Experimental and petrological constraints on local-scale interaction of biotite-amphibole gneiss with H_2O-CO_2-(K,Na) Cl fluids at middle-crustal conditions:Example from the Limpopo Complex,South Africa

Reaction textures and fluid inclusions in the -2.0 Ga pyroxene-bearing dehydration zones within the Sand River biotite-hornblende orthogneisses （Central Zone of the Limpopo Complex） suggest that the formation of these zones is a result of close interplay between dehydration process along ductile shear zones triggered by H2O-CO2-salt fluids at 750--800 ℃ and 5.5--6.2 kbar, partial melting, and later exsolution of residual brine and H2O-CO2 fluids during melt crystallization at 650--700 ℃. These processes caused local variations of water and alkali activity in the fluids, resulting in various mineral assemblages within the dehydration zone. The petrological observations are substantiated by experiments on the interaction of the Sand River gneiss with the H2O-CO2-（K, Na）Cl fluids at 750 and 800 ℃ and 5.5 kbar. It follows that the interaction of biotite-amphibole gneiss with H2O-CO2-（K, Na）CI fluids is accompanied by partial melting at 750--800 ℃. Orthopyroxene-bearing assemblages are characteristic for temperature 800 ℃ and are stable in equilibrium with fluids with low salt concentrations, while salt-rich fluids produce clinopyroxene-bearing assemblages. These observations are in good agreement with the petrological data on the dehydration zones within the Sand River olthogneisses.

Alkali control of high-grade metamorphism and granitization

We review petrologic observations of reaction textures from high-grade rocks that suggest the passage of fluids with variable alkali activities. Development of these reaction textures is accompanied by regular compositional variations in plagioclase, pyroxenes, biotite, amphibole and garnet. The textures are interpreted in terms of exchange and net-transfer reactions controlled by the K and Na activities in the fluids. On the regional scale, these reactions operate in granitized, charnockitized, syenitized etc. shear zones within high-grade complexes. Thermodynamic calculations in simple chemical systems show that changes in mineral assemblages, including the transition from the hydrous to the anhydrous ones, may occur at constant pressure and temperature due only to variations in the H2O and the alkali activities. A simple procedure for estimating the activity of the two major alkali oxides, K2O and Na2O, is imple- mented in the TWQ software. Examples of calculations are presented for well-documented dehydration zones from South Africa, southern India, and Sri Lanka. The calculations have revealed two end-member regimes of alkalis during specific metamorphic processes： rock buffered, which is characteristic for the precursor rocks containing two feldspars, and fluid-buffered for the precursor rocks without K-feldspar. The observed reaction textures and the results of thermodynamic modeling are compared with the results of available experimental studies on the interaction of the alkali chloride and carbonate-bearing fluids with metamorphic rocks at mid-crustal conditions. The experiments show the complex effect of alkali activities in the fluid phase on the mineral assemblages. Both thermodynamic calculations and experiments closely reproduce paragenetic relations theoretically predicted by D.S. Korzhinskii in the 1940s.

Huge Variety of Nuclides That Arise in the LENR Processes: Attempt at Explanation

Researches in the field of low-energy nuclear reactions (LENR) have shown a wide variety of manifestations of these phenomena. They appear in metals with hydrogen dissolved in them, in plasma, in gas discharge, in electrolysis, and even in biological systems. In addition to energy release, which far exceeds the capabilities of chemical reactions, LENR is characterized by a huge variety of emerging chemical elements. This report provides examples of appearance of many initially missing elements in different LENR installations. For example, in the nickel-hydrogen LENR reactor created in our laboratory, which worked for 7 months, Ca, V, Ti, Mn, Fe, Co, Cu, Zn, Ga, Ba, Sr, Yb, Hf were found. Moreover, new elements were found not only in the “fuel” but also in the surrounding matter. The huge variety of chemical elements that arise can be explained by the fact that in the processes of LENR, the interaction covers several atoms at once. The article discusses approaches to explaining the phenomena discovered in the process of LENR researches.

地球和月球起源的非传统模型(英文)

46亿年以来 ,地球的内力活动是由地球液体内核上升的富氢挥发物流所维持的。为了解释这些导致地球内核如此巨量氢集中的作用 ,文中提出了一个关于地球、其它行星及作为一个整体的太阳系 ,其起源与演化的非传统的岩石学模型。排氢脉冲导致洋壳扩张的增强 ,而此则与创造出造山带的地壳变动幕相关。随后大洋底板活动的减弱 ,则招致褶皱陆壳的剥蚀 ,并伴有广泛展布的玄武岩岩浆作用 ,以及大洋周边优地槽区的稳定化。地壳发展旋回的有规则重复 ,都与地球历史中岩浆作用、变质作用、成矿作用和全球灾变的特殊特点相关。在最大的地核排氢期间 ,氢流体达到了平流层 ,并在这里形成有高反射力的水冰云。它们增加了地球的反射率 ,并成为地球全球冰封的基础。平流层冰云促进了对臭氧辐射盾牌的破坏 ,从而导致继冰期之后的生物灾难。

The state of gold in phases of the Cu-Fe-S system:In situ X-ray absorption spectroscopy study

Chalcopyrite and bornite are the main Au-bearing minerals at Cu porphyry deposits,volcanogenic massive sulfide(VMS)deposits,Cu-Ni deposits of the mafic magmatic complexes,and ores of submarine sulfide edifices.Bornite and intermediate solid solutions with wide compositional variations(bnss and iss–high-temperature chalcopyrite,correspondingly),which can scavenge economic concentrations of Au,appear in the Cu-Fe-S system at ore-forming conditions.However,the state of Au in bnss and iss is yet unknown.To solve this conundrum,we synthesized samples with net chemical composition of bnss and iss,studied them by in situ X–ray absorption spectroscopy(XAS),and used the experimental data to explain the Au distribution among natural ore-forming minerals.The sulfide samples were obtained at 495–700℃ in Au-saturated system by means of salt flux method.The bnss contained1.2–1.6 log units more Au than iss:up to 18 wt.%Au in bnss vs 0.4 wt.%Au in iss at 700C.An increase of temperature resulted in the sharp increase of Au concentration in both phases,1 log unit per 100℃ at f(S2)close to S_((l)) saturation.Analysis of Au L_(3)-edge spectra recorded at 25–675℃ revealed that at 25℃ Au exists mainly in the metallic state.At t>500℃ the spectral features of Audisappear,and “chemically bound”Au predominates.The Au form of occurrence in the iss field is interpreted as Au-bearing clusters with a stromeyerite-like(CuAgS)structure.Digenite Cu_(2–x)S and bnss contain Au in a mixture of stromeyeritelike and petrovskaite-like(Au_(0.8)Ag_(1.2)S)clusters.The chemical composition of both forms is close to CuAuS,where the nearest Au neighbors are two S atoms at R_(Au-S)=2.34–2.36Å.Results of the present study allow to determine the state of Au and its concentration in the main Cu-bearing minerals of sulfide ores as a function of the T-f(S_(2))-compositional parameters.Due to the sharp increase of the CuAuS clusters stability with increasing temperature,in high-temperature ores formed at t>350℃ Au enriches Cubearing minerals in comparison with Cu-free or Cu-deficient ones.As a result,in these ores native gold,being a product of decomposition of the Au-bearing clusters,is associated with Cu-rich minerals–chalcopyrite,bornite,digenite,chalcocite.