A series of novel poly（urethane-urea）（PUU） was synthesized from poly（lactide-co-p-dioxanone） macrodiol（HO-P（LA-co-PDO）-OH）, hexamethylene diisocyanate（HDI） and butanediamine（BDA）.The obtained PUU,which i...A series of novel poly（urethane-urea）（PUU） was synthesized from poly（lactide-co-p-dioxanone） macrodiol（HO-P（LA-co-PDO）-OH）, hexamethylene diisocyanate（HDI） and butanediamine（BDA）.The obtained PUU,which is recorded as P（LA-co-PDO）-PUU here,may demonstrate enhanced phase separation and thus improved shape memory property.FTIR was employed to characterize the copolymers,and the effects of NCO/OH molar ratios on Tg of PUU was investigated by means of differential scanning calorimetry （DSC）.The results revealed the successful synthesis of P（LA-co-PDO）-PUU.In addition,the Tg of P（LA-co-PDO）-PUU increased from 37.9℃to 44.2℃with the increase NCO/OH ratios from 1.1 to 1.2.The P（LA-co-PDO）-PUU with Tg close to body temperature will have potential applications as shape memory polymers in biomedical fields,especially in minimally invasive surgery.展开更多
基金supported by the National Key Technologies R&D Program of China(No.2006BA103B04)the Natural Key Scientific and Technological Project of Chongqing(No.CSTC 2008AB0027)
文摘A series of novel poly（urethane-urea）（PUU） was synthesized from poly（lactide-co-p-dioxanone） macrodiol（HO-P（LA-co-PDO）-OH）, hexamethylene diisocyanate（HDI） and butanediamine（BDA）.The obtained PUU,which is recorded as P（LA-co-PDO）-PUU here,may demonstrate enhanced phase separation and thus improved shape memory property.FTIR was employed to characterize the copolymers,and the effects of NCO/OH molar ratios on Tg of PUU was investigated by means of differential scanning calorimetry （DSC）.The results revealed the successful synthesis of P（LA-co-PDO）-PUU.In addition,the Tg of P（LA-co-PDO）-PUU increased from 37.9℃to 44.2℃with the increase NCO/OH ratios from 1.1 to 1.2.The P（LA-co-PDO）-PUU with Tg close to body temperature will have potential applications as shape memory polymers in biomedical fields,especially in minimally invasive surgery.
