Success in locating oil pools in the Cauvery Basin,south India had been found to be based on the ability to delineate precisely the stratigraphic traps resulting from frequent sea level changes.However,recognition and...Success in locating oil pools in the Cauvery Basin,south India had been found to be based on the ability to delineate precisely the stratigraphic traps resulting from frequent sea level changes.However,recognition and delineation of them in terms of depositional units through conventional stratigraphic methods have been elusive owing to the limitations of such methods and lack of unified stratigraphic markers that could be traced at regional and basinal scale.This paper attempts to recognize depositional units in terms of chemozones,chronologic and lithostratigraphic units by assigning distinct geochemical signatures.Geochemical signatures were assigned through hierarchical delineation and discriminant function analysis.It is observed that individual depositional units could be recognized statistically with whole-rock geochemical composition.The strata under study show two second order chemozones comprising six major chemozones that in turn correspond to third order sea level cycles and minor chemozones at the scale of fourth order and/or further shorter sea level cycles.The geochemical signatures showed 100% distinctness between sample populations categorized according to chronostratigraphy and lithostratigraphy.The durations of these stratigraphic units range from 18 million years to less than a million years and indicate distinct geochemical compositional change at different time slices.By implication and also due to the close correspondence between sea level variations reported from this basin and global sea level cycles,it is suggested that recognition and correlation of individual depositional units with distal counterparts could be made accurately.Implication of these results is that stratigraphic units,at varying scales either temporally or spatially,could be assigned with unique geochemical signature,with which accurate prediction and correlation of similar units elsewhere is possible with measurable accuracy.展开更多
The distribution and the concentrations of various chemical elements in street sediments were investigated along a rural-urban boundary in Beijing, China. The statistical factor analysis of the data concerned identifi...The distribution and the concentrations of various chemical elements in street sediments were investigated along a rural-urban boundary in Beijing, China. The statistical factor analysis of the data concerned identifies two anthropogenic sources responsible for the contamination of Beijing air. The first source is a steel factory in the western part of Beijing. From this source, Mn, Fe and Ti were emitted into the atmosphere through chimneys and by wind from coal heaps used as the primary energy source for the factory. The second source is a combination of traffic, domestic heating and some small factories in the center of Beijing urban area discharging Cu, Pb, Zn and Sn. Grain-size analyses show that most of the metals in the road dust have higher concentrations in the small grain-size fraction <0.125 mm, which is the severest case because these small particles with larger specific surface area and high heavy metal contents fly up easily and float in the air for a long time. Besides the anthropogenic contamination, such elements as Y, Zr, Nb, Ce and Rb are derived mainly both from natural soils and from the deserts. This is supported by mineral-phase analysis, which shows a clear imprint of materials in road dusts coming from the west China deserts. Our results clearly show that the chemical compositions of the urban road dusts can be used to identify distinctive sources responsible for the contamination mentioned above. The study shows that the chemistry of road dusts is an important monitor to assess the contamination in the urban environment.展开更多
文摘Success in locating oil pools in the Cauvery Basin,south India had been found to be based on the ability to delineate precisely the stratigraphic traps resulting from frequent sea level changes.However,recognition and delineation of them in terms of depositional units through conventional stratigraphic methods have been elusive owing to the limitations of such methods and lack of unified stratigraphic markers that could be traced at regional and basinal scale.This paper attempts to recognize depositional units in terms of chemozones,chronologic and lithostratigraphic units by assigning distinct geochemical signatures.Geochemical signatures were assigned through hierarchical delineation and discriminant function analysis.It is observed that individual depositional units could be recognized statistically with whole-rock geochemical composition.The strata under study show two second order chemozones comprising six major chemozones that in turn correspond to third order sea level cycles and minor chemozones at the scale of fourth order and/or further shorter sea level cycles.The geochemical signatures showed 100% distinctness between sample populations categorized according to chronostratigraphy and lithostratigraphy.The durations of these stratigraphic units range from 18 million years to less than a million years and indicate distinct geochemical compositional change at different time slices.By implication and also due to the close correspondence between sea level variations reported from this basin and global sea level cycles,it is suggested that recognition and correlation of individual depositional units with distal counterparts could be made accurately.Implication of these results is that stratigraphic units,at varying scales either temporally or spatially,could be assigned with unique geochemical signature,with which accurate prediction and correlation of similar units elsewhere is possible with measurable accuracy.
文摘The distribution and the concentrations of various chemical elements in street sediments were investigated along a rural-urban boundary in Beijing, China. The statistical factor analysis of the data concerned identifies two anthropogenic sources responsible for the contamination of Beijing air. The first source is a steel factory in the western part of Beijing. From this source, Mn, Fe and Ti were emitted into the atmosphere through chimneys and by wind from coal heaps used as the primary energy source for the factory. The second source is a combination of traffic, domestic heating and some small factories in the center of Beijing urban area discharging Cu, Pb, Zn and Sn. Grain-size analyses show that most of the metals in the road dust have higher concentrations in the small grain-size fraction <0.125 mm, which is the severest case because these small particles with larger specific surface area and high heavy metal contents fly up easily and float in the air for a long time. Besides the anthropogenic contamination, such elements as Y, Zr, Nb, Ce and Rb are derived mainly both from natural soils and from the deserts. This is supported by mineral-phase analysis, which shows a clear imprint of materials in road dusts coming from the west China deserts. Our results clearly show that the chemical compositions of the urban road dusts can be used to identify distinctive sources responsible for the contamination mentioned above. The study shows that the chemistry of road dusts is an important monitor to assess the contamination in the urban environment.
