Hybrid laser technologies for deposition of thin films and basic schemes of combination of pulsed laser deposition (PLD) with magnetron sputtering and RF discharges or two lasers or three laser deposition systems are ...Hybrid laser technologies for deposition of thin films and basic schemes of combination of pulsed laser deposition (PLD) with magnetron sputtering and RF discharges or two lasers or three laser deposition systems are presented. Experiences with deposition of chromium doped diamond-like carbon (DLC) films for coating of prostheses are described. Layers of different chromium concentrations were prepared using hybrid systems (PLD + magnetron sputtering or by double PLD). Results of physical and mechanical characterization of film properties and biomedical tests of trivalent and toxic hexavalent chromium are given. Experiences with double laser deposition of DLC layers doped with silver are also mentioned.展开更多
The group-delay dispersion of an optical fiber was measured with the time-of-flight method, using fingerprint-like characteristic spectra from a mode-locked fiber laser source. To determine the group-delay dispersion ...The group-delay dispersion of an optical fiber was measured with the time-of-flight method, using fingerprint-like characteristic spectra from a mode-locked fiber laser source. To determine the group-delay dispersion up to the fourth order, least-squares fitting was applied to the overall time waveform mapped on the time axis for the fingerprint-spectral broadband pulses through a long optical fiber. The analysis of all 4003 data points reduced statistical uncertainty, and provided second-, third-, and fourth-order dispersion with uncertainties of 0.02%, 0.4%, and 4%,respectively.展开更多
A preliminary investigation on short-wavelength ablation mechanisms of poly(methyl methacrylate)(PMMA) and poly(1,4-phenylene ether ether-sulfone)(PPEES) by extreme ultraviolet(EUV) radiation at 13.5 nm using a table-...A preliminary investigation on short-wavelength ablation mechanisms of poly(methyl methacrylate)(PMMA) and poly(1,4-phenylene ether ether-sulfone)(PPEES) by extreme ultraviolet(EUV) radiation at 13.5 nm using a table-top laserproduced plasma from a gas-puff target at LLG(Gttingen) and at 46.9 nm by a 10 Hz desktop capillary discharge laser operated at the Institute of Physics(Prague) is presented.Ablation of polymer materials is initiated by photoinduced polymer chain scissions.The ablation occurs due to the formation of volatile products by the EUV radiolysis removed as an ablation plume from the irradiated material into the vacuum.In general,cross-linking of polymer molecules can compete with the chain decomposition.Both processes may influence the efficiency and quality of micro(nano)structuring in polymer materials.Wavelength is a critical parameter to be taken into account when an EUV ablation process occurs,because different wavelengths result in different energy densities in the near-surface region of the polymer exposed to nanosecond pulses of intense EUV radiation.展开更多
Three types of BaTiO3 core-amorphous nanoshell composite ceramics were processed from the same core-shell powder by standard sintering,spark-plasma sintering and two-step sintering techniques and characterized by XRD,...Three types of BaTiO3 core-amorphous nanoshell composite ceramics were processed from the same core-shell powder by standard sintering,spark-plasma sintering and two-step sintering techniques and characterized by XRD,HRSEM and broadband dielectric spectroscopy in the frequency range 10^(3)-10^(13)Hz including the THz and IR range.The samples differed by porosity and by the amount of interdiffusion from the cores to shells,in correlation with their increasing porosity.The dielectric spectra were also calculated using suitable models based on effective medium approximation.The measurements revealed a strong dielectric dispersion below the THz range,which cannot be explained by the modeling,and whose strength was in correlation with the degree of interdiffusion.It is assigned to an effect of the interdiffusion layers,giving rise to a strong interfacial polarization.It appears that the high-frequency dielectric spectroscopy is an extremely sensitive tool for detection of any gradient layers and sample inhomogeneities even in dielectric materials with negligible conductivity.展开更多
A number of laser facilities coming online all over the world promise the capability of high-power laser experiments with shot repetition rates between 1 and 10 Hz. Target availability and technical issues related to ...A number of laser facilities coming online all over the world promise the capability of high-power laser experiments with shot repetition rates between 1 and 10 Hz. Target availability and technical issues related to the interaction environment could become a bottleneck for the exploitation of such facilities. In this paper, we report on target needs for three different classes of experiments: dynamic compression physics, electron transport and isochoric heating, and laser-driven particle and radiation sources. We also review some of the most challenging issues in target fabrication and high repetition rate operation. Finally, we discuss current target supply strategies and future perspectives to establish a sustainable target provision infrastructure for advanced laser facilities.展开更多
After synthesis of an asymmetric tetradentate ONN'O' Schiff base ligand (H2L) followed by reaction of the synthesized H2L with an equimolar mixture of methanolic solutions of the VO(acac)2, a new oxidovanadium...After synthesis of an asymmetric tetradentate ONN'O' Schiff base ligand (H2L) followed by reaction of the synthesized H2L with an equimolar mixture of methanolic solutions of the VO(acac)2, a new oxidovanadium(IV) Schiff base complex (VOL) was synthesized. The Schiff base ligand and its complex were characterized by FT-IR and UV-vis spectra and C, H, N analysis, The crystal structure of VOL was also determined by single crystal X-ray analysis. The VOL complex crystallizes in monoclinic space group Cc. The Schiffbase ligand acts as a tetradentate ligand through its two'iminic nitrogens and two phenolic and acetylacetonate oxygens. Thermogravimetric analysis of the VOL showed that it decomposes in two steps and converts to mixed vanadium oxides at 477℃. In addition, thermal decomposition of the VOL complex in air at 660 ℃ leads to formation of V2O5 nanoparticles with the average size estimated from XRD 49 nm. The catalytic activity of the VOL complex was investigated in the epoxidation reaction and different reaction parameters were optimized. The results showed that the cyclic alkenes were efficiently converted to the corresponding epoxides, whereas the VOL did not appreciably convert the linear alkenes.展开更多
文摘Hybrid laser technologies for deposition of thin films and basic schemes of combination of pulsed laser deposition (PLD) with magnetron sputtering and RF discharges or two lasers or three laser deposition systems are presented. Experiences with deposition of chromium doped diamond-like carbon (DLC) films for coating of prostheses are described. Layers of different chromium concentrations were prepared using hybrid systems (PLD + magnetron sputtering or by double PLD). Results of physical and mechanical characterization of film properties and biomedical tests of trivalent and toxic hexavalent chromium are given. Experiences with double laser deposition of DLC layers doped with silver are also mentioned.
基金partly supported by KAKENHI No. 15H03968 and No. 26610081 from JSPS, the Photon Frontier Network Program of MEXT, JST-SENTAN, and JST-CREST in Japanthe European Regional Development Fund+1 种基金the European Social Fundthe state budget of the Czech Republic (project HiLASE: CZ.1.05/2.1.00/01.0027, project Postdok: CZ.1.07/2.3.00/30.0057)
文摘The group-delay dispersion of an optical fiber was measured with the time-of-flight method, using fingerprint-like characteristic spectra from a mode-locked fiber laser source. To determine the group-delay dispersion up to the fourth order, least-squares fitting was applied to the overall time waveform mapped on the time axis for the fingerprint-spectral broadband pulses through a long optical fiber. The analysis of all 4003 data points reduced statistical uncertainty, and provided second-, third-, and fourth-order dispersion with uncertainties of 0.02%, 0.4%, and 4%,respectively.
基金the support of the Ministry of Education,Youth and Sports to the HiLASE (CZ.1.05/2.1.00/01.0027)DPSSLasers (CZ.1.07/2.3.00/20.0143) projects+5 种基金co-financed from the European Regional Development-Fundsupported by the grant RVO 68407700financial support by the ‘Deutsche Forschungs-gemeinschaft’ within the Sonderforschungsbereich 755 ‘Nanoscale Photonic Imaging’the Czech Science Foundation (14-29772S)from EU COST MPO1203from the Ministry of Education,Youth and Sports,COST CZ VES14 LD14032 are also appreciated
文摘A preliminary investigation on short-wavelength ablation mechanisms of poly(methyl methacrylate)(PMMA) and poly(1,4-phenylene ether ether-sulfone)(PPEES) by extreme ultraviolet(EUV) radiation at 13.5 nm using a table-top laserproduced plasma from a gas-puff target at LLG(Gttingen) and at 46.9 nm by a 10 Hz desktop capillary discharge laser operated at the Institute of Physics(Prague) is presented.Ablation of polymer materials is initiated by photoinduced polymer chain scissions.The ablation occurs due to the formation of volatile products by the EUV radiolysis removed as an ablation plume from the irradiated material into the vacuum.In general,cross-linking of polymer molecules can compete with the chain decomposition.Both processes may influence the efficiency and quality of micro(nano)structuring in polymer materials.Wavelength is a critical parameter to be taken into account when an EUV ablation process occurs,because different wavelengths result in different energy densities in the near-surface region of the polymer exposed to nanosecond pulses of intense EUV radiation.
基金supported by the Academy of Sci-ences of the Czech Republic(project AVOZ 10100520)the Czech Science Foundation(project 202/09/0430)by COST action MP904.
文摘Three types of BaTiO3 core-amorphous nanoshell composite ceramics were processed from the same core-shell powder by standard sintering,spark-plasma sintering and two-step sintering techniques and characterized by XRD,HRSEM and broadband dielectric spectroscopy in the frequency range 10^(3)-10^(13)Hz including the THz and IR range.The samples differed by porosity and by the amount of interdiffusion from the cores to shells,in correlation with their increasing porosity.The dielectric spectra were also calculated using suitable models based on effective medium approximation.The measurements revealed a strong dielectric dispersion below the THz range,which cannot be explained by the modeling,and whose strength was in correlation with the degree of interdiffusion.It is assigned to an effect of the interdiffusion layers,giving rise to a strong interfacial polarization.It appears that the high-frequency dielectric spectroscopy is an extremely sensitive tool for detection of any gradient layers and sample inhomogeneities even in dielectric materials with negligible conductivity.
基金support from the European Cluster of Advanced Laser Light Sources(EUCALL)project which has received funding from the European Union’s Horizon 2020 research and innovation programme under agreement No 654220support of the ELI-NP team and from ELI-NP PhaseⅡ,a project co-financed by the Romanian Government and European Union through the European Regional Development Fund–the Competitiveness Operational Programme(1/07.07.2016,COP,ID 1334)+5 种基金support of the ELI-Beamlines project,mainly sponsored by the project ELI–Extreme Light Infrastructure–Phase 2(CZ.02.1.01/0.0/0.0/15–008/0000162)through the European Regional Development Fundsupport of Planet Dive,a project that has received funding from the European Research Council(ERC)under the European Union’s Horizon 2020 research and innovation programme(grant agreement N.637748)supported by the Helmholtz Association under VHNG-1141support of the European Research Council Consolidator Grant ENSURE(ERC-2014CoG No.647554)Support by the Nanofabrication Facilities Rossendorfthe Institute of Ion Beam Physics and Materials Research,HZDR
文摘A number of laser facilities coming online all over the world promise the capability of high-power laser experiments with shot repetition rates between 1 and 10 Hz. Target availability and technical issues related to the interaction environment could become a bottleneck for the exploitation of such facilities. In this paper, we report on target needs for three different classes of experiments: dynamic compression physics, electron transport and isochoric heating, and laser-driven particle and radiation sources. We also review some of the most challenging issues in target fabrication and high repetition rate operation. Finally, we discuss current target supply strategies and future perspectives to establish a sustainable target provision infrastructure for advanced laser facilities.
基金the Damghan UniversityGolestan University for financial supportsupported by the project 14-03276S of the Czech Science Foundation
文摘After synthesis of an asymmetric tetradentate ONN'O' Schiff base ligand (H2L) followed by reaction of the synthesized H2L with an equimolar mixture of methanolic solutions of the VO(acac)2, a new oxidovanadium(IV) Schiff base complex (VOL) was synthesized. The Schiff base ligand and its complex were characterized by FT-IR and UV-vis spectra and C, H, N analysis, The crystal structure of VOL was also determined by single crystal X-ray analysis. The VOL complex crystallizes in monoclinic space group Cc. The Schiffbase ligand acts as a tetradentate ligand through its two'iminic nitrogens and two phenolic and acetylacetonate oxygens. Thermogravimetric analysis of the VOL showed that it decomposes in two steps and converts to mixed vanadium oxides at 477℃. In addition, thermal decomposition of the VOL complex in air at 660 ℃ leads to formation of V2O5 nanoparticles with the average size estimated from XRD 49 nm. The catalytic activity of the VOL complex was investigated in the epoxidation reaction and different reaction parameters were optimized. The results showed that the cyclic alkenes were efficiently converted to the corresponding epoxides, whereas the VOL did not appreciably convert the linear alkenes.