A compressed sensing (CS) based channel estimation algorithm is proposed in the fast moving environment. A sparse basis expansion channel model in both time and frequency domain is given.Pilots are placed according ...A compressed sensing (CS) based channel estimation algorithm is proposed in the fast moving environment. A sparse basis expansion channel model in both time and frequency domain is given.Pilots are placed according to a novel random unit pilot matrix (RUPM) to measure the delay- Doppler sparse channel. The sparse channels are recovered by an extension group orthogonal matching pursuit (GOMP) algorithm, enjoying the diversity gain from multi-symbol processing. The relatively nonzero channel coefficients are estimated from a very limited number of pilots at a sampling rate significantly below the Nyquist rate. The simulation results show that the new channel estimator can provide a considerable performance improvement for the fast fading channels. Three significant reductions are achieved in the required number of pilots, memory requirements and computational complexity.展开更多
The Wigner-Ville distribution (WVD) and the cross Wigner-Ville distribution (XWVD) have been shown to be efficient in the estimation of instantaneous frequency (IF). But the statistical result of the IF estimati...The Wigner-Ville distribution (WVD) and the cross Wigner-Ville distribution (XWVD) have been shown to be efficient in the estimation of instantaneous frequency (IF). But the statistical result of the IF estimation from XWVD peak is much better than using WVD peak. The reason is given from a statistical point of view. Theoretical studies show that XWVD of the analyzed signal can be estimated from XWVD of the noise-contaminated signal. The estimation is unbiased, and the variance is equal to that of noise. In this case, WVD cannot be estimated from W-VD of the noise-contaminated signal. Therefore, higher SNR is required when WVD is used to analyze signals.展开更多
The interface between the active layer and the electrode is one of the most critical factors that could affect the device performance of polymer solar cells. In this work, based on the typical poly(3-hexylthiophene)...The interface between the active layer and the electrode is one of the most critical factors that could affect the device performance of polymer solar cells. In this work, based on the typical poly(3-hexylthiophene):[6,6]-phenyl C61-butyric acid methyl ester (P3HT:PCBM) polymer solar cell, we studied the effect of the cathode buffer layer (CBL) between the top metal electrode and the active layer on the device performance. Several inorganic and organic materials commonly used as the electron injection layer in an organic light-emitting diode (OLED) were employed as the CBL in the P3HT:PCBM polymer solar cells. Our results demonstrate that the inorganic and organic materials like Cs2CO3, bathophenanthroline (Bphen), and 8-hydroxyquinolatolithium (Liq) can be used as CBL to efficiently improve the device performance of the P3HT:PCBM polymer solar cells. The P3HT:PCBM devices employed various CBLs possess power conversion efficiencies (PCEs) of 3.0%-3.3%, which are ca. 50% improved compared to that of the device without CBL. Furthermore, by using the doped organic materials Bphen:Cs2CO3 and Bphen:Liq as the CBL, the PCE of the P3HT:PCBM device will be further improved to 3.5%, which is ca. 70% higher than that of the device without a CBL and ca. 10% increased compared with that of the devices with a neat inorganic or organic CBL.展开更多
A compressed sensing(CS) based channel estimation algorithm is proposed by using the delay-Doppler sparsity of the fast fading channel.A compressive basis expansion channel model with sparsity in both time and frequ...A compressed sensing(CS) based channel estimation algorithm is proposed by using the delay-Doppler sparsity of the fast fading channel.A compressive basis expansion channel model with sparsity in both time and frequency domains is given.The pilots in accordance with a novel random pilot matrix in both time and frequency domains are sent to measure the delay-Doppler sparsity channel.The relatively nonzero channel coefficients are tracked by random pilots at a sampling rate significantly below the Nyquist rate.The sparsity channels are estimated from a very limited number of channel measurements by the basis pursuit algorithm.The proposed algorithm can effectively improve the channel estimation performance when the number of pilot symbols is reduced with improvement of throughput efficiency.展开更多
By using p-bis(p - N, N-diphenyl-aminostyryl)benzene doped 2-tert-butyl-9, 10-bis-β-naphthyl)-anthracene as an emitting layer, we fabricate a high-efficiency and long-lifetime blue organic light emitting diode wit...By using p-bis(p - N, N-diphenyl-aminostyryl)benzene doped 2-tert-butyl-9, 10-bis-β-naphthyl)-anthracene as an emitting layer, we fabricate a high-efficiency and long-lifetime blue organic light emitting diode with a maximum external quantum efficiency of 6.19% and a stable lifetime at a high initial current density of 0.0375 A/cm2. We demonstrate that the change in the thicknesses of organic layers affects the operating voltage and luminous efficiency greater than the lifetime. The lifetime being independent of thickness is beneficial in achieving high-quality full-colour display devices and white lighting sources with multi-emitters.展开更多
This paper utilizes multilayer organic light-emitting diodes with a thin layer of dye molecules to study the mech- anism of charge trapping under different electric regimes. It demonstrates that the carrier trapping w...This paper utilizes multilayer organic light-emitting diodes with a thin layer of dye molecules to study the mech- anism of charge trapping under different electric regimes. It demonstrates that the carrier trapping was independent of the current density in devices using fluorescent material as the emitting molecule while this process was exactly opposite when phosphorescent material was used. The triplet-triplet annihilation and dissociation of excitons into free charge carriers was considered to contribute to the decrease in phosphorescent emission under high electric fields. Moreover, the fluorescent dye molecule with a lower energy gap and ionized potential than the host emitter was observed to facilitate the carrier trapping mechanism, and it would produce photon emission.展开更多
Quantum-confined CsPbBr_(3) perovskites are promising blue emitters for ultra-high-definition displays,but their soft lattice caused by highly ionic nature has a limited stability.Here,we endow CsPbBr_(3) nanoplatelet...Quantum-confined CsPbBr_(3) perovskites are promising blue emitters for ultra-high-definition displays,but their soft lattice caused by highly ionic nature has a limited stability.Here,we endow CsPbBr_(3) nanoplatelets(NPLs)with atomic crystal-like structural rigidity through proper surface engineering,by using strongly bound N-dodecylbenzene sulfonic acid(DBSA).A stable,rigid crystal structure,as well as uniform,orderly-arranged surface of these NPLs is achieved by optimizing intermediate reaction stage,by switching from molecular clusters to mono-octahedra,while interaction with DBSA resulted in formation of a Cs_(x)O monolayer shell capping the NPL surface.As a result,both structural and optical stability of the CsPbBr3 NPLs is enhanced by strong covalent bonding of DBSA,which inhibits undesired phase transitions and decomposition of the perovskite phase potentially caused by ligand desorption.Moreover,rather small amount of DBSA ligands at the NPL surface results in a short inter-NPL spacing in their closely-packed films,which facilitates efficient charge injection and transport.Blue photoluminescence of the produced CsPbBr_(3) NPLs is bright(nearly unity emission quantum yield)and peaks at 457 nm with an extremely narrow bandwidth of 3.7 nm at 80 K,while the bandwidth of the electroluminescence(peaked at 460 nm)also reaches a record-narrow value of 15 nm at room temperature.This value corresponds to the CIE coordinates of(0.141,0.062),which meets Rec.2020 standards for ultra-high-definition displays.展开更多
We investigated the formation of exciplex and electroluminescent absorption in ultraviolet organic light-emitting diodes(UV OLEDs) using different heterojunction structures.It is found that an energy barrier of over...We investigated the formation of exciplex and electroluminescent absorption in ultraviolet organic light-emitting diodes(UV OLEDs) using different heterojunction structures.It is found that an energy barrier of over 0.3 eV between the emissive layer(EML) and adjacent transport layer facilitates exciplex formation.The electron blocking layer effectively confines electrons in the EML,which contributes to pure UV emission and enhances efficiency.The change in EML thickness generates tunable UV emission from 376 nm to 406 nm.In addition,the UV emission excites low-energy organic function layers and produces photoluminescent emission.In UV OLED,avoiding the exciplex formation and averting light absorption can effectively improve the purity and efficiency.A maximum external quantum efficiency of 1.2%with a UV emission peak of 376 nm is realized.展开更多
We characterized the 6,12-bis{[N-(3,4-dimethylphenyl)-N-(2,4,5-trimethylphenyl)]amino} chrysene (BmPAC), which has been proven to be a blue fluorescent emission with high EL efficiency. The blue fluorescent devi...We characterized the 6,12-bis{[N-(3,4-dimethylphenyl)-N-(2,4,5-trimethylphenyl)]amino} chrysene (BmPAC), which has been proven to be a blue fluorescent emission with high EL efficiency. The blue fluorescent device exhibits good performance with an external quantum efficiency of 5.8% and current efficiency of 8.9 cd/A, respectively. Using BmPAC, we also demonstrate a hybrid phosphorescence/fluorescence white organic light-emitting device (WOLED) with high efficiency of 36.3 cd/A. In order to improve the relative intensity of blue light, we plus a blue light-emitting layer (BEML) in front of the orange light emitting layer (YEML) to take advantage of the excess singlet excitons. With the new emitting layer of BEML/YEML/BEML, we demonstrate the fluorescence/phosphorescence/fluorescence WOLED exhibits good performance with a current efficiency of 47 cd/A and an enhanced relative intensity of blue light.展开更多
This paper presents an efficient VLSI architecture of the contest-based adaptive variable length code (CAVLC) decoder with power optimized for the H.264/advanced video coding (AVC) standard. In the proposed design...This paper presents an efficient VLSI architecture of the contest-based adaptive variable length code (CAVLC) decoder with power optimized for the H.264/advanced video coding (AVC) standard. In the proposed design, according to the regularity of the codewords, the first one detector is used to solve the low efficiency and high power dissipation problem within the traditional method of table-searching. Considering the relevance of the data used in the process of runbefore's decoding, arithmetic operation is combined with finite state machine (FSM), which achieves higher decoding efficiency. According to the CAVLC decoding flow, clock gating is employed in the module level and the register level respectively, which reduces 43% of the overall dynamic power dissipation. The proposed design can decode every syntax element in one clock cycle. When the proposed design is synthesized at the clock constraint of 100 MHz, the synthesis result shows that the design costs 11 300 gates under a 0.25 μm CMOS technology, which meets the demand of real time decoding in the H.264/AVC standard.展开更多
In order to explore the novel application of the transparent hole-transporting material 5,10,15-tribenzyl-5Hdiindolo[3,2-a:3',2'-c]-carbazole(TBDI),in this article TBDI is used as an active layer but not a buffer...In order to explore the novel application of the transparent hole-transporting material 5,10,15-tribenzyl-5Hdiindolo[3,2-a:3',2'-c]-carbazole(TBDI),in this article TBDI is used as an active layer but not a buffer layer in a photodetector(PD),organic light-emitting diode(OLED),and organic photovoltaic cell(OPV) for the first time.Firstly,the absorption and emission spectra of a blend layer comprised of TBDI and electron-transporting material bis-(2-methyl-8-quinolinate) 4-phenylphenolate(BAlq) are investigated.Based on the absorption properties,an organic PD with a peak absorption at 320 nm is fabricated,and a relatively-high detectivity of 2.44×10^(11) cm· Hz^(1/2)/W under 320-nm illumination is obtained.The TBDI/tris(8-hydroxyquinoline) aluminum(Alq_3) OLED device exhibits a comparable external quantum efficiency and current efficiency to a traditional 4,4-bis[N-(l-naphthyl)-N-phenyl-amino]biphenyl(α-NPD)/Alq_3 OLED.A C_(70)-based Schottky junction with 5 wt%-TBDI yields a power conversion efficiency of 5.0%,which is much higher than 1.7%for an α-NPD-based junction in the same configuration.These results suggest that TBDI has some promising properties which are in favor of the hole-transporting in Schottky junctions with a low-concentration donor.展开更多
Organic light-emitting diode(OLED)is an electroluminescent technology that relies on charge-carrier dynamics and is a potential light source for variable environmental conditions.Here,by exploiting a self-developed lo...Organic light-emitting diode(OLED)is an electroluminescent technology that relies on charge-carrier dynamics and is a potential light source for variable environmental conditions.Here,by exploiting a self-developed low-temperature testing system,we investigated the characteristics of hole/electron transport,electro-optic conversion efficiency,and operation lifetime of OLEDs at low-temperature ranging from-40℃to 0℃and room temperature(25℃).Compared to devices operating at room temperature,the carrier transport capability is significantly decreased with reducing temperature,and especially the mobility of the hole-transporting material(HTM)and electron-transporting material(ETM)at-40℃decreases from 1.16×10-6 cm2/V·s and 2.60×10-4 cm2/V·s to 6.91×10-9 cm2/V·s and 1.44×10-5 cm2/V·s,respectively.Indeed,the temperature affects differently on the mobilities of HTM and ETM,which favors unbalanced charge-carrier transport and recombination in OLEDs,thereby leading to the maximum current efficiency decreased from 6.46 cd·A-1 at 25℃to 2.74 cd·A-1 at-40℃.In addition,blue fluorescent OLED at-20℃has an above 56%lifetime improvement(time to 80%of the initial luminance)over the reference device at room temperature,which is attributed to efficiently dissipating heat generated inside the device by the low-temperature environment.展开更多
A new numerical differentiation method with local opti- mum by data segmentation is proposed. The segmentation of data is based on the second derivatives computed by a Fourier devel- opment method. A filtering process...A new numerical differentiation method with local opti- mum by data segmentation is proposed. The segmentation of data is based on the second derivatives computed by a Fourier devel- opment method. A filtering process is used to achieve acceptable segmentation. Numerical results are presented by using the data segmentation method, compared with the regularization method. For further investigation, the proposed algorithm is applied to the resistance capacitance (RC) networks identification problem, and improvements of the result are obtained by using this algorithm.展开更多
Being a wide variety of thin-layered interconnection components in electronics packaging with relatively small scale and heterogeneous materials, conventional numerical methods may be time consuming and even inefficac...Being a wide variety of thin-layered interconnection components in electronics packaging with relatively small scale and heterogeneous materials, conventional numerical methods may be time consuming and even inefficacious to obtain an accurate prediction for the interface behavior under mechanical and/or thermal loading. Rather than resort to a fully spatial discretization in the vicinity of this interface zone, an interface model was proposed within the framework of micropolar theory by introducing discontinuous approximation. A fracture description was used to represent the microscopic failure progress inside the interface. The micropolar interface model was then numerically implemented with the finite element method. As an application, the interface behavior of a packaging system with anisotropic conductive adhesive (ACA) joint was analyzed, demonstrating its applicability and great efficiency.展开更多
Phosphor-in-glass(PiG)is a potential color convertor for high power WLEDs.A novel glass matrix with advanced performance is still a challenge.Recently,Eu^(3+)doped glass matrix has attracted much consideration mainly ...Phosphor-in-glass(PiG)is a potential color convertor for high power WLEDs.A novel glass matrix with advanced performance is still a challenge.Recently,Eu^(3+)doped glass matrix has attracted much consideration mainly due to its red compensation.A new borophosphate matrix to realize Eu^(3+)red light was designed in the Na_(2)O-ZnO-P_(2)O_(5)-B_(2)O_(3)-Eu_(2)O_(3)system.Meanwhile,a series of PiGs composed of different concentrations of Y3Al5O12:Ce phosphor and the matrix were also fabricated by re-sintering.The crystallization of Eu^(3+)based phosphate offers a novel red emission quenching apart from normal concentration quenching in the glass system.No direct energy transfer but only little reabso rption occurs between Eu^(3+)and Ce^(3+)ions.The Ce^(3+)concentration effect is obvious on the electroluminescent color.The optimized color rendering index of 79.7,the CIE coordinates near natural white and the range of CCT from 3943 to 6097 K were obtained for the packaged white light emitting diodes(WLEDs)together with the excellent CCT stability higher than about 97.5%and the quadruple thermal conductivity than that of silicon resin.The work implies borophosphate glass based PiGs with fine transparence and energy conversion efficiency are promising for excellent WLEDs,while the LED by using the PiG sample without any yellow phosphor doped is of high color purity and has a potential use as the 465 nm blue source.展开更多
Quantum dot light-emitting diodes(QLEDs)are a class of high-performance solution-processed electroluminescent(EL)devices highly attractive for next-generation display applications.Despite the encouraging advances in t...Quantum dot light-emitting diodes(QLEDs)are a class of high-performance solution-processed electroluminescent(EL)devices highly attractive for next-generation display applications.Despite the encouraging advances in the mechanism investigation,material chemistry,and device engineering of QLEDs,the lack of standard protocols for the characterization of QLEDs may cause inaccurate measurements of device parameters and invalid comparison of different devices.Here,we report a comprehensive study on the characterizations of QLEDs using various methods.We show that the emission non-uniformity across the active area,nonLambertian angular distributions of EL intensity,and discrepancies in the adopted spectral luminous efficiency functions could introduce significant errors in the device efficiency.Larger errors in the operational-lifetime measurements may arise from the inaccurate determination of the initial luminance and inconsistent methods for analyzing the luminance-decay curves.Finally,we suggest a set of recommended practices and a checklist for device characterizations,aiming to help the researchers in the QLED field to achieve accurate and reliable measurements.展开更多
Light-emitting diodes(LEDs)based on perovskite semiconductor materials with tunable emission wavelength in visible light range as well as narrow linewidth are potential competitors among current light-emitting display...Light-emitting diodes(LEDs)based on perovskite semiconductor materials with tunable emission wavelength in visible light range as well as narrow linewidth are potential competitors among current light-emitting display technologies,but still suffer from severe instability driven by electric field.Here,we develop a stable,efficient and highcolor purity hybrid LED with a tandem structure by combining the perovskite LED and the commercial organic LED technologies to accelerate the practical application of perovskites.Perovskite LED and organic LED with close photoluminescence peak are selected to maximize photon emission without photon reabsorption and to achieve the narrowed emission spectra.By designing an efficient interconnecting layer with p-type interface doping that provides good opto-electric coupling and reduces Joule heating,the resulting green emitting hybrid LED shows a narrow linewidth of around 30 nm,a peak luminance of over 176,000 cd m^(−2),a maximum external quantum efficiency of over 40%,and an operational half-lifetime of over 42,000 h.展开更多
Indium phosphide(InP) quantum dots(QDs) have shown great potential to replace the widely applied toxic cadmiumcontaining and lead perovskite QDs due to their similar emission wavelength range and emission peak width b...Indium phosphide(InP) quantum dots(QDs) have shown great potential to replace the widely applied toxic cadmiumcontaining and lead perovskite QDs due to their similar emission wavelength range and emission peak width but without intrinsic toxicity. Recently, electrically driven red and green InP-based quantum-dot light-emitting diodes(QLEDs) have achieved great progress in external quantum efficiency(EQE), reaching up to 12.2% and 6.3%, respectively. Despite the relatively poor device performance comparing with cadmium selenide(CdSe)-and perovskite-based QLEDs, these encouraging facts with unique environmental friendliness and solution-processability foreshadow the enormous potential of InP-based QLEDs for energy-efficient, high-color-quality thin-film display and solid-state lighting applications. In this article, recent advances in the research of the InP-based QLEDs have been discussed, with the main focus on device structure selection and interface research, as well as our outlook for on-going strategies of high-efficiency InP-based QLEDs.展开更多
Squaraine (SQ) dyes have been considered as efficient photoactive materials for organic solar cells. In this work, we purposely controlled the molecular aggregation of an SQ dye, 2,4-bis[4-(N,N-dibutylamino)-2-dih...Squaraine (SQ) dyes have been considered as efficient photoactive materials for organic solar cells. In this work, we purposely controlled the molecular aggregation of an SQ dye, 2,4-bis[4-(N,N-dibutylamino)-2-dihydroxyphenyl] SQ (DBSQ- (OH)2) in the DBSQ(OH)2:[6,6]-phenyl-Cel-butyric acid methyl ester (PCBM) blend film by using the thermal annealing method, to study the influence of the molecular aggregation on film properties as well as the photovoltaic performance of DBSQ(OH)2:PCBM-based bulk heterojunction (BHJ) solar cells. Our results demonstrate that thermal annealing may change the aggregation behavior of DBSQ(OH)2 in the DBSQ(OH)2:PCBM film, and thus significantly influence the surface morphology, optical and electrical properties of the blend film, as well as the photovoltaic performance of DBSQ(OH)2:PCBM BHJ cells.展开更多
Two novel 2-(4-(9,9-disubstitued-9 H-fluoren-2-yl)phenyl)-9,9-diethyl-l-phenyl-1,9-dihydrofluoreno-[2,3-d]imidazole derivatives 2 a and 2 b were synthesized and characterized.Their photophysical and electrochemical pr...Two novel 2-(4-(9,9-disubstitued-9 H-fluoren-2-yl)phenyl)-9,9-diethyl-l-phenyl-1,9-dihydrofluoreno-[2,3-d]imidazole derivatives 2 a and 2 b were synthesized and characterized.Their photophysical and electrochemical properties,thermal stability property,and electroluminescence(EL)performance of 2 b were investigated.The fabricated device based on 2 b doping into 4,4’-N,N’-dicarbazole-biphenyl(5%)as an emitter present a maximum brightness of 1272 cd/m^2 at 4 V with the CIE coordinate of(0.1590,0.0465).展开更多
基金Supported by the National Natural Science Foundation of China ( No. 60972056 ), the Innovation Foundation of Shanghai Education Committee ( No. 09ZZ89) and Shanghai Leading Academic Discipline Project and STCSM ( No.S30108, 08DZ2231100 ).
文摘A compressed sensing (CS) based channel estimation algorithm is proposed in the fast moving environment. A sparse basis expansion channel model in both time and frequency domain is given.Pilots are placed according to a novel random unit pilot matrix (RUPM) to measure the delay- Doppler sparse channel. The sparse channels are recovered by an extension group orthogonal matching pursuit (GOMP) algorithm, enjoying the diversity gain from multi-symbol processing. The relatively nonzero channel coefficients are estimated from a very limited number of pilots at a sampling rate significantly below the Nyquist rate. The simulation results show that the new channel estimator can provide a considerable performance improvement for the fast fading channels. Three significant reductions are achieved in the required number of pilots, memory requirements and computational complexity.
基金the National Natural Science Foundation of China (60472102)Shanghai Leading Academic Discipline Project (T0103)the Foundation of Shanghai Municipal Commission of Education (A10-0109-06-022)
文摘The Wigner-Ville distribution (WVD) and the cross Wigner-Ville distribution (XWVD) have been shown to be efficient in the estimation of instantaneous frequency (IF). But the statistical result of the IF estimation from XWVD peak is much better than using WVD peak. The reason is given from a statistical point of view. Theoretical studies show that XWVD of the analyzed signal can be estimated from XWVD of the noise-contaminated signal. The estimation is unbiased, and the variance is equal to that of noise. In this case, WVD cannot be estimated from W-VD of the noise-contaminated signal. Therefore, higher SNR is required when WVD is used to analyze signals.
基金Project supported by the National Natural Science Foundation of China(Grant No.61204014)the“Chenguang”Project(13CG42)+1 种基金supported by Shanghai Municipal Education Commission and Shanghai Education Development Foundation,Chinathe Shanghai University Young Teacher Training Program of Shanghai Municipality,China
文摘The interface between the active layer and the electrode is one of the most critical factors that could affect the device performance of polymer solar cells. In this work, based on the typical poly(3-hexylthiophene):[6,6]-phenyl C61-butyric acid methyl ester (P3HT:PCBM) polymer solar cell, we studied the effect of the cathode buffer layer (CBL) between the top metal electrode and the active layer on the device performance. Several inorganic and organic materials commonly used as the electron injection layer in an organic light-emitting diode (OLED) were employed as the CBL in the P3HT:PCBM polymer solar cells. Our results demonstrate that the inorganic and organic materials like Cs2CO3, bathophenanthroline (Bphen), and 8-hydroxyquinolatolithium (Liq) can be used as CBL to efficiently improve the device performance of the P3HT:PCBM polymer solar cells. The P3HT:PCBM devices employed various CBLs possess power conversion efficiencies (PCEs) of 3.0%-3.3%, which are ca. 50% improved compared to that of the device without CBL. Furthermore, by using the doped organic materials Bphen:Cs2CO3 and Bphen:Liq as the CBL, the PCE of the P3HT:PCBM device will be further improved to 3.5%, which is ca. 70% higher than that of the device without a CBL and ca. 10% increased compared with that of the devices with a neat inorganic or organic CBL.
基金supported by the National Natural Science Foundation of China(60972056)the Innovation Foundation of Shanghai Education Committee(09ZZ89)Shanghai Leading Academic Discipline Project and STCSM(S30108and08DZ2231100)
文摘A compressed sensing(CS) based channel estimation algorithm is proposed by using the delay-Doppler sparsity of the fast fading channel.A compressive basis expansion channel model with sparsity in both time and frequency domains is given.The pilots in accordance with a novel random pilot matrix in both time and frequency domains are sent to measure the delay-Doppler sparsity channel.The relatively nonzero channel coefficients are tracked by random pilots at a sampling rate significantly below the Nyquist rate.The sparsity channels are estimated from a very limited number of channel measurements by the basis pursuit algorithm.The proposed algorithm can effectively improve the channel estimation performance when the number of pilot symbols is reduced with improvement of throughput efficiency.
基金Project supported by the Science Fund of Science and Technology Commission of Shanghai Municipality,China (GrantNo. 10dz1140502)the Innovation Key Project of Education Commission of Shanghai Municipality,China (Grant No. 12ZZ091)the National Natural Science Foundation of China (Grant Nos. 61006005 and 61136003)
文摘By using p-bis(p - N, N-diphenyl-aminostyryl)benzene doped 2-tert-butyl-9, 10-bis-β-naphthyl)-anthracene as an emitting layer, we fabricate a high-efficiency and long-lifetime blue organic light emitting diode with a maximum external quantum efficiency of 6.19% and a stable lifetime at a high initial current density of 0.0375 A/cm2. We demonstrate that the change in the thicknesses of organic layers affects the operating voltage and luminous efficiency greater than the lifetime. The lifetime being independent of thickness is beneficial in achieving high-quality full-colour display devices and white lighting sources with multi-emitters.
基金Project supported by the Key Project of Shanghai Education Committee (Grant No. 08ZZ42)Science and Technology Commission of Shanghai Municipal (Grant Nos. 08PJ14053,08DZ1140702 and 08520511200)
文摘This paper utilizes multilayer organic light-emitting diodes with a thin layer of dye molecules to study the mech- anism of charge trapping under different electric regimes. It demonstrates that the carrier trapping was independent of the current density in devices using fluorescent material as the emitting molecule while this process was exactly opposite when phosphorescent material was used. The triplet-triplet annihilation and dissociation of excitons into free charge carriers was considered to contribute to the decrease in phosphorescent emission under high electric fields. Moreover, the fluorescent dye molecule with a lower energy gap and ionized potential than the host emitter was observed to facilitate the carrier trapping mechanism, and it would produce photon emission.
基金the National Key Research and Development Program of China(2022YFE0200200)National Natural Science Foundation of China(52072141,51972136,52102170)+1 种基金Postdoctoral Science Foundation of China(2021T140251)the Innovation and Technology Commission of Hong Kong SAR(MHP/068/21).
文摘Quantum-confined CsPbBr_(3) perovskites are promising blue emitters for ultra-high-definition displays,but their soft lattice caused by highly ionic nature has a limited stability.Here,we endow CsPbBr_(3) nanoplatelets(NPLs)with atomic crystal-like structural rigidity through proper surface engineering,by using strongly bound N-dodecylbenzene sulfonic acid(DBSA).A stable,rigid crystal structure,as well as uniform,orderly-arranged surface of these NPLs is achieved by optimizing intermediate reaction stage,by switching from molecular clusters to mono-octahedra,while interaction with DBSA resulted in formation of a Cs_(x)O monolayer shell capping the NPL surface.As a result,both structural and optical stability of the CsPbBr3 NPLs is enhanced by strong covalent bonding of DBSA,which inhibits undesired phase transitions and decomposition of the perovskite phase potentially caused by ligand desorption.Moreover,rather small amount of DBSA ligands at the NPL surface results in a short inter-NPL spacing in their closely-packed films,which facilitates efficient charge injection and transport.Blue photoluminescence of the produced CsPbBr_(3) NPLs is bright(nearly unity emission quantum yield)and peaks at 457 nm with an extremely narrow bandwidth of 3.7 nm at 80 K,while the bandwidth of the electroluminescence(peaked at 460 nm)also reaches a record-narrow value of 15 nm at room temperature.This value corresponds to the CIE coordinates of(0.141,0.062),which meets Rec.2020 standards for ultra-high-definition displays.
基金supported by the National Natural Science Foundation of China(Grant Nos.61136003 and 61275041)the Guangxi Provincial Natural Science Foundation,China(Grant No.2012GXNSFBA053168)
文摘We investigated the formation of exciplex and electroluminescent absorption in ultraviolet organic light-emitting diodes(UV OLEDs) using different heterojunction structures.It is found that an energy barrier of over 0.3 eV between the emissive layer(EML) and adjacent transport layer facilitates exciplex formation.The electron blocking layer effectively confines electrons in the EML,which contributes to pure UV emission and enhances efficiency.The change in EML thickness generates tunable UV emission from 376 nm to 406 nm.In addition,the UV emission excites low-energy organic function layers and produces photoluminescent emission.In UV OLED,avoiding the exciplex formation and averting light absorption can effectively improve the purity and efficiency.A maximum external quantum efficiency of 1.2%with a UV emission peak of 376 nm is realized.
基金supported by the National Natural Science Foundation of China(Grant Nos.61136003 and 61275041)the Project of Science and TechnologyCommission of Shanghai Municipality,China(Grant No.14XD1401800)
文摘We characterized the 6,12-bis{[N-(3,4-dimethylphenyl)-N-(2,4,5-trimethylphenyl)]amino} chrysene (BmPAC), which has been proven to be a blue fluorescent emission with high EL efficiency. The blue fluorescent device exhibits good performance with an external quantum efficiency of 5.8% and current efficiency of 8.9 cd/A, respectively. Using BmPAC, we also demonstrate a hybrid phosphorescence/fluorescence white organic light-emitting device (WOLED) with high efficiency of 36.3 cd/A. In order to improve the relative intensity of blue light, we plus a blue light-emitting layer (BEML) in front of the orange light emitting layer (YEML) to take advantage of the excess singlet excitons. With the new emitting layer of BEML/YEML/BEML, we demonstrate the fluorescence/phosphorescence/fluorescence WOLED exhibits good performance with a current efficiency of 47 cd/A and an enhanced relative intensity of blue light.
基金Project supported by the Applied Materials Shanghai Research and Development Foundation (Grant No.08700741000)the Foundation of Shanghai Municipal Education Commission (Grant No.2006AZ068)
文摘This paper presents an efficient VLSI architecture of the contest-based adaptive variable length code (CAVLC) decoder with power optimized for the H.264/advanced video coding (AVC) standard. In the proposed design, according to the regularity of the codewords, the first one detector is used to solve the low efficiency and high power dissipation problem within the traditional method of table-searching. Considering the relevance of the data used in the process of runbefore's decoding, arithmetic operation is combined with finite state machine (FSM), which achieves higher decoding efficiency. According to the CAVLC decoding flow, clock gating is employed in the module level and the register level respectively, which reduces 43% of the overall dynamic power dissipation. The proposed design can decode every syntax element in one clock cycle. When the proposed design is synthesized at the clock constraint of 100 MHz, the synthesis result shows that the design costs 11 300 gates under a 0.25 μm CMOS technology, which meets the demand of real time decoding in the H.264/AVC standard.
基金supported by the Funding Program for World-Leading Innovative R&D on Science and Technology(FIRST)from JSPSthe Fund from the Science and Technology Commission of Shanghai Municipality,China(Grant Nos.14DZ2280900 and 14XD1401800)the Natural Science Foundation of Shanghai(Grant No.15ZR1416600)
文摘In order to explore the novel application of the transparent hole-transporting material 5,10,15-tribenzyl-5Hdiindolo[3,2-a:3',2'-c]-carbazole(TBDI),in this article TBDI is used as an active layer but not a buffer layer in a photodetector(PD),organic light-emitting diode(OLED),and organic photovoltaic cell(OPV) for the first time.Firstly,the absorption and emission spectra of a blend layer comprised of TBDI and electron-transporting material bis-(2-methyl-8-quinolinate) 4-phenylphenolate(BAlq) are investigated.Based on the absorption properties,an organic PD with a peak absorption at 320 nm is fabricated,and a relatively-high detectivity of 2.44×10^(11) cm· Hz^(1/2)/W under 320-nm illumination is obtained.The TBDI/tris(8-hydroxyquinoline) aluminum(Alq_3) OLED device exhibits a comparable external quantum efficiency and current efficiency to a traditional 4,4-bis[N-(l-naphthyl)-N-phenyl-amino]biphenyl(α-NPD)/Alq_3 OLED.A C_(70)-based Schottky junction with 5 wt%-TBDI yields a power conversion efficiency of 5.0%,which is much higher than 1.7%for an α-NPD-based junction in the same configuration.These results suggest that TBDI has some promising properties which are in favor of the hole-transporting in Schottky junctions with a low-concentration donor.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61775130 and 11974236)the Science and Technology Commission of Shanghai Municipality Program,China(Grant Nos.19DZ2281000 and 17DZ2281000)the Research Innovation Program for College Graduates of Jiangsu Province,China(Grant Nos.KYCX202545 and KYCX202549)。
文摘Organic light-emitting diode(OLED)is an electroluminescent technology that relies on charge-carrier dynamics and is a potential light source for variable environmental conditions.Here,by exploiting a self-developed low-temperature testing system,we investigated the characteristics of hole/electron transport,electro-optic conversion efficiency,and operation lifetime of OLEDs at low-temperature ranging from-40℃to 0℃and room temperature(25℃).Compared to devices operating at room temperature,the carrier transport capability is significantly decreased with reducing temperature,and especially the mobility of the hole-transporting material(HTM)and electron-transporting material(ETM)at-40℃decreases from 1.16×10-6 cm2/V·s and 2.60×10-4 cm2/V·s to 6.91×10-9 cm2/V·s and 1.44×10-5 cm2/V·s,respectively.Indeed,the temperature affects differently on the mobilities of HTM and ETM,which favors unbalanced charge-carrier transport and recombination in OLEDs,thereby leading to the maximum current efficiency decreased from 6.46 cd·A-1 at 25℃to 2.74 cd·A-1 at-40℃.In addition,blue fluorescent OLED at-20℃has an above 56%lifetime improvement(time to 80%of the initial luminance)over the reference device at room temperature,which is attributed to efficiently dissipating heat generated inside the device by the low-temperature environment.
基金supported by the National Basic Research Program of China(2011CB013103)
文摘A new numerical differentiation method with local opti- mum by data segmentation is proposed. The segmentation of data is based on the second derivatives computed by a Fourier devel- opment method. A filtering process is used to achieve acceptable segmentation. Numerical results are presented by using the data segmentation method, compared with the regularization method. For further investigation, the proposed algorithm is applied to the resistance capacitance (RC) networks identification problem, and improvements of the result are obtained by using this algorithm.
基金supported by the National Natural Science Foundation of China (Grant No.10702037)the Shanghai Pujiang Program(Grant No.08PJ14054)the Innovation Program of Shanghai Municipal Education Commission (Grant No.09YZ01)
文摘Being a wide variety of thin-layered interconnection components in electronics packaging with relatively small scale and heterogeneous materials, conventional numerical methods may be time consuming and even inefficacious to obtain an accurate prediction for the interface behavior under mechanical and/or thermal loading. Rather than resort to a fully spatial discretization in the vicinity of this interface zone, an interface model was proposed within the framework of micropolar theory by introducing discontinuous approximation. A fracture description was used to represent the microscopic failure progress inside the interface. The micropolar interface model was then numerically implemented with the finite element method. As an application, the interface behavior of a packaging system with anisotropic conductive adhesive (ACA) joint was analyzed, demonstrating its applicability and great efficiency.
基金Project supported by the Joint Funds of the National Natural Science Foundation of China(U1932160)the National Natural Science Foundation of China(51605272)。
文摘Phosphor-in-glass(PiG)is a potential color convertor for high power WLEDs.A novel glass matrix with advanced performance is still a challenge.Recently,Eu^(3+)doped glass matrix has attracted much consideration mainly due to its red compensation.A new borophosphate matrix to realize Eu^(3+)red light was designed in the Na_(2)O-ZnO-P_(2)O_(5)-B_(2)O_(3)-Eu_(2)O_(3)system.Meanwhile,a series of PiGs composed of different concentrations of Y3Al5O12:Ce phosphor and the matrix were also fabricated by re-sintering.The crystallization of Eu^(3+)based phosphate offers a novel red emission quenching apart from normal concentration quenching in the glass system.No direct energy transfer but only little reabso rption occurs between Eu^(3+)and Ce^(3+)ions.The Ce^(3+)concentration effect is obvious on the electroluminescent color.The optimized color rendering index of 79.7,the CIE coordinates near natural white and the range of CCT from 3943 to 6097 K were obtained for the packaged white light emitting diodes(WLEDs)together with the excellent CCT stability higher than about 97.5%and the quadruple thermal conductivity than that of silicon resin.The work implies borophosphate glass based PiGs with fine transparence and energy conversion efficiency are promising for excellent WLEDs,while the LED by using the PiG sample without any yellow phosphor doped is of high color purity and has a potential use as the 465 nm blue source.
基金supported by National Natural Science Foundation of China (21975220,91833303,21922305,21873080,21703202,62122034,and 61875082)Key Research and Development Project of Zhejiang Province (2020C01001)+1 种基金National Key Research and Development Program of China (2021YFB3601700)China Postdoctoral Science Foundation (2021M702800).
文摘Quantum dot light-emitting diodes(QLEDs)are a class of high-performance solution-processed electroluminescent(EL)devices highly attractive for next-generation display applications.Despite the encouraging advances in the mechanism investigation,material chemistry,and device engineering of QLEDs,the lack of standard protocols for the characterization of QLEDs may cause inaccurate measurements of device parameters and invalid comparison of different devices.Here,we report a comprehensive study on the characterizations of QLEDs using various methods.We show that the emission non-uniformity across the active area,nonLambertian angular distributions of EL intensity,and discrepancies in the adopted spectral luminous efficiency functions could introduce significant errors in the device efficiency.Larger errors in the operational-lifetime measurements may arise from the inaccurate determination of the initial luminance and inconsistent methods for analyzing the luminance-decay curves.Finally,we suggest a set of recommended practices and a checklist for device characterizations,aiming to help the researchers in the QLED field to achieve accurate and reliable measurements.
基金the National Key Research and Development Program of China(2022YFE0200200 and 2022YFB3606504)National Natural Science Foundation of China(62174104 and 62122034)+1 种基金Program of Shanghai Academic/Technology Research Leader(22XD1421200)G.C.also thanks financial support from Shanghai S&T Committee Project 20392001100.
文摘Light-emitting diodes(LEDs)based on perovskite semiconductor materials with tunable emission wavelength in visible light range as well as narrow linewidth are potential competitors among current light-emitting display technologies,but still suffer from severe instability driven by electric field.Here,we develop a stable,efficient and highcolor purity hybrid LED with a tandem structure by combining the perovskite LED and the commercial organic LED technologies to accelerate the practical application of perovskites.Perovskite LED and organic LED with close photoluminescence peak are selected to maximize photon emission without photon reabsorption and to achieve the narrowed emission spectra.By designing an efficient interconnecting layer with p-type interface doping that provides good opto-electric coupling and reduces Joule heating,the resulting green emitting hybrid LED shows a narrow linewidth of around 30 nm,a peak luminance of over 176,000 cd m^(−2),a maximum external quantum efficiency of over 40%,and an operational half-lifetime of over 42,000 h.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51675322,61605109,and 61735004)the National Key Research and Development Program of China(Grant No.2016YFB0401702)+2 种基金Shanghai Science and Technology Committee,China(Grant No.19010500600)Shanghai Rising-Star Program,China(Grant No.17QA1401600)the Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning,China
文摘Indium phosphide(InP) quantum dots(QDs) have shown great potential to replace the widely applied toxic cadmiumcontaining and lead perovskite QDs due to their similar emission wavelength range and emission peak width but without intrinsic toxicity. Recently, electrically driven red and green InP-based quantum-dot light-emitting diodes(QLEDs) have achieved great progress in external quantum efficiency(EQE), reaching up to 12.2% and 6.3%, respectively. Despite the relatively poor device performance comparing with cadmium selenide(CdSe)-and perovskite-based QLEDs, these encouraging facts with unique environmental friendliness and solution-processability foreshadow the enormous potential of InP-based QLEDs for energy-efficient, high-color-quality thin-film display and solid-state lighting applications. In this article, recent advances in the research of the InP-based QLEDs have been discussed, with the main focus on device structure selection and interface research, as well as our outlook for on-going strategies of high-efficiency InP-based QLEDs.
基金This work was financially supported by the National Natural Science Foundation of China (Grant No. 61604093), the Shanghai Pujiang Program (16PJ1403300), the Natural Science Foundation of Shanghai (16ZR1411000), the Science and Technology Commission of Shanghai Municipality Program (17DZ2281700), and the Shanghai Software and integrated circuit industry development special funds (170401).
文摘Squaraine (SQ) dyes have been considered as efficient photoactive materials for organic solar cells. In this work, we purposely controlled the molecular aggregation of an SQ dye, 2,4-bis[4-(N,N-dibutylamino)-2-dihydroxyphenyl] SQ (DBSQ- (OH)2) in the DBSQ(OH)2:[6,6]-phenyl-Cel-butyric acid methyl ester (PCBM) blend film by using the thermal annealing method, to study the influence of the molecular aggregation on film properties as well as the photovoltaic performance of DBSQ(OH)2:PCBM-based bulk heterojunction (BHJ) solar cells. Our results demonstrate that thermal annealing may change the aggregation behavior of DBSQ(OH)2 in the DBSQ(OH)2:PCBM film, and thus significantly influence the surface morphology, optical and electrical properties of the blend film, as well as the photovoltaic performance of DBSQ(OH)2:PCBM BHJ cells.
基金supported by the National Natural Science Foundation of China (Nos.81202402,21272154)
文摘Two novel 2-(4-(9,9-disubstitued-9 H-fluoren-2-yl)phenyl)-9,9-diethyl-l-phenyl-1,9-dihydrofluoreno-[2,3-d]imidazole derivatives 2 a and 2 b were synthesized and characterized.Their photophysical and electrochemical properties,thermal stability property,and electroluminescence(EL)performance of 2 b were investigated.The fabricated device based on 2 b doping into 4,4’-N,N’-dicarbazole-biphenyl(5%)as an emitter present a maximum brightness of 1272 cd/m^2 at 4 V with the CIE coordinate of(0.1590,0.0465).