The methanol extract form the leaves of Phytolacca icosandra L.,afforded the unprecedented artificial triterpenoid fatty acid ester 1 derived from the new natural triterpenoid phytolaccagenic acid 3-O-myristate(1a),al...The methanol extract form the leaves of Phytolacca icosandra L.,afforded the unprecedented artificial triterpenoid fatty acid ester 1 derived from the new natural triterpenoid phytolaccagenic acid 3-O-myristate(1a),along with the three known triterpenoids serjanic,acinosolic and phytolaccagenic acid(2-4).Their structures were stablished by HR-EI-MS,1D and 2D NMR techniques.The possible mechanistic formation of 1 is proposed,and the in vitro toxicity of all compounds was assessed using the brine shrimp lethality assay(BSLA).展开更多
Meiofaunal communities of three small, shallow freshwater habitats sampled during the austral summer of 2013 in Greenwich Island, South Shetland Islands, Antarctica, are reported. Communities are dominated by tardigra...Meiofaunal communities of three small, shallow freshwater habitats sampled during the austral summer of 2013 in Greenwich Island, South Shetland Islands, Antarctica, are reported. Communities are dominated by tardigrades (85%), nematodes (11%), and rotifers (3%). Collembola, Oligochaeta, crustacean larvae (nauplii) and unidentified organisms account for 0.3%. Total meiofaunal densities reach 11 770 ind.cm^-2, with mean densities (ind.cm-2) of 1 365.83 ± 2 716.65 (Zone A), 523.67 ± 1 166.48 (Zone B) and 72.17 ± 110.78 (Zone C). Given the age of freshwater habitats, and the general lack of higher-tropbic level predatory taxa, those species we report are likely early stage colonizers, and these communities are at an early stage of ecological succession. Non-parametrical analysis revealed the main variables influencing meiofaunal density and distribution are related to granulometric characteristics of sediments and microphytobenthic biomass. There were close relationships between meiofaunal abundance and microphytobenthic biomass, which indicates that benthic microalgae significantly influence meiofaunal distribution. A strong correlation between nematode abundance and the percentage of silt, clay and carbon in the sediment was also shown by canonical correspondence analysis and Spearman rank correlation.展开更多
Dielectric resonator methods constitute one of the most useful techniques for the measurement of electromagnetic material properties in the microwave frequency range. Several geometric configurations are used for this...Dielectric resonator methods constitute one of the most useful techniques for the measurement of electromagnetic material properties in the microwave frequency range. Several geometric configurations are used for this purpose and, in the present paper, we consider the case of a dielectric rod enclosed in a cylindrical metallic enclosure. To carry out dielectric measurements in this system it is necessary to know the highest permittivity constant value for which the resonance condition still can be attained into the cavity. Using an approach based on magnetic and electric Hertzian potentials we have derived the set of TE and TM modes for the relevant geometry described and, then we have calculated the valid dielectric permittivity constant range of measurements for low-loss materials in a cylindrical cavity using a simple resonance frequency condition. Finally, we present a simple application of this method in order to determine the dielectric permittivity constant of heavy oil with 11 API.展开更多
A theoretical model for the propagation of acoustic waves in dry granular media is presented within the framework of the nonlinear granular elasticity. An essential ingredient is the dependence of the elastic moduli o...A theoretical model for the propagation of acoustic waves in dry granular media is presented within the framework of the nonlinear granular elasticity. An essential ingredient is the dependence of the elastic moduli on compression. For the purpose of illustration, we analyze the case of a time-harmonic plane wave propagation under isotropic compression. We derive explicit relations for the wave speed dependence with the confining pressure. The present approach provides an accurate description of acoustic wave propagation in granular packings and represents a powerful tool to interpret the results of current experiments.展开更多
基金The authors would like to thank USB-DID(project S1-IC-CB-004–15)for financial support。
文摘The methanol extract form the leaves of Phytolacca icosandra L.,afforded the unprecedented artificial triterpenoid fatty acid ester 1 derived from the new natural triterpenoid phytolaccagenic acid 3-O-myristate(1a),along with the three known triterpenoids serjanic,acinosolic and phytolaccagenic acid(2-4).Their structures were stablished by HR-EI-MS,1D and 2D NMR techniques.The possible mechanistic formation of 1 is proposed,and the in vitro toxicity of all compounds was assessed using the brine shrimp lethality assay(BSLA).
基金the Venezuelan Antarctic Program of the "Ministerio del Poder Popular para la Educacion Universitaria, Ciencia y Tecnologia"
文摘Meiofaunal communities of three small, shallow freshwater habitats sampled during the austral summer of 2013 in Greenwich Island, South Shetland Islands, Antarctica, are reported. Communities are dominated by tardigrades (85%), nematodes (11%), and rotifers (3%). Collembola, Oligochaeta, crustacean larvae (nauplii) and unidentified organisms account for 0.3%. Total meiofaunal densities reach 11 770 ind.cm^-2, with mean densities (ind.cm-2) of 1 365.83 ± 2 716.65 (Zone A), 523.67 ± 1 166.48 (Zone B) and 72.17 ± 110.78 (Zone C). Given the age of freshwater habitats, and the general lack of higher-tropbic level predatory taxa, those species we report are likely early stage colonizers, and these communities are at an early stage of ecological succession. Non-parametrical analysis revealed the main variables influencing meiofaunal density and distribution are related to granulometric characteristics of sediments and microphytobenthic biomass. There were close relationships between meiofaunal abundance and microphytobenthic biomass, which indicates that benthic microalgae significantly influence meiofaunal distribution. A strong correlation between nematode abundance and the percentage of silt, clay and carbon in the sediment was also shown by canonical correspondence analysis and Spearman rank correlation.
文摘Dielectric resonator methods constitute one of the most useful techniques for the measurement of electromagnetic material properties in the microwave frequency range. Several geometric configurations are used for this purpose and, in the present paper, we consider the case of a dielectric rod enclosed in a cylindrical metallic enclosure. To carry out dielectric measurements in this system it is necessary to know the highest permittivity constant value for which the resonance condition still can be attained into the cavity. Using an approach based on magnetic and electric Hertzian potentials we have derived the set of TE and TM modes for the relevant geometry described and, then we have calculated the valid dielectric permittivity constant range of measurements for low-loss materials in a cylindrical cavity using a simple resonance frequency condition. Finally, we present a simple application of this method in order to determine the dielectric permittivity constant of heavy oil with 11 API.
文摘A theoretical model for the propagation of acoustic waves in dry granular media is presented within the framework of the nonlinear granular elasticity. An essential ingredient is the dependence of the elastic moduli on compression. For the purpose of illustration, we analyze the case of a time-harmonic plane wave propagation under isotropic compression. We derive explicit relations for the wave speed dependence with the confining pressure. The present approach provides an accurate description of acoustic wave propagation in granular packings and represents a powerful tool to interpret the results of current experiments.