By temperature gradient method under high pressure and high temperature （HPHT）, with NiMnCo alloy as the solvent metal, at diamond-stable region of about 5.4 GPa and 1500 K, metastable regrown graphite crystals of d...By temperature gradient method under high pressure and high temperature （HPHT）, with NiMnCo alloy as the solvent metal, at diamond-stable region of about 5.4 GPa and 1500 K, metastable regrown graphite crystals of different morphology were synthesized. With B as an additive incorporated into the NiMnCo-C system, metastable regrown graphite crystals of sphere-like shape were firstly obtained under HPHT. If the growth system does not contain B, sheet-like regrown graphite crystals, most with regular hexagonal morphology, are grown upwards and standing vertically in the metal solvent. When B additive of 1.0 wt pct was added into carbon source （graphite powder）, all metastable regrown graphite crystals took on the habit of regular sphere-like morphology, and were grown by a spiral layer growth mechanism.展开更多
基金supported by the National Natural Science Foundation of China under grant No.50172018the Foundation of He nan Educational Committee undergrant No.2009A430014the Open Research Fund Program of State Key Laboratory of Superhard Materials of Jilin University under grant No.200801
文摘By temperature gradient method under high pressure and high temperature （HPHT）, with NiMnCo alloy as the solvent metal, at diamond-stable region of about 5.4 GPa and 1500 K, metastable regrown graphite crystals of different morphology were synthesized. With B as an additive incorporated into the NiMnCo-C system, metastable regrown graphite crystals of sphere-like shape were firstly obtained under HPHT. If the growth system does not contain B, sheet-like regrown graphite crystals, most with regular hexagonal morphology, are grown upwards and standing vertically in the metal solvent. When B additive of 1.0 wt pct was added into carbon source （graphite powder）, all metastable regrown graphite crystals took on the habit of regular sphere-like morphology, and were grown by a spiral layer growth mechanism.
