Geochemical Characters of Water Coproduced with Coalbed Gas and Shallow Groundwater in Liulin Coalfield of China

To reveal the geochemical characters of water coproduced with coalbed gas and shallow groundwater,water samples were collected from 12 wells of coalbed methane and 7 wells of shallow groundwater.The pH,CODMn,fCO2,total dissolved solids （TDS）,total hardness,and concentrations of metasilicic acid,sodium and kalium,calcium ion,magnesium ion,ammonium iron,bicarbonate ion,carbonate,chloride,sulfate ion,nitrate ion,fluoride,lithium,zinc,nickel,manganese,iron,boron,barium,etc.of the samples were measured.Research results showed the following：（1） Concentrations of TDS,chloride,fluoride,sodium and kalium,ammonium,iron,and barium in the water coproduced with coalbed gas exceeded the national standards of China; however,physical,chemical,and biological properties of shallow groundwater could meet the national standard.（2） The water produced from coalbed contained mainly Na-Cl·HCO3,with average TDS of 4588.5 ppm,whereas shallow groundwater contained a mixture of chemicals including Na.Mg.Ca-HCO3·SO4 and Na.Mg-HCO3·SO4,with average TDS of 663.8 ppm.（3） In general,it was observed that bicarbonate and sodium accumulated in a reducing environment and deeper system,while depletion of hydrogen ions and dissolution of sulfate,calcium,and magnesium occurred in a redox environment and shallow system.（4） Sodium and kalium,ammonium,chloride,and bicarbonate ions were the main ions found in the study area.

An examination of the presence and topography of the D'' discontinuity under the Russia–Kazakhstan border region using seismic waveform data from a deep earthquake in Spain

The D＇＇ layer,which is located atop the core–mantle boundary,has long been an area of focus for global seismology studies. A widely used approach to study the discontinuities in the D＇＇ layer involves the use of the SdS phases between the S and ScS phases,which requires that certain stringent conditions be satisfied with respect to an epicentral distance and earthquake depth. Therefore,this approach is only practical for investigating the presence and topography of velocity interfaces in certain local regions around the world. The Russia–Kazakhstan border region has been a ‘‘blind spot＇＇ with respect to this detection method. The seismic network deployed in the northeastern margin of the Tibetan Plateau has recorded relatively clear SdS phases for the MS6.3 earthquake that occurred in Spain on April 11,2010,allowing this blind spot to be studied. This paper compares the observed waveforms and synthetics and uses the travel times of the relevant phases to obtain a D＇＇ discontinuity depth between2,610 and 2,740 km in the examined area. This study provides the first results regarding the depth of the D＇＇ layer discontinuity for this region and represents an important addition to the global studies of the D＇＇ layer.

The Population Features of Methanogens and the Biodegradation of Hydrocarbons in Coal Organic Matters

Methanogens are essential in the formation of biogenic methane and have wide distribution in lakes, swamps, paddy fields and ruminant rumen in the earth surface ecosystem. As a very important greenhouse gas, methane of different sources can induce global warming （Table 1）.