High electro-catalytic graphite felt/Mn O2composite electrodes for vanadium redox flow batteries

A mild and simple synthesis process for large-scale vanadium redox flow batteries(VRFBs)energy storage systems is desirable.A graphite felt/Mn O_2(GF-MNO)composite electrode with excellent electrocatalytic activity towards VO^(2+)/VO_2^+redox couples in a VRFB was synthesized by a one-step hydrothermal process.The resulting GF-MNO electrodes possess improved electrochemical kinetic reversibility of the vanadium redox reactions compared to pristine GF electrodes,and the corresponding energy efficiency and discharge capacity at 150 m A cm^(-2)are increased by 12.5%and 40%,respectively.The discharge capacity is maintained at 4.8 A h L^(-1)at the ultrahigh current density of 250 m A cm^(-2).Above all,80%of the energy efficiency of the GF-MNO composite electrodes is retained after 120 charge-discharge cycles at 150 m A cm^(-2).Furthermore,these electrodes demonstrated that more evenly distributed catalytic active sites were obtained from the Mn O_2particles under acidic conditions.The proposed synthetic route is facile,and the raw materials are low cost and environmentally friendly.Therefore,these novel GF-MNO electrodes hold great promise in large-scale vanadium redox flow battery energy storage systems.

Layered oxide cathodes for sodium-ion batteries: From air stability, interface chemistry to phase transition

Sodium-ion batteries(SIBs)are considered as a low-cost complementary or alternative system to prestigious lithium-ion batteries(LIBs)because of their similar working principle to LIBs,cost-effectiveness,and sustainable availability of sodium resources,especially in large-scale energy storage systems(EESs).Among various cathode candidates for SIBs,Na-based layered transition metal oxides have received extensive attention for their relatively large specific capacity,high operating potential,facile synthesis,and environmental benignity.However,there are a series of fatal issues in terms of poor air stability,unstable cathode/electrolyte interphase,and irreversible phase transition that lead to unsatisfactory battery performance from the perspective of preparation to application,outside to inside of layered oxide cathodes,which severely limit their practical application.This work is meant to review these critical problems associated with layered oxide cathodes to understand their fundamental roots and degradation mechanisms,and to provide a comprehensive summary of mainstream modification strategies including chemical substitution,surface modification,structure modulation,and so forth,concentrating on how to improve air stability,reduce interfacial side reaction,and suppress phase transition for realizing high structural reversibility,fast Na+kinetics,and superior comprehensive electrochemical performance.The advantages and disadvantages of different strategies are discussed,and insights into future challenges and opportunities for layered oxide cathodes are also presented.