its Curie temperature.The BT60 was treated with hydrogen peroxide and(3-Aminopropyl)triethoxysilane.Epoxy composites with different loadings of BT60 fillers(0 wt%,0.5 wt%,and 2 wt%of epoxy)were prepared,denoted as EP-0,EP-0.5,and EP-2.It was shown that BT60 was able to maintain the DC breakdown strength when its loading was less than 2 wt%of epoxy.As the temperature exceeds 60°C,BT60 will compensate for the negative temperature coefficient effect of epoxy resin to some extent.The electrical resistivity of EP-2 was improved by 55%compared with that of neat epoxy at 90°C.It was found that the potential barrier at the grain boundary of BT60 and the deep traps in the interface between BT60 and the epoxy resin hinder the migration of carriers and thus increase the electrical resistivity of epoxy composite.展开更多
The selective abnormal growth of Goss grains in magnetic sheets of Fe-3%Si (grade Hi-B) induced by second-phase particles (AlN and MnS) was studied using a modified Monte Carlo Ports model. The starting microstruc...The selective abnormal growth of Goss grains in magnetic sheets of Fe-3%Si (grade Hi-B) induced by second-phase particles (AlN and MnS) was studied using a modified Monte Carlo Ports model. The starting microstructures for the simulations were generated from electron backscatter diffraction (EBSD) orientation imaging maps of recrystallized samples. In the simulation, second-phase particles were assumed to be randomly distributed in the initial microstructures and the Zener drag effect of particles on Goss grain boundaries was assumed to be selectively invalid because of the unique properties of Goss grain boundaries. The simulation results suggest that normal growth of the matrix grains stagnates because of the pinning effect of particles on their boundaries. During the onset of abnormal grain growth, some Goss grains with concave boundaries in the initial microstructure grow fast abnormally and other Goss grains with convex boundaries shrink and eventually disappear.展开更多
The effect of nitric oxide(NO) annealing on charge traps in the oxide insulator and transition layer in n-type4H–Si C metal–oxide–semiconductor(MOS) devices has been investigated using the time-dependent bias s...The effect of nitric oxide(NO) annealing on charge traps in the oxide insulator and transition layer in n-type4H–Si C metal–oxide–semiconductor(MOS) devices has been investigated using the time-dependent bias stress(TDBS),capacitance–voltage(C–V),and secondary ion mass spectroscopy(SIMS).It is revealed that two main categories of charge traps,near interface oxide traps(Nniot) and oxide traps(Not),have different responses to the TDBS and C–V characteristics in NO-annealed and Ar-annealed samples.The Nniotare mainly responsible for the hysteresis occurring in the bidirectional C–V characteristics,which are very close to the semiconductor interface and can readily exchange charges with the inner semiconductor.However,Not is mainly responsible for the TDBS induced C–V shifts.Electrons tunneling into the Not are hardly released quickly when suffering TDBS,resulting in the problem of the threshold voltage stability.Compared with the Ar-annealed sample,Nniotcan be significantly suppressed by the NO annealing,but there is little improvement of Not.SIMS results demonstrate that the Nniotare distributed within the transition layer,which correlated with the existence of the excess silicon.During the NO annealing process,the excess Si atoms incorporate into nitrogen in the transition layer,allowing better relaxation of the interface strain and effectively reducing the width of the transition layer and the density of Nniot.展开更多
It has been shown that the deployment of device-to-device(D2D) communication in cellular systems can provide better support for local services. However, improper design of the hybrid system may cause severe interferen...It has been shown that the deployment of device-to-device(D2D) communication in cellular systems can provide better support for local services. However, improper design of the hybrid system may cause severe interference between cellular and D2D links. In this paper, we consider transceiver design for the system employing multiple antennas to mitigate the interference. The precoder and decoder matrices are optimized in terms of sum mean squared error(MSE) and capacity, respectively. For the MSE minimization problem, we present an alternative transceiver optimization algorithm. While for the non-convex capacity maximization problem, we decompose the primal problem into a sequence of standard convex quadratic programs for efficient optimization. The evaluation of our proposed algorithms for performance enhancement of the entire D2D integrated cellular system is carried out through simulations.展开更多
Adopting organic phase change materials(PCMs) for the management of electronic devices is restricted by low thermal conductivity. In this paper, the composite PCMs are established by freeze-drying and vacuum impregnat...Adopting organic phase change materials(PCMs) for the management of electronic devices is restricted by low thermal conductivity. In this paper, the composite PCMs are established by freeze-drying and vacuum impregnation. Herein, polyethylene glycol(PEG) is induced as heat storage materials, boron nitride(BN) is embedded as filler stacking in an orderly fashion on the foam walls to improve thermal conductivity and sodium alginate(SA) is formed as supporting material to keep the shape of the composite stable. X-ray diffractometry, scanning electron microscopy-energy dispersive spectrometer, thermal gravimetric analysis, thermal conductivity meter, differential scanning calorimeter, and Fourier transform infrared were used to characterize the samples and thermal cycles were employed to measure the shape stability. The results exhibit the BN@SA/PEG composite PCMs have good chemical compatibility, stable morphology, and thermal stability. Due to the high porosity of foam, PEG endows the composite PCMs with high latent heat(149.11 and 141.59 J·g^(-1)). Simultaneously, BN@SA/PEG shows an excellent heat performance with high thermal conductivity(0.99 W·m^(-1)·K^(-1)), reusability, and shape stability, contributing the composite PCMs to application in the energy storage field. This study provides a strategy to manufacture flexible, long-serving, and shape-stable PCMs via introducing BN@SA foam as a storage framework, and these PCMs have great potential in thermal management in the electronic field.展开更多
LiBH4 was confined into activated charcoal(AC) by melt infiltration method(MI), and its effects on the hydrogen sorption properties were investigated. The N2 adsorption results reveal that melt infiltration method...LiBH4 was confined into activated charcoal(AC) by melt infiltration method(MI), and its effects on the hydrogen sorption properties were investigated. The N2 adsorption results reveal that melt infiltration method can effectively incorporated LiBH4 into AC. It can maintain the structural integrity of the scaffold and ensure the confinement effect. The nano-confined LiBH4/AC starts to release hydrogen at around 190 °C, which is 160 °C lower than that of pure LiBH4, and reaches a hydrogen desorption capacity of 13.6% at 400 °C. When rehydrogenated under the condition of 6 MPa H2 and 350 °C, it has a reversible hydrogen storage capacity of 6%, while pure LiBH4 shows almost no reversible hydrogen storage capacity under the same condition. Mass spectrometry analysis(MS) results suggest that no diborane or other impurity gases are released in the decomposition process. The apparent activation energy of dehydrogenation of LiBH4 after confinement into AC decreases from 156.0 to 121.1 k J/mol, which leads to the eminent enhancement of dehydrogenation kinetics of LiBH4.展开更多
With the development of internet of vehicles,the traditional centralized content caching mode transmits content through the core network,which causes a large delay and cannot meet the demands for delay-sensitive servi...With the development of internet of vehicles,the traditional centralized content caching mode transmits content through the core network,which causes a large delay and cannot meet the demands for delay-sensitive services.To solve these problems,on basis of vehicle caching network,we propose an edge colla-borative caching scheme.Road side unit(RSU)and mobile edge computing(MEC)are used to collect vehicle information,predict and cache popular content,thereby provide low-latency content delivery services.However,the storage capa-city of a single RSU severely limits the edge caching performance and cannot handle intensive content requests at the same time.Through content sharing,col-laborative caching can relieve the storage burden on caching servers.Therefore,we integrate RSU and collaborative caching to build a MEC-assisted vehicle edge collaborative caching(MVECC)scheme,so as to realize the collaborative caching among cloud,edge and vehicle.MVECC uses deep reinforcement learning to pre-dict what needs to be cached on RSU,which enables RSUs to cache more popular content.In addition,MVECC also introduces a mobility-aware caching replace-ment scheme at the edge network to reduce redundant cache and improving cache efficiency,which allows RSU to dynamically replace the cached content in response to the mobility of vehicles.The simulation results show that the pro-posed MVECC scheme can improve cache performance in terms of energy cost and content hit rate.展开更多
As a newly emerging computing paradigm, edge computing shows great capability in supporting and boosting 5G and Internet-of-Things (IoT) oriented applications, e.g., scientific workflows with low-latency, elastic, and...As a newly emerging computing paradigm, edge computing shows great capability in supporting and boosting 5G and Internet-of-Things (IoT) oriented applications, e.g., scientific workflows with low-latency, elastic, and on-demand provisioning of computational resources. However, the geographically distributed IoT resources are usually interconnected with each other through unreliable communications and ever-changing contexts, which brings in strong heterogeneity, potential vulnerability, and instability of computing infrastructures at different levels. It thus remains a challenge to enforce high fault-tolerance of edge-IoT scientific computing task flows, especially when the supporting computing infrastructures are deployed in a collaborative, distributed, and dynamic environment that is prone to faults and failures. This work proposes a novel fault-tolerant scheduling approach for edge-IoT collaborative workflows. The proposed approach first conducts a dependency-based task allocation analysis, then leverages a Primary-Backup (PB) strategy for tolerating task failures that occur at edge nodes, and finally designs a deep Q-learning algorithm for identifying the near-optimal workflow task scheduling scheme. We conduct extensive simulative case studies on multiple randomly-generated workflow and real-world edge-IoT server position datasets. Results clearly suggest that our proposed method outperforms the state-of-the-art competitors in terms of task completion ratio, server active time, and resource utilization.展开更多
基金supported by the State Grid Science and Technology Project (No. 5455HT160004)
文摘In order to meet the pressing demand for wide-area communication required by the Global Energy Interconnection(GEI),accelerating the construction of satellite-terrestrial Integra怕d networks that can achieve network extension and seamless global coverage has become the focus of power communication tech no logy development.In this study,we propose a satellite-terrestrial integrated network model that can support interconnection and interoperation on the IP layer between the satellite system and the怕rrestrial segment of the existing power communication system.First,the composition and function of the satellite-terrestrial collaborative network are explained.Then,the IP-based protocol stack is described,and a typical applicati on experime nt is con ducted to illustrate the particular process of this protocol stack.Fin ally,a use case of IP interconn ection that depends on GEO satellite communication is detailed.The experime ntal study has showed that the satellite-terrestrial collaborative network can efficiently support various IP applications for the GEI.
基金supported by the National Natural Science Foundation of China(51804290,22075025)the Beijing Natural Science Foundation(L182023)+1 种基金the Science and Technology Project of Global Energy Interconnection Research Institute Co.Ltd.(SGGR0000WLJS1900858)the Beijing Institute of Technology Research Fund Program for Young Scholars(2019CX04092)。
文摘The dependence on portable devices and electrical vehicles has triggered the awareness on the energy storage systems with ever-growing energy density.Lithium metal batteries(LMBs)has revived and attracted considerable attention due to its high volumetric(2046 m Ah cm-3),gravimetric specific capacity(3862 m Ah g^(-1))and the lowest reduction potential(-3.04 V vs.SHE.).However,during the electrochemical process of lithium anode,the growth of lithium dendrite constitutes the biggest stumbling block on the road to LMBs application.The undesirable dendrite not only limit the Coulombic efficiency(CE)of LMBs,but also cause thermal runaway and other safety issues due to short-circuits.Understanding the mechanisms of lithium nucleation and dendrite growth provides insights to solve these problems.Herein,we summarize the electrochemical models that inherently describe the lithium nucleation and dendrite growth,such as the thermodynamic,electrodeposition kinetics,internal stress,and interface transmission models.Essential parameters of temperature,current density,internal stress and interfacial Li+flux are focused.To improve the LMBs performance,state-of-the-art optimization procedures have been developed and systematically illustrated with the intrinsic regulation principles for better lithium anode stability,including electrolyte optimization,artificial interface layers,threedimensional hosts,external field,etc.Towards practical applications of LMBs,the current development of pouch cell LMBs have been further introduced with different assembly systems and fading mechanism.However,challenges and obstacles still exist for the development of LMBs,such as in-depth understanding and in-situ observation of dendrite growth,the surface protection under extreme condition and the self-healing of solid electrolyte interface.
基金supported by the National Thousand Talents Plan of Chinathe National Natural Science Foundation of China(Grant Nos.21673014 and U1766216)+1 种基金the 111 project(B17002)funded by the Ministry of Education of Chinathe Fundamental Research Funds for the Central Universities of China
文摘Proton exchange membrane fuel cells(PEMFC)have attracted much attention because of their high energy conversion efficiency,high power density and zero emission of pollutants.However,the high cost of the cathode platinum group metal(PGM)catalysts creates a barrier for the large-scale application of PEMFC.Tremendous efforts have been devoted to the development of low-cost PGM-free catalysts,especially the Fe-N-C catalysts,to replace the expensive PGM catalysts.However,the characterization methods and evaluation standards of the catalysts varies,which is not conducive to the comparison of PGM-free catalysts.U.S.Department of energy(DOE)is the only authority that specifies the testing standards and activity targets for PGM-free catalysts.In this review,the major breakthroughs of Fe-N-C catalysts are outlined with the reference of DOE standards and targets.The preparation and characteristics of these highly active Fe-N-C catalysts are briefly introduced.Moreover,the efforts on improving the mass transfer and the durability issue of Fe-N-C fuel cell are discussed.Finally,the prospective directions concerning the comprehensive evaluation of the Fe-N-C catalysts are proposed.
基金supported in part by the US Office of Naval Research(N00014-16-1-312,N00014-18-1-2185)in part by the National Natural Science Foundation of China(61673347,U1609214,61751205)
文摘A microgrid is hard to control due to its reduced inertia and increased uncertainties. To overcome the challenges of microgrid control, advanced controllers need to be developed.In this paper, a distributed, two-level, communication-economic control scheme is presented for multiple-bus microgrids with each bus having multiple distributed generators(DGs) connected in parallel. The control objective of the upper level is to calculate the voltage references for one-bus subsystems. The objectives of the lower control level are to make the subsystems' bus voltages track the voltage references and to enhance load current sharing accuracy among the local DGs. Firstly, a distributed consensusbased power sharing algorithm is introduced to determine the power generations of the subsystems. Secondly, a discrete-time droop equation is used to adjust subsystem frequencies for voltage reference calculations. Finally, a Lyapunov-based decentralized control algorithm is designed for bus voltage regulation and proportional load current sharing. Extensive simulation studies with microgrid models of different levels of detail are performed to demonstrate the merits of the proposed control scheme.
基金supported by the Science and Technology Project of the State Grid Corporation of China,HVDC Systems/Grids for Transnational Interconnections(Project number:SGTYHT/16-JS-198).
文摘A hybrid of line commutated converters(LCCs)and modular multi-level converters(MMCs)can provide the advantages of both the technologies.However,the commutation failure still exists if the LCC operates as an inverter in a hybrid LCC/MMC system.In this paper,the system behavior during a commutation failure is investigated.Both halfbridge and full-bridge MMCs are considered.Control strategies are examined through simulations conducted in PSCAD/EMTDC.Additionally,commutation failure protection strategies for multi-terminal hybrid LCC/MMC systems with AC and DC circuit breakers are studied.This paper can contribute to the protection design of future hybrid LCC/MMC systems against commutation failures.
基金supported by National Key Research and Development Program of China Grant No. 2016YFB0900800Fok Ying-Tong Education Foundation China Grant No. 151058+2 种基金the State Key Laboratory of Advanced Power Transmission Technology Grant No. GEIRI-SKL-2018-014the Fundamental Research Funds for the Central Universities Grant No. 2019MS011Young Elite Scientists Sponsership Program by CAST Grant No. 2016QNRC001
文摘The effects of humidity on the ground-level resultant electric field around positive DC conductors were studied both experimentally and numerically. Experiments were carried out in an artificial climate chamber, the results of which showed that the photon count and the groundlevel resultant electric field strength both increased with increasing relative humidity. Numerical calculations for different values of relative humidity were carried out, including solutions of the positive corona inception voltage and the ion-flow field, for which a photoionization model and the upstream finite element method were employed, respectively. In order to analyze the effects of humidity, three main factors were considered: the ionization coefficient, the attachment coefficient in the photoionization model and the modified ion mobility of the charged water particles. The results indicated that, with increasing relative humidity, increasing values of the effective ionization coefficient were responsible for a reduction in the inception voltage, and the reduction reinforced the ground-level resultant electric field. Moreover, due to the charged water particles and the lower ion mobility with increasing relative humidity, the space charge density distribution was enhanced, which also strengthened the ground-level resultant electric field.
基金supported by State Grid Corporation of China(No.SGRIDGKJ[2016]123)Education Department of Guangxi Zhuang Autonomous Region(No.2019KY0021)the Natural Science Foundation of Guangxi Province(2019GXNSFBA185004,2018GXNSFAA281308,2019GXNSFAA245050)。
文摘Hydrogen can serve as a carrier to store renewable energy in large scale.However,hydrogen storage still remains a challenge in the current stage.It is difficult to meet the technical requirements applying the conventional storage of compressed gaseous hydrogen in high-pressure tanks or the solid-state storage of hydrogen in suitable materials.In the present work,a gaseous and solid-state(G-S)hybrid hydrogen storage system with a low working pressure below 5 MPa for a 10 kW hydrogen energy storage experiment platform is developed and validated.A Ti-Mn type hydrogen storage alloy with an effective hydrogen capacity of 1.7 wt%was prepared for the G-S hybrid hydrogen storage system.The G-S hybrid hydrogen storage tank has a high volumetric hydrogen storage density of 40.07 kg H_(2)m^(-3) and stores hydrogen under pressure below5 MPa.It can readily release enough hydrogen at a temperature as low as-15C when the FC system is not fully activated and hot water is not available.The energy storage efficiency of this G-S hybrid hydrogen storage system is calculated to be 86.4%-95.9%when it is combined with an FC system.This work provides a method on how to design a G-S hydrogen storage system based on practical demands and demonstrates that the G-S hybrid hydrogen storage is a promising method for stationary hydrogen storage application.
基金This work was supported by the National Natural Science Foundation of China(Grant:61702048).
文摘With the growing amounts of multi-micro grids,electric vehicles,smart home,smart cities connected to the Power Distribution Internet of Things(PD-IoT)system,greater computing resource and communication bandwidth are required for power distribution.It probably leads to extreme service delay and data congestion when a large number of data and business occur in emergence.This paper presents a service scheduling method based on edge computing to balance the business load of PD-IoT.The architecture,components and functional requirements of the PD-IoT with edge computing platform are proposed.Then,the structure of the service scheduling system is presented.Further,a novel load balancing strategy and ant colony algorithm are investigated in the service scheduling method.The validity of the method is evaluated by simulation tests.Results indicate that the mean load balancing ratio is reduced by 99.16%and the optimized offloading links can be acquired within 1.8 iterations.Computing load of the nodes in edge computing platform can be effectively balanced through the service scheduling.
基金supported by National Key Research and Development Program of China (2016YFB0900500,2017YFB0903100)the State Grid Science and Technology Project (SGRI-DL-F1-51-011)
文摘The AC/DC hybrid distribution network is one of the trends in distribution network development, which poses great challenges to the traditional distribution transformer. In this paper, a new topology suitable for AC/DC hybrid distribution network is put forward according to the demands of power grid, with advantages of accepting DG and DC loads, while clearing DC fault by blocking the clamping double sub-module(CDSM) of input stage. Then, this paper shows the typical structure of AC/DC distribution network that is hand in hand. Based on the new topology, this paper designs the control and modulation strategies of each stage, where the outer loop controller of input stage is emphasized for its twocontrol mode. At last, the rationality of new topology and the validity of control strategies are verified by the steady and dynamic state simulation. At the same time, the simulation results highlight the role of PET in energy regulation.
基金supported by the State Grid Science and Technology Project (GEIRI-DL-71-17-002)
文摘This paper introduces the implementation and data analysis associated with a state-wide power quality monitoring and analysis system in China. Corporation specifications on power quality monitors as well as on communication protocols are formulated for data transmission. Big data platform and related technologies are utilized for data storage and computation. Compliance verification analysis and a power quality performance assessment are conducted, and a visualization tool for result presentation is finally presented.
基金Supported by the State Key Laboratory of Advanced Power Transmission Technology(GEIRI-SKL-2018-005).
文摘A novel antibacterial acrylate polymer composite modified with capsaicin was successfully synthesized by a two-step reaction.Capsaicin and acryloyl chloride were firstly esterified,and then applied to solution polymerization with acrylate monomers and styrene.The yield of the esterified products was about 85.3%.The polymer was characterized by Fourier transform infrared spectroscopy(FTIR),gel permeation chromatography(GPC),thermogravimetric analysis(TGA),contact angle(CA)and antibacterial ring tests.The number-average molecular weight(M_n)of the polymer was 27214,based on the capsaicin-acrylate dosage of 6.5 wt%.The TGA revealed a stable thermal property.The contact angles of the polymers films on tinplate increased from 77.5°to 86.2°with the increasing amount of capsaicin-acrylate.The antibacterial tests demonstrated excellent antimicrobial capability of the polymers.
基金The authors acknowledge the financial support from the National Key Research and Development Program of China(No.2017YFB0903901).
文摘A Monte Carlo Potts model was developed to simulate the recrystallization process of a cold-rolled ultra-thin grain-oriented silicon steel.The orientation and image quality data from electron backscatter diffraction measurements were used as input information for simulation.Three types of nucleation mechanisms,namely,random nucleation,high-stored-energy site nucleation(HSEN),and high-angle boundary nucleation(HABN),were considered for simulation.In particular,the nucleation and growth behaviors of Goss-oriented({011}<100>)grains were investigated.Results showed that Goss grains had a nucleation advantage in HSEN and HABN.The amount of Goss grains was the highest according to HABN,and it matched the experimental measurement.However,Goss grains lacked a size advantage across all mechanisms during the recrystallization process.
基金support from National Natural Science Foundation of China(No.51977186)the China Postdoctoral Science Foundation(No.2019M650029)+3 种基金the Young Elite Scientists Sponsorship Program by CAST(No.2018QNRC001)the National Key R&D Program of China(No.2017YFB0902704)the State Key Development Program of Basic Research of China(973 Program)(No.2014CB239501)the Science and Technology Project of the State Grid Corp.of China(No.52110418001Y).
文摘The DC electrical resistivity-temperature characteristic is an important property for insulating materials to operate at a high stress level.In order to improve the DC electrical resistivity at elevated temperature in a targeted way,a positive temperature coefficient(PTC)material(Ba Ti O3-based compound(BT60))was selected as the filler in this paper,whose electrical resistivity has a PTC effect when the temperature exceeds its Curie temperature.The BT60 was treated with hydrogen peroxide and(3-Aminopropyl)triethoxysilane.Epoxy composites with different loadings of BT60 fillers(0 wt%,0.5 wt%,and 2 wt%of epoxy)were prepared,denoted as EP-0,EP-0.5,and EP-2.It was shown that BT60 was able to maintain the DC breakdown strength when its loading was less than 2 wt%of epoxy.As the temperature exceeds 60°C,BT60 will compensate for the negative temperature coefficient effect of epoxy resin to some extent.The electrical resistivity of EP-2 was improved by 55%compared with that of neat epoxy at 90°C.It was found that the potential barrier at the grain boundary of BT60 and the deep traps in the interface between BT60 and the epoxy resin hinder the migration of carriers and thus increase the electrical resistivity of epoxy composite.
基金financially supported by the National Key Research and Development Program of China(No 2016YFB0700505)the China’s State Grid Corporation of Science and Technology Projects(No.SGRI-WD71-13-002)+1 种基金the National Natural Science Foundation of China(Nos.51571020 and 51371030)the Nationa High Technology Research and Development Program of China(No.2015AA034201)
文摘The selective abnormal growth of Goss grains in magnetic sheets of Fe-3%Si (grade Hi-B) induced by second-phase particles (AlN and MnS) was studied using a modified Monte Carlo Ports model. The starting microstructures for the simulations were generated from electron backscatter diffraction (EBSD) orientation imaging maps of recrystallized samples. In the simulation, second-phase particles were assumed to be randomly distributed in the initial microstructures and the Zener drag effect of particles on Goss grain boundaries was assumed to be selectively invalid because of the unique properties of Goss grain boundaries. The simulation results suggest that normal growth of the matrix grains stagnates because of the pinning effect of particles on their boundaries. During the onset of abnormal grain growth, some Goss grains with concave boundaries in the initial microstructure grow fast abnormally and other Goss grains with convex boundaries shrink and eventually disappear.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61404098 and 61274079)the Doctoral Fund of Ministry of Education of China(Grant No.20130203120017)+2 种基金the National Key Basic Research Program of China(Grant No.2015CB759600)the National Grid Science&Technology Project,China(Grant No.SGRI-WD-71-14-018)the Key Specific Project in the National Science&Technology Program,China(Grant Nos.2013ZX02305002-002 and 2015CB759600)
文摘The effect of nitric oxide(NO) annealing on charge traps in the oxide insulator and transition layer in n-type4H–Si C metal–oxide–semiconductor(MOS) devices has been investigated using the time-dependent bias stress(TDBS),capacitance–voltage(C–V),and secondary ion mass spectroscopy(SIMS).It is revealed that two main categories of charge traps,near interface oxide traps(Nniot) and oxide traps(Not),have different responses to the TDBS and C–V characteristics in NO-annealed and Ar-annealed samples.The Nniotare mainly responsible for the hysteresis occurring in the bidirectional C–V characteristics,which are very close to the semiconductor interface and can readily exchange charges with the inner semiconductor.However,Not is mainly responsible for the TDBS induced C–V shifts.Electrons tunneling into the Not are hardly released quickly when suffering TDBS,resulting in the problem of the threshold voltage stability.Compared with the Ar-annealed sample,Nniotcan be significantly suppressed by the NO annealing,but there is little improvement of Not.SIMS results demonstrate that the Nniotare distributed within the transition layer,which correlated with the existence of the excess silicon.During the NO annealing process,the excess Si atoms incorporate into nitrogen in the transition layer,allowing better relaxation of the interface strain and effectively reducing the width of the transition layer and the density of Nniot.
基金supportedin part by Science and Technology Project of State Grid Corporation of China(SGIT0000KJJS1500008)Science and Technology Project of State Grid Corporation of China:“Research and Application of Distributed Energy Resource Public Information Service Platform based on Multisource Data Fusion and Mobile Internet Technologies”Science and Technology Project of State Grid Corporation of China:“Research on communication access technology for the integration, protection, and acquisition of multiple new energy resources”
文摘It has been shown that the deployment of device-to-device(D2D) communication in cellular systems can provide better support for local services. However, improper design of the hybrid system may cause severe interference between cellular and D2D links. In this paper, we consider transceiver design for the system employing multiple antennas to mitigate the interference. The precoder and decoder matrices are optimized in terms of sum mean squared error(MSE) and capacity, respectively. For the MSE minimization problem, we present an alternative transceiver optimization algorithm. While for the non-convex capacity maximization problem, we decompose the primal problem into a sequence of standard convex quadratic programs for efficient optimization. The evaluation of our proposed algorithms for performance enhancement of the entire D2D integrated cellular system is carried out through simulations.
基金supported by the State Key Laboratory of Advanced Power Transmission Technology (GEIRI-SKL-2021-014)。
文摘Adopting organic phase change materials(PCMs) for the management of electronic devices is restricted by low thermal conductivity. In this paper, the composite PCMs are established by freeze-drying and vacuum impregnation. Herein, polyethylene glycol(PEG) is induced as heat storage materials, boron nitride(BN) is embedded as filler stacking in an orderly fashion on the foam walls to improve thermal conductivity and sodium alginate(SA) is formed as supporting material to keep the shape of the composite stable. X-ray diffractometry, scanning electron microscopy-energy dispersive spectrometer, thermal gravimetric analysis, thermal conductivity meter, differential scanning calorimeter, and Fourier transform infrared were used to characterize the samples and thermal cycles were employed to measure the shape stability. The results exhibit the BN@SA/PEG composite PCMs have good chemical compatibility, stable morphology, and thermal stability. Due to the high porosity of foam, PEG endows the composite PCMs with high latent heat(149.11 and 141.59 J·g^(-1)). Simultaneously, BN@SA/PEG shows an excellent heat performance with high thermal conductivity(0.99 W·m^(-1)·K^(-1)), reusability, and shape stability, contributing the composite PCMs to application in the energy storage field. This study provides a strategy to manufacture flexible, long-serving, and shape-stable PCMs via introducing BN@SA foam as a storage framework, and these PCMs have great potential in thermal management in the electronic field.
基金Projects(51471149,51771171) supported by the National Natural Science Foundation of ChinaProject(2015C31029) supported by Public Project of Zhejiang Province,China
文摘LiBH4 was confined into activated charcoal(AC) by melt infiltration method(MI), and its effects on the hydrogen sorption properties were investigated. The N2 adsorption results reveal that melt infiltration method can effectively incorporated LiBH4 into AC. It can maintain the structural integrity of the scaffold and ensure the confinement effect. The nano-confined LiBH4/AC starts to release hydrogen at around 190 °C, which is 160 °C lower than that of pure LiBH4, and reaches a hydrogen desorption capacity of 13.6% at 400 °C. When rehydrogenated under the condition of 6 MPa H2 and 350 °C, it has a reversible hydrogen storage capacity of 6%, while pure LiBH4 shows almost no reversible hydrogen storage capacity under the same condition. Mass spectrometry analysis(MS) results suggest that no diborane or other impurity gases are released in the decomposition process. The apparent activation energy of dehydrogenation of LiBH4 after confinement into AC decreases from 156.0 to 121.1 k J/mol, which leads to the eminent enhancement of dehydrogenation kinetics of LiBH4.
基金supported by the Science and Technology Project of State Grid Corporation of China:Research and Application of Key Technologies in Virtual Operation of Information and Communication Resources.
文摘With the development of internet of vehicles,the traditional centralized content caching mode transmits content through the core network,which causes a large delay and cannot meet the demands for delay-sensitive services.To solve these problems,on basis of vehicle caching network,we propose an edge colla-borative caching scheme.Road side unit(RSU)and mobile edge computing(MEC)are used to collect vehicle information,predict and cache popular content,thereby provide low-latency content delivery services.However,the storage capa-city of a single RSU severely limits the edge caching performance and cannot handle intensive content requests at the same time.Through content sharing,col-laborative caching can relieve the storage burden on caching servers.Therefore,we integrate RSU and collaborative caching to build a MEC-assisted vehicle edge collaborative caching(MVECC)scheme,so as to realize the collaborative caching among cloud,edge and vehicle.MVECC uses deep reinforcement learning to pre-dict what needs to be cached on RSU,which enables RSUs to cache more popular content.In addition,MVECC also introduces a mobility-aware caching replace-ment scheme at the edge network to reduce redundant cache and improving cache efficiency,which allows RSU to dynamically replace the cached content in response to the mobility of vehicles.The simulation results show that the pro-posed MVECC scheme can improve cache performance in terms of energy cost and content hit rate.
基金supported National Key R&D Program of China with Grant number 2018YFB1403602Chongqing Technological innovation foundations with Grant numbers cstc2019jscx-msxm0652 and cstc2019jscx-fxyd0385+3 种基金Chongqing Key RD project with Grant number cstc2018jszx-cyzdX0081Jiangxi Key RD project with Grant number 2018ACE50029Sponsored by technological program organized by SGCC(No.52094020000U)Technology Innovation and Application Development Foundation of Chongqing under Grant cstc2020jscx-gksbX0010.
文摘As a newly emerging computing paradigm, edge computing shows great capability in supporting and boosting 5G and Internet-of-Things (IoT) oriented applications, e.g., scientific workflows with low-latency, elastic, and on-demand provisioning of computational resources. However, the geographically distributed IoT resources are usually interconnected with each other through unreliable communications and ever-changing contexts, which brings in strong heterogeneity, potential vulnerability, and instability of computing infrastructures at different levels. It thus remains a challenge to enforce high fault-tolerance of edge-IoT scientific computing task flows, especially when the supporting computing infrastructures are deployed in a collaborative, distributed, and dynamic environment that is prone to faults and failures. This work proposes a novel fault-tolerant scheduling approach for edge-IoT collaborative workflows. The proposed approach first conducts a dependency-based task allocation analysis, then leverages a Primary-Backup (PB) strategy for tolerating task failures that occur at edge nodes, and finally designs a deep Q-learning algorithm for identifying the near-optimal workflow task scheduling scheme. We conduct extensive simulative case studies on multiple randomly-generated workflow and real-world edge-IoT server position datasets. Results clearly suggest that our proposed method outperforms the state-of-the-art competitors in terms of task completion ratio, server active time, and resource utilization.