Oxidation of As^Ⅲ by Several Manganese Oxide Minerals in Absence and Presence of Goethite

Oxidation of As^Ⅲ by three types of manganese oxide minerals affected by goethite was investigated by chemical analysis, equilibrium redox, X-ray diffraction （XRD） and transmission electron microscopy （TEM）. Three synthesized Mn oxide minerals of different types, birnessite, todorokite, and hausmannite, could actively oxidize As^Ⅲ to Asv, and greatly varied in their oxidation ability. Layer structured birnessite exhibited the highest capacity of As^Ⅲ oxidation, followed by the tunnel structured todorokite. Lower oxide hansmannite possessed much low capacity of As^Ⅲ oxidation, and released more Mn^2＋ than birnessite and todorokite during the oxidation. The maximum amount of Asv produced during the oxidation of As^Ⅲ by Mn oxide minerals was in the order： birnessite （480.4 mmol/kg） 〉 todorokite （279.6 mmol/kg） 〉 hansmannite （117.9 mmol/kg）. The oxidation capacity of the Mn oxide minerals was found to be relative to the composition, crystallinity, and surface properties. In the presence of goethite oxidation of As^Ⅲ by Mn oxide minerals increased, with maximum amounts of Asv being 651.0 mmol/kg for birnessite, 332.3 mmol/kg for todorokite and 159.4 mmol/kg for hansmannite. Goethite promoted As^Ⅲ oxidation on the surface of Mn oxide minerals through adsorption of the Asv produced, incurring the decrease of Asv concentration in solutions. Thus, the combined effects of the oxidation （by Mn oxide minerals）-adsorption （by goethite） lead to rapid oxidation and immobilization of As in soils and sediments and alleviation of the As^Ⅲ toxicity in the environments.

Responses of Runoff and Soil Erosion to Vegetation Removal and Tillage on Steep Lands

Land use and land cover change is a key driver of environmental change. To investigate the runoff and erosion responses to frequent land use change on the steep lands in the Three Gorges area, China, a rainfall simulation experiment was conducted in plots randomly selected at a Sloping Land Conversion Program site with three soil surface conditions: existing vegetation cover, vegetation removal, and freshly hoed. Simulated rainfall was applied at intensities of 60 (low), 90 (medium), and 120 mm h 1 (high) in each plot. The results indicated that vegetation removal and hoeing significantly changed runoff generation. The proportion of subsurface runoff in the total runoff decreased from 30.3% to 6.2% after vegetation removal. In the hoed plots, the subsurface runoff comprised 29.1% of the total runoff under low-intensity rainfall simulation and the proportion rapidly decreased with increasing rainfall intensity. Vegetation removal and tillage also significantly increased soil erosion. The average soil erosion rates from the vegetation removal and hoed plots were 3.0 and 10.2 times larger than that in the existing vegetation cover plots, respectively. These identified that both the runoff generation mechanism and soil erosion changed as a consequence of altering land use on steep lands. Thus, conservation practices with maximum vegetation cover and minimum tillage should be used to reduce surface runoff and soil erosion on steep lands.