The effects of alternating magnetic field on the corrosion morphologies, corrosion rate, and corrosion products of copper in 3.5% NaCl solution, sea water, and magnetized sea water were investigated using electrochemi...The effects of alternating magnetic field on the corrosion morphologies, corrosion rate, and corrosion products of copper in 3.5% NaCl solution, sea water, and magnetized sea water were investigated using electrochemical test, scanning electron microscopy/energy dispersive analysis system of X-ray （SEM/EDAX）, and X-ray diffraction （XRD）. The results show that the corrosion rate of copper in magnetized sea water is minimal. Moreover, the surface of the specimen in magnetized sea water is uniform and compact as compared with those in 3.5% NaCl solution and sea water. The corrosion products of copper in magnetized sea water are mainly Cu2O and CuCl2. However, the corrosion products in sea water are CuCl, Cu2Cl（OH）3, and FeCl3-6H2O. The electrochemical corrosion mechanisms of copper in the three media were also discussed.展开更多
The corrosion characteristics of copper in magnetic action system were investigated by mass loss method,electrochemical test,scanning electron microscopy(SEM) and energy analysis. It is found that the corrosion proces...The corrosion characteristics of copper in magnetic action system were investigated by mass loss method,electrochemical test,scanning electron microscopy(SEM) and energy analysis. It is found that the corrosion process of copper is influenced by magnetic field. The flow corrosion rate of copper decreases at the initial segment,then drives to gentle stage at the final segment. From electrochemical test,the corrosion rate of copper in the magnetized sea water is minimal compared with that in 3.5% NaCl solution and sea water. Electrochemical impedance spectroscopy(EIS) plots of copper in 3.5% NaCl,sea water and magnetized sea water are similar. However,EIS plot of copper in magnetized sea water shifts rightwards due to the effect of magnetic field on sea water. The corrosion process of copper in magnetized sea water is pitting corrosion. The surfaces of samples are finer in magnetized sea water relative to those in 3.5% NaCl solution and sea water. The corrosion products of copper include large amount of Cu element,O element and Cl element. Cu2O and CuCl2 are the primary products. This suggests that electromagnetic treatment has remarkable effect on the corrosion of copper.展开更多
The corrosion process of copper in thermal flow system was investigated through the experimental bench.According to surface variation of samples during corrosion process,the surface model of specimen was build up base...The corrosion process of copper in thermal flow system was investigated through the experimental bench.According to surface variation of samples during corrosion process,the surface model of specimen was build up based on Gaussian filter.The results show that the corrosion characterization of copper in thermal flow system is pitting corrosion.The morphology characterizations of metal corrosion process can be described using the proposed surface model.The generation and development of copper pitting process can be observed clearly.展开更多
文摘The effects of alternating magnetic field on the corrosion morphologies, corrosion rate, and corrosion products of copper in 3.5% NaCl solution, sea water, and magnetized sea water were investigated using electrochemical test, scanning electron microscopy/energy dispersive analysis system of X-ray （SEM/EDAX）, and X-ray diffraction （XRD）. The results show that the corrosion rate of copper in magnetized sea water is minimal. Moreover, the surface of the specimen in magnetized sea water is uniform and compact as compared with those in 3.5% NaCl solution and sea water. The corrosion products of copper in magnetized sea water are mainly Cu2O and CuCl2. However, the corrosion products in sea water are CuCl, Cu2Cl（OH）3, and FeCl3-6H2O. The electrochemical corrosion mechanisms of copper in the three media were also discussed.
文摘The corrosion characteristics of copper in magnetic action system were investigated by mass loss method,electrochemical test,scanning electron microscopy(SEM) and energy analysis. It is found that the corrosion process of copper is influenced by magnetic field. The flow corrosion rate of copper decreases at the initial segment,then drives to gentle stage at the final segment. From electrochemical test,the corrosion rate of copper in the magnetized sea water is minimal compared with that in 3.5% NaCl solution and sea water. Electrochemical impedance spectroscopy(EIS) plots of copper in 3.5% NaCl,sea water and magnetized sea water are similar. However,EIS plot of copper in magnetized sea water shifts rightwards due to the effect of magnetic field on sea water. The corrosion process of copper in magnetized sea water is pitting corrosion. The surfaces of samples are finer in magnetized sea water relative to those in 3.5% NaCl solution and sea water. The corrosion products of copper include large amount of Cu element,O element and Cl element. Cu2O and CuCl2 are the primary products. This suggests that electromagnetic treatment has remarkable effect on the corrosion of copper.
基金Project(2008DFR60340)supported by the International Science and Technology Cooperation of ChinaProject(2008087)supported by Scientific Technological Project of Weihai,China。
文摘The corrosion process of copper in thermal flow system was investigated through the experimental bench.According to surface variation of samples during corrosion process,the surface model of specimen was build up based on Gaussian filter.The results show that the corrosion characterization of copper in thermal flow system is pitting corrosion.The morphology characterizations of metal corrosion process can be described using the proposed surface model.The generation and development of copper pitting process can be observed clearly.
