This study explores the capabilities of ChatGPT, specifically in relation to consciousness and its performance in the Turing Test. The article begins by examining the diverse perspectives among both the cognitive and ...This study explores the capabilities of ChatGPT, specifically in relation to consciousness and its performance in the Turing Test. The article begins by examining the diverse perspectives among both the cognitive and AI researchers regarding ChatGPT’s ability to pass the Turing Test. It introduces a hierarchical categorization of the test versions, suggesting that ChatGPT approaches success in the test, albeit primarily with na?ve users. Expert users, conversely, can easily identify its limitations. The paper presents various theories of consciousness, with a particular focus on the Integrated Information Theory proposed by Tononi. This theory serves as the framework for assessing ChatGPT’s level of consciousness. Through an evaluation based on the five axioms and theorems of IIT, the study finds that ChatGPT surpasses previous AI systems in certain aspects;however, ChatGPT significantly falls short of achieving a level of consciousness, particularly when compared to biological sentient beings. The paper concludes by emphasizing the importance of recognizing ChatGPT and similar generative AI models as highly advanced and intelligent tools, yet distinctly lacking the consciousness attributes found in advanced living organisms.展开更多
The characteristics of an innovative configuration of multiple radiofrequency(RF)coils immersed in a large metallic chamber are presented.Water-cooled copper coils were mounted within the slits of double-walled glass ...The characteristics of an innovative configuration of multiple radiofrequency(RF)coils immersed in a large metallic chamber are presented.Water-cooled copper coils were mounted within the slits of double-walled glass tubes,which were immersed into a stainless-steel chamber.The coils were connected in parallel to a gamma-type matching network,powered by an RF generator operating at industrial frequency.Adjustable leads enabled optimisation of the line impedances and thus uniformly distributed RF power across the four coils.Transitions from E-to H-mode and vice versa were measured for all coils at various oxygen pressures between 5 and 25 Pa.A uniform plasma was sustained in H-mode at the absorbed power threshold,which increased monotonously with increasing pressure in the metallic chamber.All coils exhibit the same E-to H-mode transition hysteresis and need the same amount of power for transitioning from E-to H-mode.The setup enables maintaining uniform plasma in virtually any number of coils at high power without the risk of arcing and without the dead volume typical for a classical configuration with coils mounted outside the metallic chamber.展开更多
Sulfur dioxide (SO2) and nitrogen dioxide (NO2) emissions generated at coal burning power plants and from transport are a leading cause of acid deposition and chemical smog in many parts of the world. Sulfur dioxide e...Sulfur dioxide (SO2) and nitrogen dioxide (NO2) emissions generated at coal burning power plants and from transport are a leading cause of acid deposition and chemical smog in many parts of the world. Sulfur dioxide emitted by thermal power plants and from transport in Kosovo is transported via prevailing winds to other locations. Through its journey, this SO2 gas undergoes a series of chemical reactions that ultimately transform it into sulfuric acid (H2SO4) which is deposited as acid rain. As a consequence of NO2 emissions from electricity production and transport in Kosovo the ozone (O3) is formed as photochemical smog due to sunlight, which triggers the breakdown of NO2. We modeled the impact of SO2 and NO2 emissions from energy system and transport in Kosovo on acid deposition and chemical smog locally. In model we consider the role of SO2 and NO2 pollution control technologies on mitigating these impacts.展开更多
Flue gas containing volatile elements, fine fly ash particulates not retained by particle control devices, and limestone are the most important sources of trace and major elements (TMEs) in wet flue gas desulphurizati...Flue gas containing volatile elements, fine fly ash particulates not retained by particle control devices, and limestone are the most important sources of trace and major elements (TMEs) in wet flue gas desulphurization (WFGD) gypsum. In this study, samples of gypsum slurry were separated into fine and coarse fractions. Multi-elemental analysis of 45 elements in the different size fractions of gypsum, slurry waters and lignite were performed by k0-INAA (k0-instrumental neutron activation analyses). The study found that the volatile elements (Hg, Se and halogens) in the flue gas accumulate in the fine fractions of gypsum. Moreover, the concentrations of most TMEs are considerably higher in the fine fractions compared to the coarse fractions. The exceptions are Ca and Sr that primarily originate from the limestone. Variations of TMEs in the finer fractions are dependent on the presence of CaSO4·2H2O that is the main constituent of the coarse fraction. Consequently, the content of TMEs in the fine fraction is highly dependent on the efficiency of separating the fine fraction from the coarse fraction. Separation of the finer fraction, representing about 10% of the total gypsum, offers the possibility to remove effectively TMEs from WFGD slurry.展开更多
Fourier transform infrared spectroscopy(FTIR)is one of the most widely used vibrational diagnostic techniques to investigate gas-phase reactive oxygen and nitrogen species(RONS).However,the technique carries intrinsic...Fourier transform infrared spectroscopy(FTIR)is one of the most widely used vibrational diagnostic techniques to investigate gas-phase reactive oxygen and nitrogen species(RONS).However,the technique carries intrinsic challenges,particularly in relation to interfering peaks in the spectral data.This study explores the interfacial processes that occur when reactive oxygen and nitrogen species generated by a non-equilibrium air plasma interact with the metal halide windows of an FTIR gas cell,leading to the appearance and evolution of spurious absorption peaks which complicate spectral interpretation.Raman spectroscopy,X-ray photoelectron spectroscopy,time of flight secondary ion mass spectrometry and attenuated total reflectance-FTIR spectroscopy were used to elucidate the origin of spurious absorption peaks spanning the 1400-1300 cm^(-1)spectral range as a result of KBr exposure to plasma generated species.It was found that plasma exposed KBr contained a lower atomic fraction of Br which was replaced by the NO3nitrate group,the main absorbance peak of which progressively evolved with plasma exposure and affected the window transparency over the corresponding FTIR region.A correlation was revealed between KNO_(3)formation,plasma power and exposure time to a growth and change in molecular vibrational energies corresponding to asymmetric NO3stretching vibrations in the KNO_(3)structure.展开更多
The dependence of the magnetic properties on the particle size of recycled HDDR Nd-Fe-B powders was investigated,with the aim to assess the reprocessing potential of the end-of-life scrap magnets via spark plasma sint...The dependence of the magnetic properties on the particle size of recycled HDDR Nd-Fe-B powders was investigated,with the aim to assess the reprocessing potential of the end-of-life scrap magnets via spark plasma sintering(SPS).The as received recycled HDDR powder has coercivity(Hci)=830 kA/m and particles in the range from 30 to 700 μm(average 220 μm).After burr milling,the average particle size is reduced to 120 μm and subsequently the Hci of fine(milled) powder was 595 kA/m.Spark plasma sintering was exploited to consolidate the nanograined HDDR powders and limit the abnormal grain coarsening.The optimal SPS-ing of coarse HDDR powder at 750℃for 1 min produces fully dense magnets with Hci=950±100 kA/m which further increases to 1200 kA/m via thermal treatment at 750℃for 15 min.The burr milled fine HDDR powder under similar SPS conditions and after thermal treatment results in Hci=940 kA/m.The fine powder is further sieved down from 630 to less than 50 μm mesh size,to evaluate the possible reduction in Hci in relation to the particle size.The gain in oxygen content doubles for <50 μm sized particles as compared with coarser fractions(>200 μm).The XRD analysis for fractionated powder indicates an increase in Nd2O3 phase peaks in the finer(<100 μm)fractions.Similarly,the Hci reduces from 820 kA/m in the coarse particles(>200 μm) to 460 kA/m in the fine sized particles(<100μm).SPS was done on each HDDR powder fraction under the optimal conditions to measure the variation in Hci and density.The Hci of SPS-ed coarse fraction(>200 μm) is higher than 930 kA/m and it falls abruptly to just 70 kA/m for the fine sized particles(<100 μm).The thermal treatment further improves the Hci to>1000 kA/m only up to 100 μm sized fractions with>90% sintered density.The full densification(>99%) is observed only in the coarse fractions.The loss of coercivity and lack of sinterability in the fine sized particles(<100 μm) are attributed to a very high oxygen content.This implies that during recycling,if good magnetic properties are to be maintained or even increase the HDDR powder particles can be sized down only up to≥100 μm.展开更多
The atmospheric pressure plasma jet （APPJ） was used to enhance the sensitivity of industrially important polyaniline （PANI） for detection of organic vapors from amides. The gas sensing mechanism of PANI is operati...The atmospheric pressure plasma jet （APPJ） was used to enhance the sensitivity of industrially important polyaniline （PANI） for detection of organic vapors from amides. The gas sensing mechanism of PANI is operating on the basis of reversible protonation or deprotonation, whereas the driving force to improve the sensitivity after plasma modifications is unknown. Herein we manage to solve this problem and investigate the sensing mechanism of atmospheric plasma treated PANI for vapor detection of amides using urea as a model. The results from various analytical techniques indicate that the plausible mechanism responsible for the improved sensi- tivity after plasma treatment is operating through a cyclic transition state formed between the functional groups introduced by plasma treatment and urea. This transition state improved the sensitivity of PANI towards 15 ppm of urea by a factor of 2.4 times PANI. This plasma treated compared to the non-treated PANI is promising for the improvement of the sensitivity and selectivity towards other toxic and carcinogenic amide analytes for gas sensing applications such as improving material proces- sing and controlling food quality.展开更多
Since graphene has been discovered, twodimensional nanomaterials have attracted attention due to their promising tunable electronic properties. The possibility of tailoring electrical conductivity at the atomic level ...Since graphene has been discovered, twodimensional nanomaterials have attracted attention due to their promising tunable electronic properties. The possibility of tailoring electrical conductivity at the atomic level allows creating new prospective 2D structures for energy harvesting and sensing-related applications. In this respect, one of the most successful way to manipulate the physical properties of the aforementioned materials is related to the surface modification techniques employing plasma. Moreover, plasma-gaseous chemical treatment can provide a controlled change in the bandgap, increase sensitivity and significantly improve the structural stability of material to the environment as well. This review deals with recent advances in the modification of 2D carbon nanostructures for novel ‘edge’ electronics using plasma technology and processes.展开更多
K_(0.5)Na_(0.5)NbO_(3)-SrTiO_(3)(KNN-STO)thin films of different compositions were prepared by the chemical solution deposition method.While structural investigations confirmed the formation of perovskite solid soluti...K_(0.5)Na_(0.5)NbO_(3)-SrTiO_(3)(KNN-STO)thin films of different compositions were prepared by the chemical solution deposition method.While structural investigations confirmed the formation of perovskite solid solution in all developed films,dieletric experiments revealed a relaxor broad dispersive maximum in the sample with 15 mol%of STO,exhibiting for a thin film high ε′~330 at~210K.The history-dependent effects of this relaxor sample were compared to those of KNN STO ceramics and,furthermore,shown to be much weaker than in widely used lead-based ferroelectric and relaxor(Pb,L a)(Zr,Ti)O_(3) ceramics:While fatigue endurance results revealed a slight drop in polarization after 3 × 10^(5) switching cycles,the results of aging of the dielectric constant revealed no notable decrease in its values after 10^(6)s.展开更多
文摘This study explores the capabilities of ChatGPT, specifically in relation to consciousness and its performance in the Turing Test. The article begins by examining the diverse perspectives among both the cognitive and AI researchers regarding ChatGPT’s ability to pass the Turing Test. It introduces a hierarchical categorization of the test versions, suggesting that ChatGPT approaches success in the test, albeit primarily with na?ve users. Expert users, conversely, can easily identify its limitations. The paper presents various theories of consciousness, with a particular focus on the Integrated Information Theory proposed by Tononi. This theory serves as the framework for assessing ChatGPT’s level of consciousness. Through an evaluation based on the five axioms and theorems of IIT, the study finds that ChatGPT surpasses previous AI systems in certain aspects;however, ChatGPT significantly falls short of achieving a level of consciousness, particularly when compared to biological sentient beings. The paper concludes by emphasizing the importance of recognizing ChatGPT and similar generative AI models as highly advanced and intelligent tools, yet distinctly lacking the consciousness attributes found in advanced living organisms.
基金funded by the Slovenian Research Agency,project No.L2-9235(Innovative configuration of inductively coupled gaseous plasma sources for up-scaling to industrialsize reactors)core funding P2-0082(thin-film structures and plasma surface engineering)。
文摘The characteristics of an innovative configuration of multiple radiofrequency(RF)coils immersed in a large metallic chamber are presented.Water-cooled copper coils were mounted within the slits of double-walled glass tubes,which were immersed into a stainless-steel chamber.The coils were connected in parallel to a gamma-type matching network,powered by an RF generator operating at industrial frequency.Adjustable leads enabled optimisation of the line impedances and thus uniformly distributed RF power across the four coils.Transitions from E-to H-mode and vice versa were measured for all coils at various oxygen pressures between 5 and 25 Pa.A uniform plasma was sustained in H-mode at the absorbed power threshold,which increased monotonously with increasing pressure in the metallic chamber.All coils exhibit the same E-to H-mode transition hysteresis and need the same amount of power for transitioning from E-to H-mode.The setup enables maintaining uniform plasma in virtually any number of coils at high power without the risk of arcing and without the dead volume typical for a classical configuration with coils mounted outside the metallic chamber.
文摘Sulfur dioxide (SO2) and nitrogen dioxide (NO2) emissions generated at coal burning power plants and from transport are a leading cause of acid deposition and chemical smog in many parts of the world. Sulfur dioxide emitted by thermal power plants and from transport in Kosovo is transported via prevailing winds to other locations. Through its journey, this SO2 gas undergoes a series of chemical reactions that ultimately transform it into sulfuric acid (H2SO4) which is deposited as acid rain. As a consequence of NO2 emissions from electricity production and transport in Kosovo the ozone (O3) is formed as photochemical smog due to sunlight, which triggers the breakdown of NO2. We modeled the impact of SO2 and NO2 emissions from energy system and transport in Kosovo on acid deposition and chemical smog locally. In model we consider the role of SO2 and NO2 pollution control technologies on mitigating these impacts.
基金funded by the Slovenian Research Agency program P1-0143 and project L1-5446 and the young researchers programsupported by the EMPIR MercOx project(16ENV01).
文摘Flue gas containing volatile elements, fine fly ash particulates not retained by particle control devices, and limestone are the most important sources of trace and major elements (TMEs) in wet flue gas desulphurization (WFGD) gypsum. In this study, samples of gypsum slurry were separated into fine and coarse fractions. Multi-elemental analysis of 45 elements in the different size fractions of gypsum, slurry waters and lignite were performed by k0-INAA (k0-instrumental neutron activation analyses). The study found that the volatile elements (Hg, Se and halogens) in the flue gas accumulate in the fine fractions of gypsum. Moreover, the concentrations of most TMEs are considerably higher in the fine fractions compared to the coarse fractions. The exceptions are Ca and Sr that primarily originate from the limestone. Variations of TMEs in the finer fractions are dependent on the presence of CaSO4·2H2O that is the main constituent of the coarse fraction. Consequently, the content of TMEs in the fine fraction is highly dependent on the efficiency of separating the fine fraction from the coarse fraction. Separation of the finer fraction, representing about 10% of the total gypsum, offers the possibility to remove effectively TMEs from WFGD slurry.
基金financial support from the Public Agency for Research Activity of the Republic of Slovenia(awards J2-4490,J2-4451 and L2-4481)the UK Engineering and Physical Sciences Research Council(EPSRC)(awards EP/S025790/1 and EP/N021347/1)NATO(award G5814)
文摘Fourier transform infrared spectroscopy(FTIR)is one of the most widely used vibrational diagnostic techniques to investigate gas-phase reactive oxygen and nitrogen species(RONS).However,the technique carries intrinsic challenges,particularly in relation to interfering peaks in the spectral data.This study explores the interfacial processes that occur when reactive oxygen and nitrogen species generated by a non-equilibrium air plasma interact with the metal halide windows of an FTIR gas cell,leading to the appearance and evolution of spurious absorption peaks which complicate spectral interpretation.Raman spectroscopy,X-ray photoelectron spectroscopy,time of flight secondary ion mass spectrometry and attenuated total reflectance-FTIR spectroscopy were used to elucidate the origin of spurious absorption peaks spanning the 1400-1300 cm^(-1)spectral range as a result of KBr exposure to plasma generated species.It was found that plasma exposed KBr contained a lower atomic fraction of Br which was replaced by the NO3nitrate group,the main absorbance peak of which progressively evolved with plasma exposure and affected the window transparency over the corresponding FTIR region.A correlation was revealed between KNO_(3)formation,plasma power and exposure time to a growth and change in molecular vibrational energies corresponding to asymmetric NO3stretching vibrations in the KNO_(3)structure.
基金Project supported by European Community’s Horizon 2020Program [H2020/2014-2019] under grant Agreement No.674973(MSCA-ETN DEMETER)
文摘The dependence of the magnetic properties on the particle size of recycled HDDR Nd-Fe-B powders was investigated,with the aim to assess the reprocessing potential of the end-of-life scrap magnets via spark plasma sintering(SPS).The as received recycled HDDR powder has coercivity(Hci)=830 kA/m and particles in the range from 30 to 700 μm(average 220 μm).After burr milling,the average particle size is reduced to 120 μm and subsequently the Hci of fine(milled) powder was 595 kA/m.Spark plasma sintering was exploited to consolidate the nanograined HDDR powders and limit the abnormal grain coarsening.The optimal SPS-ing of coarse HDDR powder at 750℃for 1 min produces fully dense magnets with Hci=950±100 kA/m which further increases to 1200 kA/m via thermal treatment at 750℃for 15 min.The burr milled fine HDDR powder under similar SPS conditions and after thermal treatment results in Hci=940 kA/m.The fine powder is further sieved down from 630 to less than 50 μm mesh size,to evaluate the possible reduction in Hci in relation to the particle size.The gain in oxygen content doubles for <50 μm sized particles as compared with coarser fractions(>200 μm).The XRD analysis for fractionated powder indicates an increase in Nd2O3 phase peaks in the finer(<100 μm)fractions.Similarly,the Hci reduces from 820 kA/m in the coarse particles(>200 μm) to 460 kA/m in the fine sized particles(<100μm).SPS was done on each HDDR powder fraction under the optimal conditions to measure the variation in Hci and density.The Hci of SPS-ed coarse fraction(>200 μm) is higher than 930 kA/m and it falls abruptly to just 70 kA/m for the fine sized particles(<100 μm).The thermal treatment further improves the Hci to>1000 kA/m only up to 100 μm sized fractions with>90% sintered density.The full densification(>99%) is observed only in the coarse fractions.The loss of coercivity and lack of sinterability in the fine sized particles(<100 μm) are attributed to a very high oxygen content.This implies that during recycling,if good magnetic properties are to be maintained or even increase the HDDR powder particles can be sized down only up to≥100 μm.
文摘The atmospheric pressure plasma jet （APPJ） was used to enhance the sensitivity of industrially important polyaniline （PANI） for detection of organic vapors from amides. The gas sensing mechanism of PANI is operating on the basis of reversible protonation or deprotonation, whereas the driving force to improve the sensitivity after plasma modifications is unknown. Herein we manage to solve this problem and investigate the sensing mechanism of atmospheric plasma treated PANI for vapor detection of amides using urea as a model. The results from various analytical techniques indicate that the plausible mechanism responsible for the improved sensi- tivity after plasma treatment is operating through a cyclic transition state formed between the functional groups introduced by plasma treatment and urea. This transition state improved the sensitivity of PANI towards 15 ppm of urea by a factor of 2.4 times PANI. This plasma treated compared to the non-treated PANI is promising for the improvement of the sensitivity and selectivity towards other toxic and carcinogenic amide analytes for gas sensing applications such as improving material proces- sing and controlling food quality.
文摘Since graphene has been discovered, twodimensional nanomaterials have attracted attention due to their promising tunable electronic properties. The possibility of tailoring electrical conductivity at the atomic level allows creating new prospective 2D structures for energy harvesting and sensing-related applications. In this respect, one of the most successful way to manipulate the physical properties of the aforementioned materials is related to the surface modification techniques employing plasma. Moreover, plasma-gaseous chemical treatment can provide a controlled change in the bandgap, increase sensitivity and significantly improve the structural stability of material to the environment as well. This review deals with recent advances in the modification of 2D carbon nanostructures for novel ‘edge’ electronics using plasma technology and processes.
基金This project was financially supported by Slovenian Research Agency under programs P1-0125 and P2-0105 and projects PR-02908,J2-1227,and PR-03099by Ministry of Education,Science and Sport of Republic of Slovenia under Project PR-05648.
文摘K_(0.5)Na_(0.5)NbO_(3)-SrTiO_(3)(KNN-STO)thin films of different compositions were prepared by the chemical solution deposition method.While structural investigations confirmed the formation of perovskite solid solution in all developed films,dieletric experiments revealed a relaxor broad dispersive maximum in the sample with 15 mol%of STO,exhibiting for a thin film high ε′~330 at~210K.The history-dependent effects of this relaxor sample were compared to those of KNN STO ceramics and,furthermore,shown to be much weaker than in widely used lead-based ferroelectric and relaxor(Pb,L a)(Zr,Ti)O_(3) ceramics:While fatigue endurance results revealed a slight drop in polarization after 3 × 10^(5) switching cycles,the results of aging of the dielectric constant revealed no notable decrease in its values after 10^(6)s.
