Kanglemeisu A (C50H63O19N·CH3OH) is the product of an actinomyces species from a soil sample gathered in China. Kanglemeisu A belongs to the triclinic system, space group P1,unit cell:a=12.760（3）, b=10.287（2）...Kanglemeisu A (C50H63O19N·CH3OH) is the product of an actinomyces species from a soil sample gathered in China. Kanglemeisu A belongs to the triclinic system, space group P1,unit cell:a=12.760（3）, b=10.287（2）, c=9.926（2） , α=88.39（2）,β=78.64（2）, γ=89.14（2）. RANTAN direct method is used to solve the structure.The final discrepancy factor is R=0.0689, after atom coordinates and temperature factors have been refined with full matrix least squares.The structure skeleton consists of four parts, the naphthalene nucleus connected to the 5-membered ring, a 17-membered ring connected to C2, a dimethyl butane diacid extended out from C20, β-D-3,4-OO’ methylenedigitoxose passing through an oxygen bridge O6 and linked to C27 of ansa ring.展开更多
文摘Kanglemeisu A (C50H63O19N·CH3OH) is the product of an actinomyces species from a soil sample gathered in China. Kanglemeisu A belongs to the triclinic system, space group P1,unit cell:a=12.760（3）, b=10.287（2）, c=9.926（2） , α=88.39（2）,β=78.64（2）, γ=89.14（2）. RANTAN direct method is used to solve the structure.The final discrepancy factor is R=0.0689, after atom coordinates and temperature factors have been refined with full matrix least squares.The structure skeleton consists of four parts, the naphthalene nucleus connected to the 5-membered ring, a 17-membered ring connected to C2, a dimethyl butane diacid extended out from C20, β-D-3,4-OO’ methylenedigitoxose passing through an oxygen bridge O6 and linked to C27 of ansa ring.
