Here we show the results of experimental observation of decomposition of the solution components into the neighboring cells. The liquid solution under crystallization first gets into the unstable state and then decomp...Here we show the results of experimental observation of decomposition of the solution components into the neighboring cells. The liquid solution under crystallization first gets into the unstable state and then decomposes. The decomposition result is fixed in the solid phase as inhomogeneous component distribution. Our experimental results enable to argue that the eutectic pattern forms due to interface instability and spinodal decomposition of non-equilibrium solution forming in front of the interface.展开更多
We present a detailed discussion of the boundary conditions of the directed crystallization problem, a formulation of the model considering temperature fields of external sources, the mechanism of attachment of partic...We present a detailed discussion of the boundary conditions of the directed crystallization problem, a formulation of the model considering temperature fields of external sources, the mechanism of attachment of particles to the growing solid surface, the influence of interphase component absorption on the phase distribution ratio of the components as well as the calculation of the period of the morphological interface instability which is made with due regard of all the aforementioned conditions.展开更多
文摘Here we show the results of experimental observation of decomposition of the solution components into the neighboring cells. The liquid solution under crystallization first gets into the unstable state and then decomposes. The decomposition result is fixed in the solid phase as inhomogeneous component distribution. Our experimental results enable to argue that the eutectic pattern forms due to interface instability and spinodal decomposition of non-equilibrium solution forming in front of the interface.
文摘We present a detailed discussion of the boundary conditions of the directed crystallization problem, a formulation of the model considering temperature fields of external sources, the mechanism of attachment of particles to the growing solid surface, the influence of interphase component absorption on the phase distribution ratio of the components as well as the calculation of the period of the morphological interface instability which is made with due regard of all the aforementioned conditions.
