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Chemical characterization of aquifers with the same geological origin
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作者 Nathalie Gassama Haino Uwe Kasper +3 位作者 Aline Dia Nathalie Jendrzejewski Constantin Cocirta Sophie Violette 《Chinese Journal Of Geochemistry》 EI CAS 2006年第B08期158-158,共1页
关键词 岩石 交互作用 地球化学 微量元素 含水层
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Optimal parameter selection for qualitative regional erosion risk monitoring:A remote sensing study of SE Ethiopia 被引量:4
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作者 Moncef Bouaziz Mathias Leidig Richard Gloaguen 《Geoscience Frontiers》 SCIE CAS 2011年第2期237-245,共9页
Arid and semi-arid regions are susceptible to high levels of erosion. A rapid and cost effective methodological erosion assessment for these regions is required to describe and monitor the processes that control erosi... Arid and semi-arid regions are susceptible to high levels of erosion. A rapid and cost effective methodological erosion assessment for these regions is required to describe and monitor the processes that control erosion. This study uses remote sensing to describe the contribution of several factors that control erosion. Topography, land use, vegetation density, soil properties and climatic proxies are used to determine erosion risk and to provide basic maps of water and soil conservation practices. A hierarchical decision tree is used to sum and combine the weight of parameters controlling the erosion. The assigned weights of each spatial unit express the susceptibility to erosion. We focus on the catchment basin of the Maleka Wakena reservoir, located in the southeastern portion of the main Ethiopian Rift, where erosion is the major environmental problem. Three different combinations of the dominant controlling factors are yielded in this study. In order to optimize the qualitative erosion risk assessment, each combination is discussed and evaluated depending on the contribution of parameters involved in the erosion process. 展开更多
关键词 Erosion risk Remote sensing MODELING Geographic informationsystem (GIS) Ethiopia
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Thermal evolution of an ancient subduction interface revealed by Lue Hf garnet geochronology, Halilba■? Complex(Anatolia) 被引量:1
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作者 Amaury Pourteau Erik E.Scherer +3 位作者 Simon Schorn Rebecca Bast Alexander Schmidt Lisa Ebert 《Geoscience Frontiers》 SCIE CAS CSCD 2019年第1期127-148,共22页
The thermal structure of subduction zones exerts a major influence on deep-seated mechanical and chemical processes controlling arc magmatism, seismicity, and global element cycles. Accretionary complexes exposed inla... The thermal structure of subduction zones exerts a major influence on deep-seated mechanical and chemical processes controlling arc magmatism, seismicity, and global element cycles. Accretionary complexes exposed inland may comprise tectonic blocks with contrasting pressureetemperature(Pe T)histories, making it possible to investigate the dynamics and thermal evolution of former subduction interfaces. With this aim, we present new Lue Hf geochronological results for mafic rocks of the Halilbag?Complex(Anatolia) that evolved along different thermal gradients. Samples include a lawsoniteeepidote blueschist, a lawsoniteeepidote eclogite, and an epidote eclogite(all with counter-clockwise Pe T paths),a prograde lawsonite blueschist with a "hairpin"-type Pe T path, and a garnet amphibolite from the overlying sub-ophiolitic metamorphic sole. Equilibrium phase diagrams suggest that the garnet amphibolite formed at w0.6 -0.7 GPa and 800 -850℃, whereas the prograde lawsonite blueschist records burial from 2.1 GPa and 420℃ to 2.6 GPa and 520℃. Well-defined Lue Hf isochrons were obtained for the epidote eclogite(92.38 ± 0.22 Ma) and the lawsoniteeepidote blueschist(90.19 ± 0.54 Ma),suggesting rapid garnet growth. The lawsoniteeepidote eclogite(87.30 ± 0.39 Ma) and the prograde lawsonite blueschist(ca. 86 Ma) are younger, whereas the garnet amphibolite(104.5 ± 3.5 Ma) is older.Our data reveal a consistent trend of progressively decreasing geothermal gradient from granulite-facies conditions at ~104 Ma to the epidote-eclogite facies around 92 Ma, and the lawsonite blueschist-facies between 90 Ma and 86 Ma. Three Lue Hf garnet dates(between 92 Ma and 87 Ma) weighted toward the growth of post-peak rims(as indicated by Lu distribution in garnet) suggest that the HP/LT rocks were exhumed continuously and not episodically. We infer that HP/LT metamorphic rocks within the Halilbag?Complex were subjected to continuous return flow, with "warm" rocks being exhumed during the tectonic burial of "cold" ones. Our results, combined with regional geological constraints, allow us to speculate that subduction started at a transform fault near a mid-oceanic spreading centre. Following its formation, this ancient subduction interface evolved thermally over more than 15 Myr, most likely as a result of heat dissipation rather than crustal underplating. 展开更多
关键词 SUBDUCTION Lu/Hf dating of GARNET Metamorphic sole ECLOGITE BLUESCHIST LAWSONITE
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The significance of U-Pb zircon ages in zoned plutons:the case of the Flamenco pluton, Coastal Range batholith, northern Chile
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作者 Natalia Rodríguez Juan Díaz-Alvarado +3 位作者 Carlos Fernández Paulina Fuentes Christoph Breitkreuz Colombo Celso Gaeta Tassinari 《Geoscience Frontiers》 SCIE CAS CSCD 2019年第3期1073-1099,共27页
Compositionally zoned plutons, both layered and concentrically arranged, provide granitic exposures where the mechanisms and timing of the magmatic emplacement processes can be studied. The importance of in-situ geoch... Compositionally zoned plutons, both layered and concentrically arranged, provide granitic exposures where the mechanisms and timing of the magmatic emplacement processes can be studied. The importance of in-situ geochemical differentiation and the magma replenishment rates are revealed by geochemistry and field relations, together with the increasingly accurate U-Pb geochronology, which has promoted the knowledge about the pluton incremental assembly theories.The Flamenco pluton, located in the Coastal Range of northern Chile, is part of the Upper Triassic to Early Cretaceous Andean intrusives formed in the western active margin of South America, and present a normal zoned structure with mafic magmatic facies(mostly gabbros and Qtz-diorites) close to the contacts with the host metasediments, and tonalites, granodiorites and granites in the inner areas. A combined study of the field relations, geochemistry and zircon geochronology of the magmatic facies was applied to determine the emplacement sequence of the Flamenco pluton, revealing three distinguishable domains separated by metasedimentary septa. The SW area is constituted by mostly homogeneous leucocratic granodiorites that yielded an age of 213 Ma as the best estimation for their emplacement age. Distinctive geochemical characteristics, such as the absence of an Eu anomaly, the depletion in HREE, or the highest Sr, Sr/Y and Ce/Yb values among the granodioritic facies of the pluton,involve lower T and/or higher P conditions at the magmatic source according to experimental studies.These conditions were established during an early stage of the Andean magmatic arc building that is firstly defined here as Upper Triassic. The NW and E domains of the pluton were sequentially emplaced between 194 Ma and 186 Ma and both the field relations and the detailed geochronological results suggest that the mafic facies intruded latter in the emplacement sequence. To the NW, Qtz-dioritic and gabbroic externally emplaced pulses gave a younger crystallization age of 186.3 ± 1.8 Ma, and promoted the granoblastic textures and metamorphic zircon overgrowths that characterize the granodiorites located in the contact with the intermediate and felsic inner magmas, which yielded a best estimation of their emplacement age of 192 士 1.5 Ma. On the other hand, in the eastern domain, magma-magma relations are observed between gabbros and previously intruded tonalites and granodiorites. Both the mafic and intermediate facies show two main subgroups of ages that yielded 194.7 土 1.5 Ma to188.3 ± 2.1 Ma and 193.1 ± 2.2 Ma to 185.5 ± 1.4 Ma respectively. These differences are related to the variations in the magmatic addition rates, which may extend the super-solidus conditions in the eastern domain of the magmatic reservoir as is confirmed by the wider age ranges yielded by these magmatic facies. Zircon overgrowths in the host rocks yield similar ages(around 220 Ma and 205 Ma) than the oldest results obtained in the intrusive facies, indicating that metamorphism correlates with the initial stages of plutonic emplacement.Geochronological results differ between 9 Myr and 41 Myr in the eight studied samples for noninherited ages and gave very close mean ages(within analytical uncertainty) for all the intrusive units. However, we examine other characteristics such as zircon morphology, internal structure,geochemistry and statistical data to assess if the scattering of the geochronological data may be related to the different processes involved in the construction of the Flamenco pluton. We concluded that this detailed study of U-Pb zircon ages, including individual and significative groups of analyses, is useful to determine accurately the emplacement sequence and the genetic relation between the intrusive units,together with the evidences depicted by the geochemistry and field relations. 展开更多
关键词 ZIRCON U-Pb geochronology Zoned PLUTONS Andean MAGMATIC arc Sequential EMPLACEMENT Individual and statistical ZIRCON ages
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RECORD OF BLOCK ROTATION AND MAGNETIC FIELD REVERSALS IN THE TETHYAN HIMALAYA(HIDDEN VALLEY,CENTRAL NEPAL)
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作者 C.Crouzet H.Stang +1 位作者 E.Schill E.Appel 《地学前缘》 EI CAS CSCD 2000年第S1期56-57,共2页
Metasediments from the Tethyan Himalaya (TH) were sampled for paleomagnetic studies in several areas. In this paper, we will present the first results from Carboniferous and Early Triassic marly limestones from Hidden... Metasediments from the Tethyan Himalaya (TH) were sampled for paleomagnetic studies in several areas. In this paper, we will present the first results from Carboniferous and Early Triassic marly limestones from Hidden Valley (Central Nepal).. The paleomagnetic directions reflect a Tertiary overprint probably synchronous with the metamorphism. In this area, the metamorphic conditions reached during Tertiary are poorly constrained. Temperatures are probably in between 300 and 400℃. The age of the thermal event is still debated. No geochronological data is available in this area. Previously published geochronological data from the northern part of TH metasediments in India ranges from 47 to 42Ma (Ar/Ar Illite) after Weissman et al. (1999) and Bonhomme and Garzanti (1991). While in the southern part (close to HHC), biotite Ar/Ar data ranges from 30 to 26Ma in Marsyandi Valley (Coleman and Hodges, 1998) and muscovite Ar/Ar ranges from 18 to 12Ma in the upper Kali Gandaki Valley (Godin et al., 1998).. In this context, the age of the magnetization can′t be defined with precision. 展开更多
关键词 PALEOMAGNETISM Central Nepal Tethyan Himalaya block rotation thermal evolution
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Recycling process and proto-kimberlite melt metasomatism in the lithosphere-asthenosphere boundary beneath the Amazonian Craton recorded by garnet xenocrysts and mantle xenoliths from the Carolina kimberlite
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作者 Fernanda Gervasoni Tiago Jalowitzki +9 位作者 Marcelo Peres Rocha Ricardo Kalikowski Weska Eduardo Novais-Rodrigues Rodrigo Antonio de Freitas Rodrigues Yannick Bussweiler Elisa Soares Rocha Barbosa Jasper Berndt Elton Luiz Dantas Valmir da Silva Souza Stephan Klemme 《Geoscience Frontiers》 SCIE CAS CSCD 2022年第5期89-105,共17页
Here we present new data on the major and trace element compositions of silicate and oxide minerals from mantle xenoliths brought to the surface by the Carolina kimberlite,Pimenta Bueno Kimberlitic Field,which is loca... Here we present new data on the major and trace element compositions of silicate and oxide minerals from mantle xenoliths brought to the surface by the Carolina kimberlite,Pimenta Bueno Kimberlitic Field,which is located on the southwestern border of the Amazonian Craton.We also present Sr-Nd isotopic data of garnet xenocrysts and whole-rocks from the Carolina kimberlite.Mantle xenoliths are mainly clinopyroxenites and garnetites.Some of the clinopyroxenites were classified as GPP–PP–PKP(garnet-phlogopite peridotite,phlogopite-peridotite,phlogopite-K-richterite peridotite)suites,and two clinopyroxenites(eclogites)and two garnetites are relicts of an ancient subducted slab.Temperature and pressure estimates yield 855–1102℃ and 3.6–7.0 GPa,respectively.Clinopyroxenes are enriched in light rare earth elements(LREE)(La_(N)/Yb_(N)=5–62;Ce_(N)/Sm_(N)=1–3;where N=primitive mantle normalized values),they have high Ca/Al ratios(10–410),low to medium Ti/Eu ratios(742–2840),and low Zr/Hf ratios(13–26),which suggest they were formed by metasomatic reactions with CO_(2)-rich silicate melts.Phlogopite with high TiO_(2)(>2.0 wt.%),Al_(2)O_(3)(>12.0 wt.%),and FeOt(5.0–13.0 wt.%)resemble those found in the groundmass of kimberlites,lamproites and lamprophyres.Conversely,phlogopite with low TiO_(2)(<1.0 wt.%)and lower Al_(2)O_(3)(<12.0 wt.%)are similar to those present in GPP-PP-PKP,and in MARID(mica-amphibole-rutile-ilmenite-diopside)and PIC(phlogopite-ilmenite-clinopyorxene)xenoliths.The GPP-PP-PKP suite of xenoliths,together with the clinopyroxene and phlogopite major and trace element signatures suggests that an intense proto-kimberlite melt metasomatism occurred in the deep cratonic lithosphere beneath the Amazonian Craton.The Sr-Nd isotopic ratios of pyrope xenocrysts(G3,G9 and G11)from the Carolina kimberlite are characterized by high ^(143)Nd/^(144)Nd(0.51287–0.51371)and eNd(+4.55 to+20.85)accompanied with enriched ^(87)Sr/^(86)Sr(0.70405–0.71098).These results suggest interaction with a proto-kimberlite melt compositionally similar with worldwide kimberlites.Based on Sr-Nd whole-rock compositions,the Carolina kimberlite has affinity with Group 1 kimberlites.The Sm-Nd isochron age calculated with selected eclogitic garnets yielded an age of 291.9±5.4 Ma(2σ),which represents the cooling age after the proto-kimberlite melt metasomatism.Therefore,we propose that the lithospheric mantle beneath the Amazonian Craton records the Paleozoic subduction with the attachment of an eclogitic slab into the cratonic mantle(garnetites and eclogites);with a later metasomatic event caused by proto-kimberlite melts shortly before the Carolina kimberlite erupted. 展开更多
关键词 Carolina kimberlite K-rich mantle xenoliths Ancient subducted slab Proto-kimberlite melt metasomatism
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贵州独山与奥地利格拉茨中泥盆世Argutastrea珊瑚群之对比 被引量:1
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作者 廖卫华 Bernhard Hubmann 《古生物学报》 CAS CSCD 北大核心 2006年第1期52-59,共8页
锐星珊瑚(Argutastrea)是泥盆纪地层中常见的一种块状群体珊瑚,它在生物地层对比、生物地理区系划分以及古生态与古地理重建等方面都具有重要的意义。通过近年来对华南独山和奥地利格拉茨两地采集的Argutastrea群体珊瑚标本进行比较深... 锐星珊瑚(Argutastrea)是泥盆纪地层中常见的一种块状群体珊瑚,它在生物地层对比、生物地理区系划分以及古生态与古地理重建等方面都具有重要的意义。通过近年来对华南独山和奥地利格拉茨两地采集的Argutastrea群体珊瑚标本进行比较深入的对比研究,确认两地存在着一些十分相似的属种,推断彼此之间当时可能海域相通,并同属于一个老世界生物地理大区(Old World Real m)。此外,还讨论了该属与其相关的六方珊瑚(Hexagonaria)、多角珊瑚(Prismatophyllum)等属之间的异同。 展开更多
关键词 锐星珊瑚 六方珊瑚 多角珊瑚 泥盆纪 贵州独山 格拉茨
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Snowball Earth is dead! Long live Snowball Earth!
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作者 Graham A. Shields 《Episodes》 SCIE 2006年第4期287-288,共2页
关键词 瑞士 雪球 气候变化 二氧化碳 全球变暖 环境气候问题
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三水盆地古近系湖相沉积岩的氧、碳同位素地球化学记录及其环境意义 被引量:27
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作者 刘春莲 Franz T Fürsich +2 位作者 白雁 杨小强 李国强 《沉积学报》 CAS CSCD 北大核心 2004年第1期36-40,共5页
三水盆地古近系莘庄组顶部至土布心组红岗段的全岩碳酸盐稳定同位素分析结果表明其形成期间经历了多次环境变迁。根据碳酸盐氧、碳同位素比值及其相互关系的变化 ,可识别三次海水入侵期。其时δ18O值大幅度向正值漂移。而由于受有机质... 三水盆地古近系莘庄组顶部至土布心组红岗段的全岩碳酸盐稳定同位素分析结果表明其形成期间经历了多次环境变迁。根据碳酸盐氧、碳同位素比值及其相互关系的变化 ,可识别三次海水入侵期。其时δ18O值大幅度向正值漂移。而由于受有机质降解的影响 ,相应时期的δ13 C均表现为低值。在不直接受海洋影响的湖相沉积阶段 ,δ18O与δ13 C的相关程度虽然未达到典型的封闭型湖泊水平 ,但仍呈现一定的正相关变化 (r =0 .6 5 ) ,表明其湖水滞留时间较长。而频繁出现的石膏薄层沉积也指示湖盆的封闭性较好。这些均表明这一时期的三水盆地可能是一周期性封闭型湖泊。其稳定同位素组成主要受制于蒸发量 /降雨量平衡的变化。而δ13 C比值往往还受有机质活动的控制 ,更多的是反映有机质生产力。 展开更多
关键词 氧碳同位素 碳酸盐 湖相沉积 古近系 三水盆地
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Remote Gully Erosion Mapping Using ASTER Data and Geomorphologic Analysis in the Main Ethiopian Rift 被引量:3
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作者 Moncef Bouaziz Arief Wijaya Richard Gloaguen 《Geo-Spatial Information Science》 2011年第4期246-254,共9页
The Main Ethiopian Rift(MER)is an area of extreme topography underlain by post-Miocene volcanic rocks,Jurassic limestone and a Precambrian basement.A prime concern is the rapid expansion of wide gullies that are impin... The Main Ethiopian Rift(MER)is an area of extreme topography underlain by post-Miocene volcanic rocks,Jurassic limestone and a Precambrian basement.A prime concern is the rapid expansion of wide gullies that are impinging on agricultural land.We investigate the potential contribution of Advanced Space-borne Thermal Emission and Reflection Radiometer(ASTER)data and geomorphologic parameters to discern patterns and features of gully erosion in the MER.Maximum Likelihood Classifica-tion(MLC),Support Vector Machine(SVM),and Minimum Distance(MD)classifiers are used to extract different gully shapes and patterns.Several spatial textures based on Grey Level Co-occurrence Matrices(GLCMs)are then generated.Afterwards,the same classifiers are applied to the ASTER data combined with the spatial texture information.We used geomorphologic parameters ex-tracted from SRTM and ASTER DEMs to describe the geomorphologic setting and the gullies' shapes.The classifications show accuracies varying between 67% and 89%.Maps derived from this quantitative analysis allow the monitoring and mapping of land degradation as a direct result of gully-widening.This study reveals the utility of combining ASTER data and spatial textural infor-mation in discerning areas affected by gully erosion. 展开更多
关键词 ASTER数据 沟壑侵蚀 埃塞俄比亚 地貌分析 裂谷 映射 最大似然分类 空间结构信息
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Interbasinal marker intervals——A case study from the Jurassic basins of Kachchh and Jaisalmer, western India 被引量:3
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作者 PANDEY Dhirendra Kumar FüRSICH Franz Theodor 《Science China Earth Sciences》 SCIE EI CAS 2009年第12期1924-1931,共8页
The Kachchh Basin and the Jaisalmer Basin are two neighboring Mesozoic sedimentary basins at the western margin of the Indian craton. The Jurassic succession of the Kachchh Basin is more complete and more fossiliferou... The Kachchh Basin and the Jaisalmer Basin are two neighboring Mesozoic sedimentary basins at the western margin of the Indian craton. The Jurassic succession of the Kachchh Basin is more complete and more fossiliferous than that of the Jaisalmer Basin. Consequently, intrabasinal correlation of the sedimentary units has been possible in the Kachchh Basin, but not in the Jaisalmer Basin. However, some marker beds existing in the Kachchh Basin can be recognized also in the Jaisalmer Basin. Ammonite evidence shows that they are time-equivalent. The following four units form marker intervals in both basins: (1) the pebbly rudstone unit with Isastrea bernardiana and Leptosphinctes of the Kaladongar Formation (Kachchh Basin) and the Isastrea bernardiana-bearing rudstone of the Jaisalmer Formation (Jaisalmer Basin) both represent transgressive systems tract deposits dated as Late Bajocian; (2) bioturbated micrites with anomalodesmatan bivalves within the Goradongar Yellow Flagstone Member (Kachchh Basin) and bioturbated units in the Fort Member (Jaisalmer Basin) represent maximum flooding zone deposits of the Middle to Late Bathonian; (3) trough-crossbedded, sandy packto grainstones of the Raimalro Limestone Member (Kachchh Basin) and the basal limestone-sandstone unit of the Kuldhar section of the Jaisalmer Formation (Jaisalmer Basin) correspond to Late Bathonain transgressive systems tract deposits; and (4) ferruginous ooid-bearing carbonates with hardgrounds of the Dhosa Oolite member (Kachchh Basin) and the middle part of the Jajiya Member (Jaisalmer Basin) are Oxfordian transgressive systems tract deposits. The fact that in both basins similar biofacies prevailed during certain time intervals demonstrates a common control of their depositional history. As the two basins represent different tectonic settings, the most likely controlling factors were the relative sea-level changes produced by eustatic processes, a common subsidence history of the northwestern margin of the Indian craton, and the paleoclimate. 展开更多
关键词 JURASSIC interbasinal correlation MARKER BEDS sequence stratigraphy India
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Experimental constraints on the genesis of Jadeite quartzite from Shuanghe,Dabie Mountain ultra-high pressure metamorphic terrane 被引量:1
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作者 ZHANG YanFei WU Yao +2 位作者 WANG Chao JIN ZhenMin Hans-Peter SCHERTL 《Science China Earth Sciences》 SCIE EI CAS 2014年第1期104-116,共13页
Jadeite quartzite,essentially a two-phase rock made up of jadeite and quartz,is one of the most important UHP lithologies occurring in the Dabie Mountain ultrahigh pressure metamorphic belt and forms layers in biotite... Jadeite quartzite,essentially a two-phase rock made up of jadeite and quartz,is one of the most important UHP lithologies occurring in the Dabie Mountain ultrahigh pressure metamorphic belt and forms layers in biotite-plagioclase gneiss.High pressurehigh temperature studies on natural albite from the country rock gneiss were undertaken to reveal the—in parts—complex mineralogical changes that occur in the jadeite quartzite during prograde metamorphism.Experiments were conducted at 800–1200°C,in the pressure range of 2.0–3.5 GPa.One of the most intriguing results shows that the low pressure boundary of the jadeite+coesite stability field is located between about 3.2 GPa at 1000°C and 3.4 GPa at 1200°C,thus about(0.2–0.3)±0.1GPa higher than the quartz-coesite transition curve,given the uncertainty in the present study.Minor amounts of sodium and aluminum entering the structure of quartz and the intimate intergrowth texture of the run products may contribute to the observed pressure shift.Combined petrological and mineralogical studies on the run products and the natural rocks yield the following prograde reaction sequence to have occurred:The protolith of the jadeite-quartzite from Dabie Mountain is an albitized siltstone/greywacke characterized by an albite+quartz assemblage.During prograde metamorphism albite breaks down to form jadeite+quartz and thus at this stage two types of quartz can be distinguished whereas type-I-quartz already existed in the protolith,type-II-quartz represents a newly formed reaction product of albite.During further P-T-increase the pure type-I-quartz was transformed to coesite,whereas type-II-quartz(together with jadeite)was still present as a stable phase because of its impurities of Na and Al.At a later stage during further subduction,type-II-quartz also decomposes to form coesite.These studies represent an important puzzlement for a better understanding of the evolution of jadeite-quartzite from the Dabie Mountain during continental crust subduction and thus contribute to a more complete knowledge of the formation of the Dabie Mountain UHP orogenic belt in general. 展开更多
关键词 超高压变质地体 硬玉石英岩 大别山 翡翠 实验 黑云斜长片麻岩 双河 成因
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纤磷钙铝石类化合物:来自地球具工艺用途的材料(英文)
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作者 Roland G.Schwab Thomas H.Pimpl +1 位作者 Harald Schukow Dietrich 《地学前缘》 EI CAS CSCD 2000年第2期485-497,共13页
纤磷钙铝石类化合物系由自纤磷钙铝石CaAl3 (OH) 6(HPO4) (PO4)本身、经磷钙铝石CaAl3 (OH) 6(SO4) (PO4)到钾明矾石KAl3 (OH ) 6(SO4) 2 等的天然矿物族所组成的。它们表现出具有很大范围的阳离子置换系列 ,其中以Sr2 +和Ba2 +置换Ca2 ... 纤磷钙铝石类化合物系由自纤磷钙铝石CaAl3 (OH) 6(HPO4) (PO4)本身、经磷钙铝石CaAl3 (OH) 6(SO4) (PO4)到钾明矾石KAl3 (OH ) 6(SO4) 2 等的天然矿物族所组成的。它们表现出具有很大范围的阳离子置换系列 ,其中以Sr2 +和Ba2 +置换Ca2 +,REEs3 +置换Ca2 +和H+,As5 +置换P5 +,S6+/Se6+置换H+P5 +最为重要。随着置换的进行 ,其热动力学稳定性也逐渐增加。由此 ,纤磷钙铝石类化合物成为很能抗风化的矿物 ,在红土中尤其如此。厚的纤磷钙铝石层形成在闪长岩 (富Sr) ,碳酸盐岩 (富REEs)和含金石英脉 (富As)之上 ,从而保护整个磷酸盐红土 ,使之免受风化。以此方式 ,形成了桌状山脉或岛屿 ,他们具有未受覆盖的表面。这些“纤磷钙铝”石化合物为上述及其它元素形成一有效的地球化学障。“纤磷钙铝石”的这种天然地球化学固定作用可以用适当的母体或人工合成晶体来进行模拟 ,即通过金属阳离子交换或就地反应来模拟。这种固定作用还可用于处理天然和人造的放射性裂变产物、有毒的重金属元素、砷酸盐和硒酸盐、硫酸盐等。 展开更多
关键词 钾明矾石 纤磷钙铝石 磷铈铝石 地球化学障
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湖泊沉积物磁学性质的环境意义 被引量:56
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作者 胡守云 邓成龙 +1 位作者 E. Appel K. Verosub 《科学通报》 EI CAS CSCD 北大核心 2001年第17期1491-1494,共4页
对湖泊沉积物磁性矿物的来源及其鉴别方法进行了较为深入系统的分析, 发现不同湖泊沉积物的磁学参数具有不同的气候响应过程. 提出为了恢复古气候和古环境的变化过程, 详细的岩石磁学和土壤磁学研究是认识湖泊沉积物磁学性质及其环境意... 对湖泊沉积物磁性矿物的来源及其鉴别方法进行了较为深入系统的分析, 发现不同湖泊沉积物的磁学参数具有不同的气候响应过程. 提出为了恢复古气候和古环境的变化过程, 详细的岩石磁学和土壤磁学研究是认识湖泊沉积物磁学性质及其环境意义的基础. 展开更多
关键词 岩石磁学 古气候 湖泊沉积物 磁性矿物 土壤磁学 环境磁学 磁化率
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