Two-dimensional(2D)high-entropy alloys(HEAs)have emerged as promising electrocatalysts due to the benefits of polymetallic coordination and robust elec-trical conductivity.However,the multiple elements in 2D HEAs pose...Two-dimensional(2D)high-entropy alloys(HEAs)have emerged as promising electrocatalysts due to the benefits of polymetallic coordination and robust elec-trical conductivity.However,the multiple elements in 2D HEAs pose challenges in achieving a uniform composition and maintaining a 2D limit morphology,complicating their structural characterization.Furthermore,even minor adjust-ments to the composition can significantly alter the properties of 2D HEAs,underscoring the need for a deeper understanding of their structure-property relationships to advance synthesis and application.Therefore,this review crit-ically examines the intrinsic factors influencing synthesis methods and the practical applications of 2D HEAs in electrocatalysis for sustainable energy con-version.The urgency is emphasized for developing new synthesis techniques,enhancing advanced characterization methods,and gaining profound insights into the functional mechanisms of 2D HEAs.展开更多
基金China Postdoctoral Science Foundation,Grant/Award Number:2022M722867Key Research Project of Higher Education Institutions in Henan Province,Grant/Award Number:23A530001+1 种基金Henan Province Key Research and Promotion Project-Scientific and Technological Breakthroughs,Grant/Award Number:232102230088National Natural Science Foundation of China,Grant/Award Numbers:22205209,U21A200972。
文摘Two-dimensional(2D)high-entropy alloys(HEAs)have emerged as promising electrocatalysts due to the benefits of polymetallic coordination and robust elec-trical conductivity.However,the multiple elements in 2D HEAs pose challenges in achieving a uniform composition and maintaining a 2D limit morphology,complicating their structural characterization.Furthermore,even minor adjust-ments to the composition can significantly alter the properties of 2D HEAs,underscoring the need for a deeper understanding of their structure-property relationships to advance synthesis and application.Therefore,this review crit-ically examines the intrinsic factors influencing synthesis methods and the practical applications of 2D HEAs in electrocatalysis for sustainable energy con-version.The urgency is emphasized for developing new synthesis techniques,enhancing advanced characterization methods,and gaining profound insights into the functional mechanisms of 2D HEAs.
