SnO_(2)has been extensively used in the detection of various gases.As a gas sensing material,SnO_(2)has excellent physical-chemical properties,high reliability,and short adsorption-desorption time.The application of t...SnO_(2)has been extensively used in the detection of various gases.As a gas sensing material,SnO_(2)has excellent physical-chemical properties,high reliability,and short adsorption-desorption time.The application of the traditional SnO_(2)gas sensor is limited due to its higher work-temperature,low gas response,and poor selectivity.Nanomaterials can significantly impact gas-sensitive properties due to the quantum size,surface,and small size effects of nanomaterials.By applying nanotechnology to the preparation of SnO_(2),the SnO_(2)nanomaterial-based sensors could show better performance,which greatly expands the application of SnO_(2)gas sensors.In this review,the preparation method of the SnO_(2)nanostructure,the types of gas detected,and the improvements of SnO_(2)gas-sensing performances via elemental modification are introduced as well as the future development of SnO_(2)is discussed.展开更多
Understanding the effect of additive on the interfacial charge-carrier transfer dynamics is very crucial to obtaining highly efficient perovskite solar cells(PSCs).Herein,we designed a simple additive,dimethyl oxalate...Understanding the effect of additive on the interfacial charge-carrier transfer dynamics is very crucial to obtaining highly efficient perovskite solar cells(PSCs).Herein,we designed a simple additive,dimethyl oxalate(DO),functioning as an effective defect passivator of perovskite grain boundaries via the coordination interaction between the carbonyl(C=O)and the exposed Pb^(2+).The modification with DO produces pinhole-free and compact perovskite films,enhancing the transportation capability of carriers.As a consequence,the DO-treated PSCs exhibited a power conversion efficiency(PCE)of 22.19%,which is significantly higher than that of the control device without additive(19.58%).More importantly,detailed transient absorption characterization reveals that the use of additive can decrease the hot-carrier cooling dynamics,improve the carrier transfer,and eliminate nonradiative recombination in PSCs.This present work provides a profound understanding the additives effect on the carrier dynamics in PSCs toward the Shockley-Queisser limit.展开更多
Avalanche-photodiode-based near-infrared single-photon detectors have seen rapid development in the last two decades because of their enormous internal gain,high sensitivity,fast response,small vol-ume,and ease of int...Avalanche-photodiode-based near-infrared single-photon detectors have seen rapid development in the last two decades because of their enormous internal gain,high sensitivity,fast response,small vol-ume,and ease of integration.The InGaAs/InP near-infrared single-photon detector is the most widely used avalanche diode at present.Its device performance is still being continuously improved through the optimization of device structure and external quenching circuits.This paper analyzes the latest development and application of these InGaAs/InP photodiodes,then briefly re views other near-infrared single-photon detection technologies based on new materials and new mechanisms.展开更多
基金supported by National Natural Science Foundation of China(No.61761047 and 41876055)the Department of Science and Technology of Yunnan Province via the Key Project for the Science and Technology(Grant No.2017FA025)Program for Innovative Research Team(in Science and Technology)in University of Yunnan Province。
文摘SnO_(2)has been extensively used in the detection of various gases.As a gas sensing material,SnO_(2)has excellent physical-chemical properties,high reliability,and short adsorption-desorption time.The application of the traditional SnO_(2)gas sensor is limited due to its higher work-temperature,low gas response,and poor selectivity.Nanomaterials can significantly impact gas-sensitive properties due to the quantum size,surface,and small size effects of nanomaterials.By applying nanotechnology to the preparation of SnO_(2),the SnO_(2)nanomaterial-based sensors could show better performance,which greatly expands the application of SnO_(2)gas sensors.In this review,the preparation method of the SnO_(2)nanostructure,the types of gas detected,and the improvements of SnO_(2)gas-sensing performances via elemental modification are introduced as well as the future development of SnO_(2)is discussed.
基金the National Natural Science Foundation of China(22065038)the Key Project of Natural Science Foundation of Yunnan(KC10110419)+4 种基金High-Level Talents Introduction in Yunnan Province(C619300A010)the Fund for Excellent Young Scholars of Yunnan(K264202006820)International Joint Research Center for Advanced Energy Materials of Yunnan Province(202003AE140001)the Program for Excellent Young Talents of Yunnan UniversityMajor Science and Technology Project of Precious Metal Materials Genetic Engineering in Yunnan Province(No.2019ZE001-1,202002AB080001-6)for financial support.
文摘Understanding the effect of additive on the interfacial charge-carrier transfer dynamics is very crucial to obtaining highly efficient perovskite solar cells(PSCs).Herein,we designed a simple additive,dimethyl oxalate(DO),functioning as an effective defect passivator of perovskite grain boundaries via the coordination interaction between the carbonyl(C=O)and the exposed Pb^(2+).The modification with DO produces pinhole-free and compact perovskite films,enhancing the transportation capability of carriers.As a consequence,the DO-treated PSCs exhibited a power conversion efficiency(PCE)of 22.19%,which is significantly higher than that of the control device without additive(19.58%).More importantly,detailed transient absorption characterization reveals that the use of additive can decrease the hot-carrier cooling dynamics,improve the carrier transfer,and eliminate nonradiative recombination in PSCs.This present work provides a profound understanding the additives effect on the carrier dynamics in PSCs toward the Shockley-Queisser limit.
基金supported by the Major Science and Technology Project of Yunnan province(Grant No.2018ZI002)。
文摘Avalanche-photodiode-based near-infrared single-photon detectors have seen rapid development in the last two decades because of their enormous internal gain,high sensitivity,fast response,small vol-ume,and ease of integration.The InGaAs/InP near-infrared single-photon detector is the most widely used avalanche diode at present.Its device performance is still being continuously improved through the optimization of device structure and external quenching circuits.This paper analyzes the latest development and application of these InGaAs/InP photodiodes,then briefly re views other near-infrared single-photon detection technologies based on new materials and new mechanisms.
