Characterization and quantification of multi-field coupling in lithium-ion batteries under mechanical constraints

The safety and durability of lithium-ion batteries under mechanical constraints depend significantly on electrochemical,thermal,and mechanical fields in applications.Characterizing and quantifying the multi-field coupling behaviors requires interdisciplinary efforts.Here,we design experiments under mechanical constraints and introduce an in-situ analytical framework to clarify the complex interaction mechanisms and coupling degrees among multi-physics fields.The proposed analytical framework integrates the parameterization of equivalent models,in-situ mechanical analysis,and quantitative assessment of coupling behavior.The results indicate that the significant impact of pressure on impedance at low temperatures results from the diffusion-controlled step,enhancing kinetics when external pressure,like 180 to 240 k Pa at 10℃,is applied.The diversity in control steps for the electrochemical reaction accounts for the varying impact of pressure on battery performance across different temperatures.The thermal expansion rate suggests that the swelling force varies by less than 1.60%per unit of elevated temperature during the lithiation process.By introducing a composite metric,we quantify the coupling correlation and intensity between characteristic parameters and physical fields,uncovering the highest coupling degree in electrochemical-thermal fields.These results underscore the potential of analytical approaches in revealing the mechanisms of interaction among multi-fields,with the goal of enhancing battery performance and advancing battery management.

三峡库区岸生植物野古草(Arundinella anomala Steud.)光合作用对水淹的响应

为了阐明水淹对三峡库区岸生植物野古草光合作用的影响,模拟了三峡库区消落带水淹发生情况,考察了在不同水淹处理下野古草(Arundinella anomalaSteud.)的光合及叶绿素荧光特性。实验设置了对照(不进行水淹,常规供水管理)、半淹(植株置于水中,植株地上部分一半被淹没)、水下0.5m(植株置于水中,植株顶部在水面下0.5m)、水下2m(植株置于水中,植株顶部在水面下2m)4个不同的水淹深度和02、0、40d和60d等4个不同的水淹时间处理,测定了在不同水淹深度和水淹时间处理下野古草的净光合速率、总叶绿素含量、PSⅡ的最大光化学效率、电子传递速率、表观量子效率、叶绿素利用效率与羧化效率。结果发现,在水淹前期,水淹对野古草的光合特性影响较小,直到水淹60d后,才对野古草的光合特性产生明显影响,且影响程度随水淹深度的不同而不同。野古草在水淹20d和水淹40d后,各水淹处理的净光合速率与对照相比无明显降低,其中水淹20d后,半淹处理的野古草叶片净光合速率比对照还高出16.1%。水淹60d后,水下0.5m和水下2m的净光合速率显著低于对照和半淹,其净光合速率分别为7.51μmol.m-2.s-1和9.15μmol.m-2.s-1。结果表明,水淹20d和40d对野古草的电子传递速率、表观量子效率和羧化效率没有影响。水淹处理60d后,与对照植株相比,半淹处理植株的电子传递速率、表观量子效率、叶绿素利用效率和羧化效率没有明显变化,但水下0.5m和水下2m处理植株的电子传递速率、表观量子效率、叶绿素利用效率和羧化效率有明显降低。在整个实验期间,半淹处理植株的净光合速率、电子传递速率、表观量子效率和羧化效率没有受到任何不利影响。尽管在水淹60d后水下0.5m和水下2m处理植株的净光合速率、电子传递速率、表观量子效率、叶绿素利用效率和羧化效率降低,但降低后的数值仍不低于甚至高于一些自然生长的未受水淹的植物物种。研究表明,野古草对水淹具有很好的耐受能力,是一种可以用于三峡库区消落区植被构建的优良植物物种。

1770年以来青藏高原错鄂地区古气候定量恢复

通过对1999年所采错鄂CE 1孔自生碳酸盐碳、氧同位素与1955—1999年器测温度降水资料的统计分析,获取了自生碳酸盐碳、氧同位素与气候要素的定量关系,并据此恢复了1770年以来该地区的古气候。结果表明,错鄂沉积物中自生方解石氧同位素与气温显示出较好的正相关性,而与降水相关性不明显;碳同位素刚好相反,它与降水负相关,而与气温相关性不显著。1770年以来,错鄂地区在20世纪初气候环境发生了根本的改变,1900年以前降水偏少,为沼泽环境,1900年后降水增加,湖泊发育;1900年前后气温开始上升,30年代后期气温达到峰值,50年代初气温稍有下降。1935—1999年平均气温较前一百多年升高了近1℃。所获结果有较好的区域对比性。

涂铁基非晶涂层的磨粒磨损性能研究

用电弧喷涂技术在Q235钢基体上制备一种高非晶含量的Fe基合金涂层.用MLS-225型湿砂橡胶轮磨损试验机评价铁基复合涂层的磨粒磨损性能,利用光学显微镜、扫描电子显微镜和X射线衍射仪对涂层的显微组织结构、磨损表面进行分析.结果表明,涂层中含有一定量的非晶相,通过Verdon方法对XRD图谱进行Pseudo-Voigt函数拟合,计算得出涂层的非晶相含量约为49%.涂层呈典型的层状组织结构,结构致密,孔隙率低,具有很高的硬度和耐磨性,显微硬度在HV900~1 050范围内,属于硬质涂层.涂层耐磨粒磨损性能为Q235钢的12.2倍.其磨损机制主要为脆性剥落.

乐果的振动光谱及其在金/银核-壳复合粒子表面的SERS研究

联合FTIR,FT-拉曼表征了乐果的振动光谱,获得了固态及不同酸碱条件下饱和液态乐果的振动特征信息;以金/银核-壳复合粒子为基底,获得了乐果在酸碱条件下一系列浓度的表面增强拉曼散射(SERS)光谱,考察了乐果分子在该基底表面的吸附状态及其酸碱影响,推测了乐果与金/银核-壳复合粒子作用机理;结果表明:νas(NH),νas(CH3),ν(O=C-N),τ(O=C-N),ν(P—O),ν(P S),ν(C—C),δ(P—O—C)为乐果分子特征振动;酸、碱条件下,在1.0×10-3mol.L-1为乐果与基底作用的最佳浓度;乐果主要以P—O—C,O=C-C,(S—CH2),P=S,CH3与金/银核-壳复合粒子基底相作用,探讨了酸碱条件下磷酸酯键不同离解历程对吸附的影响。为研究有机磷农药的形态变化提供有益参考。

青藏高原兴措湖腹足类壳体同位素组成特征与环境意义

通过对青藏高原东部兴措湖腹足类Gyraulussibirica壳体同位素的分析 ,并与器测气象资料的相关研究 ,建立兴措湖同位素记录与对应的降水和气温间的函数关系。对区内 2 0 0年来的温度序列进行定量恢复 ,结果表明 ,青藏高原东部兴措湖地区腹足类生物壳体主要在温季生长 ,它所记录的是温季而不是全年的气候环境信息 ;Gyraulussibirica壳体δ18O指标与温季滑动平均温度明显为正相关系 ,相关系数为 0 .89;δ13C指标与温季的降水量呈正相关系 ,相关系数 0 .71;近 2 0 0年来研究区温度变化有 3个明显的阶段 ,其中 2 0世纪初的低温期温度比目前平均低 3 .7°C。

高温超导约瑟夫森结阵列的相位锁定

根据交流约瑟夫森效应,研究了嵌入Fabry-Perot谐振腔里的约瑟夫森结阵列在微波辐照下的相位锁定问题。结阵列是由生长在双晶钇稳定氧化锆(YSZ)基片上的YB2Cu3O7(YBCO)超导薄膜光刻成微桥得到的。通过优化设计,在温度为79.2K辐照频率为77.465GHz的条件下,包含620个串联约瑟夫森双晶结的结阵列在外加微波辐照下实现了相位锁定,得到了陡峭的夏皮罗台阶。其第一级夏皮罗台阶的电压约为0.1V,台阶高度约为0.17mA。试验结果表明,这种结阵列结构在电压基准的应用上有极大的优势,而且这种准光学耦合方法在太赫兹信号发生和检测方面有很好的应用前景。

抛光处理铂铝粘结层的高温氧化

采用电镀和渗铝方法制备镍基合金的铂改性铝化物粘结层,并对涂层表面进行1μm表面抛光处理,研究1 100℃空气循环高温氧化生成的氧化铝层的表面形态和断面结构。结果表明,抛光处理可有效地抑制低铂含量涂层的表面脊背和凸起形成,压制高铂含量涂层的生长层起伏。同时,量化研究表明,样品经抛光处理后,氧化铝生长层的均平方根起伏系数(RMS)在氧化至1 000 h时约为1.5,线性长度起伏(L/L0)在氧化前后基本保持恒定,而表面起伏波长随时间呈增大趋势。抛光处理后涂层的氧化铝粘结性能较好,并具有较低的氧化铝生长速率。

基于高温超导SQUID的低场核磁共振研究

采用一高温超导射频量子干涉器(HTS rf-SQUID)作为信号探测器件,研究了多种液体样品的低场核磁共振信号。通过改变测量场(简称Bm)的大小,可以探测到质子拉莫频率(简称fL)从2Hz到40kHz的信号。由于在低场核磁共振中,Bm的均匀性能很好的得到满足,因而可能得到很窄的谱线宽度。实验发现,对自来水样品,在7μT以下均可接近谱线的自然宽度。同时,在低场核磁共振条件下,样品的化学位移很小以至于消失,因而可以研究"纯"的异核间的自旋耦合谱。作者研究了低场下2,2,2-三氟乙醇的低场自旋耦合谱。另外,作者首次采用SQUID在户外探测到地球磁场下的核磁共振现象,并研究了地球磁场的涨落对测量的影响,为SQUID的低场核磁共振研究开辟了一个新的研究方向。

Geochemical Stratigraphy and Microvertebrate Assemblage Sequences across the Silurian/Devonian Transition in South China

Carbon isotope （δ13Corg） analyses of non-marine clastic rocks and neritic carbonates and black shales spanning the Silurian/Devonian transition are compared from two richly fossiliferous sequences in Qujing of East Yunnan and Zoige of Sichuan, South China. The two sections, Xishancun and Putonggou sections in South China, reveal positive δ13Corg shifts happening in the Upper Pridoli and Lower Devonian and reaching peak values as heavy as -25.2‰ （Xishancun） and -19.9‰（Putonggou） in the lowermost Lochkovian following the first occurrence of the thelodont Parathelodus and the conodont Icriodus woschmidti woschmidti （only in Putonggou Section and together with Protathyris-Lanceomyonia brachiopod fauna）. These results replicate a globally known positive shift in δ13Corg from the uppermost Silurian to the lowermost Devonian. The δ13Corg variations across the Silurian/Devonian Boundary （SDB） at the two sections in South China exhibit a shift in carbon isotopic composition similar to the detailed SDB curves from the borehole Klonk-1 drilled at top of the Klonk Global Standard Stratotype-Section and Point （GSSP） in the Prague Basin, Czech Republic. In addition, four microvertebrate assemblages, including the Liaojiaoshan, Xishancun, Yanglugou and Xiaputonggou assemblages, are recognized from the Silurian/Devonian transition exposed in the Xishancun and Putonggou sections, respectively. The results from both carbon isotope stratigraphy and microvertebrate assemblage sequences suggest that the SDB in South China is located at the base of the Xishancun Formation （between sample QX-20 and sample QX-21） in the Xishancun Section and the lower part of the Xiaputonggou Formation （between sample ZP-09 and sample ZP-10） in the Putonggou Section. The isotopic trend for organic carbon together with the changes of microvertebrate remains across the SDB can offer an approach to a potential correlation of the SDB from different sedimentary facies, which help to correlate the marine with non-marine deposits.

Climatic Signals in the Last 200 Years from Stable Isotope Record in the Shells of Freshwater Snails in Lake Xingcuo, Eastern Tibet Plateau, China

Lake Xingcuo is a small closed, hard\|water lake, situated on eastern Tibet Plateau. Stable isotope data (\{δ\{\}\+\{18\}O\} and \{δ\{\}\+\{13\}C\}) from the freshwater snail Gyraulus sibirica (Dunker) in a 34 cm long, radioactive isotope\|dated sediment core represent the last 200 years of Lake Xingcuo environmental history. Carbon and oxygen isotope ratios in the shells of the freshwater snail bear information on the isotopic composition of the water in which the shells were formed, which in turn characterizes the climatic conditions prevailing during the snail’s life span. Whole\|shell and incremental growth data were collected from modern and fossil shells from Lake Xingcuo. The \{δ\{\}\+\{18\}O\} values of modern shells from Lake Xingcuo are in equilibrium with those of modern waters, while \{δ\{\}\+\{13\}C\} values are indicative of snail dietary carbon and a lake with high \{δ\{\}\+\{13\}C\}\-\{TDIC\}. By calibrating \{δ\{\}\+\{18\}O\} and \{δ\{\}\+\{13\}C\} in the shell Gyraulus sibirica (Dunker) with instrument\|measured data for the period 1954-1992, we found that the \{δ\{\}\+\{18\}O\} of the snail shells is an efficient indicator to reveal air temperature in the warmer half year instead of that around the whole year, and that there is a certain positive correlation between index\{δ\{\}\+\{18\}O\} and the running average temperature in the warmer half\|year period. Climatic variability on eastern Tibet Plateau, for the last two centuries, has been successfully inferred from the\{δ\{\}\+\{18\}O\} record in freshwater snails in the sediments of Lake Xingcuo. As such, the last 200 years of palaeoclimatic record for this region can be separated into three periods representing oscillations between warming and cooling, which are confirmed by the Guliya ice record on the Tibet Plateau.

Ecological migration effects on the Tianchi Scenic Area in Xinjiang:from the perspective of migrant farmer families

As an important approach for relieving conflicts between ecosystems and human activities in the Tianchi Scenic Area, Xinjiang of China, an ecological migration policy was implemented, aiming to improve the regional ecological environment. The case of resettlement was closely related to the smooth implementation of the migration project. Based on the questionnaires and farmer family interviews, both changes in the ecological environment and the living conditions of migrant farmer families in the Tianchi Scenic Area were investigated in this study. The objectives were to assess the benefits of the ecological migration policy and to analyze the effects of ecological migration on migrant farmer families. The results showed that （1） awareness of the need for ecological environmental protection and the types of migrant families had a great influence on the willingness to migration; （2） since the implementation of the ecological migration project, the ecological environment in the Tianchi Scenic Area had improved significantly, particutarly in terms of returning farmland to forestry, while pressures on grassland had also been relieved to some extent; （3） the major income sources and occupations of the migrant farmer families changed, the range of their income sources declined, and their per capita incomes decreased at different degrees; and （4） nearly half of the farmer families were not satisfied with the living environment of new settlements and the decline in the quality of life had significant influences on the attitudes of migrants. In order to ensure the successful implementation of an ecological migration project, it is essential to enhance farmer awareness of needs for ecological environmental protection, and to solve resettlement problems properly.

Structural integrity and remodeling underlying functional recovery after stroke

Stroke is the second leading cause of death worldwide with about 50% of survivors being chronically disabled(Donkor,2018).The behavioral improvement seen in stroke patients in the first weeks after a stroke is contributed by behavioral compensation, reorganization in somatotopic maps and activity in peri-infarct but also distant regions which are connected to the stroke area as supported by animal studies.

Linear-regioselective hydromethoxycarbonylation of styrene using Ru-clusters/CeO2 catalyst

Hydroalkoxycarbonylation of olefins has been considered to be one of the most attractive methods to synthesize esters. Controlling the regioselectivities of linear esters(L) and branched esters(B) is a challenging project for researchers working in this reaction. Although most of the attention has been paid to control the regioselectivity through ligand design in homogeneous catalytic systems, study in the area is still limited. Herein, Ru-clusters/CeO2 is employed as a heterogeneous catalyst for the hydromethoxycarbonylation of styrene without any additives. After optimization of the reaction conditions, the conversion of styrene is > 99% with 83% and 12% regioselectivity of linear and branched ester, respectively. By using different supports(CeO2(nanoparticle), CeO2-rod, and CeO2-cube), three catalysts including Ru-clusters/CeO2, Ru/CeO2-rod, and Ru/CeO2-cube are prepared and applied in the reaction. Structural characterizations demonstrate that the L/B ratio is related to the Ru size of supported Ru catalysts. Further Raman characterization and NH3-TPD demonstrate that the metal-support interaction and the concentration of oxygen vacancy of the catalyst have a great influence on the Ru size. The mechanism and kinetic analysis for this reaction are also investigated in this work.

Soil organic matter amendments in date palm groves of the Middle Eastern and North African region:a mini-review

Countries in the Middle Eastern and North African (MENA) region are among the most water-scarce regions in the world, and their dryland soils are usually poor in organic carbon content (<0.5%). In this study, we summarize examples of how people in the few oases of the MENA region overcome environmental challenges by sustainably managing economically important date production. On the basis of the limited studies found in the existing literature, this mini-review focuses on the role of traditional soil organic matter amendments beneath the soil surface as a key tool in land restoration. We conclude that soil organic matter amendments can be very successful in restoring soil water and preventing the soil from salinization.

TBCs for Gas Turbines under Thermomechanical Loadings： Failure Behaviour and Life Prediction

The present contribution gives an overview about recent research on a TBC （thermal barrier coating） system consisted of （I） an intermetallic MCrAIY-alloy BC （bond coat） applied by VPS （vacuum plasma spraying） and （2） an YSZ （yttria stabilised zirconia） top coat APS （air plasma sprayed） at Forschungszentrum Juelich, Institute of Energy and Climate Research （IEK-2）. The influence of high temperature dwell time, maximum and minimum temperature on crack growth kinetics during thermal cycling of such plasma sprayed TBCs is investigated using scanning electron microscopy and AE （acoustic emission） analysis. Thermocyclic life in terms of accumulated time at maximum temperature decreases with increasing high temperature dwell time and increases with increasing minimum temperature. AE analysis proves that crack growth mainly occurs during cooling at temperatures below the ductile-to-brittle transition temperature of the BC. Superimposed mechanical load cycles accelerate delamination crack growth and, in case of sufficiently high mechanical loadings, result in premature fatigue failure of the substrate. A life prediction model based on TGO growth kinetics and a fracture mechanics approach has been developed which accounts for the influence of maximum and minimum temperature as well as of high temperature dwell time with good accuracy in an extremely wide parameter range.

Electrical Conductivity of Sintered Chromia Mixed with TiO_2,CuO and Mn-Oxides

The electrical conductivity of sintered Cr2O3 mixed with 2% and 5% （in molar fraction） TiO2 or CuO was investigated in the temperature range 500-900℃ in air and in At/4 vol. pct H2 atmospheres. The effect of different Mn-oxides on the electrical conductivity of Cr2O3 was also studied under the same conditions. From the conductivity measurements it is established that additions of TiO2 change the defect structure of Cr2O3 and the effect of TiO2 on the electrical conductivity is controlled by TiO2 concentration as well as temperature and O2 partial pressure of the surrounding atmosphere. The conductivity of Cr2O3 increased in air and decreased in the At/H2 atmosphere by CuO additions. The effect of CuO was discussed with possible changes in the defect concentration in Cr2O3. Mixing of Cr2O3 with different Mn-oxides at the same Mn to metal atom fraction decreased the conductivity in air and in Ar/H2 atmospheres. No clear correlation between the spinel fraction and the changes in conductivity could be found.

Magnetic field topology modeling under resonant magnetic perturbations on EAST

In order to understand the mechanism by which the resonant magnetic perturbation (RMP)mitigates or suppresses the edge-localized mode (ELM),the topological study of the edge magnetic field in ELM mitigation or suppression phase is a critical issue.To model the three-dimensional magnetic field topology superposed RMP on Experimental Advanced Superconducting Tokamak,a numerical model using the field line tracing method for both vacuum and ideal plasma response approximations is proposed.Using the numerical model,the topological change and the penetration depth of the stochastic field lines in the edge magnetic field are studied in an RMP experiment.Comparing profiles of minimum9 on edge stochastic field lines and the particle flux pattem,the ideal plasma response changes the field line penetration depth while remaining similar profile relative to vacuum approximation.To mitigate and suppress ELM strongly,the deep penetration of RMP fields and topological changes of the edge magnetic field is a key from our modeling.

Structure, dielectric and magnetodielectric properties of Bi_(1-x)Gd_xFeO_3 Ceramics

Different magnetodielectric effects were observed in Bi1-xGdxFeOa ceramics depending on gadolinium content. A positive one was observed in the samples with x ≤ 0.10 at 295 K and 16 K, and a negative one in the sample with x = 0.4 at 16 K. Structure analysis by x-ray diffraction （XRD） reveals that the samples crystallize in the R3c structure （ferroelectrics） for x 〈 0.08 and in the Pbnm structure （paraelectrics） for x ≥ 0.3 at room temperature. Temperaturedependent dielectric response and x-ray diffraction confirm the occurrence of a structural transition in the Pbnm phase at low temperature for the samples with x ≤0.4. While the positive magnetodielectric effects can be attributed to a coupling of magnetic and crystallographic structures of the R3c phase, the observed negative magnetodielectric effect in the Pbnm phase can be associated with a low-temperature modification of the Pbnm structure. The observed dualsigned magnetodielectric effects suggest that the Bi1-xGdxFeO3 oxides are a good prototype for understanding the magnetodielectric coupling mechanism in this kind of materials.

中性束在束线中的透射

本文给出TEXTOR束线中放电室送气量和气压、中性化室送气量和气压、中性化室气体靶厚、中性化转换效率、再电离、热负荷、注入TEXTOR功率和粒子数的计算和实验结果。