Preparation of hierarchical mesoporous Zn/HZSM-5 catalyst and its application in MTG reaction

The hierarchical mesoporous Zn/ZSM-5 zeolite catalyst was prepared by NaOH treatment and Zn impregnation, and its application in the conversion of methanol to gasoline （MTG） was studied. N2 adsorption-desorption results showed that the mesopores with sizes of 2-20 nm in HZ5/0.3AT was formed by 0.3 M NaOH alkali treatment. The zeolite samples after modification were also characterized by XRF, AAS, XRD, SEM and NH3-TPD methods. Zn impregnated catalyst Zn/HZ5/0.3AT exhibited dramatic improvements in catalytic lifetime and liquid hydrocarbons yield. The selectivity of aromatic hydrocarbons was also improved after Zn impregnation. It is suggested that the mesopores of Zn/HZ5/0.3AT enhanced the synergetic effect of Zn species and acid sites and the capability to coke tolerance, which were confirmed by the results of catalytic test and TGA analysis, respectively.

Efficacy and safety of bevacizumab plus chemotherapy in Chinese patients with metastatic colorectal cancer:a randomized phase Ⅲ ARTIST trial

The efficacy and safety of bevacizumab with modified irinotecan,leucovorin bolus,and 5-fluorouracil intravenous infusion(mIFL) in the first-line treatment of metastatic colorectal cancer(mCRC) has not been well evaluated in randomized clinical trials in Chinese patients.We conducted a phrase Ⅲ trial in which patients with previously untreated mCRC were randomized 2:1 to the mIFL [irinotecan(125 mg/m2),leucovorin(20 mg/m2) bolus,and 5-fluorouracil intravenous infusion(500 mg/m2) weekly for four weeks every six weeks] plus bevacizumab(5 mg/kg every two weeks) group and the mIFL group,respectively.Co-primary objectives were progression-free survival(PFS) and 6-month PFS rate.In total,214 patients were enrolled.Our results showed that addition of bevacizumab to mIFL significantly improved median PFS(4.2 months in the mIFL group vs.8.3 months in the bevacizumab plus mIFL group,P < 0.001),6-month PFS rate(25.0% vs.62.6%,P < 0.001),median overall survival(13.4 months vs.18.7 months,P = 0.014),and response rate(17% vs.35%,P = 0.013).Grades 3 and 4 adverse events included diarrhea(21% in the mIFL group and 26% in the bevacizumab plus mIFL group) and neutropenia(19% in the mIFL group and 33% in the bevacizumab plus mIFL group).No wound-healing complications or congestive heart failure occurred.Our results suggested that bevacizumab plus mIFL is effective and well tolerated as first-line treatment for Chinese patients with mCRC.Clinical benefit and safety profiles were consistent with those observed in pivotal phase Ⅲ trials with mainly Caucasian patients.

Removal of Nitrogen, Phosphorus, and Organic Pollutants From Water Using Seeding Type Immobilized Microorganisms

Objective To study the possibility of removing nitrogen, phosphorus, and organic pollutants using seeding type immobilized microorganisms. Methods Lakes P and M in Wuhan were chosen as the objects to study the removal of nitrogen, phosphorus, and organic pollutants with the seeding type immobilized microorganisms. Correlations between the quantity of heterotrophic bacteria and the total nitrogen （TN）, total phosphorus （TP）, and total organic carbon （TOC） in the two lakes were studied. The dominant bacteria were detected, inoculated to the sludge and acclimated by increasing nitrogen, phosphorus and decreasing carbon source in an intermittent, time-controlled and fixed-quantity way. The bacteria were then used to prepare the seeding type immobilized microorganisms, selecting diatomite as the adsorbent cartier. The ability and influence factors of removing nitrogen, phosphorus, and organic pollutant from water samples by the seeding type immobilized microorganisms were studied. Results The coefficients of the heterotrophic bacterial quantity correlated with TOC, TP, and TN were 0.9143, 0.8229, 0.7954 in Lake P and 0.9168, 0.7187, 0.6022 in Lake M. Ten strains of dominant heterotrophic bacteria belonging to Pseudomonas, Coccus, Aeromonas, Bacillus, and Enterobateriaceae, separately, were isolated. The appropriate conditions for the seeding type immobilized microorgansims in purifying the water sample were exposure time=24 h, pH=7.0-8.0, and quantity of the immobilized microorganisms=0.75-1g/50 mL. The removal rates of TOC, TP, and TN under the above conditions were 80.2%, 81.6%, and 86.8%, respectively. Conclusion The amount of heterotrophic bacteria in the two lakes was correlated with TOC, TP, and TN. These bacteria could be acclimatized and prepared for the immobilized microorganisms which could effectively remove nitrogen, phosphorus, and mixed organic pollutants in the water sample.

Stable Flocking Motion of Mobile Agents Following a Leader in Fixed and Switching Networks

Multiple mobile agents with double integrator dynamics, following a leader to achieve a flocking motion formation, are studied in this paper. A class of local control laws for a group of mobile agents is proposed. From a theoretical proof, the following conclusions are reached： （i） agents globally align their velocity vectors with a leader, （ii） they converge their velocities to the leaders velocity, （iii） collisions among interconnected agents are avoided, and （iv） agent＇s artificial potential functions are minimized. We model the interaction and/or communication relationship between agents by algebraic graph theory. Stability analysis is achieved by using classical Lyapunov theory in a fixed network topology, and differential inclusions and nonsmooth analysis in a switching network topology respectively. Simulation examples are provided.

Co-design for an SoC embedded network controller

With the development of Ethernet systems and the growing capacity of modem silicon technology, embedded communication networks are playing an increasingly important role in embedded and safety critical systems. Hardware/software co-design is a methodology for solving design problems in processor based embedded systems. In this work, we implemented a new 1-cycle pipeline microprocessor and a fast Ethemet transceiver and established a low cost, high performance embedded network controller, and designed a TCP/IP stack to access the Intemet. We discussed the hardware/software architecture in the forepart, and then the whole system-on-a-chip on Altera Stratix EP1S25F780C6 device. Using the FPGA environment and SmartBit tester, we tested the system＇s throughput. Our simulation results showed that the maximum throughput of Ethemet packets is up to 7 Mbps, that of UDP packets is up to 5.8 Mbps, and that of TCP packets is up to 3.4 Mbps, which showed that this embedded system can easily transmit basic voice and video signals through Ethemet, and that using only one chip can realize that many electronic devices access to the Intemet directly and get high performance.

Microstructure and cutting performance of Ti(C, N)-based cermets heat-treated in nitrogen

Ti（C, N）-based cermets were treated using hot isostatic pressing （HIP） at 1423 K in nitrogen. The microstructures compared with the as-sintered cermets were investigated using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray analysis, and electron microprobe analysis. It was found that high nitrogen activity in the surface zone resulted in the formation of gradient structure. Approximately 20-1am-deep, nitrogen-rich and titanium-rich hard surface zone was introduced by the heat treatment. The nitrogen activity was the driving force that caused the transportation of the atoms through the binder, titanium towards the surface, and tungsten and molybdenum inwards. In the surface zone, the particle size became fine, the inner rim disappeared, and the volume fraction of the outer rim and the binder phase considerably reduced. Small grains of TiN, WC, Mo2C, and nitrogen-rich carbonitlide phases formed in the surface zone during the heat treatment, improving the tlibological property of the heat-treated cermet.

An analog front-end circuit for ISO/IEC 15693-compatible RFID transponder IC

The 13.56 MHz analog front-end circuit for ISO/IEC 15693-compatible radio frequency identification (RFID) trans- ponder IC presented in this paper converts RF power to DC and extracts clock and data from the interrogator by 10% or 100% ASK modulation. The transponder sends data back to the interrogator by load modulation technology. The electrostatic discharge (ESD) protection circuits function to limit RF voltage to a safe level. An inductive coupling simulation modelling for 13.56 MHz RFID system is presented, with simulation results showing that the transponder operates over a wide range of electromagnetic field strength from Hmin (150 mA/m) to Hmax (5 A/m). The transponder IC is implemented in SMIC 0.35-μm three-metal two-poly mixed signal CMOS technology with embedded EEPROM.

Modeling and Control of Time-pressure Dispensing for Semiconductor Manufacturing

To improve the consistency of the adhesive amount dispensed by the time-pressure dispenser for semiconductor manufacturing, a non-Newtonian fluid flow rate model is developed to represent and estimate the adhesive amount dispensed in each cycle. Taking account of gas compressibility, an intelligent model-based control strategy is proposed to compensate the deviation of adhesive amount dispensed from the desired one. Both simulations and experiments show that the dispensing consistency is greatly improved by using the model-based control strategy developed in this paper.

A low-power Rijndael S-Box based on pass transmission gate and composite field arithmetic

Using composite field arithmetic in Galois field can result in the compact Rijndael S-Box. However, the power con- sumption of this solution is too large to be used in resource-limited embedded systems. A full-custom hardware implementation of composite field S-Box is proposed for these targeted domains in this paper. The minimization of power consumption is implemented by optimizing the architecture of the composite field S-Box and using the pass transmission gate (PTG) to realize the logic functions of S-Box. Power simulations were performed using the netlist extracted from the layout. HSPICE simulation results indicated that the proposed S-Box achieves low power consumption of about 130 μW at 10 MHz using 0.25 μm/2.5 V technology, while the consumptions of the positive polarity reed-muller (PPRM) based S-Box and composite field S-Box based on the conventional CMOS logic style are about 240 μW and 420 μW, respectively. The simulations also showed that the presented S-Box obtains better low-voltage operating property, which is clearly relevant for applications like sensor nodes, smart cards and radio frequency identification (RFID) tags.

Gene expression changes of urokinase plasminogen activator and urokinase receptor in rat testes at postnatal stages

Aim： To investigate the gene expression changes of urokinase plasminogen activator （uPA）/urokinase receptor （uPAR） in rat testes at postnatal stages and explore the effects of uPA/uPAR system on the rat spermatogenesis. Methods： The mRNAs of uPA and uPAR in rat testes were measured by using real-time quantitative polymerase chain reaction （PCR） at postnatal days 0, 5, 10, 15, 21, 28, 35, 42, 49 and 56, respectively. Results： The tendencies of uPA and uPAR mRNA expression were similar at most postnatal stages except for Do. The expression of uPAR mRNA in rats testes was relatively higher than that of uPA at postnatal Do, and both were decreased until D21, increased obviously at postnatal D28, reached a peak at postnatal D35, then declined sharply at postnatal D42 and retained at a low level afterwards. Conclusion： The uPA/uPAR system may be strongly linked to spermiation and spermatogenesis via regulating germ cell migration and proliferation, as well as promoting the spermiation and detached residual bodies from the mature spermatids.

Visualization of 3-D temperature distribution in a 300 MW twin-furnace coal-fired boiler

Until now, it has been difficult to obtain on-line three-dimensional (3-D) temperature distribution information which can reflect the overall combustion condition in the furnace of a coal-fired power plant boiler. A combustion monitoring system is introduced which can solve the problem efficiently. Through this system, the 3-D temperature distribution in a coal-fired boiler furnace can be obtained using a novel flame image processing technique. Briefly, we first outline the visualization principle. Then, the hardware and software design of the system in a 300 MW twin-furnace coal-fired boiler are introduced in detail. The visualization of the 3-D temperature distribution in the twin-furnace boiler is realized with an industrial computer and the Distributed Control System (DCS) of the boiler. The practical operation of the system shows that it can provide valuable combustion information of a furnace and is useful for the combustion diagnosis and adjustment in coal-fired power plants.

On the Study of Multi-Gas Data Acquisition System Based on PCI1711 Card

A data acquisition system for testing gas sensor array response to multi-gas is presented.The testing system is based on the character of the gas response of metal oxide semiconductor gas sensor array.The data acquisition is realized automatically through the real time controlling of the data acquisition card PCI1711.This system is highly attractive for electronic nose,which is a powerful tool for the discrimination of gases.

TOPOLOGY SYNTHESIS OF GEOMETRICALLY NONLINEAR COMPLIANT MECHANISMS USING MESHLESS METHODS

This paper presents a new method for topology optimization of geometrical nonlinear compliant mechanisms using the element-free Galerkin method （EFGM）. The EFGM is employed as an alternative scheme to numerically solve the state equations by fully taking advantage of its capability in dealing with large displacement problems. In the meshless method, the imposition of essential boundary conditions is also addressed. The popularly studied solid isotropic material with the penalization （SIMP） scheme is used to represent the nonlinear dependence between material properties and regularized discrete densities. The output displacement is regarded as the objective function and the adjoint method is applied to finding the sensitivity of the design functions. As a result, the optimization of compliant mechanisms is mathematically established as a nonlinear programming problem, to which the method of moving asymptotes （MMA） belonging to the sequential convex programming can be applied. The availability of the present method is finally demonstrated with several widely investigated numerical examples.

Digitalization Modeling System for Constitutive Relation of Geomaterial

A digital modeling system method is put forward for modeling constitutive relation of geomaterial including digital image subsystem for deformation measurement, numerical modeling subsystem and numerical simulation subsystem. A non-contact measurement method based on digital image processing is introduced to improve measurement of specimen deformation. Based on the method, a series of conventional tri-axial compression tests under diverse stress paths are done. Then an elasto-plastic constitutive model of soil is acquired through the numerical method of modeling constitutive law for geomaterial. Two examples of specimen deformation and ground subsidence are presented and discussed. It indicated that this method can rationally simulate the stress-strain relationship of soil, which reflects the effect of stress path on soil stress-strain relationship.

AN EFFICIENT PREDICTION METHOD FOR THE TWO-DIMENSIONAL COUPLED STRUCTURAL-ACOUSTIC ANALYSIS

A wave number method （WNM） is proposed to deal with the two-dimensional coupled structural-acoustic problem. Based on an indirect Trefftz approach, the displacement and the pressure response are approximated respectively by a set of wave functions, which exactly satisfy the governing equations and are independent of the size of the coupled system. The wave functions comprise the exact solutions of the homogeneous part of the governing equations and some particular solution functions, which arise from the external excitation. The weighting coefficients of the wave functions can be obtained by enforcing the pressure approximation to satisfy the boundary conditions and it is performed by applying the weighted residual formulation. The example is computed by the WNM and the BEM. The results show that, the WNM can attain the same accuracy and convergence as the BEM with less degrees of freedom.

The effect of multilayer structure on magnetic properties of FePt thin films

The Fe/Pt multilayer films with different structures were deposited by RF magnetron sputtering on glass substrates, and the L10-FePt films were obtained after the asdeposited samples were subjected to vacuum annealing at various temperatures. Results show that the Fe/Pt multilayer structure can effectively reduce the ordering temperature of FePt film, and the in-plane coercivity of [Fe （5.2 nm）/Pt （5.2 nm）]7 multilayers can reach 161.2 kA/m after annealed at 350℃ for 30 min. When Fe and Pt layer thickness is equal, the coercivity of the film is the largest. On the other hand, the different Fe-Pt crystalline phases such as Fe3Pt and FePt3 phases are formed after annealing when the thickness ratio of Fe/Pt deviates from 1 after annealing. When Fe and Pt have the same thickness, the thinner single layer gets the lower ordering temperature and the larger coercivity.

Preparation of Nanocrystalline Tin Dioxide Particles via the Acrylamide Polymerization Process

We report simple acrylamide polymerization process to prepare nanocrystalline tin dioxide(SnO_2) particles.A small amount of the so-called premix solution(monofunctional acrylamide and difunctional N,N'-methylenebisacrylamide) was mixed with the aqueous solution of Sn^(4+) in certain proportion,and a few drops of ammonium persulfate solution were added as initiator.When homogenized by magnetic stirring and heated to about 70℃,the mixed solution became a gel.This hydrous gel was directly decomposed by thermal treatment,resulting in obtaining rutile crystalline SnO_2 particles with a narrow size distribution typically in the range of 20 nm～40 nm.

Modeling and Stability Analysis for Non-linear Network Control System Based on T-S Fuzzy Model

Based on the T-S fuzzy model,this paper presents a new model of non-linear network control system with stochastic transfer delay.Sufficient criterion is proposed to guarantee globally asymptotically stability of this two-levels T-S fuzzy model.Also a T-S fuzzy observer of NCS is designed base on this two-levels T-S fuzzy model.All these results present a new approach for networked control system analysis and design.

AN EMPIRICAL STUDY ON USER ACCESS TO ENTERTAINMENT STREAMING MEDIA

Due to large size and different popularity for different part of the video, most proxy caches for streaming medias cache only a part of the video. Thus, an accurate understanding on the internal popularity distribution of media objects in streaming applications is very important for the development of efficient cache mechanisms. This letter shows that the internal popularity of popular streaming media obeys a k-transformed Zipf-like distribution through analyzing two 6-month long traces recorded at different streaming video servers of an entertainment video-on-demand provider. This empirical model can be used to design an efficient cach- ing algorithm.

An Improved Cooperative Tracking Model Used for Large-scale Social Foraging Swarm

An improved cooperative tracking model is proposed, which is based on the local information between mutually observable individuals with global object information, and this model is used for scalable social foraging swarm. In this model, the 'follower' individuals in the swarm take the center of the minimal circumcircle decided by the neighbors in the positive visual set of individual as its local object position. We study the stability properties of cooperative tracking behavior of social foraging swarm based on Lyapunov stability theory. Simulations show that the stable cooperative tracking behavior of the global social foraging swarm can be achieved easily, and beautiful scalability emerge from the proposed model for social foraging swarm.