The title compound, [Co（C3H4N2）2（C22H18N2O4）]·5H2O （Mr = 659.56）, has been prepared and its crystal structure was determined by X-ray diffraction method. The crystal belongs to monoclinic, space group P21/n...The title compound, [Co（C3H4N2）2（C22H18N2O4）]·5H2O （Mr = 659.56）, has been prepared and its crystal structure was determined by X-ray diffraction method. The crystal belongs to monoclinic, space group P21/n, a = 9.6808（2）, b = 26.7204（5）, c = 12.7993（3） A, β = 100.9340（10）°, V= 3250.75（12） A^3, Z = 4, Dc = 1.348 g/cm^3,μ = 0.586 mm^-1, F（000） = 1380, S = 1.131, R = 0.0689 and wR = 0.1883 for 4782 observed reflections （Ⅰ 〉 2σ（Ⅰ））. The title crystal consists of Co（Ⅱ） complex and lattice water molecules. The Co（Ⅱ） complex assumes a distorted octahedral coordination geometry, formed by one Schiff base dianion phenylenediamine-3-methoxysali-cylaldehyde and two imidazole ligands. The π-π stacking interaction occurs between nearly parallel benzene rings of the neighboring complexes.展开更多
This work provides an accurate study of the spin-l/2 relativistic particle in a magnetic field in NC phase space. By detailed calculation we find that the Dirac equation of the relativistic particle in a magnetic fiel...This work provides an accurate study of the spin-l/2 relativistic particle in a magnetic field in NC phase space. By detailed calculation we find that the Dirac equation of the relativistic particle in a magnetic field in noncommutative space has similar behaviour to what happens in the Landau problem in commutative space even if an exact map does not exist. By solving the Dirac equation in NC phase space, we not only obtain the energy level of the spin-1/2 relativistic particle in a magnetic field in NC phase space but also explicitly offer some additional terms related to the momentum-momentum non-commutativity.展开更多
基金The project was supported by the Zhejiang Provincial Natural Science Foundation of China (No. R203154)
文摘The title compound, [Co（C3H4N2）2（C22H18N2O4）]·5H2O （Mr = 659.56）, has been prepared and its crystal structure was determined by X-ray diffraction method. The crystal belongs to monoclinic, space group P21/n, a = 9.6808（2）, b = 26.7204（5）, c = 12.7993（3） A, β = 100.9340（10）°, V= 3250.75（12） A^3, Z = 4, Dc = 1.348 g/cm^3,μ = 0.586 mm^-1, F（000） = 1380, S = 1.131, R = 0.0689 and wR = 0.1883 for 4782 observed reflections （Ⅰ 〉 2σ（Ⅰ））. The title crystal consists of Co（Ⅱ） complex and lattice water molecules. The Co（Ⅱ） complex assumes a distorted octahedral coordination geometry, formed by one Schiff base dianion phenylenediamine-3-methoxysali-cylaldehyde and two imidazole ligands. The π-π stacking interaction occurs between nearly parallel benzene rings of the neighboring complexes.
基金Supported by NSFC (10447005,10575026)Open Research of SKLSM (CHJG 200902)Abdus Sdam ICTP Trieste,Italy
文摘This work provides an accurate study of the spin-l/2 relativistic particle in a magnetic field in NC phase space. By detailed calculation we find that the Dirac equation of the relativistic particle in a magnetic field in noncommutative space has similar behaviour to what happens in the Landau problem in commutative space even if an exact map does not exist. By solving the Dirac equation in NC phase space, we not only obtain the energy level of the spin-1/2 relativistic particle in a magnetic field in NC phase space but also explicitly offer some additional terms related to the momentum-momentum non-commutativity.
