Microwave-assisted tandem reaction of（Z）-arylvinyl bromides involving an elimination and homocoupling in the presence of DBU and Cul in DMF affords a variety of symmetrical 1,3-diynes in good to excellent yields.Thi...Microwave-assisted tandem reaction of（Z）-arylvinyl bromides involving an elimination and homocoupling in the presence of DBU and Cul in DMF affords a variety of symmetrical 1,3-diynes in good to excellent yields.This tandem process,eliminating the need of volatile and savory terminal alkynes,provides an alternative to the conventional homocoupling methods for the synthesis of symmetrical 1,3-diynes.展开更多
基金supported by the National Natural Science Foundation of China(No.21172059)Program for Science & Technology Innovation Talents in Universities of Henan Province (No.2011HASTIT032)+1 种基金Foundation of Jiaozuo Scientific and Technological Bureau(No.201113)Foundation of Henan Scientific and Technological Committee(No.122102310497)
文摘Microwave-assisted tandem reaction of（Z）-arylvinyl bromides involving an elimination and homocoupling in the presence of DBU and Cul in DMF affords a variety of symmetrical 1,3-diynes in good to excellent yields.This tandem process,eliminating the need of volatile and savory terminal alkynes,provides an alternative to the conventional homocoupling methods for the synthesis of symmetrical 1,3-diynes.
