The Mg-5Sn-1Ca-xGd (x=0, 1) alloys were chosen to investigate the change in solidification paths, phase formation and mechanical properties. The microstructure of as-cast Mg-5Sn-1Ca alloy is composed of α-Mg, Mg2Sn a...The Mg-5Sn-1Ca-xGd (x=0, 1) alloys were chosen to investigate the change in solidification paths, phase formation and mechanical properties. The microstructure of as-cast Mg-5Sn-1Ca alloy is composed of α-Mg, Mg2Sn and CaMgSn phases. With the addition of Gd, the formation of the Mg2Sn phase is impeded and the CaMgSn phase is refined, whereas the ultimate tensile strength and elongation decrease. The possible reasons for the variation in microstructure and mechanical properties were discussed.展开更多
The potential—pH diagrams of the Cr-H2O system at temperatures of 298, 323, 373 and 423 K were established through thermodynamic calculation with coupling of experimental results. The potential—pH diagram at 298 K a...The potential—pH diagrams of the Cr-H2O system at temperatures of 298, 323, 373 and 423 K were established through thermodynamic calculation with coupling of experimental results. The potential—pH diagram at 298 K agrees well with the previously reported results. Based on the potential—pH diagrams of the Cr-H2O and Fe-H2O systems, IR spectra and XRD pattern, the existence forms of iron in the potassium chromate were analyzed, and the methods of iron removal were investigated. The results show that the existence forms of iron in the potassium chromate are potassium ferrate. These results are instructive and helpful to the hydrometallurgical processing of chromite ore.展开更多
基金Project(2007CB613704) supported by National Basic Research Program of China
文摘The Mg-5Sn-1Ca-xGd (x=0, 1) alloys were chosen to investigate the change in solidification paths, phase formation and mechanical properties. The microstructure of as-cast Mg-5Sn-1Ca alloy is composed of α-Mg, Mg2Sn and CaMgSn phases. With the addition of Gd, the formation of the Mg2Sn phase is impeded and the CaMgSn phase is refined, whereas the ultimate tensile strength and elongation decrease. The possible reasons for the variation in microstructure and mechanical properties were discussed.
基金Project(2007CB613501) supported by the National Basic Research Program of ChinaProject(2006BAC02A05) supported by the National Science and Technology Pillar Program of ChinaProject(50904058) supported by the National Natural Science Foundation of China
文摘The potential—pH diagrams of the Cr-H2O system at temperatures of 298, 323, 373 and 423 K were established through thermodynamic calculation with coupling of experimental results. The potential—pH diagram at 298 K agrees well with the previously reported results. Based on the potential—pH diagrams of the Cr-H2O and Fe-H2O systems, IR spectra and XRD pattern, the existence forms of iron in the potassium chromate were analyzed, and the methods of iron removal were investigated. The results show that the existence forms of iron in the potassium chromate are potassium ferrate. These results are instructive and helpful to the hydrometallurgical processing of chromite ore.
