External disturbance is an important cause of underground pressure pipeline damage,which leads to accidents,and it is crucial to study the risk of damage caused by external disturbance and come up with proper preventi...External disturbance is an important cause of underground pressure pipeline damage,which leads to accidents,and it is crucial to study the risk of damage caused by external disturbance and come up with proper prevention and control measures.We reviewed literature on risk identification of underground pressure pipelines damage due to external disturbance was conducted,and a list of risk factors was formed.Based on the list of risk factors,fault tree analysis was carried out on underground pressure pipelines damage caused by external disturbances,and risk prevention and control measures were proposed through the calculation of minimum cut sets,minimum path sets,and structural importance,in hopes of providing reference for the normal operation of underground pressure pipelines.展开更多
The study of the panic evacuation process is of great significance to emergency management.Panic not only causes negative emotions such as irritability and anxiety,but also affects the pedestrians decision-making proc...The study of the panic evacuation process is of great significance to emergency management.Panic not only causes negative emotions such as irritability and anxiety,but also affects the pedestrians decision-making process,thereby inducing the abnormal crowd behavior.Prompted by the epidemiological SIR model,an extended floor field cellular automaton model was proposed to investigate the pedestrian dynamics under the threat of hazard resulting from the panic contagion.In the model,the conception of panic transmission status(PTS)was put forward to describe pedestrians’behavior who could transmit panic emotions to others.The model also indicated the pedestrian movement was governed by the static and hazard threat floor field.Then rules that panic could influence decision-making process were set up based on the floor field theory.The simulation results show that the stronger the pedestrian panic,the more sensitive pedestrians are to hazards,and the less able to rationally find safe exits.However,when the crowd density is high,the panic contagion has a less impact on the evacuation process of pedestrians.It is also found that when the hazard position is closer to the exit,the panic will propagate for a longer time and have a greater impact on the evacuation.The results also suggest that as the extent of pedestrian’s familiarity with the environment increases,pedestrians spend less time to escape from the room and are less sensitive to the hazard.In addition,it is essential to point out that,compared with the impact of panic contagion,the pedestrian’s familiarity with environment has a more significant influence on the evacuation.展开更多
Solid polymer electrolytes(SPEs)have attracted extensive attention by virtue of lightweight and flexible processability for solidstate lithium metal batteries(LMBs)with high energy density and intrinsic safety.However...Solid polymer electrolytes(SPEs)have attracted extensive attention by virtue of lightweight and flexible processability for solidstate lithium metal batteries(LMBs)with high energy density and intrinsic safety.However,the SPEs suffer from the trade-off effect between ionic conductivity and mechanical strength.Herein,we report an ionic solid-like conductor with high Li+conductivity and good thermal stability as the conductive phase of polymer electrolytes for advanced LMBs.Using poly(vinylidene fluoride-co-hexafluoropropylene)(PVDF-HFP)as the polymer matrix,the ionic solid-like conductor can be regarded as a solid plasticizer due to its advantages of non-fluidity and non-leakage.It increases the amorphous region and the dissociation degree of lithium salts in SPEs,while minimizing the loss of mechanical properties.As a result,the Li+conductivity of SPEs incorporating the ionic solid-like conductor is enhanced by four orders of magnitude compared to the blank PVDF-HFPbased electrolyte.The optimized SPE membranes can be processed as thin as 50μm with a high Young's modulus of 16.8 MPa,therefore ensuring stable long-term cycling of solid-state LMBs.The Li/Li symmetric cells stably cycled for more than 750 h without short circuits,and the LiFePO_(4)/Li solid-state batteries demonstrate excellent electrochemical performance over 350cycles with a capacity retention of 82.5%.This work provides a new strategy for designing ionic solid-like conductors as solid plasticizers for high-performance polymer electrolytes.展开更多
Semiconductor photocatalytic technology has shown great prospects in converting solar energy into chemical energy to mitigate energy crisis and solve environmental pollution problems.The key issue is the development o...Semiconductor photocatalytic technology has shown great prospects in converting solar energy into chemical energy to mitigate energy crisis and solve environmental pollution problems.The key issue is the development of high-efficiency photocatalysts.Various strategies in the state-of-the-art advancements,such as heterostructure construction,heteroatom doping,metal/single atom loading,and defect engineering,have been presented for the graphitic carbon nitride(g-C3N4)-based nanocomposite catalysts to design their surface chemical environments and internal electronic structures to make them more suitable for different photocatalytic applications.In this review,nanoarchitecture design,synthesis methods,photochemical properties,potential photocatalytic applications,and related reaction mechanisms of the modified high-efficiency carbon nitride-based photocatalysts were briefly summarized.The superior photocatalytic performance was identified to be associated with the enhanced visible-light response,fast photoinduced electron-hole separation,efficient charge migration,and increased unsaturated active sites.Moreover,the further advance of the visible-light harvesting and solar-to-energy conversions are proposed.展开更多
This study involved the construction and explosion of a large-scale(80-meter-long)underdrain and detailed investigations of the damaging impacts of a gas explosion to provide an experimental foundation for similarity ...This study involved the construction and explosion of a large-scale(80-meter-long)underdrain and detailed investigations of the damaging impacts of a gas explosion to provide an experimental foundation for similarity modeling and infrastructural designs.The experiment vividly recreated the scene and explosion damage of the"11.22″explosion accident in Qingdao,China,thus allowing for evaluations of the movements and destruction of the cover plates.The damage mechanism was determined by analyzing the overpressure curves inside and outside the underground canal.It was determined that the cover plates were first lifted by the precursor wave,which induced a maximum overpressure of 0.06 MPa and resulted in explosion venting.The pressure entered the deflagration stage at the end of the explosion.The combustion wave overpressure reached 3.115 MPa close to the initiation point,and had a significant influence on the projectile energy of the cover plates there.Overall,64%of the cover plates were only affected by the precursor wave,while 36%of the cover plates were subjected to both the precursor wave and the combustion wave;these cover plates were severely damaged.The results of this study provide fundamental insights relevant to the prevention and control of underdrain gas explosions.展开更多
基金This project was funded by Consulting Research Project of Chinese Academy of Engineering:Research on Innovative Development Strategy of Urban Safety Engineering(Project number:2020-02)。
文摘External disturbance is an important cause of underground pressure pipeline damage,which leads to accidents,and it is crucial to study the risk of damage caused by external disturbance and come up with proper prevention and control measures.We reviewed literature on risk identification of underground pressure pipelines damage due to external disturbance was conducted,and a list of risk factors was formed.Based on the list of risk factors,fault tree analysis was carried out on underground pressure pipelines damage caused by external disturbances,and risk prevention and control measures were proposed through the calculation of minimum cut sets,minimum path sets,and structural importance,in hopes of providing reference for the normal operation of underground pressure pipelines.
基金supported by the National Key Technology Research and Development Program of China(Grant No.2019YFC0810804)the National Natural Science Foundation of China(Grant No.7197010332)。
文摘The study of the panic evacuation process is of great significance to emergency management.Panic not only causes negative emotions such as irritability and anxiety,but also affects the pedestrians decision-making process,thereby inducing the abnormal crowd behavior.Prompted by the epidemiological SIR model,an extended floor field cellular automaton model was proposed to investigate the pedestrian dynamics under the threat of hazard resulting from the panic contagion.In the model,the conception of panic transmission status(PTS)was put forward to describe pedestrians’behavior who could transmit panic emotions to others.The model also indicated the pedestrian movement was governed by the static and hazard threat floor field.Then rules that panic could influence decision-making process were set up based on the floor field theory.The simulation results show that the stronger the pedestrian panic,the more sensitive pedestrians are to hazards,and the less able to rationally find safe exits.However,when the crowd density is high,the panic contagion has a less impact on the evacuation process of pedestrians.It is also found that when the hazard position is closer to the exit,the panic will propagate for a longer time and have a greater impact on the evacuation.The results also suggest that as the extent of pedestrian’s familiarity with the environment increases,pedestrians spend less time to escape from the room and are less sensitive to the hazard.In addition,it is essential to point out that,compared with the impact of panic contagion,the pedestrian’s familiarity with environment has a more significant influence on the evacuation.
基金supported by the National Key Research and Development Program of China(2023YFB2503700,and 2023YFC3008804)the National Natural Science Foundation of China(22071133)+1 种基金Beijing Municipal Science&Technology Commission(Z231100006123003)the Science Foundation of China Academy of Safety Science and Technology(2023JBKY17)。
文摘Solid polymer electrolytes(SPEs)have attracted extensive attention by virtue of lightweight and flexible processability for solidstate lithium metal batteries(LMBs)with high energy density and intrinsic safety.However,the SPEs suffer from the trade-off effect between ionic conductivity and mechanical strength.Herein,we report an ionic solid-like conductor with high Li+conductivity and good thermal stability as the conductive phase of polymer electrolytes for advanced LMBs.Using poly(vinylidene fluoride-co-hexafluoropropylene)(PVDF-HFP)as the polymer matrix,the ionic solid-like conductor can be regarded as a solid plasticizer due to its advantages of non-fluidity and non-leakage.It increases the amorphous region and the dissociation degree of lithium salts in SPEs,while minimizing the loss of mechanical properties.As a result,the Li+conductivity of SPEs incorporating the ionic solid-like conductor is enhanced by four orders of magnitude compared to the blank PVDF-HFPbased electrolyte.The optimized SPE membranes can be processed as thin as 50μm with a high Young's modulus of 16.8 MPa,therefore ensuring stable long-term cycling of solid-state LMBs.The Li/Li symmetric cells stably cycled for more than 750 h without short circuits,and the LiFePO_(4)/Li solid-state batteries demonstrate excellent electrochemical performance over 350cycles with a capacity retention of 82.5%.This work provides a new strategy for designing ionic solid-like conductors as solid plasticizers for high-performance polymer electrolytes.
基金supported by the Natural Science Foundation of Anhui Province (No. 1908085ME165)the Anhui Provincial Natural Science Key Foundation (No. 2008085UD07)the Special Funds for the Development of Local Science and Technology from the Central Government in Anhui Province (No. 803214271050)
文摘Semiconductor photocatalytic technology has shown great prospects in converting solar energy into chemical energy to mitigate energy crisis and solve environmental pollution problems.The key issue is the development of high-efficiency photocatalysts.Various strategies in the state-of-the-art advancements,such as heterostructure construction,heteroatom doping,metal/single atom loading,and defect engineering,have been presented for the graphitic carbon nitride(g-C3N4)-based nanocomposite catalysts to design their surface chemical environments and internal electronic structures to make them more suitable for different photocatalytic applications.In this review,nanoarchitecture design,synthesis methods,photochemical properties,potential photocatalytic applications,and related reaction mechanisms of the modified high-efficiency carbon nitride-based photocatalysts were briefly summarized.The superior photocatalytic performance was identified to be associated with the enhanced visible-light response,fast photoinduced electron-hole separation,efficient charge migration,and increased unsaturated active sites.Moreover,the further advance of the visible-light harvesting and solar-to-energy conversions are proposed.
基金The authors gratefully acknowledge financial support given by the National 135 Key R and D Projects(Grant Nos.2018YFF0301000)as well as from the National Science Foundation of China(Grant Nos.71861167002,51834007).
文摘This study involved the construction and explosion of a large-scale(80-meter-long)underdrain and detailed investigations of the damaging impacts of a gas explosion to provide an experimental foundation for similarity modeling and infrastructural designs.The experiment vividly recreated the scene and explosion damage of the"11.22″explosion accident in Qingdao,China,thus allowing for evaluations of the movements and destruction of the cover plates.The damage mechanism was determined by analyzing the overpressure curves inside and outside the underground canal.It was determined that the cover plates were first lifted by the precursor wave,which induced a maximum overpressure of 0.06 MPa and resulted in explosion venting.The pressure entered the deflagration stage at the end of the explosion.The combustion wave overpressure reached 3.115 MPa close to the initiation point,and had a significant influence on the projectile energy of the cover plates there.Overall,64%of the cover plates were only affected by the precursor wave,while 36%of the cover plates were subjected to both the precursor wave and the combustion wave;these cover plates were severely damaged.The results of this study provide fundamental insights relevant to the prevention and control of underdrain gas explosions.