Green Synthesis of Iron(Ⅱ,Ⅲ)-polyphenol Nanoparticles and Their Adsorption of Malachite Green

Three kinds of iron nanoparticles(FeNPs)were prepared via green route based on pomegranate(PG),green tea(GT),and mulberry(ML)extracts under ambient conditions.The obtained materials were characterized by scanning electron microscopy(SEM),transmission electronic microscopy(TEM),X-ray energy-dispersive spectrometer(EDS),X-ray diffraction(XRD),fourier transform infrared spectroscopy(FTIR),and X-ray photoelectron spectroscopy(XPS)techniques.The experimental results show that FeNPs were in the form of amorphous iron(Ⅱ,Ⅲ)-polyphenol complex with different dispersity and morphologies.GT-Fe has the smallest size range of 25-35 nm,PG-Fe has a moderate size-distribution of 30-40 nm,while ML-Fe formed a tuberous net-type with a sheeting structure.PG-Fe displays the highest removal efficiency of 90.2%in 20 min towards cationic dye of malachite green(16.6%by ML-Fe and 69.3%by GT-Fe),which is attributed to its highest polyphenol content,lowest zeta potential,as well as the most Fe^(2+)on the surface of FeNPs.The removal mechanism was mainly induced by electrostatic adsorption based on pH and zeta potential tests.

Understanding groundwater table using a statistical model

In this study, a statistical model was established to estimate the groundwater table using precipitation, evaporation, the river stage of the Liangduo River, and the tide level of the Yellow Sea, as well as to predict the groundwater table with easily measurable climate data in a coastal plain in eastern China. To achieve these objectives, groundwater table data from twelve wells in a farmland covering an area of 50 m ~ 150 m were measured over a 12-month period in 2013 in Dongtai City, Jiangsu Province. Trend analysis and correlation analysis were conducted to study the patterns of changes in the groundwater table. In addition, a linear regression model was established and regression analysis was conducted to understand the relationships between precipitation, evaporation, river stage, tide level, and groundwater table. The results are as follows： （1） The groundwater table was strongly affected by climate factors （e.g., precipitation and evaporation）, and river stage was also a significant factor affecting the groundwater table in the study area （p 〈 0.01, where p is the probability value）. （2） The groundwater table was especially sensitive to precipitation. The significance of the factors of the groundwater table were ranked in the following descending order： precipitation, evaporation, and river stage. （3） A triple linear regression model of the groundwater table, precipitation, evaporation, and river stage was established. The linear relationship between the groundwater table and the main factors was satisfied by the actual values versus the simulated values of the groundwater table （R^2 = 0.841, where R^2 is the coefficient of determination）.

Impacts of precipitation variation and soil and water conservation measures on runoff and sediment yield in the Loess Plateau Gully Region, China

The Loess Plateau of China has experienced a lengthy drought and severe soil erosion.Changes in precipitation and land use largely determine the dynamics of runoff and sediment yield in this region. Trend and mutation analyses were performed on hydrological data(1981–2012) from the Yanwachuan watershed in the Loess Plateau Gully Region to study the evolution characteristics of runoff and sediment yield. A time-series contrasting method also was used to evaluate the effects of precipitation and soil and water conservation(SWC) on runoff and sediment yield. Annual sediment yield declined markedly from 1981 to 2012 although there was no significant change in annual precipitation and annual runoff. Change points of annual runoff and annual sediment yield occurred in 1996 and 1997,respectively. Compared with that in the baseline period(1981–1996), annual runoff and annual sediment yield in the change period(1997–2012)decreased by 17.0% and 76.0%, respectively, but annual precipitation increased by 6.3%. Runoff decreased in the flood season and normal season, but increased in the dry season, while sediment yield significantly declined in the whole study period. The SWC measures contributed significantly to the reduction of annual runoff(137.9%) and annual sediment yield(135%) and were more important than precipitation. Biological measures(forestland and grassland) accounted for 61.04% of total runoff reduction, while engineering measures(terraces and dams) accounted for 102.84% of total sediment yield reduction. Furthermore, SWC measures had positive ecological effects. This study provides a scientific basis for soil erosion control on the Loess Plateau.

Study on Evaluation Method of Ecological Restoration for Soil and Water Conservation in Ningxia Hui Autonomous Region

On the basis of deeply understanding the domestic existing evaluation method of ecological restoration for soil and water conservation, under the premise of analyzing characteristics of current commonly used evaluation index of ecological restoration, based on the actual situation in Ningxia Hui Autonomous Region, taking objectivity, independence and operability as the principles, nine evaluation indexes were selected, and a set of comprehensive evaluation method of ecological restoration for water and soil conservation based on AHP was constructed. The hundred mark system corresponded with ecological restoration level, and the weight of each index in evaluation system was calculated according to comparison matrix constructed by frontline workers of soil and water conservation. The method could be used to determine difficult degree of restoration of the disturbed and destroyed ecosystem and the rationality of ecological restoration for soil and water conservation.

Correlation Analysis between Surface Water of Gusong River and Coastal Shallow Groundwater

According to the measured groundwater pollution concentration at two monitoring sections of Gusong River coast,adopting progressive dislocation correlation analysis method,correlation between surface water of Gusong River and groundwater pollution was analyzed.Result showed that propagation time of pollutant between river water and groundwater was longer.According to the water level observation data,river water level was＆gt;1 m higher than groundwater table.The groundwater infiltration parameter was determined through the field permeability test data.The Dupuit formula was used to calculate recharge and discharge relationship between river surface water and groundwater.It was obtained that the daily average recharge capacity of right-bank river water to groundwater was 3 m3,and pollution of river surface water had very small influence on groundwater.Using MATLAB software for data analysis and processing,regression equation was established.The chloride as correlation analysis example,results showed that groundwater chloride had the maximum correlation with observation well distance,and correlation with time and monitoring value of surface water was very small.The linear relationship between surface water and groundwater was not obvious.

Spatial-Temporal Variation Characteristics and Cause Analysis of Water Quality in Yinma River Basin

In order to comprehensively understand the water quality in Yinma River Basin,and to analyze the spatial-temporal variation characteristics of water quality over the years and the causes of water pollution,15 sections were selected in the Yinma River Basin.Based on the water quality monitoring data in the past decade,7 evaluation indexes including dissolved oxygen(DO),5-day biochemical oxygen demand(BOD_(5)),permanganate index(COD_(MN)),chemical oxygen demand(COD),ammonia nitrogen(NH_(4)-N),total phosphorus(TP)and total nitrogen(TN)were determined,according to the Environmental Quality Standard for Surface Water(GB3838-2002)and the historical monitoring data of rivers.The water quality of 15 sections in Yinma River Basin was comprehensively evaluated,and the water quality categories and the evolution of river water quality were analyzed.The pollution sources of Yinma River Basin were analyzed,and the constructive countermeasures were put forward according to the conclusions.

Effects of rainfall and rocky desertification on soil erosion in karst area of Southwest China

Monitoring and evaluating the evolution of rocky desertification timely and studying the characteristics of soil erosion under different rainfall patterns are of great scientific significance for regional soil and water conservation,rocky desertification control and ecological environment construction.Four periods of remote sensing image data from 2005 to 2020 were selected to study the evolution characteristics of rocky desertification and its impact on soil erosion in the controlled boundary area of Shibantang hydrological station of Yeji River Watershed,Guizhou Province,China.According to the 408 erosive rainfall events,the soil erosion under different rainfall patterns in the watershed was analyzed.The results showed that:erosive rainfall events in the study area were mainly pattern A,accounting for 57.4%of the total rainfall events;the second was pattern B,accounting for 28.9%of the total rainfall events;the rainfall pattern of C occurred occasionally.Among them,pattern A was the main rainfall pattern leading to soil and water loss and had the largest contribution rate to soil erosion in the watershed.From 2005 to 2020,the area of rocky desertification showed a decreasing trend,accounting for 72.2%from 87.9%.Spatially,rocky desertification has mainly concentrated in the middle south of the watershed since 2010,while the rocky desertification mainly concentrated in the middle and north before 2010.The effects of different grades of rocky desertification on soil erosion were different,and the soil erosion modulus in areas with the medium,severe and extremely severe rocky desertification was generally small.The soil erosion modulus estimated by the RUSLE(Revised Universal Soil Loss Equation)model was still much higher than that calculated by the data measured by the hydrological monitoring station.Therefore,the application of the RUSLE model in karst area needs to be further modified.These results can provide reference for rocky desertification control,soil erosion control and fragile ecosystem restoration in karst area.

Temporal and Spatial Variability of Dissolved Organic Carbon Concentration in the Xijiang River, South China

A whole year analysis of riverine dissolved organic carbon (DOC) concentrations in the Xijiang River (XJR), South China, showed that the mean riverine DOC concentration (1.24 mg L-1) in the XJR was notably lower than the averaged value (5.75 mg L-1) of the global riverine DOC concentration in several major rivers. There is an inconspicuous monthly fluctuation of the DOC signal in the XJR, but on a semi-yearly time scale, however, the riverine DOC concentration had significant difference between hydrological seasons. The DOC level during the flood season (1.18 mg L-1) was less than that during the non-flood season (1.40 mg L-1). Owing to the concomitance of the flushing and dilution effects of the runoff during the high-water period, the variation of riverine DOC concentration with discharge in the XJR differed from that reported in many other major rivers. The DOC export flux above the city of Wuzhou was about 0.62× 106 g C km-2 yr-1. The DOC transported during the "056" Massive Flood period comprised 30.35% of the annual total, while the discharge accounted for 36.32% of the total annual flow. The characteristics in riverine DOC concentration in the XJR were attributed to the combined effect of the geomorphologic, monsoon climatic and hydrological processes as well as land-use within the drainage basin.

Study of temperature and precipitation change in upstream mountain area of the Hexi inland river basin since 1960s

All rivers in the Hexi inland region of Gansu Province, China, originate from the northern slope of the Qilian Mountains. They are located in the southern portion of the region and respectively belong to the three large river systems from east to west, the Shiyang, Heihe and Shule river basins. These rivers are supplied by precipitation, snowmelt and ice-melt runoff from the Qilian Mountain area. Therefore, changes of precipitation and temperature in the upstream watersheds of these rivers have an important effect on changes of mountainous runoff and reasonable utilization of water resources in this region. For this reason, the Qilian Mountain area, upstream watersheds and runoff forming areas of these rivers are chosen as the study area. The change characteristics and variation trend of temperature and precipitation in this area under the backdrop of global warming axe analyzed based on observa- tional data of relational weather and hydrologic stations in the area. Results show that temperatures in the upriver mountain areas of these three large river basins have been increasing, although the increasing degree is differentially affected by global warming. The rising extent of annual and seasonal temperatures in the upstream mountain area of the Shule river basin located in the west- em Qilian Mountains, were all largest over the past 50 years. Precipitation in the upstream mountain areas of Hexi region＇ three river basins located respectively in the western, middle and eastern Qilian Mountains have been presenting an increasing trend to varying degrees as a whole for more than 50 years. This means that climate in the upstream mountain areas of Hexi region＇ three river basins are becoming increasingly warmer and moister over the past 50 years, which will be very good for the ecological en- vironment and agricultural production in the region.

Analysis of black water aggregation in Taihu Lake

Black water aggregation （BWA） in Taihu Lake is a disaster for the lake environment. It is a phenomenon resulting from water environmental deterioration and eutrophication caused by accumulation of pollutants in the lake, according to research on the water quality, pollutants of BWA, and occurrence mechanisms of BWA. Dead algae are the material base of BWA, the polluted sediment is an important factor for the formation of BWA, and hydrological and meteorological conditions such as sun light, air temperature, wind speed, and water flow are the other factors that may lead to the formation of BWA. Thioether substances such as dimethyl trisulfide are the representative pollutants of BWA. Parameters such as chlorophyll-a, DO, pH, and water temperature are sensitive indicators of BWA. Measures such as algae collection, ecological dredging, pollution control, and water diversion from the Yangtze River to the lake, are effective, and strengthening aeration is an emergency measure to control BWA.

Vegetation Index Reconstruction and Linkage with Drought for the Source Region of the Yangtze River Based on Tree-ring Data

Variations in vegetation are closely related to climate change, but understanding of their characteristics and causes remains limited. As a typical semi-humid and semi-arid cold plateau region, it is important to understand the knowledge of long term Normalized Difference Vegetation Index(NDVI) variations and find the potential causes in the source region of the Yangtze River. Based on four tree-ring width chronologies, the regional mean NDVI for July and August spanning the period 1665–2013 was reconstructed using a regression model, and it explained 43.9% of the total variance during the period 1981–2013. In decadal, the reconstructed NDVI showed eight growth stages(1754–1764, 1766–1783, 1794–1811, 1828–1838, 1843–1855, 1862–1873, 1897–1909, and 1932–1945)and four degradation stages(1679–1698, 1726–1753, 1910–1923, and 1988–2000). And based on wavelet analysis, significant cycles of2–3 yr and 3–8 yr were identified. In additional, there was a significant positive correlation between the NDVI and the Palmer Drought Severity Index(PDSI) during the past 349 yr, and they were mainly in phase. However, according to the results of correlation analysis between different grades of drought/wet and NDVI, there was significant asymmetry in extreme drought years and extreme wet years. In extreme drought years, NDVI was positively correlated with PDSI, and in extreme wet years they were negatively correlated.

Analysis of Climate Change in the Coastal Zone of Eastern China, against the Background of Global Climate Change over the Last Fifty Years: Case Study of Shandong Peninsula, China

The climate change in Shandong Peninsula, China was analyzed in this paper by the non-parametric Mann-Kendall test, Accumulated Difference Curve and Order Cluster Analysis methods, based upon the datas of annual mean, maximum and minimum temperature and annual precipitation, precipitation from June to September over the past 50 years. Results obtained showed a number of observations: 1) The annual mean temperature of Shandong Peninsula showed a significant increasing trend, with a distinct abrupt change point detected around 1990, during the past 5 decades. The warming of the Peninsula over the last 50 years was due mainly to the significant increase of annual minimum temperature. The annual maximum temperature demonstrated a mixed trend of decreasing and increasing, but was statistically insignificant, and no abrupt change was detected;2) The annual precipitation exhibited a decreasing trend during the past 5 decades, with an abrupt change detected around 1980 at most stations;but there was an earlier transition point at 1966, at a few stations. The reduction in precipitation, from June to September, was responsible mainly for the decrease of annual precipitation. Besides, the proportion of the June-September precipitation in the year declined slightly over the last 50 years;3) In comparison, the temperature evolution in Shandong Peninsula was basically consistent with most parts of China, but warmed at a faster rate over the same period;the decreasing trend of precipitation was more significant compared with the other climate zones of China. Within the Peninsula, the abrupt change of temperature and precipitation in the Southeast was earlier than that in the Northwest;the reduction of precipitation was larger in the Southeast while the increase of temperature was more significant in the Northwest. This research was of great importance to understand the climate change and its environmental effects in the coastal zone.

Hydrological processes in the Aksu River source region during the intense ablation period based on water chemistry and isotopes

Against the backdrop of global warming,the dynamics of glaciers and their water resources have significant implications for hydrological processes in the arid regions of Northwest China.The Aksu River,which is an essential inland river enriched by substantial meltwater contributions,plays a pivotal role in the economic,ecological,and social development of the region.Based on 231 water samples collected during the period of intense glacial ablation in 2023,this study conducted a comprehensive analysis of the hydrochemical and stable isotopic characteristics of the Little Kurgan glacial basin in the Aksu River source region.A Piper diagram classified the hydrochemical type of the river water as Calcium-Bicarbonate.Analysis based on a Gibbs diagram indicated that rock weathering is the predominant factor affecting the hydrochemical properties within the studied basin.Through application of principal component analysis and end-member mixing analysis,it was determined that the glacier meltwater contribution to runoff was 67%,61%,and 55%in July,August,and September,respectively.The findings of this study reveal that glacier meltwater is the principal component of the river water,and highlight the critical impact of alterations in glacier ablation on the hydrological cycle within the Aksu River source region,which is vitally important for sustainable water resource management.

Variations and trends of trans-boundary runoff in the longitudinal range-gorge region

The mountainous hydrological process usually shows high variation to climate change and human action. In the Longitudinal Range-Gorge Region（LRGR）, Southwestern China and Southeast Asian, the transboundary runoff variations are much more sensitive and complex under the interaction of climate change, ＂corridor-barrier＂ functions in LRGR,and dams building. In this paper, based on the long hydrological records（1956-2013） from three mainstream hydrological stations in Nu River,Lancang River, and Red River, the region runoff variations were analyzed. The results show out： i） the regional runoff changes were strongly influenced by the ＂Corridor-Barrier＂ functions in LRGR from west to east, the variability extent of annual runoff increased, but tended to decrease after 2009 and the reduced extents also increased; ii） the annual runoff change in the three rivers had high concentration degrees; iii） there were periodicities of 33 years of runoff change in Nu River and Lancang River, and 30 years in Red River, and the lower flow period would continue for 8-9 years in Nu River and Lancang River but only for 4 years in Red River; iv） since 2010, as the two mega dams of Xiaowan and Nuozhadu built in Lancang River mainstream, their variations of annual runoff were quite different. The research results could offer a scientific base for sustainable utilization,conservation, and management of the regional water resources

Sensitivity of mountain runoff to climate change for Urumqi and Kaidu rivers originating from the Tianshan Mountains

The mountain watersheds of Kaidu River and Urumqi River, which separately originate from the south and north-side of the Tianshan Mountains in Xinjiang, are selected as the study area. The characteristics and trends on variation of temperature, precipitation and runoff, and the correlativity between temperature, precipitation, and runoffwere analyzed based on the past 40 years of observational data from the correlative hydrological and weather stations in the study areas. Various weather scene combinations are assumed and the response models of runoff to climate change are established in order to evaluate the sensitivity of runoff to climate change in the study areas based on the foregoing analysis, Results show that all variations of temperature, precipitation, and runoff overall present an oscillating and increasing trend since the 1960s and this increase are quite evident after 1990. There is a markedly positive correlation between mountain runoff, temperature, and precipitation while there are obvious regional differences of responding degree to precipitation and temperature between mountain runoff of Ummqi River and Kaidu River Basins Also, mountain runoff of Urumqi River Basin is more sensitive to precipitation change than that of Kaidu River Basin, and mountain runoff of Kaidu River Basin is more sensitive to temperature change than that of Ummqi River Basin.

An estimation of groundwater storage variations from GRACE gravity satellites in the Heihe River Basin, northwestern China

There are only limited surface water resources available in the Heihe River Basin （HRB）, a typical inland river basin in the arid region of northwestern China, where groundwater overexploitation is a serious problem. Groundwater has become one of main resources of fresh water in the HRB. In this paper, temporal and spatial variations of groundwater in the HRB are estimated by the Gravity Recovery and Climate Experiment （GRACE） satellites. Our analysis shows that groundwater storage in the HRB reaches its highest in the summer of 2005, and then begins to decline in the following years and reaches steady status in 2008. Spatially, groundwater shows a decline in the upper HRB in the first two years and a slight increase in the following years, while this phenomenon is reversed in the middle HRB where groundwater slightly increases in 2005 and then declines in the following three years. In the lower HRB, GRACE detects a continual increase in the full six-year period. This approach is proven successful when employed in the HRB and thus offers a new insight into monitoring groundwater variations in a river basin with limited or even without any observed data.

Analysis on Hydrological Regimes of the Medium and Small Rivers in Hami of Xinjiang——Take Toudaogou Basin as an Example

[ Objective] The research aimed to analyze hydrological regimes of the medium and small rivers in Hami of Xinjiang. [ Method] According to actual observation data at Toudaogou hydrological station during 1956 -2010, climate, runoff, flood, sediment and water quality in the basin were analyzed. [ Result] Runoff in Toudaogou River was mainly from bedrock fissure water and rainfall, and depended on temperature and precipi- tation in the catchment zone. Runoff in Toudaogou River had very big change during the year. Runoff in whole year mainly concentrated during April -June, which occupied 57.9% of annual runoff. Flood in Toudaogou basin was divided into spring and summer flood from time, and snowmelt and rainstorm flood from type. Sediment load was related to terrain, gradient, runoff, precipitation, flood and process. Suspended sediment load at Toudaogou hydrological station had close relationship with the annual maximum flow capacity of flood peak, and related coefficient was 0.917. [ Conclusion] Hydrological regime in Toudaogou basin basically represented corresponding hydrological information of rivers without glacier water supply in Hami even whole western arid zone of China. The research could provide theoretical basis for scientifically using water resources of the medium and small rivers in the zone.

Biological Evaluation of Water Quality for Benthos in Typical Rivers of Eastern Jilin Province

Benthos are aquatic organisms living at the bottom of water bodies for all or most of their life history.Apart from the settled and moving living,their forms of habitat are mostly attached to the hard substrate like rocks or soft bases such as mud and sand.In addition,there are benthic species that attach to the plant surfaces or other benthic animals,and inhabit the intertidal zone.In terms of feeding methods,most benthic animals feed on suspended matter and sediment.Most of them are invertebrates and are a complex ecological group.According to the size,they can be divided into macrobenthos and meio-benthos[1].Benthos are an important part of the water ecosystem.Using a typical river(Gaya River)in eastern Jilin Province,this paper analyzed the water quality,the components of benthic organisms and their biological density through sampling surveys of three typical locations in the upper,middle and lower reaches of the Gaya River.In addition,it made a biological evaluation of the water quality of the Gaya River.

Increased southerly and easterly water vapor transport contributed to the dry-to-wet transition of summer precipitation over the Three-River Headwaters in the Tibetan Plateau

The Three-River Headwaters(TRH)region in the Tibetan Plateau is vulnerable to climate change;changes in summer(June–August)precipitation have a significant impact on water security and sustainability in both local and downstream areas.However,the changes in summer precipitation of different intensities over the TRH region,along with their influencing factors,remain unclear.In this study,we used observational and ERA5 reanalysis data and employed a precipitation categorization and water vapor budget analysis to quantify the categorized precipitation variations and investigate their possible linkages with the water vapor budget.Our results showed an increasing trend in summer precipitation at a rate of 0.9 per year(p<0.1)during 1979–2020,with a significant dry-to-wet transition in 2002.The category‘very heavy precipitation’(10 mm d−1)contributed 65.1%of the increased summer precipitation,which occurred frequently in the northern TRH region.The dry-to-wet transition was caused by the effects of varied atmospheric circulations in each subregion.Southwesterly water vapor transport through the southern boundary was responsible for the increased net water vapor flux in the western TRH region(158.2%),while southeasterly water vapor transport through the eastern boundary was responsible for the increased net water vapor flux in the central TRH(155.2%)and eastern TRH(229.2%)regions.Therefore,we inferred that the dry-to-wet transition of summer precipitation and the increased‘very heavy precipitation’over the TRH was caused by increased easterly and southerly water vapor transport.

Response of runoff in the headwater region of the Yellow River to climate change and its sensitivity analysis

Response of the runoff in the headwater region of the Yellow River to climate change and its sensibility are analyzed based on the measured data at the four hydrological stations and ten weather stations during the period 1959-2008. The result indicates that change of temperature in the region has an obvious corresponding relationship with global warming and the changes of annual average temperature in each subregion in the region have been presenting a fluctuant and rising state in the past 50 years. However the change of precipitation is more intricate than the change of temperature in the region because of the influences of the different geographical positions and environments in various areas, and the change of annual precipitation in the main runoff-producing area has been presenting a fluctuant and decreasing state in the past 50 years. And there is a remarkable nonlinear correlativity between runoff and precipitation and temperature in the region. The runoff in the region has been decreasing continuously since 1990 because the precipitation in the main run-off-producing area obviously decreases and the annual average temperature continuously rises. As a whole, the runoff in each subregion of the headwater region of the Yellow River is quite sensitive to precipitation change, while the runoff in the subregion above Jimai is more sensitive to temperature change than that in the others in the region, correspondingly.