In recent years,Pb-free CsSnI_(3) perovskite materials with excellent photoelectric properties as well as low toxicity are attracting much atten-tion in photoelectric devices.However,deep level defects in CsSnI_(3),su...In recent years,Pb-free CsSnI_(3) perovskite materials with excellent photoelectric properties as well as low toxicity are attracting much atten-tion in photoelectric devices.However,deep level defects in CsSnI_(3),such as high density of tin vacancies,structural deformation of SnI_(6)−octahedra and oxidation of Sn^(2+)states,are the major challenge to achieve high-performance CsSnI_(3)-based photoelectric devices with good stability.In this work,defect passivation method is adopted to solve the above issues,and the ultra-stable and high-performance CsSnI_(3) nanowires(NWs)photodetectors(PDs)are fabricated via incorporating 1-butyl-2,3-dimethylimidazolium chloride salt(BMIMCl)into perovskites.Through materials analysis and theoretical calculations,BMIM+ions can effectively passivate the Sn-related defects and reduce the dark current of CsSnI_(3) NW PDs.To further reduce the dark current of the devices,the polymethyl methacrylate is introduced,and finally,the dual passivated CsSnI_(3) NWPDs show ultra-high performance with an ultra-low dark current of 2×10^(-11) A,a responsivity of up to 0.237 A W^(−1),a high detectivity of 1.18×10^(12) Jones and a linear dynamic range of 180 dB.Furthermore,the unpackaged devices exhibit ultra-high stability in device performance after 60 days of storage in air(25℃,50% humidity),with the device performance remaining above 90%.展开更多
Perovskite solar cells(PSCs)have attracted significant research interest due to the rapid rise in efficiency.However,a large efficiency gap still exists between laboratory-based small devices and industrialoriented la...Perovskite solar cells(PSCs)have attracted significant research interest due to the rapid rise in efficiency.However,a large efficiency gap still exists between laboratory-based small devices and industrialoriented large-scale modules.One of the main reasons for the efficiency losses is the degraded quality and morphology of the deposited large-area films,which is closely associated with crystallization processes.In this review,we discuss the nucleation and crystallization processes in solution and vaporbased up-scaling deposition methods for large-area perovskite films.We review recent scientific achievements and technical developments that have been made in the field of large-area cells.We present the existing problems that limit the performance of large devices and extensively discuss the key influencing parameters from the perspective of nucleation and crystallization over large areas.This review highlights the importance of crystallization control in up-scaling fabrications and presents promising strategies towards large-area perovskite-based optoelectronic devices.展开更多
Antimony sulfide(Sb_(2)S_(3))is an appealing semiconductor as light absorber for solar cells due to its high absorption coefficient,appropriate band gap(~1.7 e V)and abundance of constituent elements.However,power con...Antimony sulfide(Sb_(2)S_(3))is an appealing semiconductor as light absorber for solar cells due to its high absorption coefficient,appropriate band gap(~1.7 e V)and abundance of constituent elements.However,power conversion efficiency(PCE)of Sb_(2)S_(3)-based solar cells still lags much behind the theoretically predicted due to the imperfect energy level alignment at the charge transporting layer/Sb_(2)S_(3)interfaces and hence severe charge recombination.Herein,we insert a high-temperature sintered magnesium(Mg)-doped tin oxide(SnO_(2))layer between cadmium sulfide(Cd S)and fuorine doped tin oxide to form a cascaded energy level alignment and thus mitigate interfacial charge recombination.Simultaneously,the inserted Mg-doped Sn O_(2)buffer layer facilitates the growth of the neibouring Cd S film with orientation followed by Sb_(2)S_(3)film with larger grains and fewer pinholes.Consequently,the resultant Sb_(2)S_(3)solar cells with Mg-doped SnO_(2)deliver a champion PCE of 6.31%,22.8%higher than those without a buffer layer.Our work demonstrates that deliberate absorber growth as well as efficient hole blocking upon an appropriate buffer layer is viable in obtaining solution-processed Sb_(2)S_(3)solar cells with high performance.展开更多
Transfer printing of small-molecular organic semiconductors often faces challenges due to surface adhesion mismatch.Here,we developed a sacrificing-layer-assisted transfer printing technique for the deposition of smal...Transfer printing of small-molecular organic semiconductors often faces challenges due to surface adhesion mismatch.Here,we developed a sacrificing-layer-assisted transfer printing technique for the deposition of smallmolecular thin films.High-boiling-point ethylene glycol(EG)was doped in aqueous solution poly(3,4-ethylenedioxythiophene)polystyrene sulfonate(PEDOT:PSS)as the sacrificing layer to manipulate residual water in film,which allowed chlorobenzene solution to spontaneously spread and form uniform film.展开更多
基金We acknowledge grants from the National Natural Science Foundation of China(Nos.51972101,62074117,12134010)the Shenzhen Fundamental Research Program(No.JCYJ20190808152609307).
文摘In recent years,Pb-free CsSnI_(3) perovskite materials with excellent photoelectric properties as well as low toxicity are attracting much atten-tion in photoelectric devices.However,deep level defects in CsSnI_(3),such as high density of tin vacancies,structural deformation of SnI_(6)−octahedra and oxidation of Sn^(2+)states,are the major challenge to achieve high-performance CsSnI_(3)-based photoelectric devices with good stability.In this work,defect passivation method is adopted to solve the above issues,and the ultra-stable and high-performance CsSnI_(3) nanowires(NWs)photodetectors(PDs)are fabricated via incorporating 1-butyl-2,3-dimethylimidazolium chloride salt(BMIMCl)into perovskites.Through materials analysis and theoretical calculations,BMIM+ions can effectively passivate the Sn-related defects and reduce the dark current of CsSnI_(3) NW PDs.To further reduce the dark current of the devices,the polymethyl methacrylate is introduced,and finally,the dual passivated CsSnI_(3) NWPDs show ultra-high performance with an ultra-low dark current of 2×10^(-11) A,a responsivity of up to 0.237 A W^(−1),a high detectivity of 1.18×10^(12) Jones and a linear dynamic range of 180 dB.Furthermore,the unpackaged devices exhibit ultra-high stability in device performance after 60 days of storage in air(25℃,50% humidity),with the device performance remaining above 90%.
文摘Perovskite solar cells(PSCs)have attracted significant research interest due to the rapid rise in efficiency.However,a large efficiency gap still exists between laboratory-based small devices and industrialoriented large-scale modules.One of the main reasons for the efficiency losses is the degraded quality and morphology of the deposited large-area films,which is closely associated with crystallization processes.In this review,we discuss the nucleation and crystallization processes in solution and vaporbased up-scaling deposition methods for large-area perovskite films.We review recent scientific achievements and technical developments that have been made in the field of large-area cells.We present the existing problems that limit the performance of large devices and extensively discuss the key influencing parameters from the perspective of nucleation and crystallization over large areas.This review highlights the importance of crystallization control in up-scaling fabrications and presents promising strategies towards large-area perovskite-based optoelectronic devices.
基金supported by the National Natural Science Foundation of China(Grant Nos.62074117,61904126)the Natural Science Foundation of Hubei Province,China(Grant Nos.2019AAA020,2019CFB122)+2 种基金the Natural Science Foundation of Guangdong Province(2021A1515012594)Guangdong Province Office of Education(2020ZDZX2028)the Special Funds for the Development of Strategic Emerging Industries in Shenzhen(JCYJ20190808152609307)。
文摘Antimony sulfide(Sb_(2)S_(3))is an appealing semiconductor as light absorber for solar cells due to its high absorption coefficient,appropriate band gap(~1.7 e V)and abundance of constituent elements.However,power conversion efficiency(PCE)of Sb_(2)S_(3)-based solar cells still lags much behind the theoretically predicted due to the imperfect energy level alignment at the charge transporting layer/Sb_(2)S_(3)interfaces and hence severe charge recombination.Herein,we insert a high-temperature sintered magnesium(Mg)-doped tin oxide(SnO_(2))layer between cadmium sulfide(Cd S)and fuorine doped tin oxide to form a cascaded energy level alignment and thus mitigate interfacial charge recombination.Simultaneously,the inserted Mg-doped Sn O_(2)buffer layer facilitates the growth of the neibouring Cd S film with orientation followed by Sb_(2)S_(3)film with larger grains and fewer pinholes.Consequently,the resultant Sb_(2)S_(3)solar cells with Mg-doped SnO_(2)deliver a champion PCE of 6.31%,22.8%higher than those without a buffer layer.Our work demonstrates that deliberate absorber growth as well as efficient hole blocking upon an appropriate buffer layer is viable in obtaining solution-processed Sb_(2)S_(3)solar cells with high performance.
基金financially supported by the National Natural Science Foundation of China(61875154 and 52022071)the Natural Science Foundation of Jiangsu Province,China(BK20190214)+1 种基金the National Key R&D Program of China(2020YFB2008800)China Postdoctoral Science Foundation(2021M702513)。
基金financially supported by the National Natural Science Foundation of China(No.62175189)the Shenzhen Science and Technology Program(KQTD20170330110107046)+1 种基金funding support from the Program for Promoting Academic Collaboration and Senior Talent Fostering between China and Canada,Australia,NewZealand,and Latin America(2021-109)the Joint China-SwedenMobility Programme(No.52211530052).
文摘Transfer printing of small-molecular organic semiconductors often faces challenges due to surface adhesion mismatch.Here,we developed a sacrificing-layer-assisted transfer printing technique for the deposition of smallmolecular thin films.High-boiling-point ethylene glycol(EG)was doped in aqueous solution poly(3,4-ethylenedioxythiophene)polystyrene sulfonate(PEDOT:PSS)as the sacrificing layer to manipulate residual water in film,which allowed chlorobenzene solution to spontaneously spread and form uniform film.
基金the Support Plan for Overseas Students to Return to China for Entrepreneurship and Innovation(cx2020003)the Fundamental Research Funds for the Central Universities(2020CDJQY-A028 and 2020CDJ-LHZZ-074)the Natural Science Foundation of Chongqing(cstc2020jcyj-msxmX0629)。