Analysis on the Trend of Water Quality in Haihe River Basin from 2005 to 2017

Haihe River is one of the 7 largest rivers in China. The problem of water pollution in Haihe River Basin is serious. The water quality of Haihe River Basin is generally the best in the north and the worst in the south. And the water quality of the Luanhe River is the best, the proportion of I - III is about 60%, and the water quality of the Tuhaimajia River is the worst, the proportion of >V exceeds 60%. According to the trend of water quality change, the improvement of Shandong Province in Tuhaimajia River system is the most obvious, and proportion of >V water decreased from 100% to about 30%.

Responses of soil moisture to vegetation restoration type and slope length on the loess hillslope

Soil moisture, a critical variable in the hydrologic cycle, is highly influenced by vegetation restoration type. However, the relationship between spatial variation of soil moisture, vegetation restoration type and slope length is controversial. Therefore, soil moisture across soil layers(0-400 cm depth) was measured before and after the rainy season in severe drought(2015) and normal hydrological year(2016) in three vegetation restoration areas(artificial forestland, natural forestland and grassland), on the hillslopes of the Caijiachuan Catchment in the Loess area, China. The results showed that artificial forestland had the lowest soil moisture and most severe water deficit in 100-200 cm soil layers. Water depletion was higher in artificial and natural forestlands than in natural grassland. Moreover, soil moisture in the shallow soil layers(0-100 cm) under the three vegetation restoration types did not significantly vary with slope length, but a significant increase with slope length was observed in deep soil layers(below 100 cm). In2015, a severe drought hydrological year, higher water depletion was observed at lower slope positions under three vegetation restoration types due to higher transpiration and evapotranspiration and unlikely recharge from upslope runoff. However, in 2016, a normal hydrological year, there was lower water depletion, even infiltration recharge at lower slope positions, indicating receiving a large amount of water from upslope. Vegetation restoration type, precipitation, slope length and soil depth during a rainy season, in descending order of influence, had significant effects on soil moisture. Generally, natural grassland is more beneficial for vegetation restoration than natural and artificial forestlands, and the results can provide useful information for understanding hydrological processes and improving vegetation restoration practices on the Loess

Multi-dimensional overall regulatory modes and threshold values for water cycle of the Haihe River Basin

In this study, a multi-dimensional critical regulatory criteria and decision-making mechanism based on the scientific cognition of multi-dimensional attributes and characteristics of the water cycle was proposed. This system was functioned by deeply discriminating the nature-society binary characteristics of the five-dimensional characteristics of the water cycle system of the Haihe River Basin (water resources, economy, society, ecology, and environment) under the influence of high-intensity human activities and hydrological changes and by analyzing the organic interactive relationships between the five dimensions and their overall effect on the water cycle. A GDP calculation model was constructed in this study by adjusting the water environment for water resources, after which five-dimensional normalization objective functions were established for multi-objective analysis to carry out trade-off analysis of multi-dimensional regulatory indexes. In addition, synergetic theory, entropy theory and dissipation structure theory were introduced to construct an evaluation model for multi-dimensional regulatory schemes. A water cycle multi-dimensional critical overall regulatory model system was also established. This system consisted of a multi-objective macroeconomic model (DAMOS), water resource allocation model based on rules (ROWAS), evaluation model for WEDP (EMW) and multi-dimensional regulatory scheme evaluation model (SEAMUR) as the main body. To address the national demands faced by the Haihe River Basin as a result of combinatorial schemes for different hydrological series and water amounts diverted by the south-to-north water diversion project, this study adopted a hierarchy progression method to set up the technologies, investigated multi-dimensional overall regulatory methods, proposed an overall regulation threshold value for the water cycle of the Haihe River Basin, and recommended corresponding five-dimensional regulatory schemes.

Sulfur Isotopes of Framboidal Pyrite in the Permian-Triassic Boundary Clay at Meishan Section

Pyrite framboids were found in the Permian-Triassic boundary at Meishan Section,while their sulfur isotopes were determined.The majority of framboids is less than 5μm in diameter,with some large-sized framboids.Also,euhedral gypsums were observed in the boundary clay.The authors suppose that most of the pyrite framboids formed just below the redox boundary and stopped growing after entering the lower water column.The result indicates that it was probably lower dysoxia condition in the temporal ocean.Moreover,the authors also presume that some pyrite was oxidated to sulfates accompanying the fluctuation of redox condition,which would probably be the origin of the negative sulfur isotopes of gypsum and CAS reported before.In addition,sulfur isotope of framboidal pyrite suggests that sulfur is originated from bacterial sulfate reduction in anoxic condition.Therefore, this study confirms that the ocean was widely anoxic during the Permian-Triassic transitional period. However,the redox condition in temporal ocean was probably not stable,with short-term fluctuations.

HPLC separation of higher fullerenes in the synthetical "graphite smokes" soot

Higher fullerenes(C84,C90,C92,C94 and C96) were successfully isolated from the Soxhlet extract of the synthetical "Graphote Smokes" soot(GS sample) by using a big Cosmosil Buckysep(Phenomenex) column(250 mm × 10 mm) with a large injection.The fractions isolated have been determined by high performance liquid chro-matography(HPLC) and laser desorption mass spectrometry(LDMS).It is found that there are different fullerenes molecules in different fractions with retention time.The result indicates that fullerenes do exist in GS samples.Also,it excludes the suspicion to some extent that fullerene molecules might be generated by the laser desorption process in the LDMS.In addition,it also provides the experimental basis for the study of natural higher fullerenes and might be helpful to figure out the question if higher fullerenes do exist in the natural samples.

River basin water resource compensation characteristics by set pair analysis： the Dongiiang example

Flood and drought coexist in many river basins, thus analyses of water resource compensation characteristics become important, since they are the foundation for rational utilization of floodwaters. In this research, set pair analysis （SPA）, a relatively new uncertainty analysis method, is used to study the dry and wet compensation characteristics of water resource para- meters. In addition, fuzzy membership and grey correlation degree are adopted to test the result of set pair analysis. The Dongjiang River is taken as an example and the analyzed parameters include precipitation and mean discharge from different hydrological stations. The results show that there is a high homeotype-encountering chance for precipitation and mean discharge between different stations for both dry and wet conditions; thus the compensation capacity is small. Although the mean discharge is synchronous with the precipitation in the river basin, there exists a certain degree of shift, indicating possible utilization of floodwater on a small scale. The results from SPA are consistent with that from a traditional analysis method, showing that SPA is a promising alternative method for studying river basin water resource compensation characteristics, in particular for exploring potential complements embedded in non- complementary general features.

Optimizing the operation of the Qingshitan Reservoir in the Lijiang River for multiple human interests and quasi-natural flow maintenance

For reservoir operation, maintaining a quasi-natural flow regime can benefit river ecosystems, but may sacrifice human interests. This study took the Qingshitan Reservoir in the Lijiang River as a case, and developed an optimization model to explore a trade-off solution between social-economic interests and nature flow maintenance on a monthly base. The objective function considered irrigation, cruise navigation and water supply aspects. An index of flow alteration degree was proposed to measure the difference between the regulated discharge and the natural flow. The index was then used as an additional constraint in the model besides the conventional constraints on reservoir safety. During model solving, different criteria were applied to the index, representing various degrees of alteration of the natural flow regime in the river. Through the model, a relationship between social-economic interests and flow alteration degree was established. Finally, a trade-off solution of the reservoir operation was defined that led to a favorable social-economic benefit at an acceptable alteration of the natural flow.

Patterns and drivers of CH_(4) concentration and diffusive flux from a temperate river–reservoir system in North China

Freshwater reservoirs are regarded as an important anthropogenic source of methane(CH_(4))emissions. The temporal and spatial variability of CH_(4) emissions from different reservoirs results in uncertainty in the estimation of the global CH_(4) budget. In this study, surface water CH_(4) concentrations were measured and diffusive CH_(4) fluxes were estimated via a thin boundary layer model in a temperate river–reservoir system in North China, using spatial(33 sites) and temporal(four seasons) monitoring;the system has experienced intensive aquaculture disturbance. Our results indicated that the dissolved CH_(4) concentration in the reservoir ranged from 0.07 to 0.58 μmol/L, with an annual average of 0.13 ± 0.10 μmol/L, and the diffusive CH_(4) flux across the water–air interface ranged from 0.66 to 3.61 μmol/(m^(2)·hr),with an annual average of 1.67 ± 0.75 μmol/(m^(2)·hr). During the study period, the dissolved CH_(4) concentration was supersaturated and was a net source of atmospheric CH_(4) . Notably,CH_(4) concentration and diffusive flux portrayed large temporal and spatial heterogeneity.The river inflow zone was determined to be a hotspot for CH_(4) emissions, and its flux was significantly higher than that of the tributary and main basin;the CH_(4) flux in autumn was greater than that in other seasons. We also deduced that the CH_(4) concentration/diffusive flux was co-regulated mainly by water temperature, water depth, and water productivity(Chla, trophic status). Our results highlight the importance of considering the spatiotemporal variability of diffusive CH_(4) flux from temperate reservoirs to estimate the CH_(4) budget at regional and global scales.