The Influence of the Solar Radiation Absorptivity up on the Outdoor Thermal Environment Evaluation Index and the Thermal Sensory Perceptions

When the thermal environment is under heated conditions, short-wavelength solar radiation shows a strong influence on the human body and the heat is accumulated in the human body. In order to demonstrate the effect of the short-wavelength solar radiation absorptivity of clothing on physiological temperature in an outdoor space, the relationship between the thermal environment evaluation index, ETFe, and the thermal sensory perceptions of the human body was investigated. A significant temperature difference of 2.7°C was shown for an ETFe that was thermally neutral (neither hot nor cold). The effect of short-wavelength solar radiation absorptivity was strongly apparent in ETFe when direct solar radiation was strong and in warmer outdoor spaces. In an outdoor space where the effect of the sky factor and albedo was strong, the setting of the short-wavelength solar radiation absorptivity was demonstrated to greatly impact the estimation of perceived and physiological temperature. When interviewing subjects on clothing in an outdoor space, it is essential to obtain the hue of clothing.

The Influence of Foliage Plants on Psychological and Physiological Responses

This research aims to clarify the significance of incorporating visual stimulation, in the form of foliage plants, into office desktop spaces. The experiments were conducted in a thermal environment with a temperature range that was slightly uncomfortable. The indoor thermal environment evaluation index ETF was used to measure the effects that brain stimulation of foliage plants have on comprehensive thermal senses. We focus on visual stimulation with foliage plants, and quantitatively measure shifts in thermal senses that affect the body. Thermal environment conditions were established with air temperature in three stages (25℃, 28℃ and 31℃) and the atmosphere was kept homogeneous with wall surface temperature equal to air temperature. The visual stimulations consisted of seven types of office desk image: benjamin, pothos, oxycardium, baby tears, moss ball, cacti, and no plant. At around 27℃ to 29℃ ETF, improvements in thermal sensation, as measured by thermal sensation statements, were shown to have resulted from visual stimulation benefits. Also, at around 26℃ to 29℃ ETF, improvements in comfort were shown, due to visual stimulation benefits as well, in subjects’ comfortable-sensation statements. This benefit was significant when a foliage plant’s green coverage ratio came between 0.75% and 4.67%, the range which does not create an overwhelming feeling from the foliage plant.

THE EFFECT OF RUN-IN VALUE ON DIMENSIONAL AND PHYSICAL PROPERTIES OF RASCHEL WARP KNITTED FABRICS

After run-in analysis of Raschel warp knitting,the dry and wet relaxation treatments of twelvetwo-bar warp knitted fabrics having six different knitting tightnesses were made,and some physi-cal properties of these fabrics which had been finished were tested.On the basis of these experi-ments,the effect of run-in value on dimensional properties and the relationships between run-invalue and physical properties are discussed and analysed.

THERMAL DEGRADATION OF THERMOTROPIC LIQUID CRYSTALLINE TERPOLYESTERS BASED ON VANILLIC ACID, p-HYDROXYBENZOIC ACID AND POLY(ETHYLENE TEREPHTHALATE )

Nine thermotropic liquid crystalline terpolyesters based on vaniUic acid(V), p-hydroxybenzoic acid(H) and poly(ethylene terephthalate)(E) were investigated by thermogravimetry to ascertain their thermostability and the kinetic parameters for thermal degradation. Overall activation energy data of the degradation had been calculated over the range 5 ～ 70% weight loss. The temperatures and the activation energy of the degradation lie in the ranges of 384 ～ 394 ℃ at a heating rate of 1℃/min and 176 ～ 205 KJ/mol at the weight loss of 5%, respectively, which suggests that the terpolyesters have good thermostability.

Influence of Fiber Properties and Processing Parameters on Properties of Highloft Nonwoven Bonded by Bicomponent Polyester Fibers

Highloft nonwoven was produced by heat bonding of bicomponent polyester fibers. The effect of fiber properties and processing parameters on the mechanical properties of the nonwoven was investigated. The heat bonding processing parameters for the nonwoven were optimized. The results show that the range of processing temperature is wider while the shell melting point of the bicomponent fibers (Tm1) is lower. The best processing temperature is about 15℃ higher than Tm1 while the shell melting point (Tm1) is higher.

STUDY ON THE MICROSTRUCTURE AND PROPERTY OF PET FIBER BY LASER RAMAN MICROSCOPE

In this paper, the microstructure change of one step-draw PET fiber has been studied byvarious methods, such as, Laser Raman Microscope, Wide-angle X-ray, Density-gradient andPolarizing Microscope. The computer has been used to resolve overlapped bands in the Ramanspectra. Then the band changes have been correlated with trans, gauche and stressed trans-conformations indicated by a conformational index. Based on these indices, the relationshipbetween the conformation change of glycol units in the fiber structure and the macromechanicalproperties of fiber is expounded.

THEORETICAL ANALYSIS OF KINETICS OF NONISOTHERMAL CRYSTALLIZATION OF POLYMERS

The classical crystallization theories proposed by Avrami, Evans, and Mandelkern wereextended to the nonisothermal situation. The expressions derived from the classical equations canbe expressed in either the differential form or the integral form. A method was provided so as toobtain the parameters characterizing the crystallization rate and mechanism from DSC curves withseveral constant heating or cooling rates. The rate constants of crystallization obtained from bothisothermal and nonisothermal curves of poly(ethylene terephthalate)were compared.

KINETICS OF NON-ISOTHERMAL CRYSTALLIZATION

A kinetic equation of non-isothermal crystamzation was derived by extending Avrami's equation to the non-isothermal situation. More crystallization information can be obtained from this kinetic equation. The curves of non-isothermal and isothermal crystallizations were analysed and compared for poly (ethylene terephthalate) (PET), and the results were discussed.

A COMPARISON OF FOUR RUN-IN PREDICTION METHODS IN RASCHEL WARP KNITTING

In this paper, the run-in values predicted by four methods are compared with the measuredvalues, and some suggestions have been made. The negative let-off motion is different from thepositive let-off motion, so that in the machine with negative let-off device, fabric structure is animportant factor determining the run-in value.

MODELLING OF TENSILE STRESS-STRAIN CURVE OF WOVEN FABRICS

A general shape of tensile stress-strain curves of woven fabrics is first recognised by puttingtested and predicted results together.An exponential function with two parameters is then selectedfor the prediction of tensile stress-strain relationship.The predicted results by using the proposedfunction show excellent agreement with experimental data.

ON A DIFFERENTIAL EQUATION FOR KINETICS OF NON- ISOTHERMAL CRYSTALLIZATION

A new differential equation was derived from the modified first-order kinetic model to describe the polymer crystallization processes. The crystallization experiments were carried out by means of DSC. Poly (ethylene terephthalate) resins were selected as the samples containing different catalysts. The relationships between the parameters obtained from the known Avrami equation and from one in the present paper were discussed. A method for applying the equation to determine the kinetic parameters from a constant heating and a constant cooling curve was proposed.

KINETICS OF NON-ISOTHERMAL CRYSTALLIZATION OF POLY (ETHYLENE TEREPHTHALATE) MODIFIED BY POLY (ETHYLENE GLYCOL)

The non-isothermal crystallization kinetics of poly(ethylene terephthalate) (PET) modified by poly (ethlene glycol) (PEG) were determined by DSC. The dual linear regression method was used to evaluate the relationship between the reciprocal of t 1/2 ( the half life of crystallization) and the appropriate temperature variable. The parameters such as the activation energy (Ed) for transport, the equilibrium melting temperature (T_m^0),the nucleation parameter (ψ),themaximum crystallization temperature (T_(e, max)), and the kinetic crystallizability (G) for the copolyesters were obtained. The influence of the PEG content in PET chains on the parameters characterizing crystallization kinetics and crystallization thermodynamics was discussed.

RELATION BETWEEN DYNAMIC LOSS MODULUS AND DIFFUSION COEFFICIENT IN A MODIFIED PET FIBER

The mobility of polymer chain segments is shown to play a major role in the diffusion ofdisperse dyes in a copolymerization modified PET system, monoepoxy compoundCH_3 (CH_3),OCH_2CH--CH_2 modified PET. The rate of dye diffusion (diffusion coefficient D) hasbeen related to the time-dependent mechanical property, dynamic loss modulus E', which iscontrolled by the mobility of chain segments. In this modified copolyester system, the variance ofamount of modifier in the copolyester fibers causes the change in disperse dye diffusion coefficientto fiber, and in the dynamic loss modulus of the fibers, but the relationship between the diffusionand the dynamic loss modulus is in agreement with the theoretical relation derived by Bell andDumbleton. The relation obtained in this paper is:Ln D=-2. 28Ln E'+26. 81

Skin Temperature and Body Surface Section in Non-Uniform and Asymmetric Outdoor Thermal Environment

In indoor environments and shady outdoor environments, there is little influence of short-wavelength solar radiation, so a strikingly non-uniform and asymmetric environment is not formed. In outdoor sunny environment, however, shaded areas occur even for the same site of the body, and a remarkable difference in skin temperature is considered to occur under the influence of the short-wavelength solar radiation. The purpose of this study is to clarify the influence of the non-uniform and asymmetric thermal radiation of short-wavelength solar radiation in outdoor environment on the division of the body surface section and the calculation of the mean skin temperature. The skin temperature of the front of the coronal surface, which was facing the sun and where the body received direct short-wavelength solar radiation, and the skin temperature of the rear of the coronal surface, which was in the shadow and did not receive direct short-wavelength solar radiation were respectively measured. The feet, upper arm, forearm, hand and lower leg, which are susceptible to short-wavelength solar radiation in a standing posture, had a noticeable difference in skin temperature between sites in the sun and in shade. The mean skin temperature of sites facing the sun was significantly higher than the mean skin temperature of those in the shade.

Thermal Manikin of Infant

Compared to an adult, an infant requires more consideration regarding the thermal environment so it is necessary to evaluate the thermal environment as it affects infants. However, experiments on infant subjects regarding their thermal environment based on the different heat balance of their body cannot ethically be conducted. We could instead consider using a thermal model for the human body, but thermal manikins based on heat transfer per unit area are rare. Therefore, this study aims to develop a thermal manikin to model the heat transfer per unit area and the body form of an infant in order to evaluate the infant’s thermal environment. When evaluating the thermal environment or heat balance of the body in the outside environment, it is essential to consider the asymmetry and unevenness of the temperature of the skin, as an element of the human body, and not just the unevenness and asymmetry of physical factors in the environment. Moreover, when receiving short wavelength direct solar radiation, light and shaded areas have significant differences in skin temperature. The following 20 body parts were investigated in the study: anterior head, posterior head, ventral trunk, dorsal trunk (including buttocks), right medial arm, right lateral arm, left medial arm, left lateral arm, right dorsal hand, right palmar hand, left dorsal hand, left palmar hand, right anterior leg, right posterior leg, left anterior leg, left posterior leg, right dorsal foot, right plantar foot, left dorsal foot, and left plantar foot. This paper measured the body surface area for each part of an infant’s body in order to establish the form of an infant model from the view of the heat transfer area, and verified the validity of the model.

STRUCTURE OF THERMOTROPIC LIQUID CRYSTALLINE VANILLIC ACID/P-HYDROXYBENZOIC ACID/ETHYLENE TEREPHTHALATE VHE TERPOLYESTERS

Thermotropic liquid crystalline VHE terpolyesters made from vanillic acid (V),p-hydroxybenzoic acid (H) and poly(ethylene terephthalate) (E) were studied by 400 MHz NMR spectra, wide angle X-ray diffraction,scanning electron and polarizing microscopes.It was found that the VHE terpolyesters had random sequence distribution.The VHE terpolyester films exhibited highly oriented fibrillar structure.

Preparation of epoxy resin/rare earth doped aluminate nanocomposite toward photoluminescent and superhydrophobic transparent woods

A translucent wooden substrate with long-lasting phosphorescence,high photostability and durability,tough surface,ultraviolet protection,high optical transmittance,and superhydrophobicity was developed.This long-lasting phosphorescent wooden substrate is able to continue emitting light for extended time periods.Lignin-modified wood(LMW)was immobilized with a solution of epoxy resin(ER)and rare-earth doped aluminate(REDA)phosphor nanoparticles(NPs).For an improved dispersion of pigment,REDA was synthesized in a nanoscale particle size,and characterized by transmission electron microscopy(TEM)to indicate a particle size of 8-14 nm.The crystal structure of REDA nanoparticles was also proved by X-ray diffraction(XRD).For an improved production of long-persistent phosphorescent colo rless woods,REDA must be well-dispersed in MAA without aggregation.Absorption and emissio n,as well as decay and lifetime spectra were explored.The morphologies of the wooden substrates with different ratios of REDA were investigated by scanning electron microscopy(SEM),X-ray fluorescence(XRF)analysis,Fourier transform infrared spectra(FT-IR),elemental mapping,and energy-dispersion Xray(EDXA).The phosphorescent woods show changes in color from colorless to green under ultraviolet(UV)irradiation,and to yellowish-green in the dark,as proved by the colorimetric parameters of the CIE Lab system.The afterglow wood samples display an absorbance band at 365 nm and two phosphorescent bands at 431 and 520 nm.Improved UV shielding,photostability,and hydrophobicity were explored.With increasing REDA ratio,both static contact and slide angles are found to improve in the ranges of147.6°-163.6°and 9°-14°,respectively.The long-lasting photoluminescence is optimized at a REDA ratio of 8%.The present strategy shows a large-scale production approach of multiple functional woods for many potential applications,such as smart glow in the dark windows and safety signs.

MATHEMATICAL MODELS OF MACROMOLECULAR CONFORMATIONS IN THE FORM OF RANDOM FLIGHT AND FREELY ROTATING POLYMER CHAINS

In this paper, two molecular mathematical models which simulate the conformations of a random flight chain and a freely rotating chain were suggested separately from the theory of stochastic process. We had obtained a series of results relating to conformations by means of these models. These results are not only mathematically stricter but also include the results obtained by previous workers. In an ideal state, conformation of a random flight chain is simulated as a 3-dimensional Brownian motion {r_t(ω), t>0}. We pointed out the objective meaning which was endowed to the different variables involved in a 3-dimensional Brownian motion. On this basis, the bond vector and the end-to-end state vector were defined; the distribution function and the reduced functions were thus obtained, e.g. the distribution of the end-to-end state vector which is a measure of the flexibility of a polymer chain,

SPECTRA OF TENSOR PRODUCTS AND ELEMENTARY OPERATORS

Let A,B be bounded operators on complex Banach spaces X and Y respectively. The tensor product X (?)_α Y denotes the completion of X(?)Y with respect to a quasi-uniform reasonable norm α. In the case X and Y are Hilbert spaces, Brown and Percy showed that σ(A(?)B)-σ(A)(?)σ(B). This work was generalized by Scheter and Dash, and it was further generalized by R. Harte. He computed the joint spectrum for certain system of elements in a tensor product of Banach algebras.

ON THE CHARACTER OF COMPACT OPERATOR SEQUENCE

Let E be a Banach space. If {T_m} is a sequence of uniform bounded operators such that {T_nx_n} is compact for any bounded sequence {x_n}, we say that {T_n} is a general collective cempact operator sequence.