Isolation and Characterization of Cellulose Nanofiber(CNF)from Kenaf(Hibiscus cannabinus)Bast through the Chemo-Mechanical Process

The present work emphasizes the isolation of cellulose nanofiber(CNF)from the kenaf(Hibiscus cannabinus)bast through a chemo-mechanical process.In order to develop high CNF yield with superior properties of CNF for improving compatibility in varied applications this method is proposed.The fiber purification involved pulping and bleaching treatments,whereas mechanical treatment was performed by grinding and high-pressure treatments.The kraft pulping as a delignification method followed by bleaching has successfully removed almost 99%lignin in the fiber with high pulp yield and delignification selectivity.The morphology of the fibers was characterized by scanning electron microscopy,which showed a smooth surface,fiber bundles,gel-shaped nanofiber,and an average size of 94.05 nm with 69%of CNF in 34–100 nm size.The chemo-mechanical process exhibited a more crystalline nature in CNF than pulp kenaf.The low zeta potential values exhibit the distribution of fibrils and colloidal suspension stability without any further agglomeration.A lower concentration of CNF is less stable exhibiting the product agglomeration.Therefore,the chemo-mechanical process for the isolation of CNF(Hibiscus cannabinus)from kenaf involves sustainable,low-cost,non-toxic,and cheap alternatives than other traditional methods.

Overview of the Synthesis, Characterization, and Application of Tannin-Glyoxal Adhesive for Wood-Based Composites

More than a century after its initial synthesis,urea-formaldehyde(UF)resins still have dominant applications as adhesives,paints,and coatings.However,formaldehyde in this industry produces formaldehyde emissions that are dangerous to health.Scientists have spent the last decade replacing formaldehyde and phenol with environmentally friendly substances such as glyoxal and tannin to create bio-based adhesives.This review covers recent advances in synthesizing glyoxal tannin-based resins,especially those made from sustainable raw material substitutes and changes made to synthetic processes to improve mechanical properties.The efficacy of using tannin-glyoxal adhesives in producing wood-based composites has been proven.The glyoxylate reaction forms cross-linked bridges between the aromatic sites of the tannin and glyoxal molecular structures.Glyoxal tannin adhesive with a greater percentage of glyoxal than tannin will produce an adhesive with better characteristics.The gel time reduces as the hardener concentration rises from 7.5%to 15%when glyoxal is used in adhesives.However,excessive amounts of glyoxal will result in a decrease in viscosity values.Glyoxal exhibits faster delivery degradation when it reaches a maximum temperature of approximately 130°C,although it initiates the curing process slightly slower at 110°C.Adding glyoxal to tannin-based adhesives can improve the mechanical properties of composite boards.The wet shear strength of the resulting plywood is increased by 105.4%with the addition of 5-weight percent tannin-based resin with glyoxal as a cross-linker in Soy Protein Adhesive.With glyoxal as a hardener,the panels produced showed good internal bond strengths(>0.35 MPa)and met the international standard specifications for interior-grade panels.

Fluid-rock interaction experiments with andesite at 100℃ for potential carbon storage in geothermal reservoirs

Geothermal energy extraction often results in the release of naturally occurring carbon dioxide(CO_(2))as a byproduct.Research on carbon storage using volcanic rock types other than basalt under both acidic and elevated temperature conditions has been limited so far.Our study uses batch reactor experiments at 100℃ to investigate the dissolution of andesite rock samples obtained from an active geothermal reservoir in Sumatra(Indonesia).The samples are subjected to reactions with neutral-pH fluids and acidic fluids,mimicking the geochemical responses upon reinjection of geothermal fluids,either without or with dissolved acidic gases,respectively.Chemical elemental analysis reveals the release of Ca^(2+)ions into the fluids through the dissolution of feldspar.The overall dissolution rate of the rock samples is 2.4×10^(–11)to 4.2×10^(–11)mol/(m^(2)·s),based on the Si release during the initial 7 h of the experiment.The dissolution rates are about two orders of magnitude lower than those reported for basaltic rocks under similar reaction conditions.This study offers valuable insights into the potential utilization of andesite reservoirs for effective CO_(2) storage via mineralization.

Local geoid modeling in the central part of Java, Indonesia, using terrestrial-based gravity observations

The Global Navigation Satellite System(GNSS)positioning method has been significantly developed in geodetic surveying.However,the height obtained through GNSS observations is given in a geodetic height system that needs to be converted to orthometric height for engineering applications.Information on geoid height,which can be calculated using the global geopotential mode,is required to convert such GNSS observations into orthometric height.However,its accuracy is still insufficient for most engineering purposes.Therefore,a reliable geoid model is essential,especially in areas growing fast,e.g.,the central part of Java,Indonesia.In this study,we modeled the local geoid model in the central part of Java,Indonesia,using terrestrial-based gravity observations.The Stokes'formula with the second Helmert's condensation method under the Remove-Compute-Restore approach was implemented to model the geoid.The comparison between our best-performing geoid model and GNSS/leveling observations showed that the standard deviation of the geoid height differences was estimated to be 4.4 cm.This geoid result outperformed the commonly adopted global model of EGM2008 with the estimated standard deviation of geoid height differences of 10.7 cm.

Studying the Equilibrium Points of the Modified Circular Restricted Three-body Problem: The Case of Sun–Haumea System

We intend to study a modified version of the planar Circular Restricted Three-Body Problem(CRTBP) by incorporating several perturbing parameters. We consider the bigger primary as an oblate spheroid and emitting radiation while the small primary has an elongated body. We also consider the perturbation from a disk-like structure encompassing this three-body system. First, we develop a mathematical model of this modified CRTBP.We have found there exist five equilibrium points in this modified CRTBP model, where three of them are collinear and the other two are non-collinear. Second, we apply our modified CRTBP model to the Sun–Haumea system by considering several values of each perturbing parameter. Through our numerical investigation, we have discovered that the incorporation of perturbing parameters has resulted in a shift in the equilibrium point positions of the Sun–Haumea system compared to their positions in the classical CRTBP. The stability of equilibrium points is investigated. We have shown that the collinear equilibrium points are unstable and the stability of non-collinear equilibrium points depends on the mass parameter μ of the system. Unlike the classical case, non-collinear equilibrium points have both a maximum and minimum limit of μ for achieving stability. We remark that the stability range of μ in non-collinear equilibrium points depends on the perturbing parameters. In the context of the Sun–Haumea system, we have found that the non-collinear equilibrium points are stable.

Tidal triggering of seismicity in the region of Palu, Central Sulawesi, Indonesia

This paper investigates the correlation between tidal stress and earthquakes for periods ranging from hours to months in the limited zone of the Palu region(Central Sulawesi,Indonesia).Through Schuster and binomial tests,we examined the relation between the seismicity(time density of seismic events)and tidal potential arising from the Moon and Sun,using all tidal components simultaneously and focusing on the estimation of specific terms.The results show significant correlations between the seismicity and tidal potential for S2(0.5 d)and O1(1.075 d)tidal components in the case of solely isolated earthquake events,particularly for shallow earthquakes.Meanwhile,there is a strong relationship between aftershocks and tidal components larger than the Mf period(13.661 d).Finally,the analysis of the temporal variation of the earthquake-tide relation reveals an optimal correlation for about six years before the 2018 great Palu earthquake.The correlation becomes insignificant afterwards.

A Blockchain-Assisted Distributed Edge Intelligence for Privacy-Preserving Vehicular Networks

The enormous volume of heterogeneous data fromvarious smart device-based applications has growingly increased a deeply interlaced cyber-physical system.In order to deliver smart cloud services that require low latency with strong computational processing capabilities,the Edge Intelligence System(EIS)idea is now being employed,which takes advantage of Artificial Intelligence(AI)and Edge Computing Technology(ECT).Thus,EIS presents a potential approach to enforcing future Intelligent Transportation Systems(ITS),particularly within a context of a Vehicular Network(VNets).However,the current EIS framework meets some issues and is conceivably vulnerable tomultiple adversarial attacks because the central aggregator server handles the entire systemorchestration.Hence,this paper introduces the concept of distributed edge intelligence,combining the advantages of Federated Learning(FL),Differential Privacy(DP),and blockchain to address the issues raised earlier.By performing decentralized data management and storing transactions in immutable distributed ledger networks,the blockchain-assisted FL method improves user privacy and boosts traffic prediction accuracy.Additionally,DP is utilized in defending the user’s private data from various threats and is given the authority to bolster the confidentiality of data-sharing transactions.Our model has been deployed in two strategies:First,DP-based FL to strengthen user privacy by masking the intermediate data during model uploading.Second,blockchain-based FL to effectively construct secure and decentralized traffic management in vehicular networks.The simulation results demonstrated that our framework yields several benefits for VNets privacy protection by forming a distributed EIS with privacy budget(ε)of 4.03,1.18,and 0.522,achieving model accuracy of 95.8%,93.78%,and 89.31%,respectively.

Greenhouse gas reduction of co-benefit-type wastewater treatment system for fish-processing industry: A real-scale case study in Indonesia

This study examined the application of co-benefit-type wastewater treatment technology in the fish-processing industry. Given that there was a dearth of information on fish-processing industrial wastewater in Indonesia, site surveys were conducted. For the entire fish-processing industry throughout the country, the dissemination rate of wastewater treatment facilities was less than 50%. Using a co-benefit approach, a real-scale swim-bed technology (SBT) and a system combining an anaerobic baffled reactor (ABR) with SBT (ABR–SBT) were installed in a fishmeal processing factory in Bali, Indonesia, and the wastewater system process performance was evaluated. In a business-as-usual scenario, the estimated chemical oxygen demand load and greenhouse gas (GHG) emissions from wastewater from the Indonesian fish-processing industry were 33 000 tons per year and 220 000 tons of equivalent CO_(2) per year, respectively. On the other hand, the GHG emissions in the co-benefit scenarios of the SBT system and ABR–SBT system were 98 149 and 26 720 tons per year, respectively. Therefore, introducing co-benefit-type wastewater treatment to Indonesia’s fish-processing industry would significantly reduce pollution loads and GHG emissions.

Optimization and Simulation of Plastic Injection Process using Genetic Algorithm and Moldflow

The use of plastic-based products is continuously increasing. The increasing demands for thinner products, lower production costs, yet higher product quality has triggered an increase in the number of research projects on plastic molding processes. An important branch of such research is focused on mold cooling system. Conventional cooling systems are most widely used because they are easy to make by using conventional machining processes. However, the non-uniform cooling processes are considered as one of their weaknesses. Apart from the conven- tional systems, there are also conformal cooling systems that are designed for faster and more uniform plastic mold cooling. In this study, the conformal cooling system is applied for the production of bowl-shaped product made of PP AZ564. Optimization is conducted to initiate machine setup parameters, namely, the melting temperature, injection pressure, holding pressure and holding time. The genetic algorithm method and Moldflow were used to optimize the injection process parameters at a minimum cycle time. It is found that, an optimum injection molding processes could be obtained by setting the parameters to the following values： TM=180℃; Pinj = 20MPa; Phold= 16MPa and thold=8s, with a cycle time of 14.11 s. Experiments using the conformal cooling system yielded an average cycle time of 14.19 s. The studied conformal cooling system yielded a volumetric shrinkage of 5.61% and the wall shear stress was found at 0.17 MPa. The difference between the cycle time obtained through simulations and experiments using the conformal cooling system was insignificant （below 1%）. Thus, combining process parameters optimization and simulations by using genetic algorithm method with Moldflow can be considered as valid.

Optimal Tracking Controller Design for a Small Scale Helicopter

A model helicopter is more difficult to control than its full scale counterpart. This is due to its greater sensitivity to control inputs and disturbances as well as higher bandwidth of dynamics. This work is focused on designing practical tracking controller for a small scale helicopter following predefined trajectories. A tracking controller based on optimal control theory is synthesized as a part of the development of an autonomous helicopter. Some issues with regards to control constraints are addressed. The weighting between state tracking performance and control power expenditure is analyzed. Overall performance of the control design is evaluated based on its time domain histories of trajectories as well as control inputs.

电晕放电脉冲电流波形和相位分布的测量、分析与仿真(英文)

Partial discharge(PD) is one of the most important phenomenon in high voltage insulations.In most cases, the appearance of partial discharges is related to insulation defects.Understanding partial discharges is important for diagnosis on insulation condition.Corona discharges appear when extremely high electric field appears on the conductor surface exceeding the electric field strength of the gas.The high electric field may occur at around protrusion with very sharp tip.This paper reported a holistic approach of corona discharge investigation.The needle-plane electrode system was used.The medium between the electrodes was air.The needle was made from steel with radius of curvature of 3μm(Ogura needle).Sinusoidal as well as triangular applied voltages were used.The waveform of the corona discharges was measured using a digital oscilloscope.The corona discharge pulses were measured using a phase-resolved PD measurement system.The system was able to measure the magnitude(q) and phase angle position(φ) of each PD pulses,as well as the number of discharge pulses(n).The role of applied voltage was investigated using phase-resolved analysis of corona discharge pulses through pulse sequence,pulse magnitude and pulse number analysis. Experimental results indicated that corona discharge current waveform was an impulse with rise time of about several ns and the impulse width of about 100 ns.The Fast Fourier Transform analysis indicated that the corona discharge current waveform had several spectrum peaks at frequency of 7.8 MHz,85.9 MHz,109.4 MHz and 195.3 MHz.The experimental results also showed that discharge pulses were concentrated around the peak of applied voltage for both sinusoidal and triangular voltages.The discharge magnitude,as well as its probability of occurrence,was strongly dependent on the instantaneous applied voltage.The shape ofφ-n,as well asφ-q-n PD patterns,were strongly reflected by the shape of applied voltage.In order to get deep understanding of the corona discharge,by utilizing results of the phase-resolved analysis,electrical equivalent circuits of corona discharges were proposed.The electrical equivalent circuit contained capacitances and a spark gap.For deeply understanding of PD phenomenon,computer simulation was done by using the proposed electrical equivalent circuits.The similarity of the measured and simulated PD patterns was assessed by comparing measured and simulated theφ-q-n andφ-n PD patterns.The results indicated that simulated PD patterns similar to those obtained from experiment.

Advanced Strategies to Improve Performances of Molybdenum-Based Gas Sensors

Molybdenum-based materials have been intensively investigated for high-performance gas sensor applications.Particularly,molybdenum oxides and dichalcogenides nanostructures have been widely examined due to their tunable structural and physicochemical properties that meet sensor requirements.These materials have good durability,are naturally abundant,low cost,and have facile preparation,allowing scalable fabrication to fulfill the growing demand of susceptible sensor devices.Significant advances have been made in recent decades to design and fabricate various molybdenum oxides-and dichalcogenides-based sensing materials,though it is still challenging to achieve high performances.Therefore,many experimental and theoretical investigations have been devoted to exploring suitable approaches which can significantly enhance their gas sensing properties.This review comprehensively examines recent advanced strategies to improve the nanostructured molybdenum-based material performance for detecting harmful pollutants,dangerous gases,or even exhaled breath monitoring.The summary and future challenges to advance their gas sensing performances will also be presented.

Dissolution of lateritic nickel ore using ascorbic acid as synergistic reagent in sulphuric acid solution

The dissolution of nickel and cobalt from Caldag lateritic nickel ore using the combination of sulphuric and ascorbic acids was investigated. The use of other organic acids, namely citric, maleic and stearic acids, as synergistic reagents was studied for comparison. The results revealed that the use of ascorbic and citric acids markedly improved the dissolution of cobalt compared to the other two organic acids that only showed slight synergistic effect on the leaching rate. In terms of nickel dissolution, ascorbic acid is the most effective synergist, followed by citric, maleic and stearic acids in descending order. Under the most optimized conditions found in this study, i.e., using 1 mol/L of sulphuric acid with the presence of 4 g/L of ascorbic acid at 80 ℃and solid-to-liquid ratio of 1/10, more than 99% and 98% leaching rates of cobalt and nickel, respectively, can be achieved within 4 h of leaching. In addition, the leaching performance is relatively insensitive to the change of ascorbic acid concentration from 2 to 4 g/L which is highly desirable from operational perspective.

Time Sequential and Phase-resolved Measurement and Analysis of Corona Discharge in Air and Streamer Discharge in Insulating Liquid

Insulation is one of the most important parts in a high voltage equipment.There are gaseous,liquid and solid insulations which are commonly used.In a high voltage transformer for example the insulating materials are all used.During operation of a high voltage equipment high electric stress may occur.Under extreme condition failure of the insulation may take place.Excessive electric field in air may cause corona discharges while in liquid insulation discharges may take place in the form of streamer.This paper reports experimental results on the corona and streamer discharges in air and silicone oil.The discharges were artificially generated around a needle tip in a needle-plane electrode system with gap length of 4 mm under sinusoidal and triangular voltages.The needle was made of steel with tip radius of 3 μm and curvature angle of 30°.The needle was made by Ogura Jewelry.The discharge pulses were measured using personal-computer based partial discharge(PD)measurement system with sensitivity of better than 0.5 pC.The system is able to measure discharge in time sequential.Phase-resolved analysis of the discharges was done to interpret the physical processes behind the discharges.The experimental results showed that corona discharges took place at negative half cycles.The discharges were concentrated around 270° of phase angle of applied voltage.The discharge magnitude and discharge number of corona clearly dependent on the instantaneous of applied voltage.These were strongly supported by the application of triangular voltage.Streamer discharges occurred at both positive and negative half cycles.The discharges pulses concentrated around the peak of applied voltage at phase angle of 90° and 270°.Experimental results under sinusoidal and triangular voltages revealed that streamer discharge magnitude as well as probability of occurrence was strongly dependent on the instantaneous applied voltage.

Evaluating the JEFF 3.1, ENDF/B‑VII.0, JENDL 3.3, and JENDL 4.0 nuclear data libraries for a small 100 MWe molten salt reactor with plutonium fuel

This study evaluated the nuclear data libraries for a small 100 Mega Watt electric(MWe)Molten Salt Reactor with plutonium fuel.The reactor has a power output of 100 MWe,which meets the demand for electricity generation in several regions or provinces outside Java Island.Several nuclear data libraries,such as JEFF 3.1,ENDF/B-VII.0,JENDL 3.3,and JENDL 4.0,were used for a more comprehensive evaluation.LiF–BeF_(2)–ThF_(4)–PuF_(4) was used as the initial fuel composition.The thorium and plutonium concentrations in the fuel salt were varied to obtain the optimum fuel composition,leading to critical conditions.The results showed some neutronic parameters,such as the conversion ratio,neutron spectra,and effective multiplication factors,from three different nuclear data libraries.By changing the plutonium concentration in the initial fuel salt composition,the minimum plutonium loaded for the reactor criticality during 2000 days of operation time was determined to be 0.995,0.91,0.87,and 0.90 mol%for JEFF 3.1,ENDF/B-VII.0,JENDL 3.3,and JENDL 4.0,respectively.The differences in the values of each parameter were due to several factors,such as the cross-section values and number of nuclides in the nuclear data libraries.Several safety parameters were also investigated to ensure the possibility of utilizing PuF_(4) in the reactor.

Tracer gas measurement and simulation of turbulent diffusion in mine ventilation airways

The effective diffusion coefficients in mine ventilation-flows had been obtained as 4 to 200 m^2/s by matching the measured concentration-time curves with the advec- tion-diffusion equation.The turbulent diffusion coefficients in the simple airways have good agreement with the equation proposed by Taylor.However,for complex airways in operat- ing mines,the evaluated effective diffusion coefficients in the mines show higher values than that calculated by the Taylor's equation.A numerical simulation model using with movements of discrete particles dosed into ventilation flows has been developed to simu- late diffusion phenomena of gas or dust in mine airways.Numerical simulations had been conducted on distribution of tracers in single airways with ordinary profiles of mean velocity velocity fluctuations and Reynolds stress.As one of results,long band of diffused particles is obtained at the single airway of 600 m in length,and large effective diffusion coefficient is evaluated as 20 m^2/s.

Analysis of explosion risk factor potential on coal reclaim tunnel facilities by modified analytical hierarchy process

This study focused on developing a risk assessment method for explosion at a coal reclaim tunnel （CRT） facility. The method was developed based on an analytical hierarchy process （AHP）, which is an expert system that quantifies the factors of explosion incidents, based on events and hierarchies. In this paper, the proposed model was modification from original AHP model, specifically modifying the structure from ＂alternative＇s results＂ to ＂total risk-rating＇s results＂. The total risk-rating is obtained by summing up risk-rating of each factor, where the risk-rating is a multiplication product of the risk value by the AHP weighted value. To support decision-making using the expert system, data on the real conditions of the CRT were collected and analyzed. A physical modeling of the CRT with laboratory-scale experiments was carried out to show the impact of a ventilation system in CRT on diluting the methane gas and coal dust, in order to support the quantification of AHP risk value. The criteria to evaluate the risk of explosion was constructed from six components that are： fuel, oxygen, ignition, confinement, dispersion, and monitoring system. Those components had fifty-two factors that serve as sub-components （root causes）. The main causes of explosion in CRT were found to be： mechanical ventilation failure and abnormal ventilation, breakdown of monitoring system, and coal spontaneous-combustion. Assessments of two CRT facilities at Mine A and Mine B were carried out as a case study in order to check the reliability of the developed AHP method. The results showed that the risk rating of Mine A was classified as high and Mine B was classified as medium, which is in a good agreement with the site conditions.

Numerical simulation to evaluate gas diffusion of turbulent flow in mine ventilation system

Tracer gas technique is a method to analyze the airflow path, measure the airflow quantity, and detect any recirculation or leakages in underground mine. In addition, it is also possible to evaluate the axial gas diffusion of gas in turbulent bulk flow by utilizing the tracer gas data. This paper discussed about the measurement using tracer gas technique in Cibaliung Underground Mine, Indonesia and the evaluation of effective axial diffusion coefficient, E, by numerical simulation. In addition, a scheme to treat network flow in mine ventilation system was also proposed. The effective axial diffusion coefficient for each airway was evaluated based on Taylor's theoretical equation. It is found that the evaluated diffusion coefficient agrees well with Taylor's equation by considering that the wall friction factor, f, is higher than those for smooth pipe flow. It also shows that the value of effective diffusion coefficient can be inherently determined and the value is constant when matching with other measurements. Furthermore, there are possibilities to utilize the tracer gas measurement data to evaluate the airway friction factors.

Effects of Anodizing Parameters in Tartaric-Sulphuric Acid on Coating Thickness and Corrosion Resistance of Al 2024 T3 Alloy

2024 T3 is one of aluminium alloys which are widely used in the aircraft structures. Anodizing of alluminium alloy in tartaric-sulphuric acid (TSA) electrolyte is developed to obtain more environmentally-friendly process and to produce anodize layer with better corrosion resistance. In this research work, the influences of anodizing parameters of Al 2024 T3 in TSA on the thickness, weight and corrosion resistance of the anodize layer are studied. Corrosion resistance test was carried out by conducting salt spray test for 336 hours and anodic polarization measurements using potentiostat. Results of three-factor analysis of variance (ANOVA) demonstrated that the most influencing factor that determines the thickness and weight of the anodize layer is temperature, followed by applied voltage, duration of anodizing, voltage-temperature interaction, interaction of temperature-duration of anodizing, interaction of voltage-temperature-duration of anodizing, and interaction of voltage and duration of anodizing. The pit density and corrosion current density (icorr) were found to be dependent on the coating thickness. The anodize layer with a thickness of higher than 3 μm was not experienced to pitting corrosion during 336 hours of salt spray test.

Theoretical study of CO2 hydrogenation to methanol on isolated small Pdx clusters

CO2 hydrogenation to methanol on small size Pdxclusters(x = 7, 9 and 13) has been studied using density functional theory calculations. It has been found that in contrast to metallic Pd system, these small Pdxclusters can interact well with CO2 molecule. CO2 molecule can be adsorbed with a bidendate configuration on the Pdxclusters. The formation of CO2 bidendate adsorption configuration facilitates the first step of CO2 hydrogenation reaction on the clusters. The energy profiles for formate pathway and reverse water gas shift + CO hydrogenation pathways on Pdxclusters are quite similar with Cu(111) surface, except for the first and last hydrogenation steps where the Pdxclusters have lower activation energies. This improvement causing the Pdxclusters to have a tolerable turn over frequencies values. In general, the usage of Pd in the form of small size cluster can improve the catalytic performance of metallic Pd for the CO2 hydrogenation to methanol because small size Pd cluster can act not only as an H2 dissociation center but also as a CO2 hydrogenation center.