Liquid-liquid equilibrium (LLE) data for the water + butyric acid + nonanol system have been determined experimentally at the temperatures of 298.15 K, 308.15 K and 318.15 K. Tie-line compositions were correlated by O...Liquid-liquid equilibrium (LLE) data for the water + butyric acid + nonanol system have been determined experimentally at the temperatures of 298.15 K, 308.15 K and 318.15 K. Tie-line compositions were correlated by Othmer-Tobias method. The universal quasichemical functional group activity coefficient (UNIFAC) and modified UNIFAC methods were used to predict the phase equilibrium in the system using the interaction parameters between CH3, CH2, COOH, OH and H2O functional groups. Distribution coefficients and separation factors were evaluated for the immiscibility region.展开更多
The stability constants of the binary complexes of Mn2+ with nicotinamide (NA) were determined from potentiometric pH titrations data at 15.0 , 25.0 and 35.0oC and I = 0.1,0.2,0.4 mol L-1 (NaClO4). The formation of bi...The stability constants of the binary complexes of Mn2+ with nicotinamide (NA) were determined from potentiometric pH titrations data at 15.0 , 25.0 and 35.0oC and I = 0.1,0.2,0.4 mol L-1 (NaClO4). The formation of binary 1:1 , 1:2 NA-Mn complexes at three different temperatures and the influence of three different ionic strength on their stability were reported. The thermodynamic parameters (DGof, DSof, DHof) for the complex formation reaction were estimated from stability constant at different temperatures.展开更多
Tropospheric ozone concentrations, which are an important air pollutant, are modeled by the use of an artificial intelligence structure. Data obtained from air pollution measurement stations in the city of Istanbul ar...Tropospheric ozone concentrations, which are an important air pollutant, are modeled by the use of an artificial intelligence structure. Data obtained from air pollution measurement stations in the city of Istanbul are utilized in constituting the model. A supervised algorithm for the evaluation of ozone concentration using a genetically trained multi-level cellular neural network （ML-CNN） is introduced, developed, and applied to real data. A genetic algorithm is used in the optimization of CNN templates. The model results and the actual measurement results are compared and statistically evaluated. It is observed that seasonal changes in ozone concentrations are reflected effectively by the concentrations estimated by the multilevel-CNN model structure, with a correlation value of 0.57 ascertained between actual and model results. It is shown that the multilevel-CNN modeling technique is as satisfactory as other modeling techniques in associating the data in a complex medium in air pollution applications.展开更多
Turkey is a region of special interest for Devonian researchers because it comprises Laurasian and Gondwanan components situated on different but neighbouring tectonic blocks. The respective strata include a variety o...Turkey is a region of special interest for Devonian researchers because it comprises Laurasian and Gondwanan components situated on different but neighbouring tectonic blocks. The respective strata include a variety of facies representing different shelf to marginal marine and even continental environments.展开更多
A major event of IGCP 499 in 2005 took place in Southern Siberia. In the tradition of successful joint meetings and field trips of Devonian iGCP projects and the international Subcommission on Devonian Stratigraphy （...A major event of IGCP 499 in 2005 took place in Southern Siberia. In the tradition of successful joint meetings and field trips of Devonian iGCP projects and the international Subcommission on Devonian Stratigraphy （SDS）, a very successful meeting was held at the Institute of Petroleum Geology, United Institute of Geology and Mineralogy of the Russian Academy of Sciences, Siberian Branch in Novosibitsk. The meeting, which included a splendid field trip to the South of Siberia （July 26-August 6, 2005） and well-organised technical sessions （ August 7-8, 2005）. was run by a great group from Novosibirsk under the guidance of E. A. Yolkin. A. V. Kanygin： N. K. Bakharev. N. G. Izokh, and O. T. Obut （and a wonderful learn helping to arrange the sessions and the field trip in a perfect way!）展开更多
Schiff base ligand （HL） derived from 4-hexylaniline with isatin （1H-indole-2,3-dione） and its complexes with Cu（Ⅱ）, Ni（Ⅱ） were prepared and characterized by analytical, spectroscopic （IR, UV-Vis, Mass） tec...Schiff base ligand （HL） derived from 4-hexylaniline with isatin （1H-indole-2,3-dione） and its complexes with Cu（Ⅱ）, Ni（Ⅱ） were prepared and characterized by analytical, spectroscopic （IR, UV-Vis, Mass） techniques, electrical conductivity, magnetic and thermal measurements. The crystal and molecular structure of [Cu（HL）2Cl2] was determined by a single-crystal X-ray diffraction study. The molecular structure of the title compound has an inversion center on the Cu atom.展开更多
This study focuses on vector-valued anisotropic Sobolev-Lions spaces associated with Banach spaces E0, E. Several conditions are found that ensure the continuity and compactness of embedding operators that are optimal...This study focuses on vector-valued anisotropic Sobolev-Lions spaces associated with Banach spaces E0, E. Several conditions are found that ensure the continuity and compactness of embedding operators that are optimal regular in these spaces in terms of interpolations of spaces E0 and E. In particular, the most regular class of interpolation spaces Eα between E0, E depending on α and the order of space are found and the boundedness of differential operators D^α from this space to Eα-valued Lp,γ spaces is proved. These results are applied to partial differential-operator equations with parameters to obtain conditions that guarantee the maximal Lp,γ regularity and R-positivity uniformly with respect to these parameters.展开更多
文摘Liquid-liquid equilibrium (LLE) data for the water + butyric acid + nonanol system have been determined experimentally at the temperatures of 298.15 K, 308.15 K and 318.15 K. Tie-line compositions were correlated by Othmer-Tobias method. The universal quasichemical functional group activity coefficient (UNIFAC) and modified UNIFAC methods were used to predict the phase equilibrium in the system using the interaction parameters between CH3, CH2, COOH, OH and H2O functional groups. Distribution coefficients and separation factors were evaluated for the immiscibility region.
文摘The stability constants of the binary complexes of Mn2+ with nicotinamide (NA) were determined from potentiometric pH titrations data at 15.0 , 25.0 and 35.0oC and I = 0.1,0.2,0.4 mol L-1 (NaClO4). The formation of binary 1:1 , 1:2 NA-Mn complexes at three different temperatures and the influence of three different ionic strength on their stability were reported. The thermodynamic parameters (DGof, DSof, DHof) for the complex formation reaction were estimated from stability constant at different temperatures.
文摘Tropospheric ozone concentrations, which are an important air pollutant, are modeled by the use of an artificial intelligence structure. Data obtained from air pollution measurement stations in the city of Istanbul are utilized in constituting the model. A supervised algorithm for the evaluation of ozone concentration using a genetically trained multi-level cellular neural network （ML-CNN） is introduced, developed, and applied to real data. A genetic algorithm is used in the optimization of CNN templates. The model results and the actual measurement results are compared and statistically evaluated. It is observed that seasonal changes in ozone concentrations are reflected effectively by the concentrations estimated by the multilevel-CNN model structure, with a correlation value of 0.57 ascertained between actual and model results. It is shown that the multilevel-CNN modeling technique is as satisfactory as other modeling techniques in associating the data in a complex medium in air pollution applications.
文摘Turkey is a region of special interest for Devonian researchers because it comprises Laurasian and Gondwanan components situated on different but neighbouring tectonic blocks. The respective strata include a variety of facies representing different shelf to marginal marine and even continental environments.
文摘A major event of IGCP 499 in 2005 took place in Southern Siberia. In the tradition of successful joint meetings and field trips of Devonian iGCP projects and the international Subcommission on Devonian Stratigraphy （SDS）, a very successful meeting was held at the Institute of Petroleum Geology, United Institute of Geology and Mineralogy of the Russian Academy of Sciences, Siberian Branch in Novosibitsk. The meeting, which included a splendid field trip to the South of Siberia （July 26-August 6, 2005） and well-organised technical sessions （ August 7-8, 2005）. was run by a great group from Novosibirsk under the guidance of E. A. Yolkin. A. V. Kanygin： N. K. Bakharev. N. G. Izokh, and O. T. Obut （and a wonderful learn helping to arrange the sessions and the field trip in a perfect way!）
文摘Schiff base ligand （HL） derived from 4-hexylaniline with isatin （1H-indole-2,3-dione） and its complexes with Cu（Ⅱ）, Ni（Ⅱ） were prepared and characterized by analytical, spectroscopic （IR, UV-Vis, Mass） techniques, electrical conductivity, magnetic and thermal measurements. The crystal and molecular structure of [Cu（HL）2Cl2] was determined by a single-crystal X-ray diffraction study. The molecular structure of the title compound has an inversion center on the Cu atom.
基金This work is supported by the grant of Istanbul University (Project UDP-227/18022004)
文摘This study focuses on vector-valued anisotropic Sobolev-Lions spaces associated with Banach spaces E0, E. Several conditions are found that ensure the continuity and compactness of embedding operators that are optimal regular in these spaces in terms of interpolations of spaces E0 and E. In particular, the most regular class of interpolation spaces Eα between E0, E depending on α and the order of space are found and the boundedness of differential operators D^α from this space to Eα-valued Lp,γ spaces is proved. These results are applied to partial differential-operator equations with parameters to obtain conditions that guarantee the maximal Lp,γ regularity and R-positivity uniformly with respect to these parameters.
